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Journal Article

100 Years of Corrosion Testing—Is It Time to Move beyond the ASTM D130? The Wire Corrosion and Conductive Deposit Tests

2023-09-22
Abstract The ASTM D130 was first issued in 1922 as a tentative standard for the detection of corrosive sulfur in gasoline. A clean copper strip was immersed in a sample of gasoline for three hours at 50°C with any corrosion or discoloration taken to indicate the presence of corrosive sulfur. Since that time, the method has undergone many revisions and has been applied to many petroleum products. Today, the ASTM D130 standard is the leading method used to determine the corrosiveness of various fuels, lubricants, and other hydrocarbon-based solutions to copper. The end-of-test strips are ranked using the ASTM Copper Strip Corrosion Standard Adjunct, a colored reproduction of copper strips characteristic of various degrees of sulfur-induced tarnish and corrosion, first introduced in 1954. This pragmatic approach to assessing potential corrosion concerns with copper hardware has served various industries well for a century.
Technical Paper

19-Color H2O Absorption Spectrometer Applied for Real-Time In-Cylinder Gas Thermometry in an HCCI Engine

2007-04-16
2007-01-0188
1 An all fiber-optic sensor has been developed to measure H2O mole fraction and gas temperature in an HCCI engine. This absorption-spectroscopy-based sensor utilizes a broad wavelength (1320 to 1380 nm) source (supercontinua generated by a microchip laser) and a series of fiber Bragg gratings (19 gratings centered on unique water absorption peaks) to track the formation and temperature of combustion water vapor. The spectral coverage of the system promises improved measurement accuracy over two-line diode-laser based systems. Meanwhile, the simplicity of the fiber Bragg grating chromatic dispersion approach significantly reduces the data reduction time and cost relative to previous supercontinuum-based sensors. The data provided by the system is expected to enhance studies of the chemical kinetics which govern HCCI ignition as well as HCCI modeling efforts.
Technical Paper

1985 Body Corrosion Field Survey - 5 and 6 Year Old Vehicles

1986-12-08
862025
The Body Division of the Automotive Corrosion and Prevention Committee of SAE (ACAP) concluded that an automotive body corrosion survey for public consumption was needed. The committee proceeded to develop a survey methodology and conducted an initial survey in the Detroit area. Similar surveys can be conducted at regular biyearly intervals for comparison to track the results of industry wide improvements in corrosion protection. Over two hundred 1980 and 1981 model year vehicles were surveyed covering a wide range of domestic models and some foreign models. Twenty six panel or partial panel categories were developed and evaluated for a closed car parking lot survey. Each panel was checked for perforation, blistering and surface rust.
Technical Paper

1D Fluid Dynamic Modeling of Unsteady Reacting Flows in the Exhaust System with Catalytic Converter for S.I. Engines

2000-03-06
2000-01-0210
This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.
Technical Paper

1D Model of a Copper Exchanged Small Pore Zeolite Catalyst Based on Transient SCR Protocol

2013-04-08
2013-01-1578
Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.
Technical Paper

1D Unsteady Flows with Chemical Reactions in the Exhaust Duct-System of S.I. Engines: Predictions and Experiments

2001-03-05
2001-01-0939
This paper describes some recent advances of the research work concerning the 1D fluid dynamic modeling of unsteady reacting flows in s.i. engine pipe-systems, including pre-catalysts and main catalysts. The numerical model GASDYN developed in previous work has been further enhanced to enable the simulation of the catalyst. The main chemical reactions occurring in the wash-coat have been accounted in the model, considering the mass transfer between gas and solid phase. The oxidation of CO, C3H6, C3H8, H2 and reduction of NO, the steam-reforming reactions of C3H6, C3H8, the water-gas shift reaction of CO have been considered. Moreover, an oxygen-storage sub-model has been introduced, to account for the behavior of Cerium oxides. A detailed thermal model of the converter takes into account the heat released by the exothermic reactions as a source term in the heat transfer equations. The influence of the insulating mat is accounted.
Technical Paper

