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Technical Paper

Numerical Calculation of PM Trapping and Oxidation of Diesel Particulate Filter with Catalyst by One Dimensional Model

2020-09-15
2020-01-2169
Exhaust gas from the diesel engine contains particulate matter (PM) of soot that affects human health and the environment. For the reduction of the emission of the PM, the diesel particulate filter (DPF) is placed in the exhaust system. The pressure drops increases with the PM deposit quantity in the DPF, which results in the burden of the engine. Therefore, the PM should be removed regularly by oxidation process called regeneration. Consumption of fuel is improved by optimizing the timing of regeneration. However, it is difficult to visualize the behavior of PM trapping and oxidation. We have proposed a series of models from PM deposition to the oxidation process in the DPF. In this study, the behavior of deposition and oxidation of PM in the DPF with a catalyst are calculated. The numerical calculations are performed to estimate PM deposition-oxidation process within the DPF. The results are obtained using the simplified model constructed in this study.
Technical Paper

Phenomena of PM Deposition and Oxidation in the Diesel Particulate Filter

2019-12-19
2019-01-2288
The diesel particulate filter (DPF) has attracted strong attention as a desirable after-treatment device for the particulate matter (PM) contained in exhaust gas of diesel engine. When particulate matter was deposited on a DPF, the pressure drop increases due to the PM trapping in the surface cavities of the DPF. After that, an active regeneration is required. Since more fuel is required for the regeneration in addition to the normal driving (passive regeneration), the fuel economy deteriorates. In order to improve the performance, a passive regeneration is necessary. In this study, we compared the dependence of the shape and depth of the cavity of the DPF on the PM trapping process by a comprehensive overall model and numerical calculation. We found that the pressure drop and elapsed time of the PM trapping varied, strongly depending on the cavity shape of the DPF surface. Further we examined the relative importance of the amount of PM deposit and the surface cavity shape of the DPF.
Technical Paper

Investigation of Particulate Matter Formation in a Diesel Engine Using In-Cylinder Total Sampling and Thermal Desorption-GCMS/Carbon Analysis

2019-12-19
2019-01-2276
In-cylinder total sampling technique utilizing a single-cylinder diesel engine equipped with hydraulic valve actuation system has been developed. In this study, particulate matter (PM) included in the in-cylinder sample gas was collected on a quartz filter, and the polycyclic-aromatic hydrocarbons (PAHs) component and soot were subsequently quantified by thermal desorption-gas chromatograph mass spectrometry (TD-GCMS) and a carbon analyzer, respectively. Cylinder-averaged histories of PAHs and soot were obtained by changing the sampling timing. It was found that decreasing intake oxygen concentration suppresses in-cylinder soot oxidation, and the fuel with higher aromatic and naphthenic contents accelerates soot production.
Technical Paper

Numerical Simulation of In-Cylinder Particulate Matter Formation in Diesel Combustion by CFD Coupled with Chemical Kinetics Model

2019-12-19
2019-01-2277
A reduced chemical kinetic model of diesel fuel, which can be applied to computational fluid dynamics (CFD) simulation coupled with detailed chemistry using the CONVERGE software, is developed to simulate the particulate matter (PM) formation process. We analyzed the influence of varying intake oxygen concentrations and fuel composition on the polycyclic aromatic hydrocarbons (PAHs) and soot formation processes. When the intake oxygen concentration was decreased, no significant difference was observed in PAH formation associated with soot formation, and the soot mass generated after the peak was high. When the fuel contained high levels of aromatics and naphthene, the PAH and soot formation mass increased. These tendencies were in good agreement with experimental results [1].
Technical Paper

Urea Deposit Predictions on a Practical Mid/Heavy Duty Vehicle After-Treatment System

