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Technical Paper

Advanced Exhaust Gas Thermal Management for Lowest Tailpipe Emissions - Combining Low Emission Engine and Electrically Heated Catalyst

2012-04-16
2012-01-1090
Further advancements in engine development lead to increased fuel efficiency and reduced CO₂ emission. Such low emission engine concepts require most advanced exhaust gas aftertreatment systems for lowest possible tailpipe emissions. On the other hand, the exhaust gas purification by catalytic measures experiences more and more challenges due to constantly reduced exhaust gas temperatures by more efficient engines. These challenges can be overcome by traditional catalyst heating strategies, which are known to increase fuel consumption and emissions. Alternatively, electrically heated catalysts ("EHC") can be utilized to provide a very efficient method to increase gas temperatures directly in the exhaust catalyst. This way the energy input can be tailored according to the component need and the energy loss in the system can be minimized.
Journal Article

Influence of Pre Turbo Catalyst Design on Diesel Engine Performance, Emissions and Fuel Economy

2008-04-14
2008-01-0071
This paper gives a thorough review of the HC/CO emissions challenge and discusses the effects of different diesel oxidation catalyst designs in a pre turbine and post turbine position on steady state and transient turbo charger performance as well as on HC and CO tailpipe emissions, fuel economy and performance of modern Diesel engines. Results from engine dynamometer testing are presented. Both classical diffusive and advanced premixed Diesel combustion modes are investigated to understand the various effects of possible future engine calibration strategies.
Technical Paper

Turbulent Flow Metal Substrates: A Way to Address Cold Start CO Emissions and to Optimize Catalyst Loading

2006-04-03
2006-01-1523
Modern Diesel Engines equipped with Common-Rail Direct Injection and EGR are characterized by an increasingly high combustion efficiency. Consequently the exhaust gas temperature, especially during a cold start, is significantly reduced compared to typical values measured in previous engine generations. This leads to a potential problem with CO emission limit compliance. The present paper deals with an experimental investigation of turbulent-flow metal substrates, carried out on a vehicle roller bench using a production 1.3 Liter diesel engine equipped passenger car. The tested metal supported catalysts proved to yield extremely high conversion rates both during cold start and in warm operation phase. The improved mass transfer efficiency of the advanced metal substrates is related on one hand to the optimized coating technology and, on the other hand, to the enhanced flow performance in the single converter channels which is caused by structured metal foils.
Technical Paper

Backpressure Optimized Metal Supported Close Coupled PE Catalyst - First Application on a Maserati Powertrain

2005-04-11
2005-01-1105
Future stringent emission limits both in the European Community and USA require continuously increased conversion efficiency of exhaust after-treatment systems. Besides the obvious targets of fastest light-off performance, overall conversion efficiency and durability, catalytic converters for maximum output engines require highly optimized flow properties as well, in order to create minimum exhaust backpressure for low fuel consumption. This work deals with the design, development and serial introduction of a close coupled main catalyst system using the innovative technology of Perforated Foils (PE). By means of PE-technology, channel-to-channel gas mixing within the metal substrate could be achieved leading to dramatically reduced backpressure values compared with the conventional design.
Technical Paper

Metal Supported Particulate Matter-Cat, A Low Impact and Cost Effective Solution for a 1.3 Euro IV Diesel Engine

2005-04-11
2005-01-0471
Modern Diesel Engines equipped with Common-Rail Direct Injection, EGR and optimized combustion technology have been proven to reduce dramatically engine raw emissions both in terms of Nox and Particulate Matter. As a matter of fact the recently introduced FIAT 1.3 JTD 4 Cylinder Engine achieves Euro 4 limits with aid of conventional 2-way oxidation catalyst. Nevertheless some special applications, such as platforms with relatively higher gross vehicle weight possibly yield to PM-related issues. The present paper deals with the development program carried out to design a cost effective aftertreatment solution in order to address particulate matter tailpipe emissions. The major constraint of this development program was the extremely challenging packaging conditions and the absolute demand to avoid any major impact on the system design. The flow-through metal supported PM Filter Catalyst has been extensively tested on the specific vehicle application with aid of roller bench setup.
Technical Paper

Prediction of the Efficiency of an Automotive Oil Separator: Comparison of Numerical Simulations with Experiments

2004-10-25
2004-01-3019
RENAULT has developed a numerical method for predicting the efficiency of two types of oil separator. Numerical simulation is performed with the CFD package FLUENT6. Blow-by flow is considered as an aerosol mixture and is simulated as a continuous phase (air flow) carrying a discrete phase (oil droplets). The separator is meshed using a uniform 1mm tetrahedral mesh. The inlet volume flow is assumed steady. A standard k-epsilon model is used for flow calculation. Then droplets are introduced and their trajectories are computed. The wall boundary condition is straightforward: a particle touching a wall is assumed trapped and removed from the flow. The experimental set-up for efficiency measurement includes an oil generator which produces an air/oil aerosol mixture with a user-fixed volume flow, oil mass-flow and oil droplets diameter distribution. The generator is connected to a prototype oil separator. It is equipped with length and position-adjustable plates.
Technical Paper

Development of an Emission Aftertreatment System for Hand Held Powertools

2004-03-08
2004-01-0149
This paper gives an overview of the development work for an aftertreatment system, used in hand held powertools to fulfil the corporate average US Limits. The paper will start with a description of the annual reductions in US Limits with differences in CARB and EPA legislation and the consequences of the legislation in Europe from 2007 onwards. There then follows a chapter describing space restrictions in the given muffler leading to a maximum size for the substrate. Tests results are shown, giving an idea of additional measures taken to avoid dangerous temperatures on the muffler surface and of the emitted exhaust gas. The exothermic temperature increase created under service conditions imposes an additional thermal load from the catalyst back towards the engine itself. Therefore, some modifications regarding gas flow and positioning of the catalyst had to be made to find an adequate solution for series production.
Technical Paper

