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The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

An investigation was conducted to elucidate, how the latest turbocharged, direct injection Volkswagen diesel engine generation with cylinder pressure based closed loop control, to be launched in the US in 2008, reacts to fuel variability. A de-correlated fuels matrix was designed to bracket the range of US market fuel properties, which allowed a clear correlation of individual fuel properties with engine response. The test program consisting of steady state operating points showed that cylinder pressure based closed loop control successfully levels out the influence of fuel ignition quality, showing the effectiveness of this new technology for markets with a wide range of fuel qualities. However, it also showed that within the cetane range tested (39 to 55), despite the constant combustion mid-point, cetane number still has an influence on particulate and gaseous emissions. Volatility and energy density also influence the engine's behavior, but less strongly.

The control over particulate emissions is becoming increasingly important in modern diesel engines for Heavy Duty applications, that will comply to more and more stringent emissions norms. Use of particulate traps is an effective means of achieving this with the need to regenerate the particulate trap being imperative. Passive regeneration using NO2 by conversion of NO, as well as regeneration at lower temperatures with catalyzed DPF and the influence of NOx to soot ratio on this, is the subject of the paper. Both coated and uncoated filters in fresh and aged state are evaluated at temperatures typical of passive NO2 and Oxygen-based soot regenerations and the results discussed.

After the success of the 4-cylinder 1.9-liter TDI and SDI direct-injection diesel engines in the Passat, Jetta and Polo classes, a new 3-cylinder TDI has been developed for use in the "Lupo 3L,' a compact car with a fuel consumption of 3 liters per 100 km. A new injection system with unit injectors, together with a fully electronically controlled engine management system featuring drive-by-wire- technology, a turbocharger with variable turbine geometry and a fully automated mechanical gearbox and clutch, for the first time ensures the potential to meet the stringent D4 exhaust emissions level and to achieve excellent fuel economy. The wheel-torque based engine and gearbox management systems optimize engine operation in terms of efficiency and emissions.

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.

A 3-dimensional numerical study has been conducted investigating the combustion process in a VW 1.9l TDI Diesel engine. Simulations were performed modeling the spray injection of a 5-hole Diesel injector in a pressure chamber. A graphical methodology was utilized to match the spray resulting from the widely used Discrete Droplet Spray model to pressure chamber spray images. Satisfactory agreement has been obtained regarding the simulated and experimental spray penetration and cone angles. Thereafter, the combustion process in the engine was simulated. Using engine measurements to initialize the combustion chamber conditions, the compression stroke, the spray injection and the combustion simulation was performed. The novel RTZF two-zone flamelet combustion model was used for the combustion simulation and was tested for partial load operating conditions. An objective analysis of the model is presented including the results of a numerical parameter study.

With the introduction of the New Beetle, Volkswagen is offering the next generation of the 1.9l TDI engine. Several evolutionary changes have been made to the TDI concept to further improve its emissions, efficiency and performance. Emissions performance is improved with increased fuel injection pressure, optimized fuel injectors, calibration modifications, EGR cooling and reduced crevice volume in the combustion chamber. Efficiency is improved with new oil pump, vacuum pump and water pump drive systems and the elimination of an auxiliary driveshaft. Performance and efficiency is improved with the addition of a variable geometry turbocharger, which increases torque at lower engine speeds while preserving performance at higher engine speeds. This paper describes the many enhancements found in this latest generation TDI and gives a brief lookout to the future trends in diesel engine development such as a high pressure injection system with unit injectors.

The awareness concerning environmental issues and the economical need for fuel savings leads to the introduction of new, highly efficient Diesel engines for passenger cars. An engine with common rail injection system could meet this target and, with the help of an advanced diesel exhaust aftertreatment system also fulfilled the new legislative emission regulations. Besides the efficient oxidation of carbon monoxide (CO), hydrocarbons (HC) and diesel particulates, such a system also requires a moderate reduction efficiency for nitrogen oxides (NOx) under excess oxygen conditions. The present paper illustrates the further progress in catalytic NOx-reduction under excess of oxygen by hydrocarbon enrichment using the common rail injection system.

