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The low auto-ignition temperature, rapid evaporation and high cetane number of dimethyl ether (DME) enables the use of low-pressure direct injection in compression ignition engines, thus potentially bringing the cost of the injection system down. This in turn holds the promise of bringing CI efficiency to even the smallest engines. A 50cc crankcase scavenged two-stroke CI engine was built based on moped parts. The major alterations were a new cylinder head and a 100 bar DI system using a GDI-type injector. Power is limited by carbon monoxide emission but smoke-free operation and NOx < 200ppm is achieved at all points of operation.

A model which calculates the hydrocarbon emissions from an SI engine is presented. The model was developed in order to obtain a better under-standing of experimental results from an engine operating on different fuels and lubricants. The model is based on the assumptions that fuel is stored in crevices and oil film during intake and compression followed by desorption during expansion and exhaust. The model also calculates the amount of desorbed material that undergoes in cylinder oxidation and exhaust port oxidation. The model succesfully predicts the trends followed by varying different engine parameters. The effect of changing the lubricant is of the same order of magnitude as found experimentally, but the effect of changing the fuel could not be predicted very well by the model. A possible explanation is, that the lubricant film thickness varies due to viscosity variations of the oil film, when the fuel is dissolved in the film.

An experimental study has been carried out on the homogeneous charge compression ignition (HCCI) combustion of Dimethyl Ether (DME). The study was performed as a parameter variation of engine speed and compression ratio on excess air ratios of approximately 2.5, 3 and 4. The compression ratio was adjusted in steps to find suitable regions of operation, and the effect of engine speed was studied at 1000, 2000 and 3000 RPM. It was found that leaner excess air ratios require higher compression ratios to achieve satisfactory combustion. Engine speed also affects operation significantly.

The IEA Advanced Motor Fuels Agreement has initiated this project concerning the application of biodegradable lubricants to diesel and gasoline type vehicles. Emission measurements on a chassis dynamometer were carried out. The purpose of these measurements was to compare the emissions of CO, CO2, NOx, THC, PM, lubricant-SOF and PAH from diesel and gasoline type vehicles using biodegradable lubricants and conventional lubricants. This paper describes the results of the experiments with the gasoline type vehicles only - two FFV's (Flexible Fuel Vehicles). The results from the measurements on the diesel type vehicles are described in an earlier SAE paper [1]. Lubricant consumption and fuel consumption are other important parameters that have been evaluated during the experiments. Both vehicle types were operated on conventional crude oil based fuels and alternative fuels.

The IEA Advanced Motor Fuels Agreement has initiated this project concerning the application of biodegradable lubricants to diesel and gasoline type vehicles. Emission measurements on a chassis dynamometer were carried out. The purpose of these measurements was to compare the emissions of CO, CO2, NOx, THC, PM, lubricant-SOF and PAH from one diesel and one gasoline type vehicle using biodegradable lubricants and conventional lubricants. This paper describes the results of the experiments with the diesel type vehicle only. Lubricant consumption and fuel consumption are other important parameters that have been evaluated during the experiments. Both vehicle types were operated on conventional crude oil based fuels and alternative fuels. The diesel vehicle was operated on conventional diesel fuel from a Danish fuel station, low sulfur diesel from Sweden and biodiesel, which was bought at a fuel station in Germany.

Investigations were made concerning the formation of combustion chamber deposits (CCD) in SI gas engines fueled by producer gas. The main objective was to determine and characterise CCD and PAH formation caused by the presence of the light tar compounds phenol and guaiacol in producer gas from an updraft gasifier. The work was based on previous work regarding the assumption that phenol is a soot precursor and therefore could lead to CCD formation. Laboratory experiments were conducted, where pyrolysis products of the single tar components were collected on small aluminium plates. The experiments showed that guaiacol formed significant amount of deposits. The structure observed was a lacquer type of deposit. It was determined that there was no distinct deposit formation due to phenol. Experiments were conducted with a 0.48 litre one-cylinder high compression ratio SI engine fueled by synthetic producer gas.

The effects of methanol and EGR on HCCI combustion of dimethyl ether have been tested separately in a diesel engine. The engine was equipped with a common rail injection system which allowed for random injection of DME. The engine could therefore be operated either as a normal DI CI engine or, by advancing the injection timing 360 CAD, as an HCCI engine. The compression ratio of the engine was reduced to 14.5 by enlarging the piston bowls. The engine was operated in HCCI mode with DME at an equivalence ratio of 0.25. To retard the combustion timing, methanol was port fuel injected and the optimum quantity required was determined. The added methanol increased the BMEP by increasing the total heat release and retarding the combustion to after TDC. Engine knock was reduced with increasing quantities of methanol. The highest BMEP was achieved when the equivalence ratio of methanol was around 0.12 at 1000 RPM, and around 0.76 at 1800 RPM. EGR was also used to retarding the timing.

