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Effective 1st April 2023, India's automotive emissions regulation has shifted from BS-VI Stage-1 to BS-VI Stage-2 standard the after-treatment systems need to demonstrate robust performance not just on the cycle, but also to demonstrate emissions for on-road Real Driving Emission (RDE) conditions. A stringent On-Board Diagnostics (OBD) strategy to monitor the real-time emission levels along with compliance Road Driving Emissions (RDEs) are focus areas for BS VI Stage-2 emission legislation. The maximum speed on MIDC is 90km/h in BS-VI Stage-1, Diesel Oxidation Catalyst (DOC)+Selective Catalyst Reduction Filter (SCRF®) was able to meet legislation at the lab, and now with the RDE cycle max speed of the vehicles under the M1 category <3.5 T will have the max permitted legal limit shall surpass 100 km/h for not around 3% of the span in the third phase of driving cycle for which max speed is up to 120 km/h.

This paper describes the after-treatment technology that could be used to meet a future BS-VII standard, considering close-coupled SCR (cc-SCR) to help start NOx conversion earlier. Both active (Cu/Fe-SCR based) and passive (V-SCR based) systems have the potential to meet emission limits. V-SCR may be considered in the rear position because V-SCR shows a fast response with very low N2O formation. Next-gen V-SCR technology shows significantly improved performance and durability closer to Cu-SCR. The steady-state NOx conversions over Next-Gen V-SCR were better than BS-VI V-SCR in both fresh and aged-580°C/100h conditions. High durability was also observed after engine aging of 1000h (WHTC + high load). Another big challenge in BS VII could be the PN10 requirement. With enhanced filtration coating (EFC) technology, PN emissions drop drastically in comparison to Euro VI reference without EFC to meet a future BS VII.

The New York State Department of Environmental Conservation (DEC) and Environment Canada have jointly participated along with partners the New York City Metropolitan Transit Agency (MTA); Johnson Matthey, Environmental Catalysts & Technologies; Equilon Enterprises, LLC and Corning, Inc. in a project to evaluate the effect of various combinations of fuels and aftertreatment configurations on diesel emissions. Emissions measurements were performed during engine dynamometer testing of an International DT 466E heavy-duty diesel engine. Fuels tested in the study were Diesel Fuel 1 and 2, low sulfur diesel (150 ppm), two ultralow sulfur fuels (<30 ppm), Fischer-Tropsch, Biodiesel, PuriNOx™ and two Ethanol-Diesel blends. Configurations tested were: engine out, and diesel oxidation catalyst, continuously regenerating diesel filter, and exhaust gas recirculation aftertreatment. In general, the use of more aggressive aftertreatment (ie.

It has been shown within the catalyst industry that the emission performance with higher cell density technology and therefore with higher specific geometric area is improved. The focus of this study was to compare the overall performance of high cell density catalysts, up to 1600cpsi, using a MY 2001 production vehicle with a 4.7ltr.V8 engine. The substrates were configured to be on the edge of the design capability. The goal was to develop cost optimized systems with similar emission and back pressure performance, which meet physical and production requirements. This paper will present the results of a preliminary computer simulation study and the final emission testing of a production vehicle. For the pre-evaluation a numerical simulation model was used to compare the light-off performance of different substrate designs in the cold start portion of the FTP test cycle.

Future emissions regulations proposed for the Asian automotive industry (BS VI regulations for India and NS VI regulations for China) are strict and similar to EU VI regulations. As a result, they will require both advanced NOx control as well as advanced Particulate Matter (PM) control. This will drive implementation of full Catalyzed Diesel Particulate Filter (cDPF) and simultaneous NOx control using Selective Catalytic Reduction (SCR) technologies. In this work, we present the performance of various Diesel Oxidation Catalyst (DOC), cDPF, SCR and Ammonia slip catalyst (ASC) systems utilizing the World Harmonized Transient Cycle (WHTC). Aftertreatment Systems (ATS) required for both active and passive filter regeneration applications will be discussed. The sensitivity of key design parameters like catalyst technology, PGM loading, catalyst sizing to meet the regulation limits has been investigated.

For diesel emission control technologies, reduction efficiencies of Particulate Matter (PM) control systems have been traditionally reported based on mass-based criteria. However, particle number-based criteria are now receiving increased attention. In this paper, results of real-time particle size distribution and number based evaluation of the effectiveness of multiple PM control technologies are reported on an HDD engine. An Engine Exhaust Particle Sizer (EEPS) was used for comparative analysis. The technologies that were evaluated included diesel oxidation catalysts (DOC), a DOC with an uncatalyzed wall-flow filter as a continuously regenerating diesel particulate filter (CR-DPF) system, a DOC with a catalytically coated wall-flow filter as a catalyzed CR-DPF (CCR-DPF), and a DOC with a partial filter as a continuously regenerating partial filter (CR-PF).

