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There is widespread evidence in the literature that carbonaceous deposits can accumulate on the rear of intake valves and can adversely affect engine performance. For port fuel injected engines, a number of authors have suggested that the porous nature of these intake valve deposits (IVDs) means that they can act like a “sponge”, thereby preventing the correct amount of fuel from entering the combustion chamber during transient operation, especially when the engine is cold. A combination of experimental gas adsorption measurements and computational molecular simulations were used to characterize the porous structure of a sample of IVD. Molecular simulation was then used to predict the equilibrium adsorption of various hydrocarbons, including isooctane, in IVDs. The results support the theory that adsorption of fuel components in IVDs could perturb the mixture preparation.

A practical Gasoline Compression Ignition (GCI) concept is presented that works on standard European 95 RON E10 gasoline over the whole speed/load range. A spark is employed to assist the gasoline autoignition at low loads; this avoids the requirement of a complex cam profile to control the local mixture temperature for reliable autoignition. The combustion phasing is controlled by the injection pattern and timing, and a sufficient degree of stratification is needed to control the maximum rate of pressure rise and prevent knock. With active control of the swirl level, the combustion system is found to be relatively robust against variability in charge motion, and subtle differences in fuel reactivity. Results show that the new concept can achieve very low fuel consumption over a significant portion of the speed/load map, equivalent to diesel efficiency. The efficiency is worse than an equivalent diesel engine only at low load where the combustion assistance operates.

Carbonaceous deposits can accumulate on various surfaces of the internal combustion engine and affect its performance. The porous nature of these deposits means that they act like a “sponge”, adsorbing fuel components and changing both the composition and the amount of fuel in the combustion chamber. Here we use a previously developed and validated model of engine deposits to predict adsorption of normal heptane, isooctane, toluene and their mixtures in deposits of different origin within a port fuel injected spark ignition engine (Combustion Chamber Deposits, or CCDs, and Intake Valve Deposits, or IVDs) and under different conditions. We explore the influence of molecular structure of adsorbing species, composition of the bulk mixture and temperature on the uptake and selectivity behaviour of the deposits. While deposits generally show high capacity toward all three components, we observe that selectivity behaviour is a more subtle and complex property.

Due to the recent drive to reduce CO₂ emissions, the turbocharged direct injection spark ignition (turbo DISI) gasoline engine has become increasingly popular. In addition, future turbo DISI engines could incorporate a form of charge dilution (e.g., lean operation or external EGR) to further increase fuel efficiency. Thus, the conditions experienced by the fuel before and during combustion are and will continue to be different from those experienced in naturally aspirated SI engines. This work investigates the effects of fuel properties on a modern and prototype turbo DISI engine, with particular focus on the octane appetite: How relevant are RON and MON in predicting a fuel's anti-knock performance in these modern/future engines? It is found that fuels with high RON and low MON values perform the best, suggesting the current MON requirements in fuel specifications could actually be detrimental.

Modern spark ignition engines can take advantage of better fuel octane quality either towards improving acceleration performance or fuel economy via an active ignition management system. Higher fuel octane allows for spark timing advance and consequently higher torque output and higher engine efficiency. Additionally, engines can be designed with higher compression ratios if a higher anti-knock quality fuel is used. Due to historical reasons, Research Octane (RON) and Motor Octane Number (MON) are the metrics used to characterize the anti-knock quality of a fuel. The test conditions used to compute RON and MON correlated well with those in older engines designed about 20 years ago. But the correlation has drifted considerably in the recent past due to advances in engine infrastructures mainly governed by stringent fuel economy and emission standards.

Laminar burning velocity is a fundamental combustion property of any fuel/air mixture. Formulating gasoline fuel blends having faster burning velocities can be an effective strategy for enhancing engine and vehicle performance. Formulation of faster burning fuels by changing the fuel composition has been explored in this work leading to a clear correlation between engine performance and fuel burning velocity. In principle a gasoline vehicle should be calibrated to give optimal ignition timing (also known as MBT - minimum spark advance for best torque) while at the same time avoiding any possible engine knock. However, modern downsized/boosted engines frequently tend to be limited by knock and the spark timing is retarded in respect of the optimum. In such scenarios, faster burning fuels can lead to a more optimum combustion phasing resulting in a more efficient energy transfer and hence a faster acceleration and better performance.