2018-04-03
2018-01-0960
Urea/SCR systems have been proven effective at reducing NOx over a wide range of operating conditions on mid/heavy duty diesel vehicles. However, design changes due to reduction in the size of modern compact Urea/SCR systems and lower exhaust temperature have increased the possibility of urea deposit formation. Urea deposits are formed when urea in films and droplets undergoes undesirable secondary reactions and generate by-products such as ammelide, biuret and cyanuric Acid (CYA). Ammelide and CYA are difficult to decompose which lead to the formation of solid deposits on the surface. This phenomenon degrades the performance of the after treatment system by decreasing overall mixing efficiency, lowering de-NOx efficiency and increasing pressure drop. Therefore, mitigating urea deposits is a primary design goal of modern diesel after-treatment systems.
Technical Paper

Association of Impact Velocity with Risks of Serious Injuries and Fatalities to Pedestrians in Commercial Truck-Pedestrian Accidents

2016-11-07
2016-22-0007
This study aimed to clarify the relationship between truck-pedestrian crash impact velocity and the risks of serious injury and fatality to pedestrians. We used micro and macro truck-pedestrian accident data from the Japanese Institute for Traffic Accident Research and Data Analysis (ITARDA) database. We classified vehicle type into five categories: heavy-duty trucks (gross vehicle weight [GVW] ≥11 × 103 kg [11 tons (t)], medium-duty trucks (5 × 103 kg [5 t] ≤ GVW < 11 × 103 kg [11 t]), light-duty trucks (GVW <5 × 103 kg [5 t]), box vans, and sedans. The fatality risk was ≤5% for light-duty trucks, box vans, and sedans at impact velocities ≤ 30 km/h and for medium-duty trucks at impact velocities ≤20 km/h. The fatality risk was ≤10% for heavy-duty trucks at impact velocities ≤10 km/h. Thus, fatality risk appears strongly associated with vehicle class.
Journal Article

The Performance of Multi-Cylinder Hydrogen / Diesel Dual Fuel Engine

2015-09-06
2015-24-2458
Hydrogen can be produced by electrolyzation with renewable electricity and the combustion products of hydrogen mixture include no CO, CO2 and hydrocarbons. In this study, engine performance with hydrogen / diesel dual fuel (hydrogen DDF) operation in a multi-cylinder diesel engine is investigated due to clarify advantages and disadvantages of hydrogen DDF operation. Hydrogen DDF operation under several brake power conditions are evaluated by changing a rate of hydrogen to total input energy (H2 rate). As H2 rate is increased, an amount of diesel fuel is decreased to keep a given torque constant. When the hydrogen DDF engine is operated with EGR, Exhaust gas components including carbon are improved or suppressed to same level as conventional diesel combustion. In addition, brake thermal efficiency is improved to 40% by increase in H2 rate that advances combustion phasing under higher power condition. On the other hand, NOx emission is much higher than one of conventional diesel engine.
Technical Paper

Microfluidic Simulation of Diesel Exhaust Gas and Soot Oxidation in Diesel Particulate Filter

2013-03-25
2013-01-0009
Particulate matter (PM) including soot in diesel exhaust gas is a serious atmospheric pollutant, and stricter exhaust emission standards are being set in many countries. As one of the key technologies, a diesel particulate filter (DPF) for PM trap in the after-treatment of the exhaust gas has been developed. Typically, the inlet size of filter monolith is about 2 mm, and the thickness of the filter wall is only 0.2 mm, where soot particles are removed. It is impossible to observe the small-scale phenomena inside the filter, experimentally. Then, in the present study, we conducted microfluidic simulation with soot oxidation. Here, a real cordierite filter was used in the simulation. The inner structure of the filter was scanned by a 3D X-ray CT Computed Tomography) technique. The advantage is that it is non-intrusive system, and it has a high spatial resolution in the micrometer.
Journal Article

Study of DME Diesel Engine for Low NOx and CO2 Emission and Development of DME Trucks for Commercial Use

