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A 2001 General Motors 4.3 liter V-6 marine engine was baseline emissions tested and then equipped with catalysts. Emission reduction effects of exhaust gas recirculation (EGR) were also explored. Because of a U.S. Coast Guard requirement that inboard engine surface temperatures be kept below 200°F, the engine's exhaust system, including the catalysts, was water-cooled. Engine emissions were measured using the ISO-8178-E4 5-mode steady-state test for recreational marine engines. In baseline configuration, the engine produced 16.6 g HC+NOx/kW-hr, and 111 g CO/kW-hr. In closed-loop control with catalysts, HC+NOx emissions were reduced by 75 percent to 4.1 g/kW-hr, and CO emissions were reduced by 36 percent to 70 g/kW-hr of CO. The catalyzed engine was then installed in a Sea Ray 190 boat, and tested for water reversion on both fresh and salt water using National Marine Manufacturers Association procedures.

Measurement of emissions from small utility engines has usually been accomplished using steady-state raw emissions procedures such as SAE Recommended Practice J1088. While raw exhaust measurements have the advantage of producing modal exhaust gas concentration data for design feedback; they are laborious, may influence both engine performance and the emissions themselves, and have no provision for concurrent particulate measurements. It is time to consider a full-dilution procedure similar in principle to automotive and heavy-duty on-highway emission measurement practice, leading to improvements in many of the areas noted above, and generally to much higher confidence in data obtained. When certification and audit of small engine emissions become a reality, a brief dilute exhaust procedure generating only the necessary data will be a tremendous advantage to both manufacturers and regulatory agencies.

Methods for measurement and expression of crankcase or “blowby” emissions from diesels were developed and demonstrated on a test engine. These methods were subsequently used to characterize gas and particulate emissions from two in-service engines. Crankcase emissions were evaluated under engine operating conditions corresponding to the EPA 13-mode certification test. Substances for which analyses were conducted included regulated pollutants, sulfate, trace elements, nitrosamines, individual hydrocarbons, and aldehydes. Emissions from the diesel crankcases were compared to exhaust emissions (where possible) to assess their importance. Analysis for nitrosamines was continued beyond the original effort, utilizing another test engine.

Gaseous and particulate emissions from two heavy-duty diesel engines were characterized while the engines were operated on five different fuels. Characterization included mass rates of major exhaust products, plus analysis of particulate matter for sulfate, trace elements, major elements, total solubles, and other properties. Analysis of rate and composition data was conducted with regard to fuel and engine effects on particulate. Two large particulate samples were also collected for later analysis on groups of organics present.

Emissions from a Stirling engine-powered 1986 model light-duty truck were measured using current EPA (chassis dynamometer) emissions certification procedures and certain specialized tests. Three fuels were used including unleaded gasoline, a blend of MTBE in unleaded gasoline, and JP-4. City (FTP) cycles and Highway (FET) cycles were run on all three fuels, and emissions measured during the cycles included hydrocarbons (HC), carbon monoxide (CO), and oxides of nitrogen (NOx). Fuel economy was also calculated for these tests. Additional pollutants measured during some of the tests included aldehydes, 1,3-butadiene, individual hydrocarbon species, and total particulate matter. In addition to the cyclic schedules, steady-state conditions were run on JP-4 and straight gasoline for regulated emissions and fuel economy. The conditions consisted of several simulated gradients at three vehicle speeds, plus idle.

Particulate and gaseous emissions from two light-duty diesel vehicles were measured over eight operating schedules, using five different fuels. Characterization included regulated exhaust emissions and a number of unregulated constituents. Non-routine gas measurements included phenols, hydrocarbon boiling range, and aldehydes. Particulate characterization included mass rates and concentrations, visible smoke, aerodynamic sizing, total organics, BaP, sulfate, phenols, trace elements, and major elements. Statistical analysis of emissions data was undertaken using fuel properties and operating schedule statistics as independent variables. Regressions were computed for a few variables, and analysis of variance and multiple comparisons were used where the data were not suitable for regression analysis.

The primary goal of this project was to characterize particulate emissions from a snowmobile engine through measurement of particulate matter volatile organic fraction (VOF), particle size, and biological activity. Emissions were evaluated using both a mineral oil and a biosynthetic oil. Basic criteria pollutants were also measured from diluted exhaust using conventional techniques. Particulate matter volatile organic fraction was determined using a gas chromatographic method (DFI/GC). Particle size was characterized using a scanning mobility particle sizer (SMPS), and particulate matter biological activity was measured using a modification of the Ames bioassay procedure. Results revealed that more than 99 percent of the particles were ultrafine (Dp<100nm), with a peak concentration in the nanoparticle (Dp<50nm) size range. It was also observed that the use of a biosynthetic lubricant increased both volatile and total PM mass emissions compared to the mineral lubricant.

