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Technical Paper

A Study on Combustion and Emission Characteristics of an Ammonia-Biodiesel Dual-Fuel Engine

2024-04-09
2024-01-2369
Internal combustion engines, as the dominant power source in the transportation sector and the primary contributor to carbon emissions, face both significant challenges and opportunities in the context of achieving carbon neutral goal. Biofuels, such as biodiesel produced from biomass, and zero-carbon fuel ammonia, can serve as alternative fuels for achieving cleaner combustion in internal combustion engines. The dual-fuel combustion of ammonia-biodiesel not only effectively reduces carbon emissions but also exhibits promising combustion performance, offering a favorable avenue for future applications. However, challenges arise in the form of unburned ammonia (NH3) and N2O emissions. This study, based on a ammonia-biodiesel duel-fuel engine modified from a heavy-duty diesel engine, delves into the impact of adjustments in the two-stage injection strategy on the combustion and emission characteristics.
Technical Paper

Cost-Effective D-DPF Design of Aftertreatment System for Non-Road Mobile Machinery China Stage IV

2024-04-09
2024-01-2136
Since Non-Road Mobile Machinery (NRMM) China stage IV legislation has been implemented from 2022, some engines within maximum rated power between 37 to 560 kW are required for gaseous emissions, particulate matter (PM) and particulate number (PN) control, evaluated over testing cycle of Non-Road Transient Cycle (NRTC) and Non-Road Steady Cycle (NRSC). The pollutants from diesel engines, widely used in NRMM applications, can be controlled using aftertreatment systems which are comprised of a diesel oxidation catalyst (DOC) and a diesel particulate filter (DPF), or optionally a selective catalytic reduction (SCR). In this paper, a compact D-DPF design is introduced and discussed on application in harvesters, tractors, and forklifts. Because harvesters have higher exhaust gas temperature than other applications, more passive regeneration behaviors were observed. Subsequently, a compact design of DOC catalyst on DPF (D-DPF) was studied, in other words is to coat DOC catalyst on DPF.
Technical Paper

A Dual-Fuel Model of Flame Initiation and Propagation for Modelling Heavy-Duty Engines with the G-Equation

2023-09-29
2023-32-0009
We propose a novel dual-fuel combustion model for simulating heavy-duty engines with the G-Equation. Dual-Fuel combustion strategies in such engines features direct injection of a high-reactivity fuel into a lean, premixed chamber which has a high resistance to autoignition. Distinct combustion modes are present: the DI fuel auto-ignites following chemical ignition delay after spray vaporization and mixing; a reactive front is formed on its surroundings; it develops into a well-structured turbulent flame, which propagates within the premixed charge. Either direct chemistry or the flame-propagation approach (G- Equation), taken alone, do not produce accurate results. The proposed Dual-Fuel model decides what regions of the combustion chamber should be simulated with either approach, according to the local flame state; and acts as a “kernel” model for the G- Equation model. Direct chemistry is run in the regions where a premixed front is not present.
Technical Paper

Sub-23nm Particle Emissions from China6 Gasoline Vehicles over Various Driving Cycles

2023-04-11
2023-01-0395
Sub-23nm particles emission from the light-duty vehicle is widely discussed now and possible to be counted into the next stage emission legislation, such as Euro7. In this article, 16 China6 gasoline vehicles were tested over the WLTC and two surrogate RDE lab cycles for particulate number (PN) emission, the difference between PN23 (particle size >23nm) and PN10 (particle size>10nm) emission was analyzed. Testing results showed that the average PN10 emission increased 59% compared to PN23, which will bring great challenges for those vehicles to meet the future regulation requirement if sub-23nm particle is counted. The sub-23nm particles emission was proportional to the PN23 particles emission and generated mostly from the cold start or the transient engine conditions with rich combustion. Compared to the proposal of Euro 7, PN10 emission from some tested vehicles will need further two orders of magnitude reduction.
Technical Paper

Calculation Methods Impact on Real-Driving-Emissions Particulate Number Evaluation: Moving Averaging Window in China 6 vs. Raw Mileage Averaging in Euro 6d

2022-03-29
2022-01-0567
RDE test has been introduced to the light-duty vehicle certification process in both China 6 and Euro 6d standards. The RDE test shall be performed on-road with PEMS, which is developed to complement the current laboratory certification of vehicles and ensure cars to deliver low emissions under more realistic on-road driving conditions. Particulate matter has been highly perceived as a significant contributor to human health risks and thus strictly regulated globally. For the RDE evaluation, the MAW method used by the China 6 standard is usually found less stringent than the RMA method used by the Euro 6d standard. In the present study, both of the MAW and RMA methods were applied to different driving cycles and operating conditions, which met the general RDE test requirements, yet resulted in different evaluated PN results.
Technical Paper

