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A methodology is presented with which aggregate emissions from the in-use automobile population can be calculated for any given calendar year. The data base needed for such a calculation is discussed, and areas in which further research is needed are pointed out. Results of a series of calculations are then presented showing the effect on aggregate emissions of various control strategies. The effects of an inspection/maintenance and retrofit program, different vehicle population growth rates, catalyst deterioration in use, and various schedules of new car emission standards for post-1975 vehicles are presented. It is shown that the rate at which old, higher-polluting vehicles are retired from the in-use vehicle population is the major factor in determining the rate at which aggregate emissions will decrease in the 1970s, with the precise level of post-1975 standards only becoming important in the 1980s.

This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.

Today's diesel PM reduction systems are mainly based on catalyzed particulate filter(CPF) systems. However, most of their reaction kinetics remain unresolved. Among others, the soot oxidation rate over catalyst is particularly important in the evaluation of the performance of the catalysts and the efficient control of CPF regeneration. This study, therefore, investigated the oxidation rate of carbon black (Printex-U) over various Pt supported catalysts using a flow reactor setup simulating diesel exhaust conditions. Compared to non-catalyzed soot oxidation, the oxidation rate of carbon black over Pt catalysts was to an extent shifted towards low temperatures. This activity enhancement of soot oxidation over a catalyst can be attributed principally to NO to NO2 conversion because NO2 oxidizes soot with much lower activation energy (Ea=60kJ/mol) than O2 (Ea=177kJ/mol).

Passenger cars in the United States continue to incorporate increasing levels of technology and features. However, deployment of technology requires substantial development and time in the automotive sector. Prior analyses indicate that deployment of technology in the automotive sector can be described by a logistic function. These analyses refer to maximum annual growth rates as high as 17% and with developmental times of 10-15 years. However, these technologies vary widely in complexity and function, and span decades in their implementation. This work applies regression with a logistic form to a wide variety of automotive features and technologies and, using secondary regression, identifies broader trends across categories and over time.

As part of ongoing research on hydrogen-enhanced lean burn SI engines, this paper details an experimental combustion system optimization program. Experiments focused on three key areas: the ignition system, in-cylinder charge motion produced by changes in the inlet ports, and uniformity of fuel-air mixture preparation. Hydrogen enhancement is obtained with a H2, CO, N2 mixture produced by a fuel reformer such as the plasmatron. The ignition system tests compared a standard inductive coil scheme against high-energy discharge systems. Charge motion experiments focused on the impact of different flow and turbulence patterns generated within the cylinder by restrictor plates at the intake port entrance, as well as novel inlet flow modification cones. The in-cylinder fluid motion generated by each configuration was characterized using swirl and tumble flow benches. Mixture preparation tests compared a standard single-hole pintle port fuel injector against a fine atomizing 12-hole injector.

Diesel engines are the most commonly used power plant of freight and public transportations in the world. Also, the newly developed injection system, Common Rail system, increases the demands for both light and heavy duty diesel vehicles. On the other hand, stringent emission regulations are being proposed with growing concern on NOx and PM emissions from diesel engines. Future emission regulations require advanced emission control technologies, such as EGR and SCR. Exhaust gas recirculation (EGR) is a commonly used technique to reduce NOx emission. In this paper, a model-based investigation was conducted to compare the effect of high pressure loop (HPL) EGR and low pressure loop (LPL) EGR system on NOx level and BSFC of a heavy-duty diesel engine. A WAVE model was created to simulate EURO 3 engine and each component of the engine was modeled using CATIA and WaveMesher.

This paper reviews the major changes that have occurred in spark-ignition engine design and operation over the last two decades. The automobile air pollution problem, automobile emission standards, and automobile fuel economy standards -- the factors which have and are producing these changes -- are briefly described. The major components in spark-ignition engine emission control systems are outlined, and advances in carburetion, fuel injection, ignition systems, spark retard and exhaust gas recycle strategies, and catalytic converters, are reviewed. The impact of these emission controls on vehicle fuel economy is assessed. The potential for fuel economy improvements in conventional spark-ignition engines is examined, and promising developments in improved engine and vehicle matching are outlined.

A computer simulation of the four-stroke spark-ignition engine cycle has been developed for studies of the effects of variations in engine design and operating parameters on engine performance, efficiency and NO emissions. The simulation computes the flows into and out of the engine, calculates the changes in thermodynamic properties and composition of the unburned and burned gas mixtures within the cylinder through the engine cycle due to work, heat and mass transfers, and follows the kinetics of NO formation and decomposition in the burned gas. The combustion process is specified as an input to the program through use of a normalized rate of mass burning profile. From this information, the simulation computes engine power, fuel consumption and NO emissions. Predictions made with the simulation have been compared with data from a single-cylinder CFR engine over a range of equivalence ratios, spark-timings and compression ratios.

