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NOx -SCR over Ag/ Al2O3 catalyst using ethanol (C2H5OH) as a reductant has proven its ability to significantly reduce NOx emission in a simulated engine exhaust gas environment. However the real engine exhaust gas environment is too complicated to be simulated. Therefore, the performance evaluation of the Ag/ Al2O3 catalyst in real exhaust gas environment is necessary. Moreover, the ethanol dosing device and control strategy also need to be validated for the practical use. In this paper, firstly the catalyst performance and its sulfur tolerance was tested on an engine test bench and the effect of the catalyst on PM emission was investigated. Then the aftertreatment system composed of Ag/Al2O3 catalyst + Cu/TiO2 catalyst + Pt/TiO2 catalyst and ethanol dosing control based on open loop control was designed, and the diesel engine emission with the aftertreatment system was tested according to ESC test cycle.

Particle Number (PN) have already been a big issue for developing high efficiency internal combustion engines (ICEs). In this study, controlled spark-assisted stratified compression ignition (SSCI) with moderate end-gas auto-ignition was used for reducing PN in a high compression ratio gasoline direct injection (GDI) engine. Under wide open throttle (WOT) and Maximum Brake Torque timing (MBT) condition, high external cooled exhaust gas recirculation (EGR) was filled in the cylinder, while two-stage direct injection was used to form desired stoichiometric but stratified mixture. SSCI combustion mode exhibits two-stage heat release, where the first stage is associated with flame propagation induced by spark ignition and the second stage is the result of moderate end-gas auto-ignition without pressure oscillation at the middle or late stage of the combustion process.

To monitor emission-related components/systems and to evaluate the presence of malfunctioning or failures that can affect emissions, current diesel engine regulations require the use of on-board diagnostics (OBD). For diesel particulate filters (DPF), the pressure drop across the DPF is monitored by the OBD as the pressure drop is approximately linear related to the soot mass deposited in a filter. However, sudden acceleration may cause a sudden decrease in DPF pressure drop under cold start conditions. This appears to be caused by water that has condensed in the exhaust pipe, but no detailed mechanism for this decrease has been established. The present study developed an experimental apparatus that reproduces rapid increases of the exhaust gas flow under cold start conditions and enables independent control of the amount of water as well as the gas flow rate supplied to the DPF.

Spark knock suppression with hydrogen addition was investigated at two engine speeds (2000 rpm and 4800 rpm). The experimental results showed that the spark knock is strongly suppressed with increasing hydrogen fraction at 2000 rpm while the effect is much smaller at 4800 rpm. To explain these results, chemical kinetic analyses with a two-zone combustion model were performed. The calculated results showed that the heat release in the end gas zone rises in two stages with a remarkable appearance of low temperature oxidation (LTO) at 2000 rpm, while a single stage heat release without apparent LTO process is presented at 4800 rpm due to the shorter residence time in the low temperature region.

To reduce NOx emissions from diesel engines, the urea-SCR (selective catalytic reduction) system has been introduced commercially. In urea-SCR, the freezing point of the urea aqueous solution, the deoxidizer, is −11°C, and the handling of the deoxidizer under cold weather conditions is a problem. Further, the ammonia escape from the catalyst and the generation of N2O emissions are also problems. To overcome these disadvantages of the urea-SCR system, the addition of a hydrocarbon deoxidizer has attracted attention. In this paper, a micro-reactor SCR system was developed and attached to the exhaust pipe of a single cylinder diesel engine. With the micro-reactor, the catalyst temperature, quantity of deoxidizer, and the space velocity can be controlled, and it is possible to use it with gas and liquid phase deoxidizers. The catalyst used in the tests reported here is Ag(1wt%)-γAl2O3.

Urea Selective Catalytic Reduction (SCR) has been proven to significantly reduce NOx emissions from diesel engines. The thermal decomposition of urea, which forms the ammonia as the reactant, has a crucial effect on the performance and durability of the NOx-SCR system. The incomplete thermal decomposition of urea not only reduces the NOx conversion ratio and increases the ammonia slip, but also leads to deposit formation on the catalyst surface, which will block the pore and the active sites of the catalyst and then decreases the durability of the SCR systems. In this paper, the urea thermolysis was measured using the Thermal Gravimetric Analysis (TGA) and Fourier Transform Infrared Spectroscopy (FTIR). Then, the performance of the SCR systems under different injection parameters of the Urea-water solution was investigated on a diesel engine test bench. Finally, the deposits on the catalyst were also analyzed using TGA and FTIR.

Biodiesel is an alternative, renewable, clean fuel, which can effectively reduce emissions from diesel engines. However, the effects of biodiesel on engine emissions vary due to the difference in source. In this paper, performance of five different biodiesels was studied: CME, SME, RME, PME and WME. Engine power, fuel consumption, gaseous emissions and PM, DS and none soot fraction (NSF) were investigated in a Cummins ISBe6 Euro III diesel engine fueled with five biodiesels respectively and compared with the diesel fuel. Results revealed that using different biodiesels resulted in PM reductions ranging from 53% to 69%, which included DS reduction ranging from 79% to 83%. Observations showed that fuel oxygen content and viscosity had obvious effects on DS. Higher oxygen content biodiesels produced less DS at high load while lower viscosity biodiesels produced less DS at low load.