Detection of Polar Compounds Condensed on Particulate Matter Using Capillary Electrophoresis-Mass Spectrometry

2020-04-14
2020-01-0395
A new analytical method to aid in the understanding of the organic carbon (OC) phase of particulate matter (PM) from advanced compression ignition (ACI) operating modes, is presented. The presence of NO2 and unburned fuel aromatics in ACI emissions, and the low exhaust temperatures that result from this low temperature combustion strategy, provide the right conditions for the formation of carboxylic acids and nitroaromatic compounds. These polar compounds contribute to OC in the PM and are not typically measured using nonpolar solvent extraction methods such as the soluble organic fraction (SOF) method. The new extraction and detection method employs capillary electrophoresis with electrospray ionization mass spectrometry (CE-ESI MS) and was specifically developed to determine polar organic compounds in the ACI PM emissions. The new method identified both nitrophenols and aromatic carboxylic acids in the ACI PM.
Technical Paper

Characterization of Particulate Matter Emissions from Heavy-Duty Partially Premixed Compression Ignition with Gasoline-Range Fuels

2019-04-02
2019-01-1185
In this study, the compression ratio of a commercial 15L heavy-duty diesel engine was lowered and a split injection strategy was developed to promote partially premixed compression ignition (PPCI) combustion. Various low reactivity gasoline-range fuels were compared with ultra-low-sulfur diesel fuel (ULSD) for steady-state engine performance and emissions. Specially, particulate matter (PM) emissions were examined for their mass, size and number concentrations, and further characterized by organic/elemental carbon analysis, chemical speciation and thermogravimetric analysis. As more fuel-efficient PPCI combustion was promoted, a slight reduction in fuel consumption was observed for all gasoline-range fuels, which also had higher heating values than ULSD. Since mixing-controlled combustion dominated the latter part of the combustion process, hydrocarbon (HC) and carbon monoxide (CO) emissions were only slightly increased with the gasoline-range fuels.
Technical Paper

Ignition Delay in Low Temperature Combustion

2018-04-03
2018-01-1125
Low temperature combustion (LTC) strategies present a means of reducing soot and oxides of nitrogen (NOx) emissions while simultaneously increasing efficiency relative to conventional combustion modes. By sufficiently premixing fuel and air before combustion, LTC strategies avoid high fuel-to-air equivalence ratios that lead to soot production. Dilution of the mixture lowers the combustion temperatures to reduce NOx production and offers thermodynamic advantages for improved efficiency. However, issues such as high heat release rates (HRRs), incomplete combustion, and difficulty in controlling the timing of combustion arise with low equivalence ratios and combustion temperatures. Ignition delay (the time until the start of combustion) is a way to quantify the time available for fuel and air to mix inside the cylinder before combustion. Previous studies have used ignition delay to explain trends seen in LTC such as combustion stability and HRRs.
Technical Paper

Continuous Particulate Filter State of Health Monitoring Using Radio Frequency Sensing

2018-04-03
2018-01-1260
Reliable means for on-board detection of particulate filter failures or malfunctions are needed to meet diagnostics (OBD) requirements. Detecting these failures, which result in tailpipe particulate matter (PM) emissions exceeding the OBD limit, over all operating conditions is challenging. Current approaches employ differential pressure sensors and downstream PM sensors, in combination with particulate filter and engine-out soot models. These conventional monitors typically operate over narrowly-defined time windows and do not provide a direct measure of the filter’s state of health. In contrast, radio frequency (RF) sensors, which transmit a wireless signal through the filter substrate provide a direct means for interrogating the condition of the filter itself.
Journal Article

Characterization of Hydrocarbon Emissions from Gasoline Direct-Injection Compression Ignition Engine Operating on a Higher Reactivity Gasoline Fuel

2017-03-28
2017-01-0747
Low temperature combustion engine technologies are being investigated for high efficiency and low emissions. However, such engine technologies often produce higher engine-out hydrocarbon (HC) and carbon monoxide (CO) emissions, and their operating range is limited by the fuel properties. In this study, two different fuels, a US market gasoline containing 10% ethanol (RON 92 E10) and a higher reactivity gasoline (RON 80 E0), were compared on Delphi’s second generation Gasoline Direct-Injection Compression Ignition (Gen 2.0 GDCI) multi-cylinder engine. The engine was evaluated at three operating points ranging from a light load condition (800 rpm/2 bar IMEPg) to medium load conditions (1500 rpm/6 bar and 2000 rpm/10 bar IMEPg). The engine was equipped with two oxidation catalysts, between which was located the exhaust gas recirculation (EGR) inlet. Samples were taken at engine-out, between the catalysts, and at tailpipe locations.
Technical Paper