In this study, a set of performance and emissions data, obtained from a single-cylinder divided-chamber automotive diesel engine over the normal engine operating range, is described and analyzed. The data are used to evaluate a computer simulation of the engine's operating cycle, described in a companion paper, which predicts the properties of gases inside the engine cylinder throughout the cycle, and engine efficiency, power and NOx emissions. Satisfactory agreement between predictions and measurements is obtained over most of the engine's operating range. The characteristics of the experimental pre- and main-chamber pressure versus crank angle data are then examined in detail. A heat release analysis appropriate for divided-chamber diesel engines is developed and used to obtain heat release rate profiles through the combustion process.

In an effort to both increase engine efficiency and generate new, consistent, and reliable data useful for the development of engine concepts, a modern single-cylinder 4-valve spark-ignition research engine was used to determine the response of indicated engine efficiency to combustion phasing, relative air-fuel ratio, compression ratio, and load. Combustion modeling was then used to help explain the observed trends, and the limitations on achieving higher efficiency. This paper analyzes the logic behind such gains in efficiency and presents correlations of the experimental data. The results are helpful for examining the potential for more efficient engine designs, where high compression ratios can be used under lean or dilute regimes, at a variety of loads.

Dilute operation of a SI engine offers attractive performance incentives. Lowered combustion temperatures and changes in the mixture composition inhibit NOx formation and increase the effective value of the ratio of burned gas specific heats, increasing gross indicated efficiency. Additionally, reduced intake manifold throttling minimizes pumping losses, leading to higher net indicated efficiency. These benefits are offset by the reduced combustion speed of dilute fuel-air mixtures, which can lead to high cycle-to-cycle variation and unacceptable engine behavior characteristics. Hydrogen enhancement can suppress the undesirable consequences of dilute operation by accelerating the combustion process, thereby extending the dilution limit. Hydrogen would be produced on-board the vehicle with a gasoline reforming device such as the plasmatron. High dilution at higher loads would necessitate boosting to meet the appropriate engine specific power requirements.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

The high concentration of particulate matter (PM) in diesel exhaust gas causes significant soot deposition on the wall of EGR cooler, and reduces the heat transfer performance of the EGR cooler and the reduction rate of NOx. The deposition of PM tends to be occurred more severely with "heavy wet PM," which is more frequently at the LTC (low temperature combustion) engine. The objective of this work is to evaluate the effects of soluble organic fraction (SOF) on deposit characteristics of the EGR cooler. To measure reliable mean particle concentration values and surrogate SOFs, the soot generator with SOF vaporizer was used. As for two surrogate SOFs, n-dodecane and diesel lube oil, deposit mass increased when they were injected. Especially from the experiment results, it was found that the lube oil effect was more significant than the n-dodecane effect and lube oil also had a stronger effect on reduction of thermal conductivity by filling pores in deposits.

Plasma-catalyst (Ag, Au/Al2O3) systems were applied to NOx reduction in a model lean-burn engine exhaust gas. Also, DeNOx test of real diesel exhaust gas was performed by plasma-Ag/Al2O3 system. In the case of model exhaust gas, the catalytic activity for NOx reduction was enhanced by the assistance of plasma in the wide temperature range. The NOx conversion efficiency of plasma-Ag/Al2O3 was 40∼90% under the condition of C3 H6 3200ppm (C1/NOx = 5.96) and 10% O2 over the temperature range of 250∼400°C. The plasma-Au/Al2 O3 system showed remarkable low temperature NOx reduction activity at 100∼250°C. The real engine full flow test was performed for 70% of the full load and at engine speed of 1500rpm. NOx removal of 46% from the diesel exhaust gas was achieved by the plasma-Ag/Al2O3 catalyst system at 364°C(C1/NOx = 6). In the case of higher C1/NOx = 10, the NOx conversion increased up to 73% at 381°C. Also, DeNOx engine tests were performed for full load of 1500, 2000 and 2500rpm.

