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Technical Paper

Study on Combustion and Exhaust Emissions Characteristics of Oxymethylene Dimethyl Ether Blends with Fischer-Tropsch Fuels in Diesel Engines

2023-09-29
2023-32-0167
Synthetic fuels (e-fuels) synthesized from H2 and CO by renewable electricity are expected as the next- generation diesel fuels and two types of e-fuels have received extensive attention: Fischer-Tropsch (FT) fuel and Oxymethylene dimethyl ether (OME). In this study the effects of OME blending ratios with 0 to 50 vol.% in FT fuels on combustion, emissions and spray characteristics in diesel engines are investigated. The results suggest that the OME blends to FT fuels suppressed the deterioration in combustion efficiency under low intake oxygen concentration conditions. The smoke emissions of FT fuels and OME blended fuels were both lower than those of diesel fuel and decreased with the increase in the OME blend ratio, and the soot-NOx trade-off relation in diesel engines can be improved.
Technical Paper

Chemical Kinetic Analysis with Two-Zone Model on Spark Knock Suppression Effects with Hydrogen Addition at Low and High Engine Speeds

2022-01-09
2022-32-0089
Spark knock suppression with hydrogen addition was investigated at two engine speeds (2000 rpm and 4800 rpm). The experimental results showed that the spark knock is strongly suppressed with increasing hydrogen fraction at 2000 rpm while the effect is much smaller at 4800 rpm. To explain these results, chemical kinetic analyses with a two-zone combustion model were performed. The calculated results showed that the heat release in the end gas zone rises in two stages with a remarkable appearance of low temperature oxidation (LTO) at 2000 rpm, while a single stage heat release without apparent LTO process is presented at 4800 rpm due to the shorter residence time in the low temperature region.
Journal Article

Improvements of Combustion and Emissions in a Natural Gas Fueled Engine with Hydrogen Enrichment and Optimized Injection Timings of the Diesel Fuel

2022-01-09
2022-32-0095
In a natural gas fueled engine ignited by diesel fuel, the addition of hydrogen to the engine could be a possible way to improve thermal efficiency and reduce unburned methane which has a warming potential many times that of carbon dioxide as it promotes a more rapid and complete combustion. This study carried out engine experiments using a single cylinder engine with natural gas and hydrogen delivered separately into the intake pipe, and with pilot-injection of diesel fuel. The percentages of hydrogen in the natural gas-hydrogen mixtures were varied from 0% to 50% of the heat value. The results showed that the hydrogen addition has an insignificant effect on the ignition delay of the diesel fuel and that it shortens the combustion duration. The increase in the hydrogen ratio decreased the unburned hydrocarbon emissions more than the reduction of the amount of natural gas that was replaced by the hydrogen.
Technical Paper

A Study of a Lean Homogeneous Combustion Engine System with a Fuel Reformer Cylinder

2019-12-19
2019-01-2177
The Dual-Fuel (DF) combustion is a promising technology for efficient, low NOx and low exhaust particulate matter (PM) engine operation. To achieve equivalent performance to a DF engine with only the use of conventional liquid fuel, this study proposes the implementation of an on-board fuel reformation process by piston compression. For concept verification, DF combustion tests with representative reformed gas components were conducted. Based on the results, the controllability of the reformed gas composition by variations in the operating conditions of the reformer cylinder were discussed.
Technical Paper

Kinetic Modeling of Ammonia-SCR and Experimental Studies over Monolithic Cu-ZSM-5 Catalyst

2019-01-15
2019-01-0024
Ammonia-selective catalytic reduction (SCR) systems have been introduced commercially in diesel vehicles, however catalyst systems with higher conversion efficiency and better control characteristics are required to know the actual emissions during operation and the emissions in random test cycles. Computational fluid dynamics (CFD) is an effective approach when applied to SCR catalyst development, and many models have been proposed, but these models need experimental verification and are limited in the situations they apply to. Further, taking account of redox cycle is important to have better accuracy in transient operation, however there are few models considering the cycle. Model development considering the redox reactions in a zeolite catalyst, Cu-ZSM-5, is the object of the research here, and the effects of exhaust gas composition on the SCR reaction and NH3 oxidation at high temperatures are investigated.
Journal Article

Chemical Reaction Processes of Fuel Reformation by Diesel Engine Piston Compression of Rich Homogeneous Air-Fuel Mixture

