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A comprehensive study is carried out in order to better understand combustion behavior in a direct injection Diesel engine working under multiple injection strategies, in particular when using post-injections. The aim of the study is to provide criteria to more easily define optimized injection strategies. During the study two main phenomena have been observed and characterized: an acceleration of the final stage of combustion and an apparent disconnection between the combustions of the two pulses (“split flame”). Thanks to the combustion acceleration phenomenon, if the post-injection is placed near enough the main injection, the end of combustion can take place even earlier compared to the case with a single main injection. In such conditions NOx emissions increase (most likely due to a higher temperature level during the last stage of combustion), but soot and specific fuel consumption decrease (due to a faster last phase of combustion).

Fuel film deposits on combustion chamber walls are understood to be the main source of particle emissions in GDI engines under homogenous charge operation. More precisely, the liquid film that remains on the injector tip after the end of injection is a fuel rich zone that undergoes pyrolysis reactions leading to the formation of poly-aromatic hydrocarbons (PAH) known to be the precursors of soot. The physical phenomena accompanying the fuel film deposit, evaporation, and the chemical reactions associated to the injector film are not yet fully understood and require high fidelity CFD simulations and controlled experimental campaigns in optically accessible engines. To this end, a simplified model based on physical principles is developed in this work, which couples an analytical model for liquid film formation and evaporation on the injector tip with a stochastic particle dynamics model for particle formation.

Soot radiation has an important contribution to the overall heat losses in a combustion chamber of a DI diesel engine. The aim of this study was to develop a soot radiation model coupled to a soot formation/oxidation sub-model, which is also described in the paper. On the one hand, the soot radiation model is based on the available knowledge of the radiation of a soot cloud commonly used to apply the two-color method to diesel sprays. On the other hand, it was tuned and validated with experimental data: the optical thickness, KL, obtained from the laser extinction method, and the radiation intensity at two different wavelengths. Once the model was validated, the overall radiated power was calculated taking into account the radiation absorption caused by the spray itself. This power was compared to the one released by the spray combustion process, and the results were in agreement with other studies available in the literature.

In this paper the effect of the engine load and the EGR (exhaust gas recirculation) rate on the combustion process and the pollutant emissions when using RME (rapeseed methyl-ester) is investigated. For this purpose a parametric study in a single-cylinder HSDI (high speed direct injection) engine in a wide range of operating conditions (thus trying to maximize the generality of the results) has been carried out. All the output parameters are compared with the corresponding ones for a reference diesel fuel at equivalent engine performances and operating conditions. To perform a rigorous comparison, a specific methodology has been designed based on the comparison at equivalent engine load and oxygen mass fraction in the intake manifold, so as to remove the effect of the fuel properties (derived from the different oxygen content, mainly) on the engine performances.

Engine-out soot emissions are the result of a complex balance between in-cylinder soot formation and oxidation. Soot is formed in the diffusion flame, just after the lift-off length (LOL). Size and mass of soot particles increase through the diffusion flame and finally they are partially oxidized at the flame front. Therefore, engine-out soot emissions depend on the amount of soot formed and oxidized inside the combustion chamber. There is a considerable amount of work in the literature on characterization of soot formation. However, there is a clear lack of published research related to the characterization of soot oxidation. Thus, the main objective of the current research is to provide more knowledge and insight into the soot oxidation processes. For this purpose, a combination of theoretical and experimental tools were used. In particular, in-cylinder optical thickness (KL) was quantified with an optoelectronic sensor that uses two-color pyrometry.

The dense spray region in the near-field of diesel fuel injection remains an enigma. This region is difficult to interrogate with light in the visible range and difficult to model due to the rapid interaction between liquid and gas. In particular, modeling strategies that rely on Lagrangian particle tracking of droplets have struggled in this area. To better represent the strong interaction between phases, Eulerian modeling has proven particularly useful. Models built on the concept of surface area density are advantageous where primary and secondary atomization have not yet produced droplets, but rather form more complicated liquid structures. Surface area density, a more general concept than Lagrangian droplets, naturally represents liquid structures, no matter how complex. These surface area density models, however, have not been directly experimentally validated in the past due to the inability of optical methods to elucidate such a quantity.