Exhaust emission data from several fuel effects studies were normalized and subjected to statistical analyses. The goal of this work was to determine whether emission effects of property variation in alternate-source fuels were similar, less pronounced, or more pronounced than the effects of property variation in petroleum fuels. A literature search was conducted, reviewing hundreds of studies and finally selecting nine which dealt with fuel property effects on emissions. From these studies, 15 test cases were reported. Due to the wide variety of vehicles, fuels, test cycles, and measurement techniques used in the studies, a method to relate them all in terms of general trends was developed. Statistics and methods used included bivariate correlation coefficients, regression analysis, scattergrams and goodness-of-fit determinations.

An appropriate test procedure, based on a duty cycle representative of real in-use operation, is an essential tool for characterizing engine emissions. A study has been performed to develop and validate a snowmobile engine test procedure for measurement of exhaust emissions. Real-time operating data collected from four instrumented snowmobiles were combined into a composite database for analysis and formulation of a snowmobile engine duty cycle. One snowmobile from each of four manufacturers (Arctic Cat, Polaris, Ski-Doo, and Yamaha) was included in the data collection process. Snowmobiles were driven over various on- and off-trail segments representing five driving styles: aggressive (trail), moderate (trail), double (trail with operator and one passenger), freestyle (off trail), and lake driving. Statistical analysis of this database was performed, and a five-mode steady-state snowmobile engine duty cycle was developed.

The purpose of this project was to modify existing small off-road engines to meet ARB's originally proposed 1999 emissions standards. A particular point was to show that compliance could be attained without the need to redesign the base engines. Four high-sales volume, ARB-certified 1997 model engines were selected from the following categories: 1) handheld two-stroke engine, 2) handheld four-stroke engine, 3) non-handheld side-valve engine, and 4) a non-handheld overhead-valve engine. Engines were selected, procured, and baseline emission tested using applicable ARB test procedures. Appropriate emission control strategies were then selected and applied to the four engines. Emission reduction strategies used included air/fuel ratio optimization, and catalytic aftertreatment. Following the development of the four emission-controlled engines, final, certification-quality emissions tests were performed. All four engines met ARB's original 1999 Tier 2 emission standards after development.

The Environmental Protection Agency (EPA) has proposed emission standards for nonroad spark-ignition engines rated over 19 kW. Existing emission standards adopted by the California Air Resources Board require testing on a steady-state duty cycle. This paper presents the results of measurements to characterize normal operation from forklift trucks, which are the dominant application for these engines. In combination with previous measurements with a welder to represent constant-speed applications, the measured data were used to derive a composite 20-minute transient duty cycle for emission testing for all nonroad industrial spark-ignition engines.

The goal of the project was to reduce tailpipe-out hydrocarbon (HC) plus oxides of nitrogen (NOx) emissions to 50 percent or less of the current California Air Resources Board (CARB) useful life standard of 12 g/hp-hr for Class I engines, or 9 g/hp-hr for Class II engines. Low-emission engines were developed using three-way catalytic converters, passive secondary-air induction (SAI) systems, and in two cases, enleanment. Catalysts were integrated into the engine's mufflers, where feasible, to maintain a compact package. Due to the thermal sensitivity of these engines, carburetor calibrations were left unchanged in four of the six engines, at the stock rich settings. To enable HC oxidation under such rich conditions, a simple passive supplemental air injection system was developed. This system was then tuned to achieve the desired HC+NOx reduction.

Several properties of a refinery “straightrun kerosene“, which had a narrow boiling range approximating the middle of a No. 1 diesel fuel, were altered to study their effects on regulated and unregulated exhaust emissions. Eleven fuel blends, representing changes in nitrogen content, aromatic level, boiling point distribution, olefin content, and cetane number, were evaluated in a 1975 Mercedes-Benz 240D. Statistical analysis, including regression, was performed using selected fuel properties as independent variables. Higher aromatic levels were generally associated with increased emissions, while increased olefin levels were generally associated with decreased emissions.

