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Technical Paper

Palladium/Rhodium Dual-Catalyst LEV 2 and Bin 4 Close-Coupled Emission Solutions

2007-04-16
2007-01-1263
Dual-monolith catalyst systems containing Pd/Rh three-way catalysts (TWCs) provide effective emission solutions for LEV2/Bin 5 and Bin 4 close-coupled applications at low PGM loadings. These systems combine washcoat technology and PGM distribution for front and rear catalysts resulting in optimal hydrocarbon and NOx light-off and transient NOx control. The dual-catalyst [Pd/Rh + Pd/Rh] systems are characterized as a function of Pd-Rh content, PGM location, and catalyst technology for 4-cyl [close-coupled + underfloor] systems and 6-cyl close-coupled applications. The current Pd/Rh dual-catalyst converters significantly reduce NOx emissions compared to earlier [Pd + Pt/Rh] or [Pd + Pd/Rh] LEV/ULEV systems by utilizing uniform Rh distribution and new OSC materials. These new design strategies particularly impact NOx performance, especially during transient A/F excursions.
Technical Paper

Comparison between FR-4 and Ceramic Substrate

2008-10-07
2008-36-0361
This paper investigates the application of thick film hybrid circuit technology on ceramic substrate in comparison to the main stream substrate FR-4 (Flame Retardant 4) for PCB implementation. The study is based on computer models for these very substrates in order to simulate the propagation of heat through convection and conduction within the material boundaries. In order to simulate electronic components surface mounted, different heat sources are randomly arranged on physical contact to the surface of the material under investigation. The results emphasize and discern the usage of both substrates and its most suitable environment verifying the application towards vehicular integration. Future study may include experimental analysis for simulated data verification and validation of thick film hybrid circuit technology for the automotive industry.
Technical Paper

Laser Welding: An Exploratory Study towards Continuous Improvement on Stainless Steel Welding Joints

2009-10-06
2009-36-0330
The utilization of Laser welding process has increased during last years in several areas of industry, due to many benefits that can be achieved with this technology, such as: flexibility, productivity and quality. Thus, the optimization of Laser welding processes has been considered as a “green field” to be explored by Laser manufacturers, automation companies and process/project engineers. Nowadays there are few researches that provide a roadmap for Laser welding processes improvement that approaches both the aspects and characteristics applied to evaluate the Laser weld application performance. Therefore, this paper has per its main purpose through an exploratory study to provide parameters toward continuous improvement of Laser welding process considering both types of Lasers: Laser spot weld and Laser seam weld of stainless steel joints, thus this work may be considered as theoretical and practical reference to be applied by people involved with Laser welding applications.
Technical Paper

Fatigue Behavior of Semi-Solid Formed A357-T6 Aluminum

2001-03-05
2001-01-0413
The fundamental relationship between semi-solid processing and microstructure and their effect on the flow characteristics of semi-solid metals have been studied for several years. However, how the process related microstructure influences fatigue properties has not been given the same attention. This study examines the influence of process-related microstructure on the fatigue properties of semi-solid formed A357 alloys. High-solid-fraction (62% solid) and low-solid-fraction (31% and 36% solid) semi-solid formed A357 was tested in axial fatigue with a stress ratio (R) equal to -1. The high solid fraction (HSF) material had better fatigue properties than the low solid fraction (LSF) material. This is attributed to the fatigue crack initiation mechanisms, as related to the fatigue crack initiation features and the strengths of the materials.
Technical Paper

Reliability of Resonant Micromachined Sensors and Actuators

2001-03-05
2001-01-0618
There are an increasing number of applications for resonant micromachines. Accelerometers, angular rate sensors, voltage controlled oscillators, pressure and chemical sensors have been demonstrated using this technology. Several of these devices are employed in vehicles. Vibrating devices have been made from silicon, quartz, GaAs, nickel and aluminum. Resonant microsystems are in constant motion and so present new challenges in the area of reliability for vehicular applications. The impact of temperature extremes, cyclic fatigue, stiction, thermal and mechanical shock on resonant device performance is covered.
Technical Paper