The aim of this work is to develop a combustion and emissions (NOx and soot) predictive tool that allows rapid parametric explorations of operating conditions and geometric configurations in diesel engines. This paper will present the mixing and combustion models used. All the models are constructed around a spray-mixing model. This mixing model is based on the gaseous steady jets theory. The transient behavior description of the initial and final phases of the injection-combustion process is obtained from CFD studies. The mixing model allows the determination of the instantaneous local conditions of temperature and species mass fraction, used by the ignition, premixed and diffusion combustion models. The ignition and premixed combustion models are based on a simplification and parameterization of a complete n-heptane chemical kinetics description. Some constants of the models are adjusted by a genetic algorithm with experimental information from different engines.

Traditionally the NOx prediction models use to take into account exclusively the NOx formation process. Nowadays diesel engines use to operate with high EGR rates and high fuel/air equivalence ratios, in opposition with what it was standard in the past years. In such conditions a considerable amount of NOx generated in the previous cycle (coming from the recirculated exhaust gases) or in the previous combustion is re-entrained by the flame, where a highly reducing region exists (due to a lack of oxygen and the presence of hydrocarbons and a high temperature level). Face to this fact a question arises: what happens with these re-entrained NOx?

A fundamental study to experimentally analyze the effect of cavitation in common-rail diesel nozzles on the soot formation process was carried out. The soot content was characterized by measuring the soot radiation, and an original methodology was developed to suitably characterize the soot formation process from this soot content. After a significant effort to overcome the different difficulties when analyzing the experimental data, the results seem to show a promising conclusion: cavitation reduces the soot formation rate. This reduction is explained, on the one hand, because it leads to a reduction in the effective diameter, thus diminishing the equivalence fuel/air ratio at the lift-off length; and, on the other hand, because it provokes an increase in effective velocity, thus increasing the lift-off length and reducing the corresponding equivalence fuel/air ratio.

Regulations on emissions from diesel engines are becoming more stringent worldwide. Hence there is a great deal of interest in developing engine combustion systems that offer the fuel efficiency of a diesel engine, but with low smoke and NOx emissions. Thus, premixed compression ignition combustion is an interesting way to achieve a clean and efficient engine. However, using a high reactivity fuel such as diesel fuel leads to a complex and expensive engine design. A proven way to overcome this drawback is to actively control the reactivity of the fuel using low cetane fuels such as gasoline. This strategy has been explored with single and multiple cylinder engines. However no detailed and well conducted studies of the injection process were found related to the effects of gasoline use in a standard commercial compression ignition diesel engine injection system.

The effects of wall interaction on combustion and soot formation processes of a diesel fuel jet were investigated in an optically-accessible constant-volume combustion vessel at experimental conditions typical of a diesel engine. At identical ambient and injector conditions, soot processes were studied in free jets, plane wall jets, and “confined” wall jets (a box-shaped geometry simulating secondary interaction with adjacent walls and jets in an engine). The investigation showed that soot levels are significantly lower in a plane wall jet compared to a free jet. At some operating conditions, sooting free jets become soot-free as plane wall jets. Possible mechanisms to explain the reduced or delayed soot formation upon wall interaction include an increased fuel-air mixing rate and a wall-jet-cooling effect. However, in a confined-jet configuration, there is an opposite trend in soot formation.

A prototype multi-hole diesel injector operating with n-heptane fuel from a high-pressure common rail system is used in a high-pressure and high-temperature test rig capable of reaching 1100 Kelvin and 150 bar under different oxygen concentrations. A novel optical set-up capable of visualizing the soot cloud evolution in the fuel jet from 30 to 85 millimeters from the nozzle exit with the high-speed color diffused back illumination technique is used as a result of the insertion of a high-pressure window in the injector holder opposite to the frontal window of the vessel. The experiments performed in this work used one wavelength provide information about physical of the soot properties, experimental results variating the operational conditions show the reduction of soot formation with an increase in injection pressure, a reduction in ambient temperature, a reduction in oxygen concentration or a reduction in ambient density.

