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Polyoxymethylene dimethyl ethers (OME) are synthetic fuels, which offer the property of sustainability because the reactants of production base on hydrogen and carbon dioxide on the one hand, and the air pollution control in consequence of a soot-free combustion in a diesel engine on the other hand. High exhaust gas recirculation (EGR) rates are a promising measure for nitrogen oxide (NOx) reduction without increasing particle emissions because of the resolved soot-NOx trade-off. However, EGR rates towards stoichiometric combustion in OME operation reveals other trade-offs such as methane and formaldehyde emissions. To avoid these, a lean mixture with a combination of EGR and exhaust after-treatment with selective catalytic reduction (SCR) is useful. The limitation of urea dosing due to the light-off temperature of SCR systems requires heating measures.

Oxygenated synthetic fuels such as oxymethylene ether (OME) are a promising approach to reduce the emissions of diesel engines and to improve sustainability of mobility. The soot-free combustion of OME allows an optimization of the combustion process to minimize remaining pollutants. Considering the injection system, one strategy is to decrease the rail pressure, which has a positive impact on the reduction of nitrogen oxides without increasing the particle formation. Furthermore, due to the reduced lower heating value of OME compared to diesel fuel, an adaptation of the injector nozzle is recommended. This work describes a method for analyzing the injection process for OME, using the Mie scattering effect in an optically accessible heavy-duty diesel engine. The design of the 1.75 l single cylinder engine allows operation up to 300 bar peak cylinder pressure, providing optical access through the piston bowl and through a second window lateral below the cylinder head.

The synthetic fuels dimethyl ether (DME) and polyoxymethylene dimethylether (POMDME or OME) are promising oxygenated fuels to meet the rising challenges of air pollution control, CO2-neutrality, and sustainability. The sootless combustion and high ignitability of DME and OME represent ideal properties for an application in diesel engines. However, recent investigations of oxygenates reported an increase of nanoparticles, which are known to have fatal effects on human’s health. Besides nanoparticles, ongoing discussions about future emission legislation focus on a drastic reduction of NOx. For this reason, the present work investigates different measures to reduce NOx emissions using DME/OME and a paraffinic diesel fuel (PDF) as reference. Different rail pressures, exhaust gas recirculation (EGR) rates, and injection timings are evaluated, considering the effectivity on NOx reduction and the impact on other emissions, especially on nanoparticles.