Development of numerical tools for quantitatively assessing biofuel combustion in Internal Combustion Engines and facilitating the identification of optimum operating parameters and emission strategy are challenges of engine combustion research. Biofuels obtained through e.g. a Fischer-Tropsch process (FT) are complex mixtures of wide ranges of high molecular weight hydrocarbons in the diesel and naphtha boiling range dominated by C10-C18 hydrocarbons in n-alkane, iso-alkane, alkenes, aromatic and oxygenate classes. In this paper modeling of combustion in a rapid compression machine has been performed using model compounds from a given FT biofuel distribution as surrogate fuels. Furthermore, the detailed mechanism has been reduced by applying an automatic necessity analysis removing redundant species from the detailed model.

The effects of lubricant composition on hydrocarbon emissions from a SI engine have been experimentally investigated. Results based on measurements of solubilities of different fuel components in different types of lubricants are presented. 2 lubricants and two hydrocarbons were chosen for testing in a single cylinder engine. Emissions and performance was measured for various fuel air ratios and ignition timings. The lubricant with the lowest solubility with respect to isooctane also showed the lowest hydrocarbon emissions. The influence of the lubricant was greatest at lean air fuel ratios. Xylene is much more soluble in the lubricants than isooctane and gave lower hydrocarbon emissions when the engine was operated at rich air fuel ratios. At leaner mixtures, isooctane gave lower emissions. The results indicate that the lubricant plays a contributing, but not dominating role in hydrocarbon emissions from gasoline engines.

The described investigation was carried out under the umbrella of IEA Advanced Motor Fuels Agreement. The purpose was to evaluate the emissions of carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx), particulate matter (PM) and polycyclic aromatic hydrocarbons (PAH) from vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were found in this field. In this context measurement according to the Federal Test Procedure (FTP) and the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer with a directly injected gasoline vehicle. Experiments were carried out with a reference fuel, a fuel based 70% on FT and an alkylate fuel (Aspen), which was taken to be the ultimate formula of FT gasoline.

The aim of this study is to evaluate the existing chemical kinetic mechanism reduction techniques. From here, an appropriate reduction scheme was developed to create compact yet comprehensive surrogate models for both diesel and biodiesel fuels for diesel engine applications. The reduction techniques applied here were Directed Relation Graph (DRG), DRG with Error Propagation, DRG-aided Sensitivity Analysis, and DRG with Error Propagation and Sensitivity Analysis. Nonetheless, the reduced mechanisms generated via these techniques were not sufficiently small for application in multi-dimensional computational fluid dynamics (CFD) study. A new reduction scheme was therefore formulated. A 68-species mechanism for biodiesel surrogate and a 49-species mechanism for diesel surrogate were successfully derived from the respective detailed mechanisms.

This study explores the feasibility of using a sustainable lignin-based fuel, consisting of 44 % lignin, 50 % ethanol, and 6 % water, in conventional compression ignition (CI) marine engines. Through experimental evaluations on a modified small-bore CI engine, we identified the primary challenges associated with lignin-based fuel, including engine startup and shutdown issues due to solvent evaporation and lignin solidification inside the fuel system, and deposit formation on cylinder walls leading to piston ring seizure. To address these issues, we developed a fuel switching system transitioning from lignin-based fuel to cleaning fuel with 85 vol% of acetone, 10 vol% of water and 5 vol% of ignition improving additive, effectively preventing system clogs.

The utilisation of producer gas - from thermal gasification of biomass - as a fuel for spark ignition gas engines is of vital importance to the ongoing effort of making biomass gasification a commercially feasible technology. Tests have been carried out with a 1.1 litre four-cylinder natural aspirated SI engine in conjunction with a two-stage gasifier with a nominal thermal input of 100 kW. The fuel-gas is produced from wood chips in order to get a CO2 neutral fuel for combined heat and power production. The producer gas has a very low tar and particulate content and high hydrogen content. As the gasifier was operated with varying fuel properties, engine tests were made with different fuel-gas compositions. The engine tests showed that producer gas has a power and efficiency advantage compared to natural gas when operating the engine at lean burn conditions. The engine was operated at air/fuel ratios varying from stoichiometric to extremely lean burn (λ>3).

Studies were performed with three commonly used additive metals, cerium copper, and iron, with a conventional and a low sulfur fuel in order to investigate fuel additive effects on engine particulate emissions before a particulate filter. Measurements were made on a 4 cylinder direct injection diesel engine and included total particulate mass, soluble organic fraction for both fuels, and polynuclear aromatic hydrocarbon emissions for the low sulfur fuel. The cerium based additive reduced the emissions with both fuels, with the largest effect being on the non-SOF fraction. With the other additives and the high sulfur fuel, non-SOF emissions were increased, increasing total particulate emissions. Copper was found to reduce the polynuclear aromatic hydrocarbons, and cerium was found to have the least effect. The use of an SiC wall flow filter reduced particulate and polynuclear aromatic emissions by over 90%.

