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Investigating combustion characteristics of oxygenated gasoline and gasoline blended ethanol is a subject of recent interest. The non-linearity in the interaction of fuel components in the oxygenated gasoline can be studied by developing chemical kinetics of relevant surrogate of fewer components. This work proposes a new reduced four-component (isooctane, heptane, toluene, and ethanol) oxygenated gasoline surrogate mechanism consisting of 67 species and 325 reactions, applicable for dynamic CFD applications in engine combustion and sprays. The model introduces the addition of eight C1-C3 species into the previous model (Li et al; 2019) followed by extensive tuning of reaction rate constants of C7 - C8 chemistry. The current mechanism delivers excellent prediction capabilities in comprehensive combustion applications with an improved performance in lean conditions.

Exhaust Gas Recirculation (EGR) coolers are commonly used in on-road and off-road diesel engines to reduce the recirculated gas temperature in order to reduce NOx emissions. One of the common performance behaviors for EGR coolers in use on diesel engines is a reduction of the heat exchanger effectiveness, mainly due to particulate matter (PM) deposition and condensation of hydrocarbons (HC) from the diesel exhaust on the inside walls of the EGR cooler. According to previous studies, typically, the effectiveness decreases rapidly initially, then asymptotically stabilizes over time. Prior work has postulated a deposit removal mechanism to explain this stabilization phenomenon. In the present study, five field aged EGR cooler samples that were used on construction machines for over 10,000 hours were analyzed in order to understand the deposit structure as well as the deposit composition after long duration use.

This study experimentally investigates the impact of Miller cycle strategies on the combustion process, emissions, and thermal efficiency in heavy-duty diesel engines. The experiments were conducted at constant engine speed, load, and engine-out NOx (1160 rev/min, 1.76 MPa net IMEP, 4.5 g/kWh) on a single cylinder research engine equipped with a fully-flexible hydraulic valve train system. Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC) timing strategies were compared to a conventional intake valve profile. While the decrease in effective compression ratio associated with the use of Miller valve profiles was symmetric around bottom dead center, the decrease in volumetric efficiency (VE) was not. EIVC profiles were more effective at reducing VE than LIVC profiles. Despite this difference, EIVC and LIVC profiles with comparable VE decrease resulted in similar changes in combustion and emissions characteristics.

With ongoing concerns about the elevated levels of ambient air pollution in urban areas and the contribution from heavy-duty diesel vehicles, hybrid electric vehicles are considered as a potential solution as they are perceived to be more fuel efficient and less polluting than their conventional engine counterparts. However, recent studies have shown that real-world emissions may be substantially higher than those measured in the laboratory, mainly due to operating conditions that are not fully accounted for in dynamometer test cycles. At the U.S. EPA National Fuel and Vehicle Emissions Laboratory (NVFEL) the in-use criteria emissions and energy efficiency of heavy-duty class 8 vehicles (up to 36280 kg) can be evaluated under controlled conditions in the heavy-duty chassis dynamometer test.

As European and Chinese tailpipe emission regulations for gasoline light-duty vehicles impose particulate number limits, automotive manufacturers have begun equipping some vehicles with a gasoline particulate filter (GPF). Increased understanding of how soot morphology, reactivity, and GPF loading affect GPF filtration and regeneration characteristics is necessary for advancing GPF performance. This study investigates the impacts of morphology, reactivity, and filter soot loading on GPF filtration and regeneration. Soot morphology and reactivity are varied through changes in fuel injection parameters, known to affect soot formation conditions. Changes in morphology and reactivity are confirmed through analysis using a transmission electron microscope (TEM) and a thermogravimetric analyzer (TGA) respectively.

Combined direct and port fuel injection (i.e., dual injection) in spark ignition engines is of increasing interest due to the advantages for fuel flexibility and the individual merits of each system for improving engine performance and reducing engine-out emissions. Greater understanding of the impact of dual injection will enable deriving the maximum benefit from the two injection systems. This study investigates the effects of dual injection on combustion, especially knock propensity and tolerance to exhaust gas recirculation (EGR) dilution at different levels of EGR. A baseline for comparison with dual injection results was made using direct injection fueling only. A splash blended E20 fuel was used for the direct injection only tests. For the dual injection tests, gasoline, representing 80% by volume of the total fuel, was injected using the direct injector, and ethanol, representing 20% by volume of the total fuel, was injected using the port fuel injector.

Previous work done at the University of Michigan shows the capability of the vacuum-insulated catalytic converter (VICC) to retain heat during soak and the resulting benefits in reducing cold start emissions. This paper provides an improved version of the design which overcomes some of the shortcomings of the previous model and further improves the applicability and benefits of VICC. Also, newer materials have been evaluated and their effects on heat retention and emissions have studied using the 1-D after treatment model. Cold start emissions constitute around 60% to 80% of all the hydrocarbon and CO emissions in present day vehicles. The time taken to achieve the catalyst light-off temperature in a three-way catalytic converter significantly affects the emissions and fuel efficiency. The current work aims at developing a method to retain heat in catalytic converter, thus avoiding the need for light-off and reducing cold start emissions effectively.