Beijing will implement the 4th stage emission regulations (equivalent to Euro IV) in 2008 ahead of other provinces or cites in China. Beijing Environmental Protection Bureau (EPB) organized petroleum corporations, automobile and engine manufactories as well as research institutes to test the adaptability of the fuels from Chinese refineries to the modern vehicles or engines on the road running conditions in China. In this paper, the effects of diesel fuel quality on combustion and emission of a Euro IV heavy-duty diesel engine as one part of the program were studied to provide technical data to stipulate the feasible diesel fuel standard, which should guarantee modern vehicles or engines to meet the 4th stage regulations. Eight kinds of diesel fuels with different properties, such as cetane number, distillation temperature (T90) and sulfur content, were tested on a Euro IV Cummins heavy-duty diesel engine with urea SCR after-treatment.

Beijing will implement the national 4th stage emissions standards (equivalent to Euro IV emissions standards) in advance in China from 2008. The objective of this study was to provide some technical support for proposing automotive gasoline fuel standards matching with the emission standards. In this paper, tests were conducted on two engines and one gasoline passenger vehicle meeting Euro III or IV emission standards to study the correlation between gasoline fuel properties and engine performances, including power, fuel consumption and emissions. Test results showed that the effect of octane number on engine power depended on engine technologies. High octane number had a negative effect on fuel consumption and emissions. As olefin content increased, the engine-out THC emissions decreased significantly. The vehicle test results also showed that high olefin content greatly reduced the tailpipe THC emissions.

A Homogeneous charge induced ignition (HCII) combustion, realized by in-cylinder fuel blending of gasoline and diesel fuel, was developed and carefully optimized, both on a single cylinder and a multi-cylinder light-duty diesel engines, for high thermal efficiency and near zero emissions in a wide engine-operation range up to IMEP of 1 MPa. The effects of mixing and chemical parameters of HCII combustion, which can be controlled by production-viable hard-ware using conventional gasoline and diesel fuel, include injection timing of diesel fuel, injection rate pattern of diesel fuel (such as split injection), the gasoline/diesel ratio, boost pressure and exhaust gas recirculation (EGR). Based on a single cylinder engine, the experimental result shows that the interaction of the mentioned control parameters plays decisive role in determination of exhaust emissions and thermal efficiency.

Homogeneous Charge Induced Ignition (HCII) combustion utilizes a port injection of high-volatile fuel to form a homogeneous charge and a direct injection of high ignitable fuel near the Top Dead Center (TDC) to trigger combustion. Compared to Conventional Diesel Combustion (CDC) with high injection pressures, HCII has the potential to achieve diesel-like thermal efficiency with significant reductions in NOx and PM emissions with relatively low-pressure injections, which would benefit the engine cost saving remarkably. In the first part of current investigation, experiments were conducted at medium load with single diesel injection strategy. HCII exhibited great potential of using low injection pressures to achieve low soot emissions. But the engine load for HCII was limited by high heat release rate. Thus, in the second and third part, experiments were performed at high and low load with double diesel injection strategy.

This research focuses on the potential of Homogeneous Charge Induced Ignition (HCII) combustion meeting the Euro V emission standard on a heavy-duty multi-cylinder engine using a simple after-treatment system. However, in our previous studies, it was found that the gasoline ratio was limited in HCII by the over-high compression ratio (CR). In this paper, the effects of reducing CR on the performances of HCII at medium and high loads were explored by experimental methods. It was found that by reducing CR from 18:1 to 16:1 the peak in-cylinder pressure and the peak pressure rise rate were effectively reduced and the gasoline ratio range could be obviously extended. Thus, the combustion and emission characteristics of HCII at medium and high loads were noticeably improved. Soot emissions can be significantly reduced because of the increase of premixed combustion ratio. The reduction could be over 50% especially at high load and high speed conditions.

A new ignition method named Flame Accelerated Ignition (FAI) is proposed in this paper. The FAI system composes of a spark plug and a flame acceleration tunnel with annular obstacles inside. The FAI was experimentally investigated on a rapid compression machine (RCM) with optical accessibility and a single-cylinder heavy duty research engine. In RCM, the flame is significantly accelerated and the combustion process is evidently enhanced by FAI. The ignition delay and the combustion duration are both sharply decreased compared with conventional spark ignition (CSI) case. According to the optical diagnostics, the flame rushes out of the exit of the flame acceleration tunnel at maximum axial speed over 40 m/s, which exceeds 10 times that of CSI flame propagation. In radial direction, the flame curls outwards near the tunnel exit and keeps growing afterwards.