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

The retrofitting of diesel engines with oxidation catalyst and particulate filter technology for the reduction of particulate matter (PM), hydrocarbons (HC) and carbon monoxide (CO) emissions has become an established practice. The design and performance of such systems have been commercially proven to the point that the application of these technologies is a cost effective means for states to effectively meet pollution reduction goals. One of the reasons that these technologies are so widely applied is because they can be sized and fitted based on easily measurable vehicle parameters and published engine emission information. These devices generally work passively with basic temperature and back pressure monitoring devices being used to alert the operator to upset conditions. The application of an effective NOx reduction technology in similar retrofit installation, is more complicated. There are no passive NOx reduction technologies that can be retrofit onto HDD vehicles.

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. Typical 2013 Heavy Duty Diesel emission control systems include a DOC upstream of a catalyzed soot filter (CSF) which is followed by urea injection and the SCR sub-assembly. There is a strong desire to further increase the NOx conversion capability of such systems, which would enable additional fuel economy savings by allowing engines to be calibrated to higher engine-out NOx levels. One potential approach is to replace the CSF with a diesel particulate filter coated with SCR catalysts (SCRF® technology, hereafter referred to as SCR-DPF) while keeping the flow-through SCR elements downstream, which essentially increases the SCR volume in the after-treatment assembly without affecting the overall packaging.

Selective Catalytic Reduction (SCR) systems have been demonstrated as effective solutions for controlling NOx emissions from Heavy Duty diesel engines. Future HD diesel engines are being designed for higher engine out NOx to improve fuel economy, while discussions are in progress for tightening NOx emissions from HD engines post 2020. This will require increasingly higher NOx conversions across the emission control system and will challenge the current aftertreatment designs. Typical 2010/2013 Heavy Duty systems include a diesel oxidation catalyst (DOC) along with a catalyzed diesel particulate filter (CDPF) in addition to the SCR sub-assembly. For future aftertreatment designs, advanced technologies such as cold start concept (dCSC™) catalyst, SCR coated on filter (SCRF® hereafter referred to as SCR-DPF) and SCR coated on high porous flow through substrates can be utilized to achieve high NOx conversions, in combination with improved control strategies.

Selective Catalytic Reduction (SCR) systems have been demonstrated as effective solutions for controlling NOx emissions from Heavy Duty diesel engines. Future HD diesel engines are being designed for higher engine out NOx to improve fuel economy, which will require increasingly higher NOx conversion to meet emission regulations. For future aftertreatment designs, advanced technologies such as SCR coated on filter (SCRF®) and SCR coated on high porous flow through substrates can be utilized to achieve high NOx conversion. In this work, different options were evaluated for achieving high NOx conversion. First, high performance NOx control catalysts were designed by using SCRF unit followed by additional SCR on high porosity substrates. Second, different control strategies were evaluated to understand the effect of reductant dosing strategy and thermal management on NOx conversion. Tests were carried out on a HD engine under transient test cycles.

The EPA implemented the Urban Bus Retrofit/Rebuild (UBRR) Program for transit buses built before 1994 in an effort to lower the amount of PM emissions in densely populated urban areas. The objective of the program is to provide certified emission control technologies that reduce PM emissions from older buses by 25% or to below 0.1 g/bhp-hr. This paper reviews the development of a retrofit kit that has been certified under the UBRR program to meet the 0.1 g/bhp-hr PM emission requirements on DDC 6V92TA engines with both mechanical (MUI) and electronic (DDEC) fuel injection controls. The kit is a combination of specific and modified engine parts and a catalytic exhaust after-treatment device. The kit replaces existing parts with a new camshaft, a uniquely configured cylinder kit and specified turbocharger, blower and injector. For the MUI engines the cam timing, injector height and fuel modulator are set at specific values to achieve the lowest possible PM level.

Diesel oxidation catalyst and particulate filter technologies are well established and their applications are well known. However, there are certain limitations with both technologies due to their inherent technical characteristics. Both technologies get 75-90% reduction of HC and CO. A typical oxidation catalyst can be applied to almost any heavy duty diesel application and achieve 20 to 30% reduction in PM mass but no significant reduction in the number of PM particles. On the other hand, diesel particulate filters are very effective at removing >90% of the particles by mass and >99% by number. Unfortunately, passive DPF technology cannot be applied to all applications since the filter regeneration is limited by engine out NOx to PM ratio as well as exhaust temperature. For this reason, particulate filters can not universally be applied to older “dirtier” engines with high PM emissions.