The Solution for Steady State Temperature Distribution in Monolithic Catalytic Converters

2001-03-05
2001-01-0941
This paper presents a simplified thermal model for round catalytic converters in steady state operation. Using this model, the analytic solution for the temperature distribution in the monolithic substrate is obtained. This analytic solution in the substrate is, then, combined with those in the intumescent mat [1] and the metal shell to obtain the temperature profile in the radial direction of the converter except for three unknown temperatures at the three material interfaces, which can be solved using an Excel application program. This analytical temperature solution facilitates the studies of the effects of various design parameters such as the exhaust gas temperature, exhaust gas flow rate, substrate cell geometry, converter dimensions, and ambient temperature and flow, etc.
Technical Paper

Instrument Panel Skin Manufactured with 100% Recycled TPO Material

2002-03-04
2002-01-1262
Desiring to push thermoplastic poly-olefin (TPO) technology to its fullest limits and to confirm our position as the leader in the manufacturing of environmentally friendly TPO instrument panels, we have designed a process to manufacture 100% recycled instrument panel skins. This closed-loop process begins with extruding 100% recycled TPO flake into sheet stock to be painted and vacuum formed. The painted sheet is vacuum formed and the offal is ground into regrind flake, ready to be extruded again, thus completing the closed-loop process. This paper will describe a 100% closed loop recycling process for TPO instrument panels, discuss the intense validation process for recycled material and prove the robustness and durability of this interior solution.
Technical Paper

Impact of Alkali Metals on the Performance and Mechanical Properties of NOx Adsorber Catalysts

2002-03-04
2002-01-0734
Performance of two types of NOx adsorber catalysts, one based on Ba and the other based on Ba with alkali metals, was compared fresh and after thermal aging. Incorporation of sodium(Na), potassium(K) and cesium(Cs) into NOx adsorber washcoat containing barium significantly increases the NOx conversions in the temperature range of 350-600°C over that of the alkali metal free NOx adsorber catalysts. NOx performance benefit and HC performance penalty were observed on both engine dynamometer and vehicle tests for the “Ba+alkali metals” NOx adsorber catalysts. “Ba+alkali metals” NOx adsorber catalysts also demonstrate superior sulfur resistance with better NOx performance after repeated sulfur poisonings and desulfations over the “Ba based” NOx adsorber catalysts.
Technical Paper

Development of an Analytical Tool for Multilayer Stack Assemblies

2011-10-06
2011-28-0083
The development of an analytical model for multilayer stack subjected to temperature change is demonstrated here. Thin continuous layers of materials bonded together deform as a plate due to their differing coefficients of thermal expansion upon subjecting the bonded materials to the change in temperature. Applications of such structures can be found in the electronics industry (the study of warpage issues in printed circuit boards) or in the aerospace industry as (the study of laminated thin sheets used as skin structures for load bearing members such as wings and fuselage). In automotive electronics, critical high-power packages (IGBT, Power FETs) include several layers of widely differing materials (aluminum, solder, copper, ceramics) subjected to wide temperature cyclic ranges. Modeling of such structures by using three-dimensional finite element methods is usually time consuming and may not exactly predict the inter-laminar strains.
Technical Paper

USE OF CFD SIMULATION TO PREDICT CAVITATION IN AUTOMOTIVE HEATER CORES

2005-11-22
2005-01-4027
Several heater cores failed due to erosion by cavitation. After analysis, most of failures were explained by the presence of impurities in the heater core. It was then decided with the customer to use CFD simulation in order to prove that the cavitation was not caused by design concept of the tank. In this paper, we present the results of heater core simulations done in 2D and in 3D with Fluent. The objective is to simulate the pressure and velocity distribution within the heater core and to verify if the zones of low pressure are below the saturation vapour pressure of the fluid causing cavitation. In these areas, the deterioration of the tubes might occur due to erosion by cavitation.
Technical Paper

Use of CFD Simulation to Predict Fan Power and Airflow Pattern Inside the Climatic Chamber