Emission Performance of Low Cetane Naphtha as Drop-In Fuel on a Multi-Cylinder Heavy-Duty Diesel Engine and Aftertreatment System

2017-03-28
2017-01-1000
Greenhouse gas regulations and global economic growth are expected to drive a future demand shift towards diesel fuel in the transportation sector. This may create a market opportunity for cost-effective fuels in the light distillate range if they can be burned as efficiently and cleanly as diesel fuel. In this study, the emission performance of a low cetane number, low research octane number naphtha (CN 34, RON 56) was examined on a production 6-cylinder heavy-duty on-highway truck engine and aftertreatment system. Using only production hardware, both the engine-out and tailpipe emissions were examined during the heavy-duty emission testing cycles using naphtha and ultra-low-sulfur diesel (ULSD) fuels. Without any modifications to the hardware and software, the tailpipe emissions were comparable when using either naphtha or ULSD on the heavy duty test cycles.
Journal Article

A Progress Review on Soot Experiments and Modeling in the Engine Combustion Network (ECN)

2016-04-05
2016-01-0734
The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.
Technical Paper

Real-Time Engine and Aftertreatment System Control Using Fast Response Particulate Filter Sensors

2016-04-05
2016-01-0918
Radio frequency (RF)-based sensors provide a direct measure of the particulate filter loading state. In contrast to particulate matter (PM) sensors, which monitor the concentration of PM in the exhaust gas stream for on-board diagnostics purposes, RF sensors have historically been applied to monitor and control the particulate filter regeneration process. This work developed an RF-based particulate filter control system utilizing both conventional and fast response RF sensors, and evaluated the feasibility of applying fast-response RF sensors to provide a real-time measurement of engine-out PM emissions. Testing with a light-duty diesel engine equipped with fast response RF sensors investigated the potential to utilize the particulate filter itself as an engine-out soot sensor.
Journal Article

Effects of Oil Formulation, Oil Separator, and Engine Speed and Load on the Particle Size, Chemistry, and Morphology of Diesel Crankcase Aerosols

2016-04-05
2016-01-0897
The recirculation of gases from the crankcase and valvetrain can potentially lead to the entrainment of lubricant in the form of aerosols or mists. As boost pressures increase, the blow-by flow through both the crankcase and the valve cover increases. The resulting lubricant can then become part of the intake charge, potentially leading to fouling of intake components such as the intercooler and the turbocharger. The entrained aerosol which can contain the lubricant and soot may or may not have the same composition as the bulk lubricant. The complex aerodynamic processes that lead to entrainment can strip out heavy components or volatilize light components. Similarly, the physical size and numbers of aerosol particles can be dependent upon the lubricant formulation and engine speed and load. For instance, high rpm and load may increase not only the flow of gases but the amount of lubricant aerosol.
Journal Article

Applying Advanced CFD Analysis Tools to Study Differences between Start-of-Main and Start-of-Post Injection Flow, Temperature and Chemistry Fields Due to Combustion of Main-Injected Fuel

2015-09-06
2015-24-2436
This paper is part of a larger body of experimental and computational work devoted to studying the role of close-coupled post injections on soot reduction in a heavy-duty optical engine. It is a continuation of an earlier computational paper. The goals of the current work are to develop new CFD analysis tools and methods and apply them to gain a more in depth understanding of the different in-cylinder environments into which fuel from main- and post-injections are injected and to study how the in-cylinder flow, thermal and chemical fields are transformed between start of injection timings. The engine represented in this computational study is a single-cylinder, direct-injection, heavy-duty, low-swirl engine with optical components. It is based on the Cummins N14, has a cylindrical shaped piston bowl and an eight-hole injector that are both centered on the cylinder axis. The fuel used was n-heptane and the engine operating condition was light load at 1200 RPM.
Technical Paper

