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A diesel piloted natural gas engine's performance varies depending on operating conditions and has performed best under medium to high loads. It can often equal or better the fuel conversion efficiency of a diesel-only engine in this operating range. This paper presents a study performed on a multi-cylinder Cummins ISB 6.7L diesel engine converted to run stoichiometric natural gas/diesel micro-pilot combustion with a maximum diesel contribution of 10%. This study systematically quantifies and ranks the sensitivity of control factors on combustion and performance while operating at medium loads. The effects of combustion control parameters, including the pilot start of injection, pilot injection pressure, pilot injection quantity, exhaust gas recirculation, and global equivalence ratio, were tested using a design of experiments orthogonal matrix approach.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

Gasoline compression ignition (GCI) technology shows the potential to obtain high thermal efficiencies while maintaining low soot and NOx emissions in light-duty engine applications. Recent experimental studies and numerical simulations have indicated that high reactivity gasoline-like fuels can further enable the benefits of GCI combustion. However, there is limited empirical data in the literature studying the gasoline compression ignition process at relevant in-cylinder conditions, which are required for further optimizing combustion system designs. This study investigates the temporal and spatial evolution of the compression ignition process of various high reactivity gasoline fuels with research octane numbers (RON) of 71, 74 and 82, as well as a conventional RON 97 E10 gasoline fuel. A ten-hole prototype gasoline injector specifically designed for GCI applications capable of injection pressures up to 450 bar was used.

Extensive studies have addressed diesel sprays under non-vaporizing, vaporizing and combusting conditions respectively, but further insights into the mechanism by which combustion alters the macroscopic characteristics including the spray penetration and the shape of the spray under diesel engine conditions are needed. Contradictory observations are reported in the literature regarding the combusting diesel spray penetration compared to the inert conditions, and it is an objective of this study to provide further insights and analyses on the combusting spray characteristics by expanding the range of operating parameters. Parameters varied in the studies are charge gas conditions including oxygen levels of 0 %, 15%, 19%, charge densities of 22.8 & 34.8 kg/m3, and charge temperatures of 800, 900 & 1050 K for injection pressures of 1200, 1500, and 1800 bar with a single-hole injector with a nozzle diameter of 100 μm.

Reactivity Controlled Compression Ignition (RCCI) is a promising dual-fuel Low Temperature Combustion (LTC) mode with significant potential for reducing NOx and particulate emissions while improving or maintaining thermal efficiency compared to Conventional Diesel Combustion (CDC) engines. The large reactivity difference between diesel and Natural Gas (NG) fuels provides a strong control variable for phasing and shaping combustion heat release. In this work, the Brake Thermal Efficiencies (BTE), emissions and combustion characteristics of a light duty 1.9L, four-cylinder diesel engine operating in single fuel diesel mode and in Diesel-NG RCCI mode are investigated and compared. The engine was operated at speeds of 1300 to 2500 RPM and loads of 1 to 7 bar BMEP. Operation was limited to 10 bar/deg Maximum Pressure Rise Rate (MPRR) and 6% Coefficient of Variation (COV) of IMEP.

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

The increased availability of natural gas (NG) in the United States (US) and its relatively low cost compared to diesel fuel has heightened interest in the conversion of medium duty (MD) and heavy duty (HD) engines to NG fueled combustion systems. The aim for development for these NG engines is to realize fuel cost savings and reduce harmful emissions while maintaining durability. Transforming part of the vehicle fleet to NG is a path to reduce dependence on crude oil. Traditionally, port-fuel injection (PFI) or premixed NG spark-ignited (SI) combustion systems have been used for MD and HD engines with widespread use in the US and Europe. But this technology exhibits poor cycle efficiency and is load limited due to knock phenomenon. Direct Injection of NG during the compression stroke promises to deliver improved thermal efficiency by avoiding excessive premixing and extending the lean limits which helps to extend the knock limit.

For spark-ignition gasoline engines operating under the wide speed and load conditions required for light duty vehicles, ignition quality limits the ability to minimize fuel consumption and NOx emissions via dilution under light and part load conditions. In addition, during transients including tip-outs, high levels of dilution can occur for multiple combustion events before either the external exhaust gas can be adjusted and cleared from the intake or cam phasing can be adjusted for correct internal dilution. Further improvement and a thorough understanding of the impact of the ignition system on combustion near the dilution limit will enable reduced fuel consumption and robust transient operation. To determine and isolate the effects of multiple parameters, a variable output ignition system (VOIS) was developed and tested on a 3.5L turbocharged V6 homogeneous charge direct-injection gasoline engine with two spark plug gaps and three ignition settings.