In this reported work, 2-dimsensional computational fluid dynamics studies of n-heptane combustion and soot formation processes in the Sandia constant-volume vessel are carried out. The key interest here is to elucidate how the chemical kinetics affects the combustion and soot formation events. Numerical computation is performed using OpenFOAM and chemistry coordinate mapping (CCM) approach is used to expedite the calculation. Three n-heptane kinetic mechanisms with different chemistry sizes and comprehensiveness in oxidation pathways and soot precursor formation are adopted. The three examined chemical models use acetylene (C2H2), benzene ring (A1) and pyrene (A4) as soot precursor. They are henceforth addressed as nhepC2H2, nhepA1 and nhepA4, respectively for brevity. Here, a multistep soot model is coupled with the spray combustion solver to simulate the soot formation/oxidation processes.

About 2000 hours of gas engine operation with producer gas from biomass as fuel has been conducted on the gasification combined heat and power (CHP) demonstration and research plant, named “Viking” at the Technical University of Denmark. The plant and engine have been operated continuously and unmanned for five test periods of approximately 400 hours each. Two different control approaches have been applied and investigated: one where the flow rate of the producer gas is fixed and the engine operates with varying excess of air due to variation in gas composition and a second where the excess of air in the exhaust gas is fixed and the flow rate of produced gas from the gasifier is varying. It was seen that the optimal control approach regarding the gasifier operation resulted in engine operation with significant variation of the NOx emissions Producer gas properties and contaminations have been investigated.

The main purpose of this study was to investigate the influence of diesel engine conditions on the mutagenic activity of the exhaust. Special emphasis was put on investigation of the influence of nitrogen oxides content. Experiments with a diesel engine have been carried out in the laboratory and the emissions of carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx) and particulate matter (PM) have been measured at different engine conditions. The particulate matter was extracted in order to obtain the soluble organic fraction (SOF), and this fraction was analyzed for mutagenic activity in the Salmonella/microsome assay (AMES test). It was found that the mutagenic activity evidently depended on the PAH content (PAH = Polycyclic Aromatic Hydrocarbons) of the exhaust gas rather than the NOx content. However, the percentage of the direct mutagenic activity of the total mutagenic activity increased as the NOx content in the exhaust gas increased.

A novel base metal-palladium catalytic coating was applied on commercial silicon carbide wall flow diesel filters and tested in an engine test bench. This catalytic coating limits the NO2 formation and even removes NO2 within a wide temperature range. Soot combustion, HC conversion and CO conversion properties are comparable to current platinum-based coatings, but at a lower cost. This paper compares the results from engine bench tests of present commercial solutions as regards NO2-, HC-, CO-removal and soot combustion with the novel coating. Furthermore, emission test results from base metal-palladium coated diesel particulate filters installed on operating taxis and related test cycle data are presented. A significant reduction in NO2 emission compared to present technology is measured.

The paper describes the optimization of a 50 cc crankcase scavenged two-stroke diesel engine operating on dimethyl ether (DME). The optimization is primarily done with respect to engine efficiency. The underlying idea behind the work is that the low weight, low internal friction and low engine-out NOx of such an engine could make it ideal for future vehicles operating on second-generation biofuels. Data is presented for the performance and emissions at the current state of development of the engine. Brake efficiencies above 30% were obtained despite the small size of the engine. In addition, efficiencies near the maximum were found over a wide operating range of speeds and loads. Maximum bmep is 500 kPa. Results are shown for engine speeds ranging from 2000 to 5000 rpm and loads from idle to full load. At all speeds and loads NOx emissions are below 200 ppm and smokeless operation is achieved. Design improvements relative to an earlier prototype are described.

Engine experiments were carried out on a six cylinder DI-diesel engine using synthetic fuel and lubricant containing no PAH (Polycyclic Aromatic Hydrocarbons) [1]. By selectively doping the fuel and oil with pyrene, the effect of fuel and oil originating PAH on the exhaust emissions could be investigated. The experimental results are analyzed in a new way by suggesting a general transport model for PAH. By estimating as many transport quantities as possible it is attempted to gain knowledge about the most dominant mechanisms. The main finding is not surprisingly that for commercial fuels containing substantial concentrations of PAH, the by far major contributor to exhaust PAH is unburned fuel PAH. The concentration of PAH in the oil sump affects only weakly the PAH concentration in the exhaust for engines operating on commercial fuels. The PAH desorbing from the liner are getting burned efficiently, thereby being insignificant.