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Journal Article

Reversibility of Gasoline Sulfur Effects on the Exhaust Emissions of Late Model Vehicles

2014-04-01
2014-01-1624
The U.S. EPA has proposed a Tier 3 rule to lower average NMOG+NOx emissions from new light duty vehicles by approximately 80% from 2017 to 2025. Early in this time period, gasoline-fueled vehicles are expected to use technologies similar to California SULEV-II/PZEV certified models currently in limited production. These late model vehicles feature engine control systems that promote rapid catalyst light-off and are designed for ultra-high catalyst conversion efficiency. To enable the use of advanced catalyst coatings and materials, the EPA is also proposing to limit the sulfur content of gasoline to an annual average of 10 ppm while optionally maintaining the current maximum cap of 80 ppm. Fuel sulfur is known to poison precious metal-based catalysts, and the impact on emissions is well understood for older technology vehicles. However, there is a lack of test data on the sensitivity and reversibility of late model vehicle emissions to sulfur.
Technical Paper

Impacts of B20 Biodiesel on Cordierite Diesel Particulate Filter Performance

2009-11-02
2009-01-2736
Engine laboratory tests were conducted to assess the impact of B20 biodiesel on the performance of cordierite diesel particulate filters (DPFs). Test fuels included 20% soy based methyl ester blended into ultra low sulfur diesel fuel, and two ULSD on-road market fuels. B20 has a higher cetane number, boiling point and oxygen content than typical on-road diesel fuels. A comparative study was performed using a model year 2007 medium duty diesel truck engine. The aftertreatment system included a diesel oxidation catalyst (DOC) followed by a cordierite wall flow DPF. A laboratory-grade supplemental fuel doser was used in the exhaust stream for precise regeneration of the DPF. Tests revealed that the fuel dosing rate was higher and DOC fuel conversion efficiency was poorer for the B20 fuel during low exhaust temperature regenerations. The slip of B20 fuel past the DOC was shown to produce significantly higher exotherms in the DPF during regeneration.
Technical Paper

Weight Effect on Emissions and Fuel Consumption from Diesel and Lean-Burn Natural Gas Transit Buses

2007-08-05
2007-01-3626
Transit agencies across the United States operate bus fleets primarily powered by diesel, natural gas, and hybrid drive systems. Passenger loading affects the power demanded from the engine, which in turn affects distance-specific emissions and fuel consumption. Analysis shows that the nature of bus activity, taking into account the idle time, tire rolling resistance, wind drag, and acceleration energy, influences the way in which passenger load impacts emissions. Emissions performance and fuel consumption from diesel and natural gas powered buses were characterized by the West Virginia University (WVU) Transportable Emissions Testing Laboratory. A comparison matrix for all three bus technologies included three common driving cycles (the Braunschweig Cycle, the OCTA Cycle, and the ADEME-RATP Paris Cycle). Each bus was tested at three different passenger loading conditions (empty weight, half weight, and full weight).
Technical Paper

Neural Network Modeling of Emissions from Medium-Duty Vehicles Operating on Fisher-Tropsch Synthetic Fuel

2007-04-16
2007-01-1080
West Virginia University has conducted research to characterize the emissions from medium-duty vehicles operating on Fischer-Tropsch synthetic gas-to-liquid compression ignition fuel. The West Virginia University Transportable Heavy Vehicle Emissions Testing Laboratory was used to collect data for gaseous emissions (carbon dioxide, carbon monoxide, oxides of nitrogen, and total hydrocarbon) while the vehicles were exercised through a representative driving schedule, the New York City Bus Cycle (NYCB). Artificial neural networks were used to model emissions to enhance the capabilities of computer-based vehicle operation simulators. This modeling process is presented in this paper. Vehicle velocity, acceleration, torque at rear axel, and exhaust temperature were used as inputs to the neural networks. For each of the four gaseous emissions considered, one set of training data and one set of validating data were used, both based on the New York City Bus Cycle.
Technical Paper