In this study, a DOC catalyst was experimentally studied in an engine test cell with a2010 Cummins 6.7L ISB diesel and a production aftertreatment system. The test matrix consisted of steady state, active regeneration with in-cylinder fuel dosing and transient conditions. Conversion efficiencies of total hydrocarbon (THC), CO, and NO were quantified under each condition. A previously developed high-fidelity DOC model capable of predicting both steady state and transient active regeneration gaseous emissions was calibrated to the experimental data. The model consists of a single 1D channel where mass and energy balance equations were solved for both surface and bulk gas regions. The steady-state data were used to identify the activation energies and pre-exponential factors for CO, NO and HC oxidation, while the steady-state active regeneration data were used to identify the inhibition factors. The transient data were used to simulate the thermal response of the DOC.

A numerical analysis was performed to study the variation of the laminar burning speed of gasoline-ethanol blend, pressure, temperature and dilution using the one-dimensional premixed flame code CHEMKIN™. A semi-detailed validated chemical kinetic model (142 species and 672 reactions) for a gasoline surrogate fuel was used. The pure components in the surrogate fuel consist of n-heptane, isooctane and toluene. The ethanol mole fraction was varied from 0 to 85 percent, initial pressure from 4 to 8 bar, initial temperature from 300 to 600K, and the EGR dilution from 0 to 32% to represent the in-cylinder conditions of a spark-ignition engine. The laminar flame speed is found to increase with ethanol concentration and temperature but decrease with pressure and dilution.

Exhaust gas recirculation (EGR) has been employed in a diesel engine to reduce NOx emissions by diluting the fresh air charge with gases composed of primarily N2, CO2, H2O, and O2 from the engines exhaust stream. The addition of EGR reduces the production of NOx by lowering the peak cylinder gas temperature and reducing the concentration of O2 molecules, both of which contribute to the NOx formation mechanism. The amount of EGR has been typically controlled using an open loop control strategy where the flow of EGR was calibrated to the engine speed and load and controlled by the combination of an EGR valve and the ratio of the boost and exhaust back pressures. When oxygenated biofuels with lower specific energy are used, the engine control unit (ECU) will demand a higher fuel rate to maintain power output, which can alter the volumetric flow rate of EGR. In addition, oxygenated biofuels affect the oxygen concentration in the intake manifold gas stream.

A laboratory flow reactor study was utilized to determine the durability impact of alkali metal (Na and K) exposure on three Pt/Pd-based diesel oxidation catalysts (DOC), two vanadium-based selective catalytic reduction (SCR) catalysts, and two Cu/zeolite-based SCR catalysts. All catalyst samples were contaminated by direct deposition of Na or K by an incipient wetness technique. The activity impact on the contaminated DOCs was accomplished by evaluating for changes in CO and HC light-off. The activity impact on the contaminated SCR catalysts was accomplished by evaluating for changes in the Standard SCR Reaction, the Fast SCR Reaction, the Ammonia Oxidation Reaction, and the Ammonia Storage Capacity. Contamination levels of 3.0 wt% Na was found to have a higher negative impact on Pt-based and zeolite containing DOCs for T-50 CO and HC light-off.

Urea selective catalytic reduction (SCR) catalysts have the capability to deliver the high NOx conversion efficiencies required for future emission standards. However, the potential for the occasional over-temperature can lead to the irreversible deactivation of the SCR catalyst. On-board diagnostics (OBD) compliance requires monitoring of the SCR function to make sure it is operating properly. Initially, SCR catalyst performance metrics such as NOx conversion, NH3 oxidation, NH3 storage capacity, and BET surface area are within normal limits. However, these features degrade with high temperature aging. In this work, a laboratory flow reactor was utilized to determine the impact on these performance metrics as a function of aging condition. Upon the completion of a full time-at-temperature durability study, four performance criteria were established to help determine a likely SCR failure.

