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2-Butanone (C4H8O) is a promising alternative fuel candidate as a pure as well as a blend component for substitution in standard gasoline fuels. It can be produced by the dehydrogenation of 2-butanol. To describe 2-butanone's basic combustion behaviour, it is important to investigate key physical properties such as the laminar burning velocity. The laminar burning velocity serves on the one hand side as a parameter to validate detailed chemical kinetic models. On the other hand, especially for engine simulations, various combustion models have been introduced, which rely on the laminar burning velocity as the physical quantity describing the progress of chemical reactions, diffusion, and heat conduction. Hence, well validated models for the prediction of laminar burning velocities are needed. New experimental laminar burning velocity data, acquired in a high pressure spherical combustion vessel, are presented for 1 atm and 5 bar at temperatures of 373 K and 423 K.

A comprehensive methodology for predicting the transient thermal response of spark-ignition engines subject to time-varying boundary conditions is presented. The approach is based on coupling a cycle-resolved quasi-dimensional simulation of in-cylinder thermodynamic events with a resistor-capacitor (R-C) thermal network of the various component and fluid interactions throughout the engine and exhaust system. The dynamic time step of the thermal solution is limited by either the frequency of the prescribed time-dependent boundary conditions or by the minimum thermal time constant of the R-C network. To demonstrate the need for fully-coupled, transient thermodynamic and heat transfer solutions, model behavior is first explored for step-change and staircase variations of engine operating conditions.

A computer simulation of the Homogenous Charge Compression Ignition (HCCI) four-stroke engine has been developed for combustion and performance studies. The simulation couples models for mass, species, and energy within a zero-dimensional framework. The combustion process is described via a user-defined chemical kinetic mechanism. The CHEMKIN libraries have been used to formulate a stiff chemical kinetic solver suitable for integration within a complete engine cycle simulation, featuring models of gas exchange, turbulence and wall heat transfer. For illustration, two chemical kinetics schemes describing hydrogen and natural gas chemistry have been implemented in the code. The hydrogen scheme is a reduced one, consisting of 11 species and 23 reactions. The natural gas chemistry is described via the GRI-mechanism 3.0 that considers 53 species and 325 reactions, including NOx chemistry.

This study presents a systematic methodology for performing transient heat release analysis in a diesel engine. Novel techniques have been developed to infer the mass of air trapped in the cylinder and the mass of fuel injected on a cycle-by-cycle basis. The cyclic mass of air trapped in the cylinder is found accounting for pressure gradients, piston motion and short-circuiting during the valve overlap period. The cyclic mass of fuel injected is computed from the injection pressure history. These parameters are used in conjunction with cycle-resolved pressure data to accurately define the instantaneous thermodynamic state of the mixture. This information is used in the calculation and interpretation of transient heat release profiles.

Compared to conventional injection techniques, Gasoline Direct Injection (GDI) has a lot of advantages such as increased fuel efficiency, high power output and low emission levels, which can be more accurately controlled. Therefore, this technique is an important topic of today's injection system research. Although the operating conditions of GDI injectors are simpler from a numerical point of view because of smaller Reynolds and Weber numbers compared to Diesel injection systems, accurate simulations of the breakup in the vicinity of the nozzle are very challenging. Combined with the complications of experimental techniques that could be applied inside the nozzle and at the nozzle exit, this is the reason for the lack of understanding the primary breakup behavior of current GDI injectors.

Simultaneous reduction of engine pollutants (e.g., CO, THC, NOx, and soot) is one of the main challenges in the development of new combustion systems. Low-temperature combustion (LTC) concepts in compression ignition (CI) engines like premixed charged compression ignition (PCCI) make use of pre-injections to create a partly homogenous mixture. In the PCCI combustion regime, a direct correlation between injection and pollutant formation is no longer present because of long ignition delay times. In LTC combustion systems, the in-cylinder pressure sensor is normally used to help the combustion control. However, to allow the control of PCCI engines, new sensor concepts are investigated to obtain additional information about the PCCI combustion for advanced controller structures. In LTC combustion systems like gasoline-controlled autoignition (GCAI) concepts, the application of ion current sensors enables additional monitoring of the combustion process with real-time capability.