In Gasoline Direct Injection engines, direct exposure of the injector to the flame can cause combustion products to accumulate on the nozzle, which can result in increased particulate emissions. This research observes the impact of injector fouling on particulate emissions and the associated injector spray pattern and shows how both can be reversed by utilising fuel detergency. For this purpose multi-hole injectors were deliberately fouled in a four-cylinder test engine with two different base fuels. During a four hour injector fouling cycle particulate numbers (PN) increased by up to two orders of magnitude. The drift could be reversed by switching to a fuel blend that contained a detergent additive. In addition, it was possible to completely avoid any PN increase, when the detergent containing fuel was used from the beginning of the test. Microscopy showed that increased injector fouling coincided with increased particulate emissions.

The accepted model of conventional diesel combustion [1] assumes a rich premixed flame slightly downstream of the maximum liquid penetration. The soot generated by this rich premixed flame is burnt out by a subsequent diffusion flame at the head of the jet. Even in situations in which the centre of combustion (CA50) is phased optimally to maximize efficiency, slow late stage combustion can still have a significant detrimental impact on thermal efficiency. Data is presented on potential late-stage combustion improvers in a EURO VI compliant HD engine at a range of speed and load points. The operating conditions (e.g. injection timings, EGR levels) were based on a EURO VI calibration which targets 3 g/kWh of engine-out NOx. Rates of heat release were determined from the pressure sensor data. To investigate late stage combustion, focus was made on the position in the cycle at which 90% of the fuel had combusted (CA90). An EN590 compliant fuel was tested.

The octane appetite of an engine is frequently characterised by the so-called K value. It is usually assumed that K is dependent only on the thermodynamic conditions in the engine when knock occurs. In this work we test this hypothesis: further analysis was conducted on experimental results from SAE 2019-01-0035 in which a matrix of fuels was tested in a single cylinder engine. The fuels consisted of a relatively small number of components, thereby simplifying the analysis of the chemical kinetic proprieties. Through dividing the original fuel matrix into subsets, it was possible to explore the variation of K value with fuel properties. It was found that K value tends to increase slightly with RON. The explanation for this finding is that higher RON leads to advanced ignition timing (i.e. closer to MBT conditions) and advanced ignition timing results in faster combustion because of the higher pressures and temperatures reached in the thermodynamic trajectory.

In recent years, boosted and downsized engines have gained much attention as a promising technology to improve fuel economy; however, knocking is a common issue of such engines that requires attention. To understand the knocking phenomenon under downsized and boosted engine conditions deeply, fuels with different Research Octane Number (RON) and Motor Octane Number (MON) were prepared, and the knocking performances of these fuels were evaluated using a single cylinder engine, operated under a variety of conditions. Experimental results showed that the knocking performance at boosted conditions depend on both RON and MON. While higher RON showed better anti-knocking performance, lower MON showed better anti-knocking performance. Furthermore, the tendency for a reduced MON to be beneficial became stronger at lower engine speeds and higher boost pressures, in agreement with previously published modelling work.

Planar Laser-Induced Fluorescence has been widely accepted and applied to measurements of fuel concentration distributions in IC engines. The need for such measurements has increased with the introduction of Direct Injection (DI) gasoline engines, where it is critical to understand the influence of mixture inhomogeneity on ignition and subsequent combustion, and in particular the implications for cyclic variability. The apparent simplicity of PLIF has led to misunderstanding of the technique when applied to quantitative measurements of fuel distributions. This paper presents a series of engineering methods for optimizing, calibrating and referencing, which together demonstrate a quantitative measure of fuel concentration with an absolute accuracy of 10%. PLIF is widely used with single component fuels as carriers for the fluorescent tracers.

In the present study, Large Eddy Simulations (LES) have been performed with a 3D model of a step nozzle injector, using n-pentane as the injected fluid, a representative of the high-volatility components in gasoline. The influence of fuel temperature and injection pressure were investigated in conditions that shed light on engine cold-start, a phenomenon prevalent in a number of combustion applications, albeit not extensively studied. The test cases provide an impression of the in-nozzle phase change and the near-nozzle spray structure across different cavitation regimes. Results for the 20oC fuel temperature case (supercavitating regime) depict the formation of a continuous cavitation region that extends to the nozzle outlet. Collapse-induced pressure wave dynamics near the outlet cause a transient entrainment of air from the discharge chamber towards the nozzle.