2011-08-30
2011-01-1961
Study of DME diesel engines was conducted to improve fuel consumption and emissions of its. Additionally, DME trucks were built for the promotion and the road tests of these trucks were executed on EFV21 project. In this paper, results of diesel engine tests and DME truck driving tests are presented. As for DME diesel engines, the performance of a DME turbocharged diesel engine with LPL-EGR was evaluated and the influence of the compression ratio was also explored. As for DME trucks, a 100,000km road test was conducted on a DME light duty truck. After the road test, the engine was disassembled for investigation. Furthermore, two DME medium duty trucks have been developed and are now the undergoing practical road testing in each area of two transportation companies in Japan.
Technical Paper

Transient Behavior of VOCs Emission and Particle Size Distribution during Active Regeneration of Diesel Particulate Filter Equipped Diesel Engine

2011-08-30
2011-01-2087
In order to reduce fine particle emission, a diesel particulate filter (DPF) has begun to be equipped to a diesel engine. During regeneration of DPF, nanoparticles are known to be formed downstream of DPF. VOCs emission during regeneration is of interest in view of toxicity and formation mechanism of nanoparticles. A heavy duty diesel engine equipped with DPF was investigated to measure particle and VOCs emissions using PTR-TOFMS (Proton Transfer Reaction - Time of Flight Mass Spectrometer). PTR-TOFMS is a new on-line mass spectrometer using chemical ionization and its application to engine exhaust measurements is new. During active regeneration of the DPF, fine particle emission was increased by nucleation. But VOCs as well as THC emissions increased prior to particle increase. After the regeneration the particle and VOCs emissions decreased immediately to the level of normal operation.
Journal Article

Simultaneous Improvement of Fuel Consumption and Exhaust Emissions on a Multi-Cylinder Camless Engine

2011-04-12
2011-01-0937
Further improvement in fuel consumption is needed for diesel engines to address regulatory requirement particularly for heavy duty diesel in Japan enforced in 2015, in addition to the compliance to the regulatory requirements for exhaust emission, which seems to be more stringent in future. The authors have participated in the project of “Comprehensive Technological Development of Innovative, Next-Generation, Low-Pollution Vehicles” organized by New Energy and Industrial Technology Development Organization (NEDO), and innovative devices such as multi stage boosting system, ultra high-pressure fuel injection system and variable valve actuation (camless) system had been developed in this project from a standpoint of simultaneous improvement of fuel consumption and exhaust emission. In camless system, intake and exhaust valves are driven by hydraulic pressure. So, fully flexible setting of opening and closure timings and lift of the intake and exhaust valves is possible.
Technical Paper

Development of the on-board dry DeSOx filter for diesel exhaust

2009-09-13
2009-24-0154
NOx emitted from diesel is one of the main air pollutants for most countries. To reduce the emission of NOx could promote to diffuse diesel vehicles. A NOx storage/reduction (NSR) catalyst has been developed for the diesels. The catalyst for NSR is strongly poisoned by sulfur. We have found good reaction of CaCO3 with sulfur dioxide by using a thermogravimetry. We obtained desulfurization breakthrough characteristic for the sample of the CaCO3 which is washcoated on the monolith. As a result, this sample which has specific surface area, of 100 m2/g, absorbed SO2 about 0.43 ~ 0.45 g−SO2/g−CaCO3. In this experimental condition, The conversion of the sulfate does not depend on the amount of the supported CaCO3. The absorption efficiency of these samples were more than 99.4%. According to this result, it was found that the necessary amount of the absorbent was supposed to be 0.538 kg or 2.1 L for 100,000 km running.
Journal Article

Analysis of Butane Diffusion in Activated Carbon Canister

2009-04-20
2009-01-0976
A canister filled with activated carbon prevents the emission of hydrocarbon into the air, through repeated adsorption and desorption process. A small amount of hydrocarbon, with n-butane as one of the major components, remains inside the canister. The diffusion of this residual n-butane affects Diurnal Breathing Loss performance. This study reports the quantitative difference of n-butane diffusion and breakthrough under three experimental conditions. Furthermore, diffusion speed, which is an important factor in the analysis of canister performance and the design development of canister, was also calculated.
Journal Article

