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Exhaust emissions from various kinds of clean diesel fuels were evaluated using a commercial DI diesel engine in comparison with the emissions from a commercial diesel fuel containing 0.05% sulfur. The blending of a light paraffinic fuel to a commercial diesel fuel reduces HC, CO, PM and NOx emissions and a light fuel with aromatics or kerosene reduces PM and NOx but not HC and CO. The PM and NOx emissions from the paraffinic fuel are lower than these from the kerosene, and these emissions are decreased with an increase in the blending ratio of both light fuels to a commercial diesel fuel. Reformulated diesel fuels such as a clean city diesel fuel and fuels with few aromatics reduce PM and NOx emissions more than commercial diesel fuel, and the reduction rate is highly dependent on aromatic content. The effects on emissions of blending soybean methyl ester or tripropylene glycol methyl ether to a commercial diesel fuel were evaluated.

A fundamental understanding of the relationship between chemical composition and combustion quality may provide an improved means of assessing fuel combustion characteristics. As such, a fuel parameter based on the average molecular structure of multi-component fuels, including petroleum-derived fuels and alternative fuels such as bio-fuel, is applied to predict both ignition and anti-knock quality. This parameter is derived from proton nuclear magnetic resonance (1H-NMR) analysis indicating hydrogen type distribution of fuel molecules. The predicted cetane number (PCN) calculated by the equation developed with 1H-NMR in this study shows a good correlation to the cetane number for a wide range of fuels.

DiMethyl Ether (DME) has been known to be an outstanding fuel for combustion in diesel cycle engines for nearly twenty years. DME has a vapour pressure of approximately 0.5MPa at ambient temperature (293K), thus it requires pressurized fuel systems to keep it in liquid state which are similar to those for Liquefied Petroleum Gas (mixtures of propane and butane). The high vapour pressure of DME permits the possibility to optimize the fuel injection characteristic of direct injection diesel engines in order to achieve a fast evaporation and mixing with the charged gas in the combustion chamber, even at moderate fuel injection pressures. To understand the interrelation between the fuel flow inside the nozzle spray holes tests were carried out using 2D optically accessed nozzles coupled with modelling approaches for the fuel flow, cavitation, evaporation and the gas dynamics of 2-phase (liquid and gas) flows.

This paper presents experimental results of the reduction of both particulate and NOx emitted from direct injection diesel engines by a two stage combustion process. The primary combustion is made very rich to reduce NOx and then the particulate is oxidized by strong turbulence generated during the secondary combustion. The rich mixture is formed by low pressure fuel injection and a small cavity combustion chamber configuration. The strong turbulence is generated by a jet of burned gas from an auxiliary chamber installed at the cylinder head. The results showed that NOx was reduced significantly while maintaining fuel consumption and particulate emissions. An investigation was also carried out on the particulate reduction process in the combustion chamber with the turbulence by gas sampling and in-cylinder observation with an optical fiber scope and a high speed camera.

Recently, dimethyl ether (DME) has been attracting much attention as a clean alternative fuel, since the thermal efficiency of DME powered diesel engine is comparable to diesel fuel operation and soot free combustion can be achieved. In this experiment, the effect of ambient pressure on DME spray was investigated with observation of droplet size such as Sauter mean diameter (SMD) by the shadowgraph and image processing method. The higher ambient pressure obstructs the growth of DME spray, therefore faster breakup was occurred, and liquid column was thicker with increasing the ambient pressure. Then engine performances and exhaust emissions characteristics of DME diesel engine were investigated with various compression ratios. The minimum compression ratio for the easy start and stable operation was obtained at compression ratio of about 12.

To date, the DME combustion mechanism has been investigated by in-cylinder gas sampling, numerical calculations and observation of combustion radicals. It has been possible to quantify the emission intensities of in-cylinder combustion using a monochromator, and to observe the emitting species as images by using band-pass filters. However, the complete band images were not observed since the broadband (thermal) intensity may be stronger than band spectra intensities. Emission intensities of DME combustion radicals from a pre-mixed burner flame have been measured using a spectroscope and photomultiplier. Results were compared to other fuels, such as n-butane and methane, then, in this study, to better understand the combustion characteristics of DME, emission intensities near CH bands of an actual DI diesel engine fueled with DME were measured, and band spectra emitted from the engine were defined. Near TDC, emission intensities did not vary with wavelength.

The demands of application of dual-axis chassis dynamometers (4WD-CHDY) have increased recently due to the improvement of performance of 4WD-CHDY and an increase in the number of 4WD vehicles which are difficult to convert to 2WD. However, there are few evaluations of any differences between fuel economy and exhaust emission levels in the case of 2WD-CHDY with conversion from 4WD to 2WD (2WD-mode) and 4WD-CHDY without conversion to 2WD (4WD-mode). Fuel economy and exhaust emission tests of 4WD vehicle equipped with a typical 4WD mechanism were performed to investigate any differences between the case of the 2WD-mode and the 4WD-mode. In these tests, we measured ‘work at wheel’ (wheel-work) using wheel torque meters. A comparison of the 2WD-mode and the 4WD-mode reveals a difference of fuel economy (2WD-mode is 1.5% better than that of 4WD-mode) and wheel-work (2WD-mode is 3.9% less than that of 4WD-mode). However, there are almost no differences of exhaust emission levels.