Syngas (synthesis gas) aided combustion from various fuel reforming strategies is of increasing interest in boosted lean burn SI engines due to its impact on dilution tolerance and knock resistance. Due to the interest in reformed fuels, more concrete understanding of how to leverage syngas supplementation under various lean conditions is essential to optimize engine performance and derive the most benefit from the availability of syngas in the combustion process. While the impact of syngas supplementation on combustion stability has been studied adequately, detailed understanding of the impact of syngas on knocking is still limited. Hence, this study investigates the effect of syngas (H2/CO) addition on knock tendency under boosted EGR (Exhaust Gas Recirculation) and air diluted conditions. Syngas amount is controlled on an energy basis from 0% to 15% to compare the difference between EGR and air dilution.

The automotive industry has been witnessing a major shift towards downsized boosted direct injection engines due to diminishing petroleum reserves and increasingly stringent emission targets. Boosted engines operate at a high mean effective pressure (MEP), resulting in higher in-cylinder pressures and temperatures, effectively leading to increased possibility of abnormal combustion events like knock and pre-ignition. Therefore, the compression ratio and boost pressure in modern engines are restricted, which in-turn limits the engine efficiency and power. To mitigate conditions where the engine is prone to knocking, the engine control system uses spark retard and/or mixture enrichment, which decrease indicated work and increase specific fuel consumption. Several researchers have advocated water injection as an approach to replace or supplement existing knock mitigation techniques.

The Honda Particulate Matter Index (PMI) is a very helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and vehicle OEMs as a metric to understand a fuels impact on automotive engine sooting, in preparation for new global emissions regulations. The calculation of the index involves generating detailed hydrocarbon analysis (hydrocarbon molecular speciation) using gas chromatography laboratory equipment and the PMI calculation requires the exact list of compounds and correct naming conventions to work properly. The analytical methodology can be cumbersome, when the gas chromatography methodology has to be adjusted for new compounds that are not in the method, or if the compounds are not matching the list for quantification. Also, the method itself is relatively expensive, and not easily transferrable between labs.

Cooled EGR provides benefits in better fuel economy and lower emissions by reducing knocking tendency and decreasing peak cylinder temperature in gasoline engines. However, GDI engines have high particle emissions due to limited mixing of fuel and air, and these particle emissions can be a major source of EGR cooler fouling. In order to improve our knowledge of GDI engine EGR cooler fouling, the effects of tube geometry and coolant temperature on EGR cooler performance and degradation were studied using a four cylinder 2.0L turbocharged GDI engine. In addition, deposit microstructure was analyzed to explore the nature of deposits formed under GDI engine operation. The results of this study showed that a dented tube geometry was more effective in cooling the exhaust gas than a smooth tube due to its large surface area and turbulent fluid motion. However, more deposits were accumulated and higher effectiveness loss was observed in the dented tube.

This experimental study involves optimization of the scheduling of diesel post injections to reduce soot emissions from a light-duty diesel engine. Previous work has shown that certain post injection schedules can reduce engine-out soot emissions when compared to conventional injection schedules for the same engine load. The purpose of this study is to investigate the impact of post injection scheduling for a range of engine conditions on a light duty multicylinder turbodiesel engine (1.9L GM ZDTH). For each engine operating condition, a test grid was developed so that only two variables (post injection duration and the commanded dwell time between main injection and post injection) were varied, with all other conditions held constant, in order to isolate the effects of the post injection schedule. Results have identified two distinct regimes of post injection schedules that reduce soot emissions.

Ammonia, often present in exhaust gas samples, is a polar molecule gas that interacts with walls of the gas sampling and analysis equipment resulting in delayed instrument response. A set of experiments quantified various materials and process parameters of a heated sample line system for ammonia (NH3) response using a Fourier Transform infrared spectrometer (FTIR). Response attenuation rates are due to mixing and diffusion during transport as well as NH3 wall storage. Mixing/diffusion effects cause attenuation with a time constant 1-10 seconds. Wall storage attenuation has a time constant 10-200 seconds. The effects of sample line diameter and length, line temperature, line material, hydrated versus dry gas, and flow rate were examined. All of these factors are statistically significant to variation of at least one of the time constants. The NH3 storage on the sample system walls was calculated as a function of the experimental test as well.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

In this study, the performance and emissions of a 4 cylinder 2.5L light-duty diesel engine with methane fumigation in the intake air manifold is studied to simulate a dual fuel conversion kit. Because the engine control unit is optimized to work with only the diesel injection into the cylinder, the addition of methane to the intake disrupts this optimization. The energy from the diesel fuel is replaced with that from the methane by holding the engine load and speed constant as methane is added to the intake air. The pilot injection is fixed and the main injection is varied in increments over 12 crank angle degrees at these conditions to determine the timing that reduces each of the emissions while maintaining combustion performance as measured by the brake thermal efficiency. It is shown that with higher substitution the unburned hydrocarbon (UHC) emissions can increase by up to twenty times. The NOx emissions decrease for all engine conditions, up to 53%.