2005 Fuel Cell Vehicle and its Magnesium Power Distribution Unit

2005-04-11
2005-01-0339
The High Voltage Power Distribution Unit (PDU) is constructed of magnesium in support of Fuel Cell Electric Vehicle (FCEV) weight reduction efforts. The PDU distributes and controls a nominal 75 kilowatts of power generated by the Fuel Cell, the primary source of High Voltage power, to all the vehicle loads and accessories. The constraints imposed on the design of the PDU resulted in a component highly susceptible to general and galvanic corrosion. Corrosion abatement was the focus of the PDU redesign. This paper describes the redesign efforts undertaken by Ford personnel to improve the part robustness and corrosion resistance.
Technical Paper

2006 Corvette Z06 Carbon Fiber Fender- Engineering, Design, and Material Selection Considerations

2005-04-11
2005-01-0468
General Motor's Corvette product engineering was given the challenge to find mass reduction opportunities on the painted body panels of the C6 Z06 through the utilization of carbon fiber reinforced composites (CFRC). The successful implementation of a carbon fiber hood on the 2004 C5 Commemorative Edition Z06 Corvette was the springboard for Corvette Team's appetite for a more extensive application of CFRC on the C6 Z06 model. Fenders were identified as the best application for the technology given their location on the front of the vehicle and the amount of mass saved. The C6 Z06 CFRC fenders provide 6kg reduction of vehicle mass as compared to the smaller RRIM fenders used on the Coupe and Convertible models.
Technical Paper

2006 Corvette Z06 Carbon Fiber Structural Composite Panels- Design, Manufacturing and Material Development Considerations

2005-04-11
2005-01-0469
The General Motors Corvette Product Engineering Team is in a continual search for mass-reduction technologies which provide performance improvements that are affordable and add value for their customers. The structural composite panels of the C6 Z06 provided a unique opportunity to extend the use of carbon fiber reinforced materials to reduce mass and enhance performance. The entire vehicle set of composite panels was reviewed as candidates for material substitution, with the selection criteria based on the cost per kg of mass saved, tooling cost required, and the location of the mass to be saved. Priority was extended to mass savings at the front of the vehicle. After a carefully balanced selection process, two components, both requiring redesign because of the Z06’s wider stance, met the criteria: the Front Wheelhouse Outer Panel and Floor Panels. The current Floor Panels, first used on the C5, are large and are a balsawood-cored glass fiber reinforced composite design.
Technical Paper

2013 SRT Viper Carbon Fiber X-Brace

2013-04-08
2013-01-1775
The 2013 SRT Viper Carbon Fiber X-Brace, styled by Chrysler's Product Design Office (PDO), is as much of a work of art as it is an engineered structural component. Presented in this paper is the design evolution, development and performance refinement of the composite X-Brace (shown in Figure 1). The single-piece, all Carbon Fiber Reinforced Plastic (CFRP) X-Brace, an important structural component of the body system, was developed from lightweight carbon fiber material to maximize weight reduction and meet performance targets. The development process was driven extensively by virtual engineering, which applied CAE analysis and results to drive the design and improve the design efficiency. Topology optimization and section optimization were used to generate the initial design's shape, form and profile, while respecting the package requirements of the engine compartment.
Technical Paper

2022-Global Kinetic Modeling of a Commercial DOC Based on a Reduced Synthetic Gas Bench Protocol

2022-03-29
2022-01-0558
Various techniques are constantly being devised to accelerate model generation leading to shorter product development cycle. This work proposes and implements a reduced synthetic gas bench (SGB) test protocol for a commercial Pt-Pd diesel oxidation catalyst (DOC) that can be used to develop global reaction kinetics. The kinetics thus developed were implemented in a 1D model to predict DOC emissions accurately over a wide operating window. Hydrocarbons (HCs) in the exhaust were categorized as Propylene (C3H6) representing partially oxidized hydrocarbons and n-Decane (C10H22) representing unburnt fuel. Test protocols were defined using the order of inhibition of the various species present in the exhaust, namely, CO, NOx (NO+NO2) and HC for the specific reaction under consideration. The oxidation reactions for CO and HCs were found to be inhibited competitively by CO and HCs; both the NOx species inhibited these reactions to the same extent.
Standard