Selective Catalytic Reduction stands for an effective methodology for the reduction of NOx emissions from Diesel engines and meeting current and future EURO standards. For it, the injection of Urea Water Solution (UWS) plays a major role in the process of reducing the NOx emissions. A LES approach for turbulence modelling allows to have a description of the physics which is a very useful tool in situations where experiments cannot be performed. The main objective of this study is to predict characteristics of the flow of interest inside the injector as well as spray morphology in the near field of the spray. For it, the nozzle geometry has been reconstructed from X-Ray tomography data, and an Eulerian-Eulerian approach commonly known as Mixture Model has been applied to study the liquid phase of the UWS with a LES approach for turbulence modeling. The injector unit is subjected to typical low-pressure working conditions.

During the past decades, the Nitrogen Oxides (NOx) emission limitations have become stricter, promoting the development of after-treatment systems like Selective Catalytic Reduction (SCR) for emission reduction purposes. The Urea-Water Solution (UWS) spray characteristics can directly have an effect on the SCR efficiency. To understand the droplet breakup and mixing of the UWS with the surrounding air under different operating conditions, a computational campaign has been set up. The main objective of the present study is to recreate the spray injection process, as well as the chemical processes that the UWS spray undergoes, and to analyze the optimal injection angle to maximize the amount of ammonia generated during the injection process by means of Computational Fluid Dynamics (CFD). A Eulerian-Lagrangian framework has been employed to track the evolution of the injected droplets within a Reynolds-Averaged Navier-Stokes (RANS) turbulence formulation.

Schlieren/shadowgraphy has been adopted in the combustion research as a standard technique for tip penetration analysis of sprays under diesel-like engine conditions. When dealing with schlieren images of reacting sprays, the combustion process and the subsequent light emission from the soot within the flame have revealed both limitations as well as considerations that deserve further investigation. Seeking for answers to such concerns, the current work reports an experimental study with this imaging technique where, besides spatial filtering at the Fourier plane, both short exposure time and chromatic filtering were performed to improve the resulting schlieren image, as well as the reliability of the subsequent tip penetration measurement. The proposed methodology has reduced uncertainties caused by artificial pixel saturation (blooming).

The increasingly stringent antipollution legislation and the necessity of a continuous control of the pollutant emissions lead to the development, among others, of NOx estimation models to be included in the engine control system and the on-board diagnostic system. Two elements are important for a good estimation of these pollutant emissions: the knowledge of the combustion process, which is available via the instantaneous pressure signal, and the flame temperature, which is estimated from the in-cylinder conditions (mainly from the air temperature and oxygen concentration). All these parameters could be nowadays available and even analyzed on the vehicle during normal engine operation. In this paper we intend to assess the NOx estimation sensitivity to inaccuracies in the input parameters to identify the critical parameters in this estimation. The NOx emissions model which has been developed and used for this purpose in the frame of this research is based on the Zeldovich mechanism.

In this work a detailed soot model based on stationary flamelets is used to simulate soot emissions of a reactive Diesel spray. In order to represent soot formation and oxidation processes properly, a calibration of the soot reaction rates has to be performed. This model calibration is usually performed on basis of engine out soot measurements. Contrary to this, in this work the soot model is calibrated on local soot concentrations along the spray axis obtained from laser extinction chamber measurements. The measurements are performed with B7 certification Diesel and a series production multihole injector to obtain engine similar boundary conditions. In order to ensure that the flow and mixture field is captured well by the CFD-simulation, the simulated liquid penetration lengths and flame lift-off lengths are compared to chamber measurements.

The Selective Catalytic Reduction (SCR) system has great potential in reducing NOx emissions. The urea-water solution (UWS) is the preferred method on vehicles for obtaining the ammonia, the required reductant for SCR. The UWS spray is necessary to transform exhaust gas into nitrogen and water and plays an important role in the performance of this system. The UWS needs to be properly mixed with the exhaust gas coming from the engine before entering the SCR, therefore the solution must be injected in the exhaust pipe in a way that it completely vaporizes in order to reduce deposit formation and guaranteeing a proper functioning and durability of the NOx reduction system. Achieving complete vaporization of the UWS spray is not an easy task, mainly due to reduced package space. Another challenge for converting UWS to ammonia is the latent energy in the exhaust.