The oxidation of soot (carbon black) which is assisted by Pt/CeO2 catalyst is studied using a flow reactor system simulating the condition of diesel exhaust. In this study, the temperature programmed oxidation (TPO) scheme is mainly used for different NO and O2 concentrations and soot oxidation rate is evaluated by monitoring both CO and CO2 concentrations. Pt/CeO2 catalyst lowers the temperature of the peak CO/CO2 concentrations significantly when there is either NO or O2. Oxidation starts at 200°C and the peak CO2 concentration is observed at 360°C, which depends on the amount of catalyst and NO concentration. The effect of catalyst on NO2 recycling is also investigated. For this purpose, two different types of sample have been prepared. For the mixed case, 10mg of carbon black is mixed with 50mg of Pt/CeO2 catalyst under conditions of loose contact. For the unmixed case, the catalyst layer is placed on top of soot layer without mixing.

Two features to facilitate chemical reactions at low temperature, non-thermal plasma and the weak dependency of photocatalyst on temperature, have been exploited by many researchers to effectively decompose hydrocarbon emissions emitted until the light-off of a three-way catalyst in spark ignition engines. To develop a realizable emissions reduction reactor, as part of such effort, this study investigates for the three model gases, propylene, n-butane and acetylene: 1) the conversion efficiency of the emissions reduction reactor, which utilizes the effect of dissociation, ionization-by-collision of the non-thermal plasma and the photocatalytic effect of TiO2, and 2) the concentrations of the products such as acetaldehyde, acetic acid, polymerized hydrocarbons and NO2. The operating parameters to obtain the plasma energy density ranging from 7.8 to 908 J/L were varied.

This vehicle simulation study estimates the fuel economy benefits of an HCCI engine system and assesses the NOx, HC and CO aftertreatment performance required for compliance with emissions regulations on U.S. and European regulatory driving cycles. The four driving cycles considered are the New European Driving Cycle, EPA City Driving Cycle, EPA Highway Driving Cycle, and US06 Driving Cycle. For each driving cycle, the following influences on vehicle fuel economy were examined: power-to-weight ratio, HCCI combustion mode operating range, driving cycle characteristics, requirements for transitions out of HCCI mode when engine speeds and loads are within the HCCI operating range, fuel consumption and emissions penalties for transitions into and out of HCCI mode, aftertreatment system performance and tailpipe emissions regulations.

HC-SCR is more convenient when compared to urea-SCR, since for HC-SCR, diesel fuel can be used as the reductant which is already available onboard the vehicle. However, the DeNOX efficiency for HC-SCR is lower than that of urea-SCR in both low and high temperature windows. In an attempt to improve the DeNOX efficiency of HC-SCR, the effect of hydrogen were evaluated for the fresh and aged catalyst over 2 wt.% Ag/Al₂O₃ using a Euro-4 diesel engine. In this engine bench test, diesel fuel as the reductant was injected directly into the exhaust gas stream and the hydrogen was supplied from a hydrogen bomb. The engine was operated at 2,500 rpm and BMEP 4 bar. The engine-out NOX was around 180 ppm-200 ppm. H₂/NOX and HC₁/NOX ratios were 5, 10, 20, and 3, 6, 9, respectively. The HC-SCR inlet exhaust gas temperatures were around 215°C, 245°C, and 275°C. The catalyst volumes used in this test were 2.5L and 5L for both fresh and aged catalysts.

Previous research has shown the potential benefits of running an engine with excess air. The challenges of running lean have also been identified, but not all of them have been fundamentally explained. Under high dilution levels, a lean limit is reached where combustion becomes unstable, significantly deteriorating drivability and engine efficiency, thus limiting the full potential of lean combustion. This paper expands the understanding of lean combustion by explaining the fundamentals behind this rapid rise in combustion variability and how this instability can be reduced. A flame entrainment combustion model was used to explain the fundamentals behind the observed combustion behavior in a comprehensive set of lean gasoline and hydrogen-enhanced cylinder pressure data in an SI engine. The data covered a wide range of operating conditions including different compression ratios, loads, types of dilution, fuels including levels of hydrogen enhancement, and levels of turbulence.

A model has been developed which predicts engine-out hydrocarbon (HC) emissions for spark-ignition engines. The model consists of a set of scaling laws that describe the individual processes that contribute to HC emissions. The model inputs are the critical engine design and operating variables. This set of individual process scaling relations was then calibrated using production spark-ignition engine data at a fixed light-load operating point. The data base consisted of engine-out HC emissions from two-valve and four-valve engine designs with variations in spark timing, valve timing, coolant temperature, crevice volume, and EGR, for five different engines. The model was calibrated separately for the three different engines to accommodate differences in engine design details and to determine the relative magnitudes of each of the major sources. A good fit to this database was obtained.