A prototype chromel-alumel overlapping thin-film thermocouple (TFTC) has been developed for transient heat transfer measurements in ceramic-coated combustion chambers. The TFTC has been evaluated using various metallurgical techniques such as scanning electron microscopy, energy dispersive x-ray detection, and Auger electron spectroscopy. The sensor was calibrated against a standard thermocouple in ice, boiling water, and a furnace at 1000°C. The microstructural and chemical analysis of the thin-films showed the alumel film composition was very similar to the bulk material, while the chromel film varied slightly. An initial set of ceramic plug surface temperatures was taken while motoring and firing the engine at 1900 rpm to verify thermocouple operation. The data shows a 613 K mean temperature and a 55 K swing for the ceramic surface compared with a 493 K mean temperature and a 20 K swing for the metal surface at the same location.

A reduced kinetic reaction mechanism for the autoignition of dimethyl ether is presented in this paper. Dimethyl ether has proven to be one of the most attractive alternatives to traditional fossil fuels for compression ignition engines. It can either be produced from biomass or from fossil oil. For dimethyl ether, Fischer et al. (Int. J.Chem. Kinet. 32 ( 12 ) (2000) 713-740) proposed a detailed reaction mechanism consisting of 79 species and 351 elementary reactions. In the present work, this detailed mechanism is systematically reduced to 31 species and 49 reactions. The reduced mechanism is discussed in detail with special emphasis on the high temperature thermal decomposition of dimethyl ether and on the fuel specific depleting reactions, which produce the methoxymethyl radical. In addition, a reaction pathway analysis for low temperature combustion is applied, where hydroperoxy-methylformate is found to be the dominating parameter for the low temperature regime.

A telemetry linkage system has been developed for piston temperature measurements in a direct-injection diesel engine. In parallel with the development of the telemetry linkage system, fast response thermocouples were installed at three piston locations - two on the bowl surface and one on the crown surface. A novel design was used to achieve electrical continuity between the piston and the connecting rod by means of a flexible steel strap pivoted on the piston skirt. The telemetry linkage system was then used to transport the electrical wires from the thermocouples to the external data acquisition system. A series of tests was run to determine the effects of location and load on piston surface temperatures. Surface temperature profiles varied substantially among the three locations, reflecting the differences in the combustion and heat flow characteristics of their surrounding regions.

The European Commission has released strict emission regulations for passenger cars in the past decade in order to improve air quality in cities and limit harmful emission exposure to humans. In the near future, even stricter regulations containing more realistic/demanding driving scenarios and covering more exhaust gas components are expected to be released. Passenger cars fueled with gasoline are one contributor to unhealthy air conditions, due to the fact that gasoline engines emit harmful air pollutants. One option to minimize harmful emissions would be to utilize specifically tailored, low emission synthetic fuels or fuel blends in internal combustion engines. Methyl formate and dimethyl carbonate are two promising candidates to replace or substitute gasoline, which in previous studies have proven to significantly decrease harmful pollutants.

An early-design methodology for predicting both expected fuel economy and catalyst-out CO, HC and NOx concentrations during arbitrarily-defined transient cycles is presented. The methodology is based on utilizing a vehicle-powertrain model with embedded maps of fully warmed up engine-out performance and emissions, and appropriate temperature-dependent correction factors to account for not fully warmed up conditions during transients. Similarly, engine-out emissions are converted to catalyst-out emissions using conversion efficiencies based on the catalyst brick temperature. A crucial element of the methodology is hence the ability to predict heat flows and component temperatures in the engine and the exhaust system during transients, consistent with the data available during concept definition and early design phases.

Stringent fuel economy and emissions regulations have driven development of new mixture preparation technologies and increased spark-ignition engine complexity. Additional degrees of freedom, brought about by devices such as cam phasers and charge motion control valves, enable greater range and flexibility in engine control. This permits significant gains in fuel efficiency and emission control, but creates challenges related to proper engine control and calibration techniques. Accurate experimental characterization of high degree of freedom engines is essential for addressing the controls challenge. In particular, this paper focuses on the evaluation of three experimental residual gas fraction measurement techniques for use in a spark ignition engine equipped with dual-independent variable camshaft phasing (VVT).

We have developed a methodology for analysis of Premixed Charge Compression Ignition (PCCI) engines that applies to conditions in which there is some stratification in the air-fuel distribution inside the cylinder at the time of combustion. The analysis methodology consists of two stages: first, a fluid mechanics code is used to determine temperature and equivalence ratio distributions as a function of crank angle, assuming motored conditions. The distribution information is then used for grouping the mass in the cylinder into a two-dimensional (temperature-equivalence ratio) array of zones. The zone information is then handed on to a detailed chemical kinetics model that calculates combustion, emissions and engine efficiency information. The methodology applies to situations where chemistry and fluid mechanics are weakly linked.