2017-11-15
2017-32-0120
To extend the operational range of premixed diesel combustion, fuel reformation by piston induced compression of rich homogeneous air-fuel mixtures was conducted in this study. Reformed gas compositions and chemical processes were first simulated with the chemistry dynamics simulation, CHEMKIN Pro, by changing the intake oxygen content, intake air temperature, and compression ratio. A single cylinder diesel engine was utilized to verify the simulation results. With the simulation and experiments, the characteristics of the reformed gas with respect to the reformer cylinder operating condition were obtained. Further, the thermal decomposition and partial oxidation reaction mechanisms of the fuel in extremely low oxygen concentrations were obtained with the characteristics of the gas production at the various reaction temperatures.
Technical Paper

Experimental Study of Flame Accelerated Ignition on Rapid Compression Machine and Heavy Duty Engine

2017-10-08
2017-01-2242
A new ignition method named Flame Accelerated Ignition (FAI) is proposed in this paper. The FAI system composes of a spark plug and a flame acceleration tunnel with annular obstacles inside. The FAI was experimentally investigated on a rapid compression machine (RCM) with optical accessibility and a single-cylinder heavy duty research engine. In RCM, the flame is significantly accelerated and the combustion process is evidently enhanced by FAI. The ignition delay and the combustion duration are both sharply decreased compared with conventional spark ignition (CSI) case. According to the optical diagnostics, the flame rushes out of the exit of the flame acceleration tunnel at maximum axial speed over 40 m/s, which exceeds 10 times that of CSI flame propagation. In radial direction, the flame curls outwards near the tunnel exit and keeps growing afterwards.
Technical Paper

An Investigation of the Transient DPF Pressure Drop under Cold Start Conditions in Diesel Engines

2017-10-08
2017-01-2372
To monitor emission-related components/systems and to evaluate the presence of malfunctioning or failures that can affect emissions, current diesel engine regulations require the use of on-board diagnostics (OBD). For diesel particulate filters (DPF), the pressure drop across the DPF is monitored by the OBD as the pressure drop is approximately linear related to the soot mass deposited in a filter. However, sudden acceleration may cause a sudden decrease in DPF pressure drop under cold start conditions. This appears to be caused by water that has condensed in the exhaust pipe, but no detailed mechanism for this decrease has been established. The present study developed an experimental apparatus that reproduces rapid increases of the exhaust gas flow under cold start conditions and enables independent control of the amount of water as well as the gas flow rate supplied to the DPF.
Technical Paper

Experimental Investigation of Improving Homogeneous Charge Induced Ignition (HCII) Combustion at Medium and High Load by Reducing Compression Ratio

2017-03-28
2017-01-0765
This research focuses on the potential of Homogeneous Charge Induced Ignition (HCII) combustion meeting the Euro V emission standard on a heavy-duty multi-cylinder engine using a simple after-treatment system. However, in our previous studies, it was found that the gasoline ratio was limited in HCII by the over-high compression ratio (CR). In this paper, the effects of reducing CR on the performances of HCII at medium and high loads were explored by experimental methods. It was found that by reducing CR from 18:1 to 16:1 the peak in-cylinder pressure and the peak pressure rise rate were effectively reduced and the gasoline ratio range could be obviously extended. Thus, the combustion and emission characteristics of HCII at medium and high loads were noticeably improved. Soot emissions can be significantly reduced because of the increase of premixed combustion ratio. The reduction could be over 50% especially at high load and high speed conditions.
Technical Paper

Impingement and Adhesion on Cylinder Liners with Post Diesel Fuel Injections

2016-10-17
2016-01-2193
Diesel particulate filters (DPF) are widely used in diesel engines, and forced regeneration is necessary to remove particulate matter (PM) accumulating on the DPF. This may be achieved with fuel injected after the main combustion is complete, the socalled “post fuel injection”, and supplied to the diesel oxidation catalyst (DOC) upstream of the DPF. This increases the exhaust gas temperature in the DOC and the DPF is regenerated with the high temperature gas flow. In most cases, the post fuel injection takes place at 30-90CA ATDC, and fuel may impinge on and adhere to the cylinder liner wall in some cases. Buddie and Pischinger [1] have reported a lubricant oil dilution with the post fuel injection by engine tests and simulations, and adhering fuel is a cause of worsening fuel consumption. In this paper, the impingement and adhesion of post diesel fuel injections on the cylinder liner was investigated by an optical method with a high pressure constant volume chamber (ϕ110mm, 883cm3).
Technical Paper

Performance Improvements in a Natural Gas Dual Fuel Compression Ignition Engine with 250 MPa Pilot Injection of Diesel Fuel as an Ignition Source