Measured and Predicted Soot Particle Emissions from Natural Gas Engines

2015-09-06
2015-24-2518
Due to the new challenge of meeting number-based regulations for particulate matter (PM), a numerical and experimental study has been conducted to better understand particulate formation in engines fuelled with compressed natural gas. The study has been conducted on a Heavy-Duty, Euro VI, 4-cylinder, spark ignited engine, with multipoint sequential phased injection and stoichiometric combustion. For the experimental measurements two different instruments were used: a condensation particle counter (CPC) and a fast-response particle size spectrometer (DMS) the latter able also to provide a particle size distribution of the measured particles in the range from 5 to 1000 nm. Experimental measurements in both stationary and transient conditions were carried out. The data using the World Harmonized Transient Cycle (WHTC) were useful to detect which operating conditions lead to high numbers of particles. Then a further transient test was used for a more detailed and deeper analysis.
Journal Article

Numerical Study of RCCI and HCCI Combustion Processes Using Gasoline, Diesel, iso-Butanol and DTBP Cetane Improver

2015-04-14
2015-01-0850
Reactivity Controlled Compression Ignition (RCCI) has been shown to be an attractive concept to achieve clean and high efficiency combustion. RCCI can be realized by applying two fuels with different reactivities, e.g., diesel and gasoline. This motivates the idea of using a single low reactivity fuel and direct injection (DI) of the same fuel blended with a small amount of cetane improver to achieve RCCI combustion. In the current study, numerical investigation was conducted to simulate RCCI and HCCI combustion and emissions with various fuels, including gasoline/diesel, iso-butanol/diesel and iso-butanol/iso-butanol+di-tert-butyl peroxide (DTBP) cetane improver. A reduced Primary Reference Fuel (PRF)-iso-butanol-DTBP mechanism was formulated and coupled with the KIVA computational fluid dynamic (CFD) code to predict the combustion and emissions of these fuels under different operating conditions in a heavy duty diesel engine.
Journal Article

Multi-Dimensional-Modeling-Based Development of a Novel 2-Zone Combustion Chamber Applied to Reactivity Controlled Compression Ignition Combustion

2015-04-14
2015-01-0840
A novel 2-zone combustion chamber concept (patent pending) was developed using multi-dimensional modeling. At minimum volume, an axial projection in the piston divides the volume into distinct zones joined by a communication channel. The projection provides a means to control the mixture formation and combustion phasing within each zone. The novel combustion system was applied to reactivity controlled compression ignition (RCCI) combustion in both light-duty and heavy-duty diesel engines. Results from the study of an 8.8 bar BMEP, 2600 RPM operating condition are presented for the light-duty engine. The results from the heavy-duty engine are at an 18.1 bar BMEP, 1200 RPM operating condition. The effect of several major design features were investigated including the volume split between the inner and outer combustion chamber volumes, the clearance (squish) height, and the top ring land (crevice) volume.
Journal Article

Characterization of Reactivity Controlled Compression Ignition (RCCI) Using Premixed Gasoline and Direct-Injected Gasoline with a Cetane Improver on a Multi-Cylinder Engine

2015-04-14
2015-01-0855
The focus of the present study was to characterize Reactivity Controlled Compression Ignition (RCCI) using a single-fuel approach of gasoline and gasoline mixed with a commercially available cetane improver on a multi-cylinder engine. RCCI was achieved by port-injecting a certification grade 96 research octane gasoline and direct-injecting the same gasoline mixed with various levels of a cetane improver, 2-ethylhexyl nitrate (EHN). The EHN volume percentages investigated in the direct-injected fuel were 10, 5, and 2.5%. The combustion phasing controllability and emissions of the different fueling combinations were characterized at 2300 rpm and 4.2 bar brake mean effective pressure over a variety of parametric investigations including direct injection timing, premixed gasoline percentage, and intake temperature. Comparisons were made to gasoline/diesel RCCI operation on the same engine platform at nominally the same operating condition.
Journal Article

Load Limit Extension in Pre-Mixed Compression Ignition Using a 2-Zone Combustion System

2015-04-14
2015-01-0860
A novel 2-zone combustion system was examined at medium load operation consistent with loads in the light duty vehicle drive cycle (7.6 bar BMEP and 2600 rev/min). Pressure rise rate and noise can limit the part of the engine map where pre-mixed combustion strategies such as HCCI or RCCI can be used. The present 2-zone pistons have an axial projection that divides the near TDC volume into two regions (inner and outer) joined by a narrow communication channel defined by the squish height. Dividing the near TDC volume provides a means to prepare two fuel-air mixtures with different ignition characteristics. Depending on the fuel injection timing, the reactivity of the inner or outer volume can be raised to provide an ignition source for the fuel-air mixture in the other, less reactive volume. Multi-dimensional CFD modeling was used to design the 2-zone piston geometry examined in this study.
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