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. Typical 2010 Heavy-Duty systems include a DOC along with a catalyzed soot filter (CSF) in addition to the SCR sub-assembly. There is a strong desire to further increase the NOx conversion capability of such systems, to enable additional fuel economy savings by allowing engines to be calibrated to higher engine-out NOx levels. One potential approach is to replace the CSF with a diesel particulate filter coated with SCR catalysts (SCR-DPF) while keeping the flow-through SCR elements downstream, which essentially increases the SCR volume in the after-treatment assembly without affecting the overall packaging. In this work, a system consisting of SCR-DPF was evaluated in comparison to the DOC + CSF components from a commercial 2010 DOC + CSF + SCR system on an engine with the engine EGR on (standard engine-out NOx) and off (high engine-out NOx).

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. There is a drive to reduce the overall packaging volume of the aftertreatment system for these applications. In addition, more active SCR catalysts will be needed as the applications become more challenging: e.g. lower temperatures and higher engine out NOx, for fuel consumption improvements. One approach to meet the challenges of reduced volume and/or higher NOx reduction is to increase the active site density of the SCR catalyst by coating higher amount of SCR catalyst on high porosity substrates (HPS). This approach could enable the reduction of the overall packaging volume while maintaining similar NOx conversion as compared to 2010/2013 systems, or improve the NOx reduction performance for equivalent volume and NH3 slip.

Diesel Particulate Filters (DPFs) such as the Continuously Regenerating Technology (CRT®) particulate filters are known to be highly effective in reducing PM emissions from diesel engines. Passive DPFs such as the CRT filter operate by collecting soot in the filter and subsequently oxidizing this soot in the presence of NO2 generated by an upstream Diesel Oxidation Catalyst (DOC). Both the NO2 generation and subsequent soot oxidation reactions require a certain minimum exhaust temperature. In addition, the engine out NOx to PM ratio is also critical for continuous and successful regeneration of the filter. However, these criteria may not always be met, particularly on low temperature applications such as refuse vehicles and newer low NOx (2.5 g/bhp-hr NOx) engines. This paper discusses the development of an actively regenerating diesel particulate filter (ACR-DPF) system for retrofit applications on heavy duty diesel vehicles.

The study presented in this paper focuses on measures to minimize exhaust gas emissions to meet SULEV targets on a V6 engine by using a cost efficient system configuration. The study consists of three parts. A) In the first stage, the influence of engine management both on raw emissions and catalyst light off performance was optimized. B) Afterwards, the predefined high cell density catalyst system was tested on an engine test bench. In this stage, thermal data and engine out emissions were used for modeling and prediction of light-off performance for further optimized catalyst concepts. C) In the final stage of the program, the emission performance of the test matrix, including high cell density as well as multifunctional single substrate systems, are studied during the FTP cycle. The presented results show the approach to achieve SULEV emission compliance with innovative engine control strategies in combination with a cost effective metallic catalyst design.

Diesel engine emission regulations throughout the world have progressed over the last 20 years. In the U.S. the most stringent medium/heavy duty standard will be implemented for on highway vehicles starting in 2010. Although changes to engine design will improve engine out emissions, in order to meet both PM and NOx regulations, combination systems including PM and NOx aftertreatment, are planned to be utilized. In order to achieve the required regulations, a new substrate technology has been developed using advanced “turbulent” flow characteristics, and it has been combined with a novel approach to reduce system complexity: the “SCRi™” or “SCR integrated” system. Such a system uses a continuously operating PM-Metalit with advanced “turbulent” SCR-catalysts in a unique configuration. The reduction of both PM and NOx also has to be seen in context with its effect on CO2 emissions.

The modern Diesel engine is one of the most versatile power sources available for mobile applications. The high fuel economy and torque of the Diesel engine has long resulted in global application for heavy-duty applications. Moreover, the high power and excellent driveability of today's turbo-charged small high-speed Diesel engines, coupled with their low CO2 emissions, has resulted in an increasing demand for Diesel powered light-duty vehicles. However, the demand for Diesel vehicles can only be realised if their exhaust emissions meet the increasingly stringent emissions legislation being introduced around the world. In the USA, both HDD and LDD vehicles are meeting strict emissions legislations since 2007 with the introduction of particle filters which will be further restricted from 2010 with the use of additional NOx contr5ol systems. In Europe, similar strict requirements are being implemented with Euro IV, Euro V and finally through Euro VI legislations.

Particulate emission from diesel engines is one of the most important pollutants in urban areas. With increasing worldwide regulatory requirements to lower particulate matter (PM) standards for heavy duty diesel powered vehicles, the interest in diesel particulate filter based emission control solutions such as the Continuously Regenerating Technology (CRT®) have significantly increased. This system has been applied to thousands of heavy-duty diesel vehicles in Europe over the last six years to meet various local and governmental requirements, while recently introduced in the US. Among the numerous demonstration programs taking place in the US, one important one is the evaluation of CRT filter systems on urban transit buses in NY City. Here, several NY City transit buses with DDC Series 50 engines have been equipped with CRT filters and operating on ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000.