Parametric Study of 2007 Standard Heavy-Duty Diesel Engine Particulate Matter Sampling System

2007-01-23
2007-01-0060
Heavy-Duty Diesel (HDD) engines' particulate matter (PM) emissions are most often measured quantitatively by weighing filters that collect diluted exhaust samples pre- and post-test. PM sampling systems that dilute exhaust gas and collect PM samples have different effects on measured PM data. Those effects usually contribute to inter-laboratory variance. The U.S. Environmental Protection Agency (EPA)'s 2007 PM emission measurement regulations for the test of HDD engines should reduce variability, but must also cope with PM mass that is an order of magnitude lower than legacy engine testing. To support the design of a 2007 US standard HDD PM emission sampling system, a parametric study based on a systematic Simulink® model was performed. This model acted as an auxiliary design tool when setting up a new 2007 HDD PM emission sampling system in a heavy-duty test cell at West Virginia University (WVU). It was also designed to provide assistance in post-test data processing.
Technical Paper

Effects of Average Driving Cycle Speed on Lean-Burn Natural Gas Bus Emissions and Fuel Economy

2007-01-23
2007-01-0054
Although diesel engines still power most of the heavy-duty transit buses in the United States, many major cities are also operating fleets where a significant percentage of buses is powered by lean-burn natural gas engines. Emissions from these buses are often expressed in distance-specific units of grams per mile (g/mile) or grams per kilometer (g/km), but the driving cycle or route employed during emissions measurement has a strong influence on the reported results. A driving cycle that demands less energy per unit distance than others results in higher fuel economy and lower distance-specific oxides of nitrogen emissions. In addition to energy per unit distance, the degree to which the driving cycle is transient in nature can also affect emissions.
Technical Paper

Regulated Emissions from Heavy Heavy-Duty Diesel Trucks Operating in the South Coast Air Basin

2006-10-16
2006-01-3395
Heavy duty diesel vehicle (HDDV) emissions are known to affect air quality, but few studies have quantified the real-world contribution to the inventory. The objective of this study was to provide data that may enable ambient emissions investigators to m,odel the air quality more accurately. The 25 vehicles reported in this paper are from the first phase of a program to determine representative regulated emissions from Heavy Heavy-Duty Diesel Trucks (HHDDT) operating in Southern California. Emissions data were gathered using a chassis dynamometer, full flow dilution tunnel, and research grade analyzers. The subject program employed two truck test weights and four new test modes (one was idle operation), in addition to the Urban Dynamometer Driving Schedule (UDDS), and the AC50/80 cycle. The reason for such a broad test cycle scope was to determine thoroughly how HHDDT emissions are influenced by operating cycle to improve accuracy of models.
Technical Paper

Correlation Study of PM and NOx for Heavy-Duty Vehicles Across Multiple Drive Schedules

2004-10-25
2004-01-3022
When heavy-duty truck emissions are expressed in distance-specific units (such as g/mile), the values may depend strongly on the nature of the test cycle or schedule. Prior studies have compared emissions gained using different schedules and have proposed techniques for translating emissions factor rates between schedules. This paper reviews emissions data from the 5-mode CARB HHDDT Schedule, UDDS Schedule, and a steady-state cycle (AC5080), with reference to each other. NOX and PM emissions are the two components of emissions which are reviewed. A heavy-duty chassis dynamometer was used for emissions characterization along with a full scale dilution tunnel. The vehicle test weights were simulated at 30,000 lbs, 56,000 lbs, and 66,000 lbs. For each vehicle, average data from one mode or cycle have been compared with average data for a different mode or cycle.
Technical Paper