Computational analysis on the mechanism and control method for DME fueled HCCI type combustion was carried out on the basis of the chemical kinetics. The calculation results were verified experimentally using a single cylinder test engine. Analysis of the results showed that DME oxidation is governed by production/consumption behavior of OH, because DME oxidation is initiated by dehydrogenation with OH radicals. It was also shown that the overall oxidation reaction could be controlled by adding substances which react competitively with OH in the dehydrogenation reactions of DME. Of the substances we tested, formaldehyde was most effective. It was confirmed by engine testing that by adding a small amount of formaldehyde to the DME/air mixture, the heat evolved in the low temperature reactions was reduced and the reaction appearance timing was retarded.

A feasibility study of an LPG DI diesel engine has been carried out to study the effectiveness of two selected cetane enhancing additives: Di-tertiary-butyl peroxide (DTBP) and 2-Ethylhexyl nitrate (EHN). When more than either 5 wt% DTBP or 3.5 wt% 2EHN was added to the base fuel (100 % butane), stable engine operation over a wide range of engine loads was possible (BMEPs of 0.03 to 0.60 MPa). The thermal efficiency of LPG fueled operation was found to be comparable to diesel fuel operation at DTBP levels over 5 wt%. Exhaust emissions measurements showed that NOx and smoke levels can be significantly reduced using the LPG+DTBP fuel blend compared to a light diesel fuel at the same experimental conditions. Correlations were derived for the measured ignition delay, BMEP, and either DTBP concentration or cetane number. When propane was added to a butane base fuel, the ignition delay became longer.

The effect of the fuel properties on diesel exhaust emissions was investigated using a commercial DI diesel and a prototype diesel engine with fuel jet impingement(OSKA--DH). The new type of diesel engine has a unique concept for the mixture formation process and is regarded as a clean diesel engine. Four types of fuels were prepared to investigated the effect of fuel properties such as cetane number, composition, oxygen content in fuel and oxygenate type on exhaust emissions for both of the engines. The decrease in cetane number caused an increase in NOx and a decrease in PM for the DI diesel engine because of the long ignition delay. However, in case of the OSKA-DH engine, a decrease in cetane number seldom caused an increase in PM emission. Although NOx and PM from aromatic fuel were higher than those from paraffinic fuel, the fuel effect for the OSKA-DH engine was smaller than that for the DI diesel engine.

The effect of fuel properties on the performance of a new type of diesel engine with fuel jet impingement was investigated in comparison with the performance of a DI diesel engine. The new engine has a unique mixture formation process, but the details have not been well investigated. Therefore, the combustion processes of the engine was observed with a transparent piston engine and a high-speed camera system. Observations of the combustion process showed that after impingement, the fuel diffused almost symmeterically into the shape of a disk. Ignition usually started near the cavity wall and extented toward the center of the combustion chamber. The flame appeared to extend from the inside cavity radius to the outside cavity radius because of the strong squish flow. The fuel consisted of petroleum derived samples with a wide range of cetane number and viscosity. High cetane number resulted in reduced NOx mass emission from both engines, but an increased amount of smoke was emitted.

In transportation sector, higher engine thermal efficiency is currently required to solve the energy crisis and environmental problems. In spark ignition (SI) engine, lean-burn strategy is the promising approach to improve thermal efficiency and lower emissions. Olefins are the attractive component for gasoline additives, because they are more reactive and have advantage in lean limit extension. However, owing to lower research octane number (RON), it is expected to exhibit the drawback to reducing the anti-knock performance. The experiments were performed using a single-cylinder engine for 6 fuel types including gasoline blends which have difference in RON varying between 90.4 and 100.2. The results showed that adding olefin content to the premium gasoline provided unfavorable effect on auto-ignition as the auto-ignition happened at unburned gas temperature of 808 K which was 52 K lower at excess air of 2.0. Thus, it reduced anti-knock performance.

Diesel engines have to face the prospect of running on heavy and/or low cetane fuels in the future because of the expected changes in base stock and demand. The effect of physical properties and composition of fuels on the ignition delay and cetane rating is examined. The experiments were conducted on fuels having a very wide range of physical properties and C.N., in a CFR engine. The ignition delay is measured under the standard ASTM D-613 procedure and under varying needle opening pressures, and coolant temperatures. The ignition delay of some fuels is found to be dependent on the physical properties and composition of the fuels in addition to the cetane number. The cetane rating according to ASTM-D613 procedure is found to take place under hot engine conditions with a single stage ignition process. At lower compression ratios, a two stage ignition was observed.