2016-10-17
2016-01-2306
The engine performance and the exhaust gas emissions in a dual fuel compression ignition engine with natural gas as the main fuel and a small quantity of pilot injection of diesel fuel with the ultra-high injection pressure of 250 MPa as an ignition source were investigated at 0.3 MPa and 0.8 MPa IMEP. With increasing injection pressure the unburned loss decreases and the thermal efficiency improves at both IMEP conditions. At the 0.3 MPa IMEP the THC and CO emissions are significantly reduced when maintaining the equivalence ratio of natural gas with decreasing the volumetric efficiency by intake gas throttling, but the NOx emissions increase and excessive intake gas throttling results in a decrease in the indicated thermal efficiency. Under the 250 MPa pilot injection condition simultaneous reductions in the NOx, THC, and CO emissions can be established with maintaining the equivalence ratio of natural gas by intake gas throttling.
Journal Article

Experimental Investigation of Homogeneous Charge Induced Ignition (HCII) with Low-Pressure Injection to Reduce PM Emissions in a Heavy-Duty Engine

2016-04-05
2016-01-0775
Homogeneous Charge Induced Ignition (HCII) combustion utilizes a port injection of high-volatile fuel to form a homogeneous charge and a direct injection of high ignitable fuel near the Top Dead Center (TDC) to trigger combustion. Compared to Conventional Diesel Combustion (CDC) with high injection pressures, HCII has the potential to achieve diesel-like thermal efficiency with significant reductions in NOx and PM emissions with relatively low-pressure injections, which would benefit the engine cost saving remarkably. In the first part of current investigation, experiments were conducted at medium load with single diesel injection strategy. HCII exhibited great potential of using low injection pressures to achieve low soot emissions. But the engine load for HCII was limited by high heat release rate. Thus, in the second and third part, experiments were performed at high and low load with double diesel injection strategy.
Technical Paper

Semi-Premixed Diesel Combustion with Twin Peak Shaped Heat Release Using Two-Stage Fuel Injection

2016-04-05
2016-01-0741
Characteristics of semi-premixed diesel combustion with a twin peak shaped heat release (twin combustion) were investigated under several in-cylinder gas conditions in a 0.55 L single cylinder diesel engine with common-rail fuel injection, super-charged, and with low pressure loop cooled EGR. The first-stage combustion fraction, the second injection timing, the intake oxygen concentration, and the intake gas pressure influence on thermal efficiency related parameters, the engine noise, and the exhaust gas emissions was systematically examined at a middle engine speed and load condition (2000 rpm, 0.7 MPa IMEP). The twin peak shaped heat release was realized with the first-stage premixed combustion with a sufficient premixing duration from the first fuel injection and with the second fuel injection taking place just after the end of the first-stage combustion.
Technical Paper

An Experimental Study Using Spark-Assisted Stratified Compression Ignition (SSCI) Hybrid Combustion Mode for Engine Particle Number (PN) Reduction in a High Compression Ratio Gasoline Engine

2016-04-05
2016-01-0758
Particle Number (PN) have already been a big issue for developing high efficiency internal combustion engines (ICEs). In this study, controlled spark-assisted stratified compression ignition (SSCI) with moderate end-gas auto-ignition was used for reducing PN in a high compression ratio gasoline direct injection (GDI) engine. Under wide open throttle (WOT) and Maximum Brake Torque timing (MBT) condition, high external cooled exhaust gas recirculation (EGR) was filled in the cylinder, while two-stage direct injection was used to form desired stoichiometric but stratified mixture. SSCI combustion mode exhibits two-stage heat release, where the first stage is associated with flame propagation induced by spark ignition and the second stage is the result of moderate end-gas auto-ignition without pressure oscillation at the middle or late stage of the combustion process.
Technical Paper

Development of a Micro-Reactor HC-SCR System and the Evaluation of NOx Reduction Characteristics

2015-09-01
2015-01-2021
To reduce NOx emissions from diesel engines, the urea-SCR (selective catalytic reduction) system has been introduced commercially. In urea-SCR, the freezing point of the urea aqueous solution, the deoxidizer, is −11°C, and the handling of the deoxidizer under cold weather conditions is a problem. Further, the ammonia escape from the catalyst and the generation of N2O emissions are also problems. To overcome these disadvantages of the urea-SCR system, the addition of a hydrocarbon deoxidizer has attracted attention. In this paper, a micro-reactor SCR system was developed and attached to the exhaust pipe of a single cylinder diesel engine. With the micro-reactor, the catalyst temperature, quantity of deoxidizer, and the space velocity can be controlled, and it is possible to use it with gas and liquid phase deoxidizers. The catalyst used in the tests reported here is Ag(1wt%)-γAl2O3.
Technical Paper

