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As passenger cars are progressively moving towards more electrification, Plug-in Hybrid Electric Vehicles (PHEVs) may play a greater role. Several questions arise regarding their performance in real-world conditions, their optimal configuration - in terms of battery capacity, fuel and powertrain used - and their pollutant emissions. In this context, two PHEVs complying with Euro 6d standards were evaluated on a chassis-dyno and on-road using the same road profile, complying with RDE requirements. The two vehicles differ only by their powertrain, one being diesel-fueled, and the other being gasoline-fueled. The vehicles were tested under various conditions, including charge depleting and charge sustaining modes (i.e., tests respectively starting with a fully charged battery and a discharged battery), with various fuel compositions including traditional fossil-based fuels, 100% renewable Hydrotreated Vegetable Oil (HVO) and 100% renewable gasoline, blended with 20% v/v ethanol (E20).

In Europe, the development and implementation of new regulatory test procedures including the chassis dynamometer (CD) based World Harmonised Light Duty Test Procedure (WLTP) and the Real Driving Emissions (RDE) procedure, has been driven by the close scrutiny that real driving emissions and fuel consumption from passenger cars have come under in recent times. This is due to a divergence between stated certification performance and measured on-road performance, and has been most pointed in the case of NOx (oxides of nitrogen) emissions from diesel cars. The RDE test is certainly more relevant than CD test cycles, but currently certification RDE cycles will not necessarily include the most extreme low speed congested or low temperature conditions which are likely to be more challenging for NOx after-treatment systems.

The performance of an extended stroke spark ignition engine has been assessed by cycle simulation. The base engine is a modern turbo-charged 4-stroke passenger car spark-ignition engine with 10:1 compression ratio. A complex crank mechanism is used so that the intake stroke remains the same while the expansion-to-intake stroke ratio (SR) is varied by changing the crank geometry. The study is limited to the thermodynamic aspect of the extended stroke; the changes in friction, combustion characteristic, and other factors are not included. When the combustion is not knock limited, an efficiency gain of more than 10 percent is obtained for SR = 1.5. At low load, however, there is an efficiency lost due to over-expansion. At the same NIMEP, the extended stroke renders the engine more resistant to knock. At SR of 1.8, the engine is free from knock up to 14 bar NIMEP at 2000 rpm. Under knocking condition, the required spark retard to prevent knocking is less with the extended stroke.

The spark ignition engine particulate number (PN) emissions have been correlated to a particulate matter index (PMI) in the literature. The PMI value addresses the fuel effect on PN emission through the individual fuel species reactivity and vapor pressure. The latter quantity is used to account for the propensity of the non-volatile fuel components to survive to the later part of the combustion event as wall liquid films, which serve as sources for particulate emission. The PMI, however, does not encompass the suppression of vaporization by the evaporative cooling of fuel components, such as ethanol, that have high latent heat of vaporization. This paper assesses this evaporative cooling effect on PN emissions by measurements in a GDI engine operating with a base gasoline which does not contain oxygenate, with a blend of the gasoline and ethanol, and with a blend of the gasoline, ethanol, and a hydrocarbon additive so that the blend has the same PMI as the original gasoline.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

The NOx emissions during the crank-start and cold fast-idle phases of a GDI engine are analyzed in detail. The NOx emissions of the first 3 firing cycles are studied under a wide set of parameters including the mass of fuel injected, start of injection, and ignition timing. The results show a strong dependence of the NOx emissions with injection timing; they are significantly reduced as the mixture is stratified. The impact of different valve timings on crank-start NOx emissions was analyzed. Late intake and early exhaust timings show similar potential for NOx reduction; 26-30% lower than the baseline. The combined strategy, resulting in a large symmetric negative valve overlap, shows the greatest reduction; 59% lower than the baseline. The cold fast-idle NOx emissions were studied under different equivalence ratios, injection strategies, combustion phasing, and valve timings. Slightly lean air-fuel mixtures result in a significant reduction of NOx.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

The combustion process after auto-ignition is investigated. Depending on the non-uniformity of the end gas, auto-ignition could initiate a flame, produce pressure waves that excite the engine structure (acoustic knock), or result in detonation (normal or developing). For the “acoustic knock” mode, a knock intensity (KI) is defined as the pressure oscillation amplitude. The KI values over different cycles under a fixed operating condition are observed to have a log-normal distribution. When the operating condition is changed (over different values of λ, EGR, and spark timing), the mean (μ) of log (KI/GIMEP) decreases linearly with the correlation-based ignition delay calculated using the knock-point end gas condition of the mean cycle. The standard deviation σ of log(KI/GIMEP) is approximately a constant, at 0.63. The values of μ and σ thus allow a statistical description of knock from the deterministic calculation of the ignition delay using the mean cycle properties

An ignition delay correlation encompassing the effects of temperature, pressure, residual gas, EGR, and lambda (on both the rich and lean sides) has been developed. The procedure uses the individual knocking cycle data from a boosted direct injection SI engine (GM LNF) operating at 1250 to 2000 rpm, 8-14 bar GIMEP, EGR of 0 to 12.5%, and lambda of 0.8 to 1.3 with a certification fuel (Haltermann 437, with RON=96.6 and MON=88.5). An algorithm has been devised to identify the knock point on individual pressure traces so that the large data set (of some thirty three thousand cycles) could be processed automatically. For lean and for rich operations, the role of the excess fuel, air, and recycled gas (which has excess air in the lean case, and hydrogen and carbon monoxide in the rich case) may be treated effectively as diluents in the ignition delay expression.