Dual fuel combustion with premixed natural gas as the main fuel and diesel fuel as the ignition source was investigated in a 0.83 L, single cylinder, DI diesel engine. At low loads, increasing the equivalence ratio of natural gas to around 0.5 with intake throttling makes it possible to reduce the THC and CO emissions as well as to improve the thermal efficiency. At high loads, increasing the boost pressure moderates the combustion, but increases the THC and CO emissions, resulting in deterioration of the thermal efficiency. The EGR is essential to suppress the rapid combustion. As misfiring occurs with a compression ratio of 14.5 and there is excessively rapid combustion with 18.5 compression ratio, 16.5 is a suitable compression ratio.

According to China's “oil-poor, gas-litte, coal-rich” structure of energy resources, to promote the development of coal-based methanol fuel as a clean alternative to gasoline and diesel fuel is one of the most realistic options. So the adaptability of methanol gasoline blend fuel used in the gasoline engine and vehilce should be investigated. Engine load performance, engine out emission, air fuel ratio variation and combustion characteristics were tested in a PFI Euro III gasoline engine using gasoline, M10, M15, M20, M30 as fuel without any modification of the engine. Air fuel ratio, light-off temperature and load characteristics of catalystic conversion coefficient were also investigated. And effects of methanol content on fuel consumption and vehicle out emissions of a Euro - vehicle are analyzed.

Soot emissions in the combustion process of diesel engines are greatly harmful to the environment and human health. Consequently, there is large interest and great efforts in decreasing soot emission from diesel engines to meet the increasingly stringent emission standards. The mechanisms of soot formation and oxidation so far have not been well understood. Laser induced incandescence (LII) is particularly suited to measure the instantaneous spatial distribution of the soot volume concentration, which can offer much needed detailed information of soot distribution for better understanding of soot formation and oxidation. In this paper, a two-color laser induced incandescence (2C-LII) technique was implemented for measuring absolute soot volume fraction in a laminar diesel fuel diffusion flame.

Knocking is the main obstacle of increasing compression ratio to improve the thermal efficiency of gasoline engines. In this paper, the concept of stratified stoichiometric mixture (SSM) was proposed to suppress knocking in gasoline engines. The rich mixture near the spark plug increases the speed of the flame propagation and the lean mixture in the end gas suppresses the auto ignition. The overall air/fuel ratio keeps stoichiometric to solve the emission problem using three way catalysts (TWC). Moreover, both the rich zone and lean zone lead to soot free combustion due to homogeneous mixture. The effect on the knocking of homogeneous and stratified mixture was studied in a direct injection spark ignition (DISI) engine using numerical simulation and experimental investigation respectively.

Multi-mode combustion is an ideal combustion strategy to utilize HCCI for internal combustion engines. It combines HCCI combustion mode for low-middle load and traditional SI mode for high load and high speed. By changing the cam profiles from normal overlap for SI mode to the negative valve overlap (NVO) for HCCI mode, as well as the adjustment of direct injection strategy, the combustion mode transition between SI and HCCI was realized in one engine cycle. By two-step cam switch, the throttle action is separated from the cam action, which ensures the stabilization of mode transition. For validating the feasibility of the stepped switch, the influence of throttle position on HCCI combustion was carefully studied. Based on the research, the combustion mode switch was realized in one engine cycle; the whole switch process including throttle action was realized in 10 cycles. The entire process was smooth, rapid and reliable without any abnormal combustion such as knocking and misfiring.

A catalyst surfaced on Ag/Al2O3 substrate for the selective catalyst reduction (SCR) of NOx by ethanol was evaluated in a diesel engine, and the effect of the catalyst on the reduction of NOx from the diesel engine under the EURO III ESC test modes was also investigated. The reductant injecting device was designed by means of computational fluid dynamics (CFD) analysis, and the engine test bench including the reductant injection system for the evaluation of the NOx-SCR catalyst performance was established. On the bench, the SCR catalyst with the ethanol reductant was tested at different temperatures and space velocities (SV), and integrated with an oxidation catalyst to reduce the diesel exhaust emissions of NOx, HC and CO. Under the conditions of the SV=30,000 h-1 and the exhaust temperature range of 350∼420°C, the NOx conversion efficiency is high over 90% and low beyond the temperature range.

The engine performance and the exhaust gas emissions in a dual fuel compression ignition engine with natural gas as the main fuel and a small quantity of pilot injection of diesel fuel with the ultra-high injection pressure of 250 MPa as an ignition source were investigated at 0.3 MPa and 0.8 MPa IMEP. With increasing injection pressure the unburned loss decreases and the thermal efficiency improves at both IMEP conditions. At the 0.3 MPa IMEP the THC and CO emissions are significantly reduced when maintaining the equivalence ratio of natural gas with decreasing the volumetric efficiency by intake gas throttling, but the NOx emissions increase and excessive intake gas throttling results in a decrease in the indicated thermal efficiency. Under the 250 MPa pilot injection condition simultaneous reductions in the NOx, THC, and CO emissions can be established with maintaining the equivalence ratio of natural gas by intake gas throttling.