Creation and Evaluation of a Medium Heavy-Duty Truck Test Cycle

2003-10-27
2003-01-3284
The California Air Resources Board (ARB) developed a Medium Heavy-Duty Truck (MHDT) schedule by selecting and joining microtrips from real-world MHDT. The MHDT consisted of three modes; namely, a Lower Speed Transient, a Higher Speed Transient, and a Cruise mode. The maximum speeds of these modes were 28.9, 58.2 and 66.0 mph, respectively. Each mode represented statistically selected truck behavior patterns in California. The MHDT is intended to be applied to emissions characterization of trucks (14,001 to 33,000lb gross vehicle weight) exercised on a chassis dynamometer. This paper presents the creation of the MHDT and an examination of repeatability of emissions data from MHDT driven through this schedule. Two trucks were procured to acquire data using the MHDT schedule. The first, a GMC truck with an 8.2-liter Isuzu engine and a standard transmission, was tested at laden weight (90% GVW, 17,550lb) and at unladen weight (50% GVW, 9,750lb).
Technical Paper

Emissions from Diesel-Fueled Heavy-Duty Vehicles in Southern California

2003-05-19
2003-01-1901
Few real-world data exist to describe the contribution of diesel vehicles to the emissions inventory, although it is widely acknowledged that diesel vehicles are a significant contributor to oxides of nitrogen (NOx) and particulate matter (PM) in Southern California. New data were acquired during the Gasoline/Diesel PM Split Study, designed to collect emissions data for source profiling of PM emissions from diesel- and gasoline-powered engines in the South Coast (Los Angeles) Air Basin in 2001. Regulated gases, PM and carbon dioxide (CO2) were measured from 34 diesel vehicles operating in the Southern California area. Two were transit buses, 16 were trucks over 33,000 lbs. in weight, 8 were 14,001 lbs. to 33,000 lbs. in weight and 8 were under 14,001 lbs. in weight. The vehicles were also grouped by model year for recruiting and data analysis.
Technical Paper

Speciation of Organic Compounds from the Exhaust of Trucks and Buses: Effect of Fuel and After-Treatment on Vehicle Emission Profiles

2002-10-21
2002-01-2873
A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).
Technical Paper

Fuel Additive and Blending Approaches to Reducing NOx Emissions from Biodiesel

2002-05-06
2002-01-1658
Blending of 20% biodiesel with petroleum diesel is well known to cause a significant reduction in PM emissions but also can cause NOx emissions to increase by 1 to 3 percent. This study has examined a number of approaches for NOx reduction for 20% biodiesel/petroleum diesel blends (B20). These approaches included blending with a nominally 10% aromatic diesel, zero aromatic Fisher-Tropsch (FT) diesel, and use of fuel additives. Biodiesel produced from soybean oil and from yellow grease was examined. Testing was conducted in at 1991 DDC Series 60 truck engine using the U.S. heavy-duty FTP. Emissions of NOx, PM, CO, and THC are reported. Relative to certification diesel the B20 fuels exhibited 20% lower PM emissions but 3.3 and 1% higher NOx emissions for soy and yellow grease based blends, respectively. The 10% aromatic fuel exhibited 12% lower PM and 6% lower NOx. FT diesel had the lowest emissions with a 33% reduction in PM and 16% lower NOx.
Technical Paper

Measurement of Brake-specific NOX Emissions using Zirconia Sensors for In-use, On-board Heavy-duty Vehicle Applications

2002-05-06
2002-01-1755
Emissions tests for heavy -duty diesel-fueled engines and vehicles are normally performed using engine dynamometers and chassis dynamometers, respectively, with laboratory grade gaseous concentration measurement analyzers and supporting test equipment. However, a considerable effort has been recently expended on developing in-use, on-board tools to measure brake-specific emissions from heavy -duty vehicles with the highest degree of accuracy and precision. This alternative testing methodology would supplement the emissions data that is collected from engine and chassis dynamometer tests. The on-board emissions testing methodology entails actively recording emissions and vehicle operating parameters (engine speed and load, vehicle speed etc.) from vehicles while they are operating on the road. This paper focuses on in-use measurements of NOX with zirconium oxide sensors and other portable NOX detectors.
Technical Paper

Chemical Speciation of Exhaust Emissions from Trucks and Buses Fueled on Ultra-Low Sulfur Diesel and CNG

2002-03-04
2002-01-0432
A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.
Technical Paper