Evaluation Method for Pressure Loss using Energy Dissipation

2008-04-14
2008-01-0250
In order to make more effective use of simulation, a new evaluation method on pressure loss has been developed. Using this method, the location and amount of pressure loss is clarified. As a result, enormous simulation data have been used effectively. The authors have confirmed the validity of the method about fundamental shapes.
Technical Paper

In Situ Observation of Catalysis Reactions Using Transmission Electron Microscope

2008-04-14
2008-01-1266
Transmission electron microscope (TEM) is a powerful tool for studying catalyst materials at nano-size and/or atomic level. Conventional TEM usually needs to be observed at room temperature in high vacuum conditions. A gaseous atmosphere and high temperature condition may change the properties of catalyst materials. Recently we developed an in situ observation system in TEM for observing the oxidation and reduction under a gas atmosphere at high temperature. Using the new in situ observation system in TEM, the morphological changes of the nano particle and support were observed in the heated gaseous atmosphere at atomic level in real time.
Technical Paper

Nano Particle Emission Evaluation of State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI) and Fuel Qualities Effects (EtOH, ETBE, FAME, Aromatics and Distillation)

2007-10-29
2007-01-4083
Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.
Technical Paper

Unregulated Emissions Evaluation of Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI), State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), and Fuel Qualities Effects (EtOH, ETBE, Aromatics and FAME)

2007-10-29
2007-01-4082
In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.
Technical Paper

Direct Simulation for Aerodynamic Noise from Vehicle Parts

2007-08-05
2007-01-3461
Flows around a forward facing step and a fence are simulated on structured grid to estimate aerodynamic noise by using direct simulation. Calculated results of sound pressure level show quantitatively good agreement with experimental results. To estimate aerodynamic noise from 3D complex geometry, a simplified side mirror model is also calculated. Averaged pressure distribution on the mirror surface as well as pressure fluctuations on the mirror surface and ground are simulated properly. However, calculated result of sound pressure level at a location is about 20dB higher than experiment due to insufficient spatial resolution. To capture the propagation of sound waves, more accuracy seems to be required.
Technical Paper

Expansion of Premixed Compression Ignition Combustion Region by Supercharging Operation and Lower Compression Ratio Piston

2007-08-05
2007-01-3614
Various premixed diesel combustion concepts are suggested as the way of simultaneous reduction of NOx and PM emission from diesel engines. However, every combustion concept has common problems, such as difficulty of ignition timing control, a great deal of HC and CO emissions and limiting the operation region to low load operation. The purpose of this study is to expand the operation region of Premixed Compression Ignition (PCI) combustion, which is a premixed diesel combustion concept that realizes the fuel injection around the top dead center. As a result of examining it with EGR, supercharging operation and low compression ratio piston, PCI combustion region was expanded to cover higher load operation. And the high load region was limited by not only stoichiometric air fuel ratio but also permissible maximum in-cylinder pressure.
Technical Paper

R&D and Analysis of Energy Consumption Improvement Factor for Advanced Clean Energy HEVs

2005-10-24
2005-01-3828
Ultra-low energy consumption and ultra-low emission vehicle technologies have been developed by combining petroleum-alternative clean energy with a hybrid electric vehicle (HEV) system. Their component technologies cover a wide range of vehicle types, such as passenger cars, delivery trucks, and city buses, adsorbed natural gas (ANG), compressed natural gas (CNG), and dimethyl ether (DME) as fuels, series (S-HEV) and series/parallel (SP-HEV) for hybrid types, and as energy storage systems (ESSs), flywheel batteries (FWBs), capacitors, and lithium-ion (Li-ion) batteries. Evaluation tests confirmed that the energy consumption of the developed vehicles is 1/2 of that of conventional diesel vehicles, and the exhaust emission levels are comparable to Japan's ultra-low emission vehicle (J-ULEV) level.
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