265°F Vacuum Cure, Epoxy Prepregs

2017-11-08
WIP
AMS6566
The purpose of this specification is to allow procurement of a defined material corresponding to statistically derived material properties published in CMH-17. This material is intended for use in laminate applications with a service temperature up to 180 °F. They are typically used in structural applications requiring high strength and stiffness. This is the base specification and it will have one slash/detail specs.
Standard

265°F Vacuum Cure, Epoxy Prepregs Type 42, Class 2, Grade 193, Style 12K-193-SFP-OSI

2017-11-10
WIP
AMS6566/1
The purpose of this specification is to allow procurement of a defined material corresponding to statistically derived material properties published in CMH-17. This material is intended for use in laminate applications with a service temperature up to 180 °F. They are typically used in structural applications requiring high strength and stiffness. This is the base specification and it will have one slash/detail specs.
Standard

265°F, Autoclave Vacuum Bag Cure, Epoxy Prepreg, Type 33, Class 1, Grade 148, Intermediate Modulus Carbon Fiber

2017-11-10
WIP
AMS6568/1
The purpose of this specification is to allow procurement of a defined material corresponding to statistically derived material properties published in CMH-17. This material is intended for use in laminate applications with a service temperature up to 180 °F. They are typically used in structural applications requiring high strength and stiffness. This is the base specification and it will have three slash/detail specs.
Standard

265°F, Autoclave Vacuum Bag Cure, Epoxy Prepreg, Type 40, Class 2, Grade 195, Style 3K-PW, Standard Modulus Carbon Fiber

2017-11-10
WIP
AMS6568/2
The purpose of this specification is to allow procurement of a defined material corresponding to statistically derived material properties published in CMH-17. This material is intended for use in laminate applications with a service temperature up to 180 °F. They are typically used in structural applications requiring high strength and stiffness.
Standard

265°F, Autoclave Vacuum Bag Cure, Epoxy Prepregs

2017-11-08
WIP
AMS6568
The purpose of this specification is to allow procurement of a defined material corresponding to statistically derived material properties published in CMH-17. This material is intended for use in laminate applications with a service temperature up to 180 °F. They are typically used in structural applications requiring high strength and stiffness. This is the base specification and it will have three slash/detail specs.
Standard

350 °F Autoclave Cure, Low Flow Toughened Epoxy Prepregs

2015-12-02
CURRENT
AMS3961
The intent of this specification is for the procurement of the material listed on the QPL and, therefore, no qualification or equivalency threshold values are provided. Users that intend to conduct a new material qualification or equivalency program shall refer to the Quality Assurance section of this base specification, AMS3961. All material qualification and equivalency data has been archived and is available for review upon request. Contact the CMH-17 Secretariat (www.cmh17.org) for additional information.
Standard

350 °F Autoclave Cure, Low Flow Toughened Epoxy Prepregs

2019-03-12
WIP
AMS3961A
The intent of this specification is for the procurement of the material listed on the QPL and, therefore, no qualification or equivalency threshold values are provided. Users that intend to conduct a new material qualification or equivalency program shall refer to the Quality Assurance section of this base specification, AMS3961. All material qualification and equivalency data has been archived and is available for review upon request. Contact the CMH-17 Secretariat (www.cmh17.org) for additional information.
Standard

350 °F Autoclave Cure, Low Flow Toughened Epoxy Prepregs, Type 35, Class 1, Grade 190, Fiber 1

2019-03-12
WIP
AMS3961/3A
The intent of this specification is for the procurement of the material listed on the QPL and, therefore, no qualification or equivalency threshold values are provided. Users that intend to conduct a new material qualification or equivalency program shall refer to the Quality Assurance section of the base specification, AMS3961. All material qualification and equivalency data has been archived and is available for review upon request. Contact the CMH-17 Secretariat (www.cmh17.org) for additional information.
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