Search Results

Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

This paper focusses on the application of bioalcohols (ethanol and butanol) derived from seaweed in Heavy-Duty (HD) Compression Ignition (CI) combustion engines. Seaweed-based fuels do not claim land and are not in competition with the food chain. Currently, the application of high octane bioalcohols is limited to Spark Ignition (SI) engines. The Reactivity Controlled Compression Ignition (RCCI) combustion concept allows the use of these low carbon fuels in CI engines which have higher efficiencies associated with them than SI engines. This contributes to the reduction of tailpipe CO2 emissions as required by (future) legislation and reducing fuel consumption, i.e. Total-Cost-of-Ownership (TCO). Furthermore, it opens the HD transport market for these low carbon bioalcohol fuels from a novel sustainable biomass source. In this paper, both the production of seaweed-based fuels and the application of these fuels in CI engines is discussed.

Green zones are challenging problems for the thermal management systems of hybrid vehicles. This is because within the green zone the engine is turned off, and the only way to keep the aftertreatment system warm is lost. This means that there is a risk of leaving the green zone with a cold and ineffective aftertreatment system, resulting in high emissions. A thermal management strategy that heats the aftertreatment system prior to turning off the engine, in an optimal way, to reduce the NOx emissions when the engine is restarted, is developed. The strategy is also used to evaluate under what conditions pre-heating is a suitable strategy, by evaluating the performance in simulations using a model of a heavy-duty diesel powertrain and scenario designed for this purpose.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Partially Premixed Combustion has shown the potential of low emissions of nitrogen oxides (NOx) and soot with a simultaneous improvement in fuel efficiency. Several research groups have shown that a load range from idle to full load is possible, when using low-octane-number refinery streams, in the gasoline boiling range. As such refinery streams are not expected to be commercially available on the short term, the use of naphtha blends that are commercially available could provide a practical solution. The three blends used in this investigation have been tested in a single-cylinder engine for their emission and efficiency performance. Besides a presentation of the sensitivity to injection strategies, dilution levels and fuel pressure, emission performance is compared to legislated emission levels. Conventional diesel combustion benchmarks are used for reference to show possible improvements in indicated efficiency.

Partially Premixed Combustion has shown the potential of high efficiency, emissions of nitrogen oxides (NOx) and soot below future emissions regulations, and acceptable acoustic noise. Low-octane-number gasoline fuels were shown to be most suitable for this concept, with the reactivity determining the possible load range. Other researchers have used several refinery streams, which might be produced by a refinery if they were required to do so without additional investment. Some of refinery streams are, however, not expected to be commercially available on the short term. For the present investigation, n-butanol (BuOH) has been selected as a blend component in diesel, and is used from 50 - 100%. The blends then have a reactivity range similar to the refinery streams, so single-cylinder engine tests for their emission and efficiency performance can also be used to determine their applicable load range.

The purpose of the European « SPACE LIGHT » (Whole SPACE combustion for LIGHT duty diesel vehicles) 3-year project launched in 2001 is to research and develop an innovative Homogeneous internal mixture Charged Compression Ignition (HCCI) for passenger cars diesel engine where the combustion process can take place simultaneously in the whole SPACE of the combustion chamber while providing almost no NOx and particulates emissions. This paper presents the whole project with the main R&D tasks necessary to comply with the industrial and technical objectives of the project. The research approach adopted is briefly described. It is then followed by a detailed description of the most recent progress achieved during the tasks recently undertaken. The methodology adopted starts from the research study of the in-cylinder combustion specifications necessary to achieve HCCI combustion from experimental single cylinder engines testing in premixed charged conditions.

In-cylinder visualization, combustion stratification, and engine-out particulate matter (PM) emissions were investigated in an optical engine fueled with Haltermann straight-run naphtha fuel and corresponding surrogate fuel. The combustion mode was transited from homogeneous charge compression ignition (HCCI) to conventional compression ignition (CI) via partially premixed combustion (PPC). Single injection strategy with the change of start of injection (SOI) from early to late injections was employed. The high-speed color camera was used to capture the in-cylinder combustion images. The combustion stratification was analyzed based on the natural luminosity of the combustion images. The regulated emission of unburned hydrocarbon (UHC), carbon monoxide (CO) and nitrogen oxides (NOX) were measured to evaluate the combustion efficiency together with the in-cylinder rate of heat release.

Reactivity controlled compression ignition through in-cylinder blending gasoline and diesel to a desired reactivity has previously been shown to give low emission levels and a clear simultaneous efficiency advantage. To determine the possible viability of the concept for on-road application, the control space of injection parameters with respect to combustion phasing is presented. Four injection strategies have been investigated, and for each the respective combustion phasing response is presented. Combustion efficiency is shown to be greatly affected by both the injection-timing and injection-strategy. All injection strategies are shown to break with the common soot-NOx trade-off, with both smoke and NOx emissions being near or even below upcoming legislated levels. Lastly, pressure rise rates are comparable with conventional combustion regimes with the same phasing. The pressure rise rates are effectively suppressed by the high dilution rates used.

The development of thermally durable zeolite NH3/Urea-SCR formulations coupled with that of high porosity filters substrates has opened the way to integrate PM and NOx control into a single device, namely an SCR-coated Diesel Particulate Filter (SCRF). A few experimental works are already present in the literature regarding SCRF systems, mainly addressing the DeNOx performances of the system (in both presence and absence of soot) under both steady state and transient conditions. The purpose of the present work is to perform a simulation study focused on phenomena which are expected to play key roles in SCRF systems, such as coupling of reaction and diffusion phenomena, soot effect on DeNOx activity, SCR coating effect on soot regeneration and filtration efficiency and competition between soot oxidation and DeNOx processes involving NO2.

Partially premixed compression ignition combustion is one of the low temperature combustion techniques which is being actively investigated. This approach provides a significant reduction of both soot and NOx emissions. Comparing to the homogeneous charge compression ignition mode, PPCI combustion provides better control on ignition timing and noise reduction through air-fuel mixture stratification which lowers heat release rate compared to other advanced combustion modes. In this work, CFD simulations were conducted for a low and a high air-fuel mixture stratification cases on a light-duty optical engine operating in PPCI mode. Such conditions for PRF70 as fuel were experimentally achieved by injection timing and spray targeting at similar thermodynamic conditions.

Post-injection strategies prove to be a valuable option for reducing soot emission, but experimental results often differ from publication to publication. These discrepancies are likely caused by the selected operating conditions and engine hardware in separate studies. Efforts to optimize not only engine-out soot, but simultaneously fuel economy and emissions of nitrogen oxides (NOx) complicate the understanding of post-injection effects even more. Still, the large amