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TWC exposure to extreme temperature could result in irreversible damage or thermal failure. Thus, a strategy embedded in the engine control unit (ECU) called catalyst overheating protection (COP) will be activated to prevent TWC overheating. When COP is activated, the command air-fuel ratio will be enriched to cool the catalyst monolith down. Fuel enrichment has been proven a main prerequisite for ammonia formation in hot TWCs as a by-product of NOx reduction. Hence, COP events could theoretically be a source of post-catalyst ammonia from petrol vehicles, but this theory is yet to be confirmed in published literature. This paper validated this hypothesis using a self-programmed chassis-level test. The speed of the test vehicle was set to constant while the TWC temperature was raised stepwise until a COP event was activated.

This paper presents the PN (Particle Number) and some gaseous emissions results from a group of SI (Spark Ignition) passenger cars including HEV (Hybrid Electric Vehicle), PFI (Port Fuel Injection) and GDI (Gasoline Direction Injection) vehicles. The PEMS (Portable Emission Measurement System) was used for on-board emission measurements. The vehicles were driven using the routes complying with the EU Real Driving Emissions (RDE) test procedures required in the European Commission Regulation (EU) 2016/427, i.e. starting in an urban driving mode and then continuing into a rural driving mode and ending with motorway driving mode part. The percentage of these three segments is approximately 33%, 33%, 33% respectively. The total test time was between 90 to 120 minutes. The vehicles’ driving parameters such as road speed, tailpipe exhaust temperatures and energy consumption were recorded and their correlations with emissions were investigated.

This paper presents the emissions results and operational behavior of two hybrid vehicles over EU legislative Real Driving Emissions (RDE) and other on-road testing cycles. The behavior of one hybrid vehicle during real world driving is investigated, including analyses of air-fuel ratio and catalyst temperature changes, in order to elucidate the reasons for the emissions results seen in the other hybrid vehicle over an RDE cycle. It was observed that the catalyst cooled down over time when the hybrid vehicle SI (Spark Ignition) engine was turned off, meaning that when the engine restarted the catalyst efficiency was decreased until it was able to light-off once again. This leads to increases in the tailpipe emissions of CO, NOx and hydrocarbons after the engine restarts. In addition to this problem, the engine restarts demanded fuel enrichment, which resulted in incomplete combustion and further increases in CO and PN emissions.

Light-duty China-6, which is among the most stringent vehicle exhaust emission standards globally, mandates the monitoring and reporting of real driving emissions (RDE) from July, 2023. In the process of regulation promulgation and verification, more than 300 RDE tests have been performed on over 50 China-5 and China-6 certified models. This technical paper endeavors to summarize the experience of RDE practice in China, and discuss the impacts of some boundary conditions (including vehicle dynamic parameters, data processing methods, hybrid propulsion and testing altitude) on the result of RDE measurement. In general, gasoline passenger cars confront few challenges to meet the upcoming RDE NOx requirement, but some China-5 certified samples, even powered by naturally-aspirated engines may have PN issues. PN emissions from some GDI-hybrid powertrain systems also need further reduction to meet China-6 RDE requirements.

The drive characteristics and gaseous emissions of legislated Real Driving Emissions (RDE) test data from 8 different spark ignition vehicles were compared to data from corresponding Worldwide harmonized Light vehicles Test Cycle (WLTC) tests. The effect of the official RDE exclusion of cold start and idling on the RDE test, and the effect of the use of the moving averaging window (MAW) analysis technique, were simultaneously investigated. Specific attention was paid to differences in drive characteristics of the three different driving modes and the effect this had on the distance-based CO2, CO and NOx emission factors for each. The average velocity of the RDE tests was marginally greater than the WLTC tests, while the average acceleration was smaller. The CO2 emission appeared on average 4% lower under the RDE tests compared to the WLTC tests, while the CO was 60% lower. The NOx values were 34% lower under the RDE testing, and appeared to be linked to the average acceleration.

Along with the booming expansion of private car preservation, many Chinese cities are now struggling with hazy weather and ground-level ozone contamination. Although central government has stepped up efforts to purify skies above China, counter-strategies to curb ground-level ozone is comparatively weak. By using maximum incremental reactivity (MIR) method, this paper estimated the ozone forming potential for twenty-five Euro-3 to Euro-5 passenger cars burning conventional gasoline, methanol-gasoline, ethanol-gasoline, neat methanol and compressed natural gas (CNG). The results showed that, for all the fuel tested, VOC/NOx ratios and SR values decreased with the upgrading of emission standard. Except for Euro-3 M100 and Euro-4 M85, SR values for alternative fuel were to different degrees smaller than those for gasoline. When the emission standard was shifted from Euro-4 to Euro-5, OFP values estimated for gasoline vehicle decreased.

As a probable solution to both energy and environmental crisis, methanol and methanol gasoline have been used as gasoline surrogates in several provinces of China. Most recently, the Ministry of Environmental Protection of China is drafting a special emission standard for methanol-fueled light-duty vehicles. Given the scarcity of available data, this paper evaluated regulated emissions, carbonyl compounds and particulate matter from a China-5 certificated gasoline/methanol dual-fuel vehicle over New European Driving Cycle (NEDC). The results elucidated that in context with gasoline mode, CO emitted in methanol mode decreased 11.2%, while no evident changes of THC and NOx emissions were noticed with different fueling regimes. The total carbonyls and formaldehyde have increased by 39.5% and 19.8% respectively after switching from gasoline to methanol. A remarkable decrease of 65.6% in particulate matter was observed in methanol mode.

The partially premixed combustion (PPC) was realized in a 6-cylinder heavy turbocharged diesel engine with single injection and EGR strategies. Combined with chemical reaction mechanism, the combustion and emission processes of this mode was analyzed using level-set turbulent flame propagation model. Based on the experiments and simulations, the impacts of PPC on the heat release, NOx and PM emissions were further investigated. The results show that both the early-injection and late-injection strategies have a two-stage heat release and significantly higher premixed combustion proportion than the conventional combustion mode, however, mixing controlled combustion was also observed in the late-injection mode. The NOx and PM emission was reduced simultaneously in PPC. However, in the late-injection strategy, this was achieved at the expense of increased HC emission. The dynamic process of the core components in PPC was much different from those in conventional diesel spray combustion.

Compressed natural gas (CNG) is widely used as an alternative option in spark ignition engines because of its better fuel economy and in part cleaner emissions. To cope with the haze weather in Beijing, about 2000 gasoline/CNG dual-fuel taxis are servicing on-road. According to the government's plan, the volume of alternative fuel and pure electric vehicle will be further increased in the future. Thus, it is necessary to conduct an evaluation on the effectiveness of alternative fuel on curbing vehicular emissions. This research examined the regulated emissions and particulate matter of gasoline/CNG dual-fuel taxi over New European Driving Cycle (NEDC). Emission tests in gasoline- and CNG-fuelled, cold- and warm-start modes were done for all five taxies. Test vehicles, Hyundai Elantra, are powered by 1.6L spark-ignited engines incorporated with 5-gear manual gearboxes.

This present paper described an experimental study on the combustion and emission characteristics of a diesel engine at idle at different altitudes. Five altitudes ranging from 550m to up to 4500m were investigated. Combustion parameters including in-cylinder pressure and temperature, heat release, fuel mass burning and so forth, together with emission factors including CO, HC, NOx and PM were tested and analyzed. The result of on-board measurement manifested that in-cylinder pressure descended consistently with the rising of altitude, while both the maximum in-cylinder temperature and exhaust temperature ascended with the altitude. It was found that ignition delay was lengthened at higher altitude, but the combustion duration became shorter. The crank angle towards 90% fuel burnt has hardly changed with the variation of altitude. As for heat release, the difference of slopes observed at different altitudes was quite slight.

This work concerns the oxidation of biodiesel surrogates in a CI engine. An experimental study has been carried out in a single-cylinder common-rail CI engine with soybean biodiesel and two biodiesel surrogates containing neat methyl decanoate and methyl decanoate/n-heptane blends. Tests have been conducted with various intake oxygen concentrations ranging from 21% to approximately 9% at intake temperatures of 25°C and 50°C. The results showed that the ignition delay and smoke emissions of neat methyl decanoate were closer to that of soybean biodiesel as compared with methyl decanoate/n-heptane blends. A reduced chemical kinetic mechanism for the oxidation of methyl decanoate has been developed and applied to model internal combustion engines. A KIVA code, coupled with the Chemkin chemistry solver, was used as the computational platforms. The effects of various intake oxygen concentrations on the in-cylinder emissions of OH and soot were discussed.

A Euro 2 SI (Spark Ignition) Mondeo was investigated for a fully warmed-up vehicle on a simple urban driving loop. Emissions were monitored using an on-board Horiba OBS (On-Board emission measurement System) 1300. 10 laps of a 0.6 km loop were driven by each driver and this involved 4 junctions per lap. Statistical analysis of 20 drivers was made over 27 repeat junction events for each driver. The statistical analysis of the data showed that for all drivers the CO₂, speed and throttle position were more typical Gaussian in their distribution. NOx and CO on the other hand were lognormal in their distribution. Acceleration, positive and negative throttle jerks (rate of change of throttle angle) were borderline Gaussian. HC (Hydrocarbon) emissions were not Gaussian and there was some evidence for a gamma distribution and for a lognormal distribution. Comparison of mean HC emissions between the drivers was therefore not reliable.

An on-board emission measurement system (PEMS), the Horiba OBS 1300, was installed in Euro 1-4 SI cars of the same model to investigate the impact of vehicle technology on exhaust emissions, under urban driving conditions with a fully warmed-up catalyst. A typical urban driving loop cycle was used with no traffic loading so that driver behavior without the influence of other traffic could be investigated. The results showed that under real world driving conditions the NOx emissions exceeded the legislated values and only at cruise was the NOx emissions below the legislated value. The higher NOx emissions during real-world driving have implications for higher urban Ozone formation. With the exception of the old EURO1 vehicle, HC and CO emissions were under control for all the vehicles, as these are dominated by cold start issues, which were not included in this investigation.

Regulated and non-regulated tailpipe exhaust emissions were measured under real world urban driving conditions using a set of in-vehicle FTIR emission measurement system, which is able to measure 65 emission components simultaneously at a rate of 0.5 Hz. A EURO3 emission compliant SI car was used as a probe vehicle. An urban driving cycle was used for the test and four repeated journeys were conducted. The results were compared to EU emissions legislation. The results show that the TWC needed approximately 200 seconds to reach full conversion efficiency. THC and NOx emissions exceeded the EURO 3 exhaust emission legislation. CO2 emissions were well above the type approval value of this type of the vehicle. Greenhouse gases (methane and nitrous oxide) and toxic hydrocarbons such as benzene were predominantly emitted during cold start period from 0 to 200 seconds of the engine start. The results had a reasonable repeatability for most of the emissions.

An in-vehicle FTIR emission measurement system was used to investigate the exhaust emissions under different real world urban driving conditions. Five different driving cycles were developed based on real world urban driving conditions including urban free flow driving, junction maneuver, congested traffic and moderate speed cruising. The test vehicle was a EURO 2 emission compliant SI car equipped with temperature measurement along the exhaust pipe across the catalyst and real time fuel consumption measurement system. Both regulated and non-regulated emissions were measured and analyzed for different driving cycles. All journeys were started from cold. The engine warm up features and emissions as a function of engine warm up for different driving conditions were investigated.

A commercial on-board exhaust emissions measurement system, the Horiba OBS-1300, was evaluated in a series of chassis dynamometer test trails. A EURO 1 (petrol) SI passenger car, operated under normal and rich combustion conditions, and a combination of static and transient sampling provided a wide range of measurement conditions for the evaluation exercise. The chassis dynamometer facility incorporated an ‘industry standard’ measurement system comprising MEXA-7400 gas analyzer and CVS bag sampling system which were used as ‘benchmarks’ for the evaluation of both OBS-1300 component (exhaust flow meter and species analyzer) measurements and ‘daughter’ emission measurements for regulated gas-phase species (CO, CO2, HC and NOx). Trials demonstrated very good to reasonable agreement for exhaust flow and CO, CO2 and HC concentration measurements during static (R2 ≈ 0.97, 0.99, 0.99 and 0.97, respectively) and transient (R2 ≈ 0.88, 0.96, 0.95 and 0.86, respectively) testing.

The transport sector is one of the major contributors to greenhouse gas emissions. This study investigated three greenhouse gases emitted from road transport: CO2, N2O and CH4 emissions as a function of engine warm up and driving cycles. Five different urban driving cycles were developed and used including free flow driving and congested driving. An in-vehicle FTIR (Fourier Transform Inferred) emission measurement system was installed on a EURO2 emission compliant SI (Spark Ignition) car for emissions measurement at a rate of 0.5 HZ under real world urban driving conditions. This emission measurement system was calibrated on a standard CVS (Constant Volume Sampling) measurement system and showed excellent agreement on CO2 measurement with CVS results. The N2O and CH4 measurement was calibrated using calibration gas in lab. A MAX710 real time in-vehicle fuel consumption measurement system was installed in the test vehicle and real time fuel consumption was then obtained.

Exhaust emissions were measured under real world urban driving conditions using a set of in-vehicle FTIR emission measurement system, which is able to measure 65 emission components simultaneously at a rate of 0.5 Hz. The test vehicle was a modern EURO4 emission compliant SI car equipped with temperature measurement along the exhaust pipe across the catalyst so as to match thermal characteristics to emission profiles. A free flow urban driving cycle was used for the test and four repeated journeys were conducted. The results were compared to EU emissions legislation. The results show that the warm up of the lubricating oil needed 15 minutes. The TWC needed about 200 seconds to reach full conversion efficiency. CO, THC and NOx emissions exceeded the EURO4 exhaust emission legislation. CO2 emissions were well above the type approval value of this vehicle.

EURO 1, 2 3 and 4 SI (Spark Ignition) Ford Mondeo passenger cars were compared for their real world cold start emissions using an on-board FTIR (Fourier Transform Infrared) exhaust emission measurement system. The FTIR system can measure up to 65 species including both regulated and non-regulated exhaust pollutants at a rate of 0.5 Hz. The driving parameters such as speed, fuel consumption and air/fuel ratio were logged. The coolant water, lube oil and exhaust temperatures were also recorded. A typical urban driving cycle including a loop and a section of straight road was used for the comparison test as it was similar to the legislative ECE15 urban driving cycle. Exhaust emissions were calculated for the whole journey average and compared to EU legislation. The cold start transient emissions were also investigated as a separate parameter and this was where there was the greatest difference between the four vehicles.

A FTIR in-vehicle on-road emission measurement system was installed in a EURO 2 emissions compliant SI car to investigate exhaust emissions under different urban traffic conditions. The real time fuel consumption and vehicle traveling speed was measured and logged. The temperatures were measured along the exhaust pipe so as to monitor the thermal characteristics and efficiency of the catalyst. Two real world driving cycles were developed with different traffic conditions. One (WP cycle) was located in a quiet area with few traffic interference and the other one (HPL cycle) was in a busy area with more traffic variations. The test car was pre-warmed before each test to eliminate cold start effect. The driving parameters were analyzed for two real world cycles. The WP cycle had higher acceleration rate, longer acceleration mode and shorter steady speed driving mode and thus harsher than the HPL cycle.