In light of increasingly stringent CO2 emission targets, Original Equipment Manufacturers (OEM) have been driven to develop engines which deliver improved combustion efficiency and reduce energy losses. In spark ignition engines one strategy which can be used to reach this goal is the full utilization of fuel octane number. Octane number is the fuel´s knock resistance and is characterized as research octane number (RON) and motor octane number (MON). Engine knock is caused by the undesired self-ignition of the fuel air mixture ahead of the flame front initiated by the spark. It leads to pressure fluctuations that can severely damage the engine. Modern vehicles utilize different strategies to avoid knock. One extreme strategy assumes a weak fuel quality and, to protect the engine, retards the spark timing at the expense of combustion efficiency. The other extreme carefully detects knock in every engine cycle and retards the spark timing only when knock is detected.

Stringent regulations on fuel economy have driven major innovative changes in the internal combustion engine design. (E.g. CAFE fuel economy standards of 54.5 mpg by 2025 in the U.S) Vehicle manufacturers have implemented engine infrastructure changes such as downsizing, direct injection, higher compression ratios and turbo-charging/super-charging to achieve higher engine efficiencies. Fuel properties therefore, have to align with these engine changes in order to fully exploit the possible benefits. Fuel octane number is a key metric that enables high fuel efficiency in an engine. Greater resistance to auto-ignition (knock) of the fuel/air mixture allows engines to be operated at a higher compression ratio for a given quantity of intake charge without severely retarding the spark timing resulting in a greater torque per mass of fuel burnt. This attribute makes a high octane fuel a favorable hydrocarbon choice for modern high efficiency engines that aim for higher fuel economy.

The effects of lubricant oil and fuel properties on low speed pre-ignition (LSPI) occurrence in boosted S.I. engines were experimentally evaluated with multi-cylinder engine and de-correlated oil and fuel matrices. Further, the auto-ignitability of fuel spray droplets and evaporated homogeneous fuel/oil mixtures were evaluated in a combustion bomb and pressure differential scanning calorimetry (PDSC) tests to analyze the fundamental ignition process. The work investigated the effect of engine conditions, fuel volatility and various lubricant additives on LSPI occurrence. The results support the validity of aspects of the LSPI mechanism hypothesis based on the phenomenon of droplets of lubricant oil/fuel mixture (caused by adhesion of fuel spray on the liner wall) flying into the chamber and autoigniting before spark ignition.

Combustion in direct injection spark ignition (DISI) engines is strongly influenced by the in-cylinder charge motion. The charge motion depends both on the injection strategy as well as the geometry of the combustion chamber/air intake system and the physical location of the injectors (side mounted vs. centrally mounted). For boosted and downsized DISI engines, many manufacturers are favouring a single late injection or a split injection strategy. This has the advantage of creating high levels of turbulence which leads to faster combustion and improved thermodynamic efficiency. Furthermore the charge cooling offers enhanced knock resistance, thereby allowing more spark advance. The calibration of such engines is critical: the prize of greater thermodynamic efficiency must be balanced against the risks of charge inhomogeneity, namely excessive particulate emissions and poor drivability.

Octane appetite of modern engines has changed as engine designs have evolved to meet performance, emissions, fuel economy and other demands. The octane appetite of seven modern vehicles was studied in accordance with the octane index equation OI=RON-KS, where K is an operating condition specific constant and S is the fuel sensitivity (RONMON). Engines with a displacement of 2.0L and below and different combinations of boosting, fuel injection, and compression ratios were tested using a decorrelated RONMON matrix of eight fuels. Power and acceleration performance were used to determine the K values for corresponding operating points. Previous studies have shown that vehicles manufactured up to 20 years ago mostly exhibited negative K values and the fuels with higher RON and higher sensitivity tended to perform better.

Gasoline Compression Ignition (GCI) has been identified as a technology which could give both high efficiency and relatively low engine-out emissions. The introduction of any new vehicle technology requires widespread availability of appropriate fuels. It would be ideal therefore if GCI vehicles were able to operate using the standard grade of gasoline that is available at the pump. However, in spite of recent progress, operation at idle and low loads still remains a formidable challenge, given the relatively low autoignition reactivity of conventional gasoline at these conditions. One conceivable solution would be to use both diesel and gasoline, either in separate tanks or blended as a single fuel (“dieseline”). However, with this latter option, a major concern for dieseline would be whether a flammable mixture could exist in the vapour space in the fuel tank.