Recent approval of emission standards for small utility engines by the California Air Resources Board(1)* suggests that substantial reductions in emissions from small utility engines will soon be required. While 1994 standards may be met with simple engine adjustments or modifications, 1999 standards are much more stringent and may require the use of catalysts in conjunction with other emission reduction technologies. Assessing the feasibility of candidate emission control strategies is an important first step. Various emission reduction technologies were applied to three different 4-stroke engines. Emission tests were conducted to determine the effectiveness of air/fuel ratio changes, thermal oxidation, exhaust gas recirculation, and catalytic oxidation with and without supplemental air. Results of these evaluations, along with implications for further work, are presented. One engine's emissions were reduced below the levels of 1999 ARB standards.

A major gap exists in available baseline emissions data on the small utility engine population between the mid-1970's and present day. As part of the input required for a standard-setting process, the California Air Resources Board has funded limited laboratory emission measurements on a number of modern small engines, both 2-stroke and 4-stroke designs. Exhaust constituents characterized in this study include total hydrocarbons, reactive hydrocarbons (RHC), methane, CO, NOx, CO2, O2, aldehydes, and particulate matter. A total of nine engines were evaluated, spanning the range from the smallest widely-used 2-strokes (about 20 cc displacement) to 4-strokes approaching 20 hp.

Snowmobile engine emissions are of concern in environmentally sensitive areas, such as Yellowstone National Park (YNP). A program was undertaken to determine potential emission benefits of use of bio-based fuels and lubricants in snowmobile engines. Candidate fuels and lubricants were evaluated using a fan-cooled 488-cc Polaris engine, and a liquid-cooled 440-cc Arctco engine. Fuels tested include a reference gasoline, gasohol (10% ethanol), and an aliphatic gasoline. Lubricants evaluated include a bio-based lubricant, a fully synthetic lubricant, a high polyisobutylene (PIB) lubricant, as well as a conventional, mineral-based lubricant. Emissions and fuel consumption were measured using a five-mode test cycle that was developed from analysis of snowmobile field operating data.

Emissions from two heavy-duty four stroke direct injection engines designed to use methanol fuel, one using Diesel pilot fuel injection and the other using spark ignition, were characterized in this program along with those from a comparably-sized Diesel engine. Emissions evaluated during both steady-state and transient FTP procedures included regulated gases (HC, CO, and NOx), unburned methanol, aldehydes, other gaseous organics, total particulate, sulfate, soluble organics in particulate and BaP. The engines adapted for methanol fuel and using catalysts emitted less HC, CO, particulate, soluble organics, and BaP than the Diesel fueled engine.

The Environmental Protection Agency (EPA) is developing emission standards for nonroad spark-ignition engines rated over 19 kW. Existing emission standards adopted by the California Air Resources Board for these engines were derived from emission testing with new engines, with an approximate adjustment applied to take deterioration into account. This paper describes subsequent testing with two LPG-fueled engines that had accumulated several thousand hours of operation with closed-loop control and three-way catalysts. These engines were removed from forklift trucks for characterization and optimization of emission levels. Emissions were measured over a wide range of steady-state points and several transient duty cycles. Optimized emission levels from the aged systems were generally below 1.5 g/hp-hr THC+NOx and 10 g/hp-hr CO.

To characterize exhaust emissions from water-cooled 2-stroke outboard motors (the predominant type), four new motors were tested on dynamometer stands. The engines ranged from 4-65 hp in size, and operating conditions were chosen along lines of simulated boat loading. All the measurements were taken at steady-state conditions. Emission concentrations were measured in raw exhaust gas and after the gases had been bubbled through water in a specially constructed tank. Constituents measured included hydrocarbons, CO, CO2, NO, NOx, O2, light hydrocarbons, and aldehydes. Emissions of sulfur oxides (SOx) were estimated on the basis of fuel consumed, and all the exhaust emissions data were used with available information on population and usage of motors to estimate exhaust emission factors and national exhaust emissions impact.

The research program on which this paper is based included both laboratory emission measurements and extrapolation of results to the national population of heavy-duty farm, construction, and industrial engines. Emission tests were made on four gasoline engines and eight diesel engines typical of those used in F, C, and I equipment. Gaseous and particulate emissions were measured during engine operation on well-accepted steady-state procedures, and diesel smoke was measured during both steady-state conditions and the Federal smoke test cycle. Emissions measured were hydrocarbons, CO, CO2, NO, NOx, O2, aliphatic aldehydes, light hydrocarbons, particulate, and smoke. Emission of sulfur oxides (SOx) was estimated on the basis of fuel consumed, and both evaporative and blowby hydrocarbons were also estimated where applicable (gasoline engines only). Data on emissions obtained from this study were compared with those available in the literature, where possible.