The EPEFE study (European Programme on Emissions, Fuels and Engine Technologies), /1/ and other programmes have identified an increase in tailpipe NOx emissions with reduced gasoline aromatics content for modern 3-way controlled catalyst vehicles. This effect occurs with fully warmed-up catalyst under closed-loop operation. In order to understand the reasons for this effect VW and Shell have mechanistically investigated the effects of fuel properties on EMS (engine management system) and catalyst performance. Fuels with independent variation of oxygen, aromatics and mid-range volatility were tested in different VW engines. λ was monitored using sensors located both pre and post catalyst. The results confirmed that reducing gasoline aromatics content reduced engine-out emissions but increased tailpipe NOx emissions. It could be shown that differences in H/C ratio led to differences in the hydrogen content of engine-out emissions which affected the reading of the λ sensor.

Volkswagen is the first automobile manufacturer to supply a passenger car with a direct fuel injection diesel engine to the US market, starting 1996. To meet the stringent US exhaust gas legislation the very successful European 1.9 liter TDI engine has been further developed for the 1996 and 1997 Passat. This TD1 incorporates a number of innovations in advanced diesel technology. Emissions-reducing innovations include: reduced crevice volume higher injection pressures upgraded injection management integrated EGR manifold system EGR cooling diesel catalytic converter This TDI engine configuration is also to be offered in the 1997 Golf and Jetta class and the new Passat in model year 1998. Over the coming years the TDI engine concept will be further optimized by utilizing variations of the above innovations.

Quantitative 1-D spatially-resolved NO LIF measurements in the combustion chamber of a mass-production SI engine with port-fuel injection using a tunable KrF excimer laser are presented. One of the main advantages of this approach is that KrF laser radiation at 248 nm is only slightly absorbed by the in-cylinder gases during engine combustion and therefore it allows measurements at all crank angles. Multispecies detection turned out to be crucial for this approach since it is possible to calculate the in-cylinder temperature from the detected Rayleigh scattering and the simultaneously acquired pressure traces. Additionally, it allows the monitoring of interfering emissions and spectroscopic effects like fluorescence trapping which turned out to take place. Excitation with 248 nm yields LIF emissions at shorter wavelengths than the laser wavelength (at 237 and 226 nm).

There is an increasing interest in running gasoline fueled passenger cars lean of stoichiometric air to fuel (A/F) ratio to improve fuel economy. These types of engines will operate at lean A/F ratios during cruising at partial load and return to stoichiometric or even rich conditions when more power is required. The challenge for the engine and catalyst manufacturer is to develop a system which will combine the high activity rates of a state-of-the-art three way catalyst (TWC) with the ability to reduce nitrogen oxides (NOx) under excess of oxygen. The target is to achieve the future legislation limits (EURO III/IV) in the European Union. Recent developments in automotive pollution control catalysis have shown that the utilization of NOx adsorption materials is a suitable way for reduction of NOx emissions of gasoline fueled lean burn engines.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

For high-speed imaging a newly developed eight-fold CCD camera, which permits framing rates of up to one million pictures per second, was used to obtain pictures of the injected sprays during the operation of a diesel engine. For the particular case studied here the framing rate was set at 50,000 pictures per second. This rate was sufficient to resolve the temporal development of the sprays in the transparent version of the four-cylinder, in-line, 1.9 litre DI production diesel engine of Volkswagen. The advantage of the camera is that it needs no light pulses for illumination, but can operate with a continuous light source. Each of the CCD chips is arranged around a central eight face reflecting pyramid, which splits the light coming from the camera lens to each CCD chip. The chips can be shuttered freely (asynchronously) at programmable inter-frame spacings thus permitting operation with continuous illumination. In this particular case a 30 Watt halogen lamp was used.