New Barrier Test and Assessment Protocol to Control Compatibility

2004-03-08
2004-01-1171
After a lot of researches in the field of compatibility through testing and accident analysis, the current knowledge allows us to propose a new test protocol able to control the two issues of compatibility: partner and self protection. In other words, the procedure would be able to assess the most relevant parameters: structural interaction (geometry / stiffness) and compartment strength (stiffness). The most effective way to meet this target is to control both of them at the same time, thus avoiding many test regulations. The new final protocol will be a mix of two very well known test configurations: current frontal regulation in Europe (ECE 94) to assess compartment strength and structural integrity through vehicle and dummy criteria Progressive Deformable Barrier test (PDB) to assess and control force distribution through barrier deformation.
Technical Paper

FTP and US06 Performance of Advanced High Cell Density Metallic Substrates as a Function of Varying Air/Fuel Modulation

2003-03-03
2003-01-0819
The influence of catalyst volume, cell density and precious metal loading on the catalyst efficiency were investigated to design a low cost catalyst system. In a first experiment the specific loading was kept constant for a 500cpsi and a 900cpsi substrate. In a second experiment the palladium loading was reduced on the 900cpsi substrate and the same PM loading was applied to a 1200cpsi substrate with lower volume. Finally the loading was further reduced for the 1200cpsi substrate. The following parameters were studied after aging: Catalyst performance of standard cell density compared to high cell density technology Light-off performance and catalyst efficiency as a function of Palladium loading and substrate cell density Catalyst efficiency as a function of AFR biasing The performance of the aged catalysts was investigated in a lambda sweep test and in light-off tests at an engine bench.
Technical Paper

Dilution Interest on Turbocharged SI Engine Combustion

2003-03-03
2003-01-0629
This paper presents a prospective combustion study about dilution effects on turbocharged SI engine at full load. It proposes a comparative analysis between lean burn and cooled exhaust gas recirculation (EGR) operation as knock improvement artifice in substitute of enrichment. The study was led on a four cylinder 2L engine on stationary test bench. A specific EGR circuit was designed in order to achieve high control of the temperature and mass flow of the recirculated gas. Thanks to instantaneous pressure cylinder transducers, a combustion analysis was carried out using an home-made code. 1-D simulations (WAVE code) were used to complete the analysis on volumetric efficiency and turbocharger behaviour. A real advantage of cooled EGR was observed in the study compared to lean burn or enrichment in terms of performance, heat exchange and specific fuel consumption.
Technical Paper

Research Results and Progress in LeaNOx II -A Co-operation for Lean NOx Abatement

2000-10-16
2000-01-2909
In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.
Technical Paper

A Laboratory Study of NOX Reduction During the Rich Operating Period Over a NOX Storage Catalyst

1999-10-25
1999-01-3502
The behaviour of a NOx storage catalyst in powdered form and containing a storage component based on alkaline metal was investigated under rich conditions. Experiments were conducted in a fixed-bed flow reactor with the space velocity set at 45,000 h-1. From these experiments it was possible to extract the fractional NOx reduction and the efficiency of use of the reductant. With 0.9% CO as a reductant at 350°C, complete utilisation of CO was achieved up to 70% NOx conversion as treatment time was increased. To obtain 90% NOx conversion required longer times, and 23% of the CO did not participate in the reduction of NOX. A reductant balance shows that about 40% of the CO added is used to reduce the catalyst surface when the flow is switched from lean to rich. The ranking of efficiencies of different reductant gases at 350°C gave the following sequence: 0.9% H2 ≈ 0.9% CO > 1285 ppm toluene > 3000 ppm propene ≈ 1125 ppm i-octane > 3000 ppm propane.
Technical Paper

Development of Increased Test Conditions for Close-Coupled Catalyst Applications

1996-10-01
962079
To meet LEV/ULEV - requirements, a considerable amount of development work was necessary to ensure suitable efficiency and durability of catalyst systems [1, 2, 3]. In addition to active emission reduction systems like the Electrically Heated Catalyst (EHC), Exhaust Gas Ignition (EGI) and the burner, passive systems like the HC-trap and Closed-Coupled Catalysts (CCC) are practical solutions to fulfill tighter emission requirements [4, 5, 6, 7]. Depending on the application, thermo-mechanical stresses, vibrations and efficiency degradation through aging increases with the reduction of the distance between the engine and the catalytic converter. Therefore, the test procedures which were suitable for converters which were to be placed in underfloor positions, needed to be modified according to the load spectra acting on close-coupled catalysts. This paper describes a new test strategy used during the development and design verification phase of catalytic converter systems.
Technical Paper

Research Results on Processes and Catalyst Materials for Lean NOx Conversion

1996-10-01
962041
In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.
Technical Paper

Optimization of an Electrically-Heated Catalytic Converter System Calculations and Application

1993-03-01
930384
From SAE-Papers and several publications, the easy, effective function and management of an EHC-System is well known. The direction of the development is now to reduce the electrical energy consumption and to show the mechanical durability of the heating structure. This paper shows that it is possible to minimize the energy consumption and that the required service life can be in principle achieved with the introduction of these developments. The physical characteristics such as mass, geometrical surface area, cell density and electrical resistance of the EHC construction could be optimized to save energy. This, in conjunction with the operating parameters of the engine, the controlling of the secondary air and the catalyst configuration, will enable the goals to be met. The design of the converter, the physical characteristics and the results of the tests are shown with the Porsche 944 S2 and 968 applications.
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