The engine and its exhaust flow behaviors are investigated in a turbo-charged gasoline direct injection engine under simulated cold-fast-idle condition. The metrics of interest are the exhaust sensible and chemical enthalpy flows, and the exhaust temperature, all of which affect catalyst light off time. The exhaust sensible enthalpy flow is mainly a function of combustion phasing; the exhaust chemical enthalpy flow is mainly a function of equivalence ratio. High sensible and chemical enthalpy flow with acceptable engine stability could be obtained with retarded combustion and enrichment. When split injection is employed with one early and one later and smaller fuel pulse, combustion retards with early secondary injection in the compression stroke but advances with late secondary injection. Comparing gasoline to E85, the latter produces a lower exhaust temperature because of charge cooling effect and because of a faster combustion.

Factors affecting the pressure rise rate, and consequently the high-load limit, in the sequential ignition of a homogeneous charge in a temperature gradient have been identified. The pressure rise rate decreases with an increase in the magnitude of the temperature gradient and an increase in the sensitivity of the constant volume ignition delay time to temperature. It increases with an increase in the intrinsic reaction rate (i.e., the reaction rate for a charge of uniform composition and temperature). Since the ignition delay time and the intrinsic reaction rate are directly related to fuel properties, the high-load limit is sensitive to fuel selection. The above three factors are used to explain the high-load limit obtained from a knock limited Controlled Auto-Ignition (CAI) engine with a homogeneous charge operating with three different fuels. The fuel comparisons are made with the engine operating at the same combustion phasing.

The heat release characteristics in terms of the maximum pressure rise rate (MPRR) and combustion phasing in a partially premixed compression ignition (PPCI) engine are studied using a calibration gasoline. Early port fuel injection provides a nearly homogeneous charge, into which a secondary fuel pulse is added via direct injection (DI) to provide stratification which is affected by the timing of the start of injection (SOI). As the SOI the DI fuel is retarded from early compression, MPRR first decreases, then increases substantially, and decreases again. The MPRR correlates mostly with the combustion phasing. The SOI timing plays an indirect role. The observation is explained by a bulk heat release process of which the rate increases with temperature rather than by a sequential ignition process. Observations from compression ignition of representative homogeneous charges in a Rapid Compression Machine support this explanation.

The knock metric for controlled auto-ignition (CAI) engines is assessed by considering the physical processes that establish the pressure wave that contributes to the acoustic radiation of the engine, and by analyzing pressure data from a CAI engine. Data sets from the engine operating with port fuel injection, early direct injection and late direct injection are used to monitor the effect of mixture composition stratification. Thermodynamic analysis shows that the local pressure rise produced by heat release has to be discounted by the work spent in acoustic expansion against the ambient pressure to properly predict the pressure wave amplitude. Based on this analysis, a modified correlation between the pressure wave amplitude and the maximum pressure rise rate (MPRR) is developed by introducing an MPRR offset to account for the expansion work.

The loss mechanisms associated with engine downsizing, boosting and compression ratio change are assessed. Of interest are the extents of friction loss, pumping loss, and crevice loss. The latter does not scale proportionally with engine size. These losses are deconstructed via a cycle simulation model which encompasses a friction model and a crevice loss model for engine displacement of 300 to 500 cc per cylinder. Boost pressure is adjusted to yield constant torque. The compression ratio is varied from 8 to 20. Under part load, moderate speed condition (1600 rpm; 13.4 Nm/cylinder brake torque), the pumping work reduces significantly with downsizing while the work loss associated with the crevice volume increases. At full load (1600 rpm; 43.6 Nm/cylinder brake torque), the pumping work is less significant. The crevice loss (normalized to the fuel energy) is essentially the same as in the part load case. The sensitivities of the respective loss terms to downsizing are reported.

The effects of cooled exhaust gas recirculation (EGR) on a boosted direct-injection (DI) spark ignition (SI) engine operating at stoichiometric equivalence ratio, gross indicated mean effective pressure of 14-18 bar, and speed of 1500-2500 rpm, are studied under constant fuel condition at each operating point. In the presence of EGR, burn durations are longer and combustion is more retard. At the same combustion phasing, the indicated specific fuel consumption improves because of a decrease in heat loss and an increase in the specific heat ratio. The knock limited spark advance increases substantially with EGR. This increase is due partly to a slower combustion which is equivalent to a spark retard, as manifested by a retarded value of the 50% burn point (CA50), and due partly to a slower ignition chemistry of the diluted charge, as manifested by the knock limited spark advance to beyond the value offered by the retarded CA50.

The fuel effects on HCCI operation in a spark assisted direct injection gasoline engine are assessed. The low load limit has been extended with a pilot fuel injection during the negative valve overlap (NVO) period. The fuel matrix consists of hydrocarbon fuels and various ethanol blends and a butanol blend, plus fuels with added ignition improvers. The hydrocarbon fuels and the butanol blend do not significantly alter the high or the low limits of operation. The HCCI operation appears to be controlled more by the thermal environment than by the fuel properties. For E85, the engine behavior depends on the extent that the heat release from the pilot injected fuel in the NVO period compensates for the evaporative cooling of the fuel.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

The NOx emission and knock characteristics of a PFI engine operating on ethanol/gasoline mixtures were assessed at 1500 and 2000 rpm with λ =1 under Wide-Open-Throttle condition. There was no significant charge cooling due to fuel evaporation. The decrease in NOx emission and exhaust temperature could be explained by the change in adiabatic flame temperature of the mixture. The fuel knock resistance improved significantly with the gasohol so that ignition could be timed at a value much closer or at MBT timing. Changing from 0% to 100% ethanol in the fuel, this combustion phasing improvement led to a 20% increase in NIMEP and 8 percentage points in fuel conversion efficiency at 1500 rpm. At 2000 rpm, where knocking was less severe, the improvement was about half (10% increase in NIMEP and 4 percentage points in fuel conversion efficiency).