2004-11-16
2004-01-3254
For A/C and cooling systems development is usual send vehicles to US or Europe for wind tunnel tests, witch is expensive and has a long lead-time. Here in Brazil Delphi has at the Piracicaba Technical Center a chamber equipped with temperature control and chassis dynamometer. There is a up-grade project for it that consist in add ducts with fans inside the chamber that will get air from the chamber, already in the right temperature, accelerate and homogenate the air flow and blow it out direct to the front end of the vehicle. For development purposes may be possible eliminate totally the necessity of sending vehicle abroad. It was then decided to use CFD simulation to predict firstly the required fan power necessary to supply winds until 120 km/h at the front end of the vehicle and secondly predict the airflow pattern inside the chamber, considering chamber inlet air, chamber outlet air, exhaust outlet, duct outlet and flow pattern around the vehicle.
Technical Paper

A Study of a Fast Light-Off Planar Oxygen Sensor Application for Exhaust Emissions Reduction

2000-03-06
2000-01-0888
It is well known that hydrocarbon reduction during a cold start is a major issue in achieving ultra low emissions standards. This paper describes one of the possible approaches for reducing the cold-start hydrocarbon emissions by using a fast “light-off” planar oxygen sensor. The goal of this study was to verify the operation characteristics of Delphi's fast “light-off” planar oxygen sensor's (INTELLEK OSP) operating characteristics and the closed-loop performance for achieving improved hydrocarbon control for stringent emission standards. Tests were conducted in open-loop and closed-loop mode under steady and transient conditions using a 1996 model year 2.4-liter DOHC in-line 4-cylinder engine with a close-coupled catalytic converter. Overall performance of the OSP showed relatively quick reaction time to reach the operating temperature.
Technical Paper

Palladium and Platinum/Rhodium Dual-Catalyst Emission Solutions for Close-Coupled or Underfloor Applications

2000-03-06
2000-01-0860
Dual-brick catalyst systems containing Pd-only catalysts followed by Pt/Rh three-way catalysts (TWCs) are effective emission solutions for both close-coupled and underfloor LEV/ULEV applications due to optimal hydrocarbon light-off, NOx control, and balance of precious metal (PGM) usage. Dual-brick [Pd +Pt/Rh] systems on 3.8L V-6 LEV-calibrated vehicles were characterized as a function of PGM loading, catalyst technology, converter volumes, and substrate cell density. While hydrocarbon emissions improve with increasing Pd loading, decreasing the front catalyst volume at constant Pd content (resulting in higher Pd density) improved light-off emissions. Use of 600cpsi substrates improved underfloor NMHC emissions on a 3.8L vehicle by ∼ 6-10mg/mi compared to 400cpsi catalysts, and thus allowing reduction of catalyst volume while achieving ULEV emission levels without air addition.
Technical Paper

An Engine Coolant Temperature Model and Application for Cooling System Diagnosis

2000-03-06
2000-01-0939
A coolant temperature model of an internal combustion engine has been formulated to meet the new On-Board Diagnostics II (OBD II) requirement for coolant temperature rationality. The model utilizes information available within the production Engine Control Module (ECM). The temperature prediction capability has been tested for various “real-world” driving conditions and cycles along with regulated drive cycles. The model can be calibrated to find the appropriate timing for initiation of a diagnostic algorithm for engine cooling system and Coolant Temperature Sensor (CTS) faults. A diagnostic scheme has been developed to detect and isolate various types of cooling system failures using engine soak time information available from a low power timer in the ECM.
Technical Paper

Optimization of Oxygen Sensor

2000-03-06
2000-01-1364
Optimization of the mechanical aspects of a heated conical oxygen sensor for desired performances, such as low heater power, good poison resistance, fast light-off, and broad temperature range, etc. was achieved with computer modeling. CFD analysis was used to model the flow field in and around a sensor in an exhaust pipe to predict the convection coefficients, poisoning, and switching time. Heat transfer analysis coupled with electrical heating was applied to predict temperature and light-off time. Results of the optimization are illustrated, with good agreements between modeling and testing.
Technical Paper