The effects of fuel properties on white smoke emission from the latest DI diesel engine were investigated with a new type of white smoke meter. The new smoke meter could distinguish fuel effects on smoke much more than the conventional PHS meter. The repeatability of the smoke meter was better than that of the PHS meter. Cetane number was the dominant factor for smoke emission. Distillation temperature and composition also affected emission. A nitrate type cetane improver was effective for reducing emission. White smoke was analyzed with GC and HPLC and compounds in white smoke from low cetane number fuel were found almost the same as in fuel. But those from high cetane number fuel consisted of compounds in fuel and many combustion products.

Under hot transient conditions, the effects of gasoline properties, such as the research octane number (RON), the motor octane number (MON) and types of components on acceleration performance were investigated using four ‘Premium Gasoline Required Vehicles’ which are Japanese commercial vehicles equipped with knock sensors (KSs) and an electronic control unit (ECU) to prevent the engines from knocking. Regarding the fuel, two series of fuels were used. One of them {Primary Reference Fuel Series (PRF series)} was prepared to investigate the effectiveness of the octane number of PRF (ON). The other {Components Series (COMP series)} was prepared to investigate the effects of fuel components on the same. Fuels in the COMP series had almost the same RON level, which was almost equal to 90. In the PRF series, the acceleration performance of all vehicles were improved as ON increased.

Smoke emission from single-cylinder DI and IDI diesel engines was shown to strongly depend on oxygen content in fuel regardless of oxygenate molecular structure. Thus, with cetane improver and oxygenate used in combination in a proportion determined from blending properties and potential cost for modern heavy-duty DI diesel engines were assessed. The combined use of nitrate type cetane improver with glycol ether type oxygenate reduced particulate, HC, and CO emission but not that of NOx. Particulate reduction depended on oxygenate content. Oxygenate at less than 5% with cetane improver seldom worsened volume-based fuel economy compared with the base hydrocarbon fuel.

Performance and the compatibility of methyl tertiary butyl ether (MTBE) as a blending component for motor gasolines were assessed for Japanese passenger cars. MTBE was found to be an excellent road octane booster. But fuel consumption and exhaust emissions of MTBE-containing gasoline were observed to differ from conventional gasoline. The addition of MTBE changed the equivalence ratio of the mixture and reduced the calorific value of the fuel. Engine cleanliness, ORI and crankcase oil deterioration were not influenced by MTBE gasoline. MTBE gasoline was compatible with the elastomers and metals used for fuel system of Japanese passenger cars and was found to behave similarly to conventional gasoline. From these results, MTBE was judged to be an excellent octane appreciator in motor fuel for Japanese passenger cars.

Selected as an alternative diesel fuel based on consideration regarding the relationship between the fuel molecular structure and exhaust emission and criteria as alternative fuels, Dimethylacetal (DMA) was evaluated in both a direct injection (DI) diesel and a Direct Fuel Injection Impingement Diffusion Combustion Diesel (OSKA-D) engines. Since DMA with a 1% commercial-type cetane improver has 53 for the cetane number, no ignition-assist divice such as a spark plug is needed, unlike methanol. According to the DI diesel engine test, the NOx emission for DMA was almost equal to that for hydrocarbon diesel fuel, but smoke for DMA was much lower than that for diesel fuel. The OSKA-D engine test showed that NOx emission for DMA was much lower than that for diesel fuel and smoke emission for DMA was zero under all engine conditions.

The addition of soybean methyl ester (SME) to diesel fuel has significantly reduced HC and PM emissions, but it increases the NOx emission slightly when measured with exhaust emission evaluation mode for heavy-duty DI diesel engines or D-13 mode in Japan. Also, under partial load conditions, the SME addition increases the PM emission due to an increase in the SOF emission. However, the addition of lighter fractions or kerosene to diesel fuel reduces NOx and PM emissions but increases HC and CO emissions measured by D-13 mode. In addition, under full load conditions, the lighter fuel seldom reduces PM emission. Therefore, the exhaust emissions emitted from the blends of SME, kerosene, and cetane improver to low sulfur diesel fuel are evaluated using the latest DI diesel engine with a turbo-charger and inter-cooler. The clean fuel reduces over 20% of PM under a wide range of engine conditions including D-13 mode without an increase in NOx, HC, and CO emissions.

In this study, a homogeneous mixture of natural-gas and air was used in a compression ignition engine to reduce NOx emissions and improve thermal efficiency. In order to control ignition timing and combustion, a small amount of DME was mixed with the natural-gas. Engine performance and the exhaust characteristics were investigated experimentally. Results show the following: the engine can run over quite a large load range if a certain amount of DME is added into natural-gas. By optimizing the proportion of DME to natural-gas, NOx emissions can be lowered to near zero levels if the mixture is lean enough. Thermal efficiency is higher than that obtained with normal diesel fuel operation.