Five small two-stroke engine designs were tested at different air/fuel ratios, under steady state and transient cycles. The effects of combustion chamber design, carburetor design, lean burning, and fuel composition on performance, hydrocarbon and carbon monoxide emissions were studied. All tested engines had been designed to run richer than stoichiometric in order to obtain satisfactory cooling and higher power. While hydrocarbon and carbon monoxide emissions could be greatly reduced with lean burning, engine durability would be worsened. However, it was shown that the use of a catalytic converter with acceptably lean combustion was an effective method of reducing emissions. Replacing carburetion with in-cylinder fuel injection in one of the engines resulted in a significant reduction of hydrocarbon and carbon monoxide emissions.

For compliance with legislative regulations as well as restricted resources of fossil fuel, it is essential to further reduce engine-out emissions and increase engine efficiency. As a result of lower peak temperatures and increased homogeneity, premixed Low-Temperature Combustion (LTC) has the potential to simultaneously reduce nitrogen oxides (BSNOx) and soot. However, LTC can lead to higher emissions of unburnt total hydrocarbons (BSTHC) and carbon monoxide (BSCO). Furthermore, losses in efficiency are often observed, due to early combustion phasing (CA50) before top dead center (bTDC). Various studies have shown possibilities to counteract these drawbacks, such as split-injection strategies or different nozzle geometries. In this work, the combination of both is investigated. Three different nozzle geometries with included spray angles of 100°, 120°, and 148° and four injection strategies are applied to investigate the engine performance.

Especially for internal combustion engine simulations, various combustion models rely on the laminar burning velocity. With respect to computational time needed for CFD, the calculation of laminar burning velocities using a detailed chemical mechanism can be replaced by incorporation of approximation formulas, based on rate-ratio asymptotics. This study revisits an existing analytical approximation formula [1]. It investigates applicable temperature, pressure, and equivalence ratio ranges with special focus on engine combustion conditions. The fuel chosen here is methane and mixtures are composed of methane and air. The model performance to calculate the laminar burning velocity are compared with calculated laminar burning velocities using existing state of the art detailed chemical mechanisms, the GRI Mech 3.0 [2], the ITV RWTH [3], and the Aramco mechanism [4].

Homogeneous charge compression ignition (HCCI) has received much attention in recent years due to its ability to reduce both fuel consumption and NO emissions compared to normal spark-ignited (SI) combustion. However, due to the limited operating range of HCCI, production feasible engines will need to employ a combination of combustion strategies, such as stoichiometric SI combustion at high loads and leaner burn spark-assisted compression ignition (SACI) and HCCI at intermediate and low loads. The goal of this study was to extend the high load limit of HCCI into the SACI region while maintaining a stoichiometric equivalence ratio. Experiments were conducted on a single-cylinder research engine with fully flexible valve actuation. In-cylinder pressure rise rates and combustion stability were controlled using cooled external EGR, spark assist, and negative valve overlap. Several engine loads within the SACI regime were investigated.

Direct injection (DI) compressed natural gas (CNG) engines are emerging as a promising technology for highly efficient and low-emission engines. However, the design of DI systems for compressible gas is challenging due to supersonic flows and the occurrence of shocks. An outwardly opening poppet-type valve design is widely used for DI-CNG. The formation of a hollow cone gas jet resulting from this configuration, its subsequent collapse, and mixing is challenging to characterize using experimental methods. Therefore, numerical simulations can be helpful to understand the process and later to develop models for engine simulations. In this article, the results of high-fidelity large-eddy simulation (LES) of a stand-alone injector are discussed to understand the evolution of the hollow cone gas jet better.

Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Homogenous Charge Compression Ignition (HCCI) engines offer a good potential for achieving high fuel efficiency while virtually eliminating NOx and soot emissions from the exhaust. However, realizing the full fuel economy potential at the vehicle level depends on the size of the HCCI operating range. The usable HCCI range is determined by the knock limit on the upper end and the misfire limit at the lower end. Previously proven high sensitivity of the HCCI process to thermal conditions leads to a hypothesis that combustion chamber deposits (CCD) could directly affect HCCI combustion, and that insight about this effect can be helpful in expanding the low-load limit. A combustion chamber conditioning process was carried out in a single-cylinder gasoline-fueled engine with exhaust re-breathing to study CCD formation rates and their effect on combustion. Burn rates accelerated significantly over the forty hours of running under typical HCCI operating conditions.