Diesel aftertreatment systems configured with a diesel oxidation catalyst (DOC) upstream of an urea selective catalytic reduction (SCR) catalyst run the risk of precious metal contamination. During active diesel particulate filter (DPF) regeneration events, the DOC bed temperature can reach up to 850°C. Under these conditions, precious metal (especially Pt) can be volatized and then deposited on a downstream SCR catalyst. In this paper, the impact of ultra-low contamination of platinum group metals (PGM) on the SCR catalyst was studied. A method based on precious metal volatilization of a Pt-rich DOC at 850°C and under lean gas conditions was employed to contaminate downstream FeSCR and CuSCR formulations. The contamination resulted in poor NOx conversion (via NOx remake) and excessive N2O formation. The precious metal volatilization method was employed to screen various Pt/Pd based DOCs to avoid contamination of the downstream FeSCR.

Passenger and light duty diesel vehicles will require up to 90% NOx conversion over the Federal Test Procedure (FTP) to meet future Tier 2 Bin 5 standards. This accomplishment is especially challenging for low exhaust temperature applications that mostly operate in the 200 - 350°C temperature regime. Selective catalytic reduction (SCR) catalysts formulated with Cu/zeolites have shown the potential to deliver this level of performance fresh, but their performance can easily deteriorate over time as a result of high temperature thermal deactivation. These high temperature SCR deactivation modes are unavoidable due to the requirements necessary to actively regenerate diesel particulate filters and purge SCRs from sulfur and hydrocarbon contamination. Careful vehicle temperature control of these events is necessary to prevent unintentional thermal damage but not always possible. As a result, there is a need to develop thermally robust SCR catalysts.

In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.

With concerns continuing to grow with respect to global warming from greenhouse gases, further regulations are being examined, developed and are expected for the emission of CO2 as an automobile exhaust. Renewable alternate fuels offer the potential to significantly reduce the CO2 impact of transportation. Hydrogen as a spark - ignition (SI) engine fuel provides this potential for significant CO2 reduction when generated from renewable resources. In addition, hydrogen has advantageous combustion properties including a wide flammable mixture range which facilitates lean burning and high dilution, fast combustion energy release and zero CO2 emissions. However, the high burning rates and fast energy release can lead to excessive in-cylinder pressures and temperatures resulting in combustion knock and high NOx emissions at stoichiometric operation.

Steady-state particulate loading experiments were conducted on an advanced production catalyzed particulate filter (CPF), both with and without a diesel oxidation catalyst (DOC). A heavy-duty diesel engine was used for this study with the experiments conducted at 20, 40, 60 and 75 % of full load (1120 Nm) at rated speed (2100 rpm). The data obtained from these experiments were used and are necessary for calibrating the MTU 1-D 2-Layer CPF model. These experimental and modeling results were compared to previous research conducted at MTU that used the same engine but an earlier development version of the combination of DOC and CPF. The motivation for the comparison of the two systems was to determine whether the reformulated production catalysts performed as good or better than the early development catalysts. The results were compared to understand the filtration and oxidation differences between the two DOC+CPF and the CPF-only aftertreatment systems.

Model-based control strategies are important for meeting the dual objective of maximizing NOx reduction and minimizing NH3 slip in urea-SCR catalysts. To be implementable on the vehicle, the models should capture the essential behavior of the system, while not being computationally intensive. This paper discusses the adequacy of two different reduced order SCR catalyst models and compares their performance with a higher order model. The higher order model assumes that the catalyst has both diffusion and reaction kinetics, whereas the reduced order models contain only reaction kinetics. After describing each model, its parameter identification and model validation based on experiments on a Navistar I6 7.6L engine are presented. The adequacy of reduced order models is demonstrated by comparing the NO, NO2 and NH3 concentrations predicted by the models to their concentrations from the test data.

An experimental and modeling study was conducted to study the passive regeneration of a catalyzed particulate filter (CPF) by the oxidation of particulate matter (PM) via thermal and Nitrogen dioxide/temperature-assisted means. Emissions data in the exhaust of a John Deere 6.8 liter, turbocharged and after-cooled engine with a low-pressure loop EGR and a diesel oxidation catalyst (DOC) - catalyzed particulate filter (CPF) in the exhaust system was measured and used for this study. A series of experiments was conducted to evaluate the performance of the DOC, CPF and DOC+CPF configurations at various engine speeds and loads.