Search Results

It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.

The objectives of the present work are to investigate the regulated and unregulated (particle) emissions of a classical and modern 2-stroke and a typical 4-stroke scooter with different ethanol blend fuels. There is also comparison of two different ethanol fuels: pure ethanol (E) *) and hydrous ethanol (EH) which contains 3.9% water and is denatured with 1.5% gasoline. Special attention is paid in this research to the hydrous ethanol, since the production costs of hydrous ethanol are much less than those for (dry) ethanol. The vehicles are with carburettor and without catalyst, which represents the most frequent technology in Eastern Asia and offers the information of engine-out emissions. Exhaust emissions measurements have been performed with fuels containing ethanol (E), or hydrous ethanol (EH) in the portion of 5, 10, 15 and 20% by volume. During the test systematical analysis of particle mass (PM) and nano-particles counts (NP) were carried out.

A direct injection system in which fuel was injected through the cylinder wall was developed and detailed investigation was made for the purpose of reducing short-circuit of fuel in 2-stroke engines. As a result of dynamo tests using 430cc single cylinder engine, it was found that the injector was best attached at a location as close to TDC as possible on the rear transfer port side, and that the entire amount of fuel should be injected towards the piston top surface. Emissions were worsened if fuel was injected towards the exhaust port or spark plug. Although the higher injection pressure resulted in large emissions reduction effects, it did not have a significant effect on fuel consumption. When a butterfly exhaust valve, known to be effective against irregular combustion in the light load range, was applied, it was found to lead to further reductions in HC emission and fuel consumption while also improving combustion stability.

The CBR [1] (Controlled Burn Rate) is a port deactivation concept developed by AVL and is already applied in series production cars. The benefit of this concept is the low engine-out emission (CO, HC and NOx) and good fuel economy. By creating turbulent kinetic energy at the correct time and place in the combustion chamber a rapid and stable combustion occurs which allows to run the engine well above a Lambda Excess Air Ratio of 1.5. The CBR system features two different intake ports, one charge motion port and one filling port. Additionally a device for port-deactivation (slider, butterfly) is applied. At part load points and lower engine speeds the filling port is switched off. The CBR concept was now evoluted for compact engines as CCBR - with carburetor and as CBR Light - for engines with electronic fuel injection. CCBR stands for Carbureted Controlled Burn Rate.

The road transportation sector is undergoing significant changes, and new green scenarios for sustainable mobility are being proposed. In this context, a diversification of the vehicles’ propulsion, based on electric powertrains and/or alternative fuels and technological improvements of the electric vehicles charging stations, are necessary to reduce greenhouse gas emissions. The adoption of internal combustion engines operating with alternative fuels, like methanol, may represent a viable solution for overcoming the limitations of actual grid connected charging infrastructure, giving the possibility to realize off-grid charging stations. This work aims, therefore, at investigating this last aspect, by evaluating the performance of an internal combustion engine fueled with methanol for stationary applications, in order to fulfill the potential demand of an on off-grid charging station.

Two Cummins B5.9L engines were fueled with 100% biodiesel in excess of 48 months by the Agricultural Engineering Department at the University of Missouri-Columbia. The engines used to power Dodge pickups. The engine lubricating oil was sampled at 1000 mile intervals for analysis. Statistical analysis of the engine lubricating oil indicated that the wear metal levels in the lubricating oil were normal. A reduction in power was noted when the engines were tested using a chassis dynamometer. The 1991 pickup has been driven 110,451 km and the 1992 pickup has been driven approximately 177,022 km. The pickups averaged 6.9 km/L. Engine fuel efficiency and material compatibility issues are addressed in the paper.

Nine identical 40-ft. transit buses were operated on B20 and diesel for a period of two years - five of the buses operated exclusively on B20 (20% biodiesel blend) and the other four on petroleum diesel. The buses were model year 2000 Orion V equipped with Cummins ISM engines, and all operated on the same bus route. Each bus accumulated about 100,000 miles over the course of the study. B20 buses were compared to the petroleum diesel buses in terms of fuel economy, vehicle maintenance cost, road calls, and emissions. There was no difference between the on-road average fuel economy of the two groups (4.41 mpg) based on the in-use data, however laboratory testing revealed a nearly 2% reduction in fuel economy for the B20 vehicles. Engine and fuel system related maintenance costs were nearly identical for the two groups until the final month of the study.

A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.

Engines and fuels for transport as well as off-road applications are facing a double challenge: bring local pollution to the level requested by the most stringent city air quality standard reduce CO2 emission in order to minimize the global warming risk. These goals stimulate new developments both of conventional and alternative engines and fuels technologies. New combustion processes known as Controlled Auto-Ignition (CAI™) for gasoline engine and Homogeneous Charge Compression Ignition (HCCI) for Diesel engine are the subject of extensive research world wide and particularly at IFP for various applications such as passenger cars, heavy-duty trucks and buses as well as small engines. Because of the thermo-chemistry of the charge, the thermal NOx formation and the soot production are in principle much lower than in flames typical of conventional engines.