Evaluation of Propulsion Drive System Technologies for Hybrid Vehicles

2000-04-02
2000-01-1532
This paper summarizes the results of an investigation of high risk, high potential technologies for hybrid vehicle drive applications and investigate potential solutions for the technical risk items associated with these technologies. The study consisted of the design, build, and test of different types of electric machines to understand their performance, efficiency, and manufacturability to develop hybrid vehicles with cost and performance similar to the present day IC engine based vehicles, but with lower emissions and better fuel economy. Machine technologies examined include synchronous reluctance, permanent magnet, and switched reluctance. Test data for various machine technologies is presented along with a discussion of the technical risk associated with each technology.
Technical Paper

Evaluation of Corona Reactors of Several Geometries for a Plasma Assisted Nitrogen Oxide Emission Reduction Device

2000-10-16
2000-01-2899
Proposed vehicle emissions regulations for the near future have prompted automotive manufactures and component suppliers to focus heavily on developing more efficient exhaust aftertreatment devices to lower emissions from spark and compression ignition engines. One of the primary pollutants from lean-burn engines, especially from diesels, are oxides of nitrogen (NOx). Current three-way catalytic converters will not have adequate performance to meet future emission reduction requirements. Therefore, there is a need for researchers and engineers to develop efficient exhaust aftertreatment devices that will reduce NOx emissions from lean-burn engines. These devices must have very high conversion of NOx gases, be unaffected by exhaust-gas impurity such as sulfur, and have minimal impact on vehicle operations and fuel economy. An effective technology for NOx control that is currently receiving a lot of attention is a non-thermal plasma system.
Technical Paper

Application of Non-Thermal Plasma Assisted Catalyst Technology for Diesel Engine Emission Reduction

2000-08-21
2000-01-3088
With new legislation and federal regulation for vehicle emission levels, automotive and truck manufacturers have been prompted to focus on emission control technologies that limit the level of exhaust pollutants. One of the primary pollutants, especially from diesel engines, is oxides of nitrogen (NOx). One possible solution to this pollution challenge is to design a more efficient internal combustion engine, which would require better engine operating parameter controls. However, there are limitations associated with such tight engine management. This need has led researchers and engineers to focus on the development of exhaust aftertreatment devices that will reduce NOx emissions with current diesel engines. An optimum aftertreatment device must be unaffected by exhaust-gas impurity poisoning such as sulfur products, and must have minimal impact on vehicle operations and fuel economy.
Technical Paper

Analytical Solution for Heat Flow in Cylinder and Its Application in Calculating Converter Skin Temperature

2000-03-06
2000-01-0301
In the catalytic converter, the thermal conductivity of the insulation material (intumescent mat) placed between the ceramic catalyst and the metal shell is strongly dependent on the temperature, resulting in the solving of non-linear heat conduction equations. In this paper, the analytic solution for the steady heat flow in a cylinder with temperature dependent conductivity is given. Using this analytic solution for the mat and including convection and radiation at the converter skin, an analytical expression for calculating converter skin temperature is obtained. This expression can be easily incorporated in a Fortran code to calculate the temperatures.
Technical Paper

Evaluation of a Non-Thermal Plasma System for Remediation of NOx in Diesel Exhaust

1999-10-25
1999-01-3639
With ever more stringent CO2 emissions mandates, many automobile manufacturers are seeking the fuel economy benefits of diesel and lean-burn gasoline engines. At the same time the emissions standards that diesel and gasoline engines will have to meet in the next decade continue to reduce. Proposed solutions for meeting the stringent emissions standards all appear to have limitations, such as propensities to poisoning from sulfur, narrow operating temperature windows, and requirements for controls that give rapid rich excursions. Non-thermal plasma-catalyst systems have shown good performance in bench testing while being largely unaffected by these same issues. A two-stage system with a unique non-thermal plasma reactor combined with a zeolite-based catalyst has been constructed and shown to work over a wide temperature range.
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