Year-Long Evaluation of Trucks and Buses Equipped with Passive Diesel Particulate Filters

2002-03-04
2002-01-0433
A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.
Technical Paper

Development of Truck Engine Technologies for Use with Fischer-Tropsch Fuels

2001-09-24
2001-01-3520
The Fischer-Tropsch (FT) process can be used to synthesize diesel fuels from a variety of energy sources, including coal, natural gas and biomass. Diesel fuels produced from the FT process are essentially sulfur-free, have very low aromatic content, and have excellent ignition characteristics. Because of these favorable attributes, FT diesel fuels may offer environmental benefits over transportation fuels derived from crude oil. Previous tests have shown that FT diesel fuel can be used in unmodified engines and have been shown to lower regulated emissions. Whereas exhaust emissions reductions from these previous studies have been impressive, this paper demonstrates that far greater exhaust emissions reductions are possible if the diesel engine is optimized to exploit the properties of the FT fuels. A Power Stroke 7.3 liter turbocharged diesel engine has been modified for use with FT diesel.
Technical Paper

Research Approach for Aging and Evaluating Diesel Lean-NOx Catalysts

2001-09-24
2001-01-3620
The goal of the Diesel Emissions Control-Sulfur Effects (DECSE) program was to determine the impact of diesel fuel sulfur levels on emissions control devices that could lower emissions of oxides of nitrogen (NOX) and particulate matter (PM) from on-highway trucks and buses. West Virginia University (WVU) performed evaluations of lean-NOx catalysts to determine the effects of fuel sulfur content on emissions reduction efficiency and catalyst durability in the first 250 hours of operation. A Cummins ISM370 engine (10.8 liter, 370 horsepower), typical of heavy -duty truck applications, was utilized to evaluate high-temperature lean-NOX catalyst while a Navistar T444E (7.3 liter, 210 horsepower), typical of medium-duty applications, was used to evaluate low-temperature catalyst. Catalysts were evaluated periodically during the first 250 hours of exposure to exhaust from engines operated on 3ppm, 30ppm, 150ppm and 350ppm sulfur content diesel fuel.
Technical Paper

Emission Reductions and Operational Experiences With Heavy Duty Diesel Fleet Vehicles Retrofitted with Continuously Regenerated Diesel Particulate Filters in Southern California

2001-03-05
2001-01-0512
Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.
Technical Paper

Hybrid Diesel-Electric Heavy Duty Bus Emissions: Benefits Of Regeneration And Need For State Of Charge Correction

2000-10-16
2000-01-2955
Hybrid diesel electric buses offer the advantage of superior fuel economy through use of regenerative braking and lowered transient emissions by reducing the need of the engine to follow load as closely as in a conventional bus. With the support of the Department of Energy (DOE), five Lockheed Martin-Orion hybrid diesel-electric buses were operated on the West Virginia University Transportable Laboratory in Brooklyn, New York. The buses were exercised through a new cycle, termed the Manhattan cycle, that was representative of today's bus use as well as the accepted Central Business District Cycle and New York Bus Cycle. Emissions data were corrected for the state of charge of the batteries. The emissions can be expressed in units of grams/mile, grams/axle hp-hr and grams/gallon fuel. The role of improved fuel economy in reducing oxides of nitrogen relative to conventional automatic buses is evident in the data.
Technical Paper

An Evaluation of Natural Gas versus Diesel in Medium-Duty Buses

2000-10-16
2000-01-2822
Significant numbers of transit buses now operate on natural gas. With support of the U.S. Department of Energy, the National Renewable Energy Laboratory has evaluated the cost, performance, and emissions of alternative fuel buses around the country. In this study, three natural gas and three closely matched diesel buses were compared. The buses, built by World Trans, were 26′5″long and used 1997 Cummins B-series engines. Particulate matter and oxides of nitrogen emissions from the natural gas buses were significantly lower than those from the diesel buses. However, the diesel buses had lower operating costs and higher fuel efficiency than the natural gas buses.
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