A mobile and dispersed power system is necessary for an advanced technological-industrial society. Today's petroleum-based system discharges waste products and heat and is growing exponentially. Energy resource commitment has already intersected “ultimate” low-cost petroleum supplies in the United States and will do so for the world before 2000; this portends major changes and cost increases. The twenty-first century system for mobile-dispersed power will reflect the energy source selected to replace petroleum-for example, coal, solar insolation, or uranium. It will incorporate a fuel intermediate such as methanol, ammonia, or hydrogen, and a suitably matched “engine.” The complete change will require more than 25 years because of the magnitude, fragmentation, structural gaps, complexity, and variety of the mobile-dispersed power system.

A gasoline Road Octane study was conducted by the Coordinating Research Council (CRC) to evaluate the effects of heavy aromatics (C9 and heavier) and ethanol content on Road Octane performance independent of Research Octane Number (RON) and Motor Octane Number (MON). Maximum-throttle and part-throttle Road ON’s were found to be well predicted by equations containing only RON and MON terms. Heavier aromatics were found to have a small adverse effect on both maximum-throttle and part-throttle Road ON independent of its direct effects on RON and MON. The all-car data did not show a significant ethanol-content effect, but eight of the thirty-seven cars did show significant effects for ethanol content.

The conversion design strategy, and emissions and performance results for a dedicated propane, vapour injected, 1995 Dodge Dakota truck are reported. Data is obtained from the University of Waterloo entry in the 1997 Propane Vehicle Challenge. A key feature of the design strategy is its focus on testing and emissions while preserving low engine speed power for drivability. Major changes to the Dakota truck included the following: installation of a custom shaped fuel tank, inclusion of a fuel temperature control module, addition of a vaporizer and a fuel delivery metering unit, installation of a custom vapour distribution manifold, addition of an equivalence ratio electronic controller, inclusion of a wide range oxygen sensor, addition of an exhaust gas recirculation cooler and installation of thermal insulation on the exhaust system. A competition provided natural gas catalyst was used.

As part of the 1997 Propane Vehicle Challenge, a team of twelve UTEP students converted a 1996 Dodge Grand Caravan with a 3.3 L V6 engine to dedicated Liquefied Petroleum Gas (LPG) operation according to the 1997 Propane Vehicle Challenge (PVC) competition rules (16). The 1997 UTEP team developed an LPG liquid phase port fuel injection (LPP-FI) system for the minivan. The UTEP design strategy combines simplicity and sound engineering practices with the effective use of heat resistant materials to maintain the LPG in the liquid phase at temperatures encountered in the fuel delivery system. The team identified two options for fuel storage with in-tank fuel pumps. The competition vehicle incorporates a five-manifold eight inch diameter Sleegers Engineering LPG tank fitted with a Walbro LPTS in-tank pump system, providing a calculated range of 310 city miles and 438 highway miles.

This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

The Injection Rate Shaping consists in a novel injection strategy to control air-fuel mixing quality via a suitable variation of injection timing that affects the injection rate profile. This strategy has already provided to be useful to increase combustion efficiency and reduce pollutant emissions in the modern compression ignition engines fed with fossil Diesel fuel. But nowadays, the ever more rigorous emission targets are enhancing a search for alternative fuels and/or new blends to replace conventional ones, leading, in turn, a change in the air-fuel mixture formation. In this work, a 1D model of spray injection aims to investigate the combined effects of both Injection Rate Shaping and alternative fuels on the air-fuel mixture formation in a compression ignition engine. In a first step, a ready-made model for conventional injection strategies has been set up for the Injection Rate Shaping.

The introduction of more stringent standards for engine emissions requires a steady development of exhaust gas aftertreatment in addition to an optimized cylinder combustion. The reduction of the cold start phase can help significantly to lower cycle emissions. With the goal of optimizing the overall emission performance this study presents a comprehensive simulation approach. A well established 1D gas dynamics and engine simulation model is extended by three key features. These are models for combustion and pollutant production in the cylinder, models for the pollutant conversion in a catalyst, and a general species transport model. This allows to consider an arbitrary number of chemical species and reactions in the entire system.

This work describes an experimental and numerical investigation of the thermal transient of i.c. engine exhaust systems. A prototype of exhaust system has been investigated during a NEDC cycle in two different configurations. Firstly an uncoated catalyst has been adopted to consider only the effect of the gas-wall heat transfer. The measurements have been repeated on the same exhaust system equipped with a coated catalyst to point out the contribution of the chemical reactions to the thermal transient of the system. The measured values have been compared to the predicted results carried out with a 1D thermo fluid dynamic code, developed in-house to account for the thermal transient of the system and the chemical reactions occurring in the catalyst.

This paper describes some recent advances of the research work concerning the 1D fluid dynamic modeling of unsteady reacting flows in s.i. engine pipe-systems, including pre-catalysts and main catalysts. The numerical model GASDYN developed in previous work has been further enhanced to enable the simulation of the catalyst. The main chemical reactions occurring in the wash-coat have been accounted in the model, considering the mass transfer between gas and solid phase. The oxidation of CO, C3H6, C3H8, H2 and reduction of NO, the steam-reforming reactions of C3H6, C3H8, the water-gas shift reaction of CO have been considered. Moreover, an oxygen-storage sub-model has been introduced, to account for the behavior of Cerium oxides. A detailed thermal model of the converter takes into account the heat released by the exothermic reactions as a source term in the heat transfer equations. The influence of the insulating mat is accounted.