Improvement of Combustion and Emissions in a Dual Fuel Compression Ignition Engine with Natural Gas as the Main Fuel

2015-04-14
2015-01-0863
Dual fuel combustion with premixed natural gas as the main fuel and diesel fuel as the ignition source was investigated in a 0.83 L, single cylinder, DI diesel engine. At low loads, increasing the equivalence ratio of natural gas to around 0.5 with intake throttling makes it possible to reduce the THC and CO emissions as well as to improve the thermal efficiency. At high loads, increasing the boost pressure moderates the combustion, but increases the THC and CO emissions, resulting in deterioration of the thermal efficiency. The EGR is essential to suppress the rapid combustion. As misfiring occurs with a compression ratio of 14.5 and there is excessively rapid combustion with 18.5 compression ratio, 16.5 is a suitable compression ratio.
Journal Article

Molecular Structure of Hydrocarbons and Auto-Ignition Characteristics of HCCI Engines

2014-11-11
2014-32-0003
The chemical composition of marketed gasoline varies depending on the crude oil, refinery processes of oil refineries, and season. The combustion characteristics of HCCI engines are very sensitive to the fuel composition, and a fuel standard for HCCI is needed for HCCI vehicles to be commercially viable. In this paper, the effects of the structure of the fuel components on auto-ignition characteristics and HCCI engine performance were investigated. The engine employed in the experiments is a research, single cylinder HCCI engine with a compression ratio of 14.7. The intake manifold was equipped with a heater attachment allowing control of the intake air temperature up to 150 °C at 2000 rpm. Thirteen kinds of hydrocarbons, 4 kinds of paraffins, 3kinds of naphthenes, and 6 kinds of aromatics, were chosen for the investigation, and 20vol% of each of the pure hydrocarbons was blended with the 80 vol% of PFR50 fuel.
Technical Paper

Visualization Analysis of Diesel Combustion with Water and Diesel Fuel Emulsified Blend in a Constant Volume Chamber Vessel

2014-11-11
2014-32-0127
Diesel-like combustion of an emulsified blend of water and diesel fuel in a constant volume chamber vessel was visualized with high speed color video, further analyzing with a 2-D two color method and shadowgraph images. When the temperature at the fuel injection is 900 K, here while the combustion with unblended diesel fuel in the vessel is similar to ordinary diesel combustion with diffusive combustion, combustion with the emulsified fuel is similar to premixed diesel combustion with a large premixed combustion and very little diffusive combustion. With the emulsified fuel the flame luminosity and temperature are lower, the luminous flame and high temperature regions are smaller, and the duration of the luminous flame is shorter than with diesel fuel. This is due to promotion of premixing with increases in the ignition delay and decreases in the combustion temperature with the water vaporization.
Journal Article

Combustion Characteristics of Emulsified Blends of Water and Diesel Fuel in a Diesel Engine with Cooled EGR and Pilot Injection

2013-10-15
2013-32-9022
Water and diesel fuel emulsions containing 13% and 26% water by volume were investigated in a modern diesel engine with relatively early pilot injection, supercharging, and cooled EGR. The heat release from the pilot injection with water emulsions is retarded toward the top dead center due to the poor ignitability, which enables larger pilot and smaller main injection quantities. This characteristic results in improvements in the thermal efficiency due to the larger heat release near the top dead center and the smaller afterburning. With the 26% water emulsion, mild, smokeless, and very low NOx operation is possible at an optimum pilot injection quantity and 15% intake oxygen with EGR at or below 0.9 MPa IMEP, a condition where large smoke emissions are unavoidable with regular unblended diesel fuel. Heat transfer analysis with Woschni's equation did not show the decrease in cooling loss with the water emulsion fuels.
Technical Paper

Research on Gasoline Homogeneous Charge Induced Ignition (HCII) by Diesel in a Light-Duty Engine

2013-04-08
2013-01-1666
Gasoline engines suffer low thermal efficiency and diesel engines have the emission problem of the trade-off between NOx and soot emissions. Homogeneous Charge Induced Ignition (HCII) is introduced using a port injection of gasoline to form a homogeneous charge and using a direct injection of diesel fuel to ignite. HCII has the potential to achieve high thermal efficiency and low emission combustion. However, HCII combustion mode still has problems of high THC emissions at low load and high pressure rise rate at high load. In order to improve the gasoline reactivity and reduce THC emissions, double injection of diesel was applied in HCII mode. In order to reduce peak pressure rise rate (PPRR), a two-staged high-temperature heat release is achieved at suitable engine condition. The effects of HCII mode on combustion and emission characteristics are studied in a light-duty engine.
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