The spray development, combustion and emissions in a 1.9L optical, four-cylinder, direct-injection diesel engine were investigated by means of pressure analysis, high-speed cinematography, the two-colour method and exhaust gas analysis for various levels of exhaust gas recirculation (EGR), three EGR temperatures (uncontrolled, hot and cold) and three fuels (diesel, n-heptane and a two-component fuel 7D3N). Engine operating conditions included 1000 rpm/idle and 2000 rpm/2bar with EGR-rates ranging from 0 to 70%. Independent of rate, EGR was found to have a very small effect on spray angle and spray tip penetration but the auto-ignition sites seemed to increase in size and number at higher EGR-rates with associated reduction in the flame luminosity and flame temperature, by, say, 100K at 50% EGR.

The formation of soot during the first phase and the oxidation of soot during the later phase of the combustion in a direct-injection diesel engine have been investigated in detail by an extinction method. The experiments were performed in a 1.9 l near-production high-speed four-cylinder in-line direct-injection diesel engine for passenger cars for different rates of exhaust gas recirculation (EGR) and for different fuels. The measurements result in crank angle resolved and cycle-averaged soot mass concentrations in the piston bowl and the combustion chamber. The results show that with increasing EGR-rates the amount of soot formed is increased only slightly but the amount of soot oxidized during combustion decreases significantly. This is assumed to be the main reason for the increase of soot in the exhaust gas with increasing EGR-rates.

Non-intrusive temperature measurements based on single-line laser-induced fluorescence of molecular oxygen in the transparent IDEA Diesel engine were investigated. Oxygen molecules were excited to fluorescence with a narrowband, tunable ArF excimer laser at 193 nm. The resulting fluorescence signals were recorded with an image-intensified CCD camera. The temperature increase during the compression phase of the four-cylinder direct injection Diesel engine could be evaluated from the LIF signals. In the crank angle range of the measurements, good agreement between measured and calculated temperatures (polytropic compression) was observed.

The NO formation is essentially determined by the flame temperature. In an engine the latter depends on the composition of the fuel and the intake gas. In this study the efficiency of various NO reducing measures is analysed by means of a comparison of measurements and computations for the Most frequent operation point of a 1.9 1 DI Diesel engine. The O2 concentration, which is shown to be the dominant source of influence on the flame temperature and NO formation, is varied using synthetic gas mixtures or by EGR. The molar heat capacity of CO2 and H2O in the recirculated exhaust gas, the intake temperature and the H/C ratio in the fuel are less important for the formation of NO. Measures which reduce the NO formation increase the ignition delay and thereby the fraction of the premixed combustion. The impact of EGR on the combustion process is illustrated by high speed filming.

To date, several non-SCR catalysts and catalytic systems have been suggested for NOX reduction under oxygen rich (lean) conditions, such as those which exist in diesel engine exhaust gas. However, the performance of such catalysts and catalyst systems is not clear when used on actual diesel engines. This paper reports on experimental results obtained when lean NOx catalysts are applied to diesel engine exhaust. Particularly, the catalysts' NOx performance is examined when secondary hydrocarbons are added as reducing agents directly in the exhaust gas stream. In addition, the effect of different catalyst formulations and secondary hydrocarbon addition on particulate emissions is monitored. Finally, partial system optimization is performed and the applicability of such catalysts and systems to engines operating under the US Heavy Duty Transient Cycle is examined.

The combustion and pollutant formation processes in a 1.9 I IDI Diesel engine are simulated with the SPEED computational fluid dynamics (CFD) code. A part and a full load simulation of the production engine and a full load simulation of a modified engine design are analyzed. The mixing and combustion process is visualized for all cases by means of the isosurfaces of stoichiometric mixture. The correlation of this surface with global quantities as heat release, mean pressure and temperature and swirl ratio is emphasized. The global properties are presented resolved for the swirl, main chamber and the swirl chamber throat separately. The formation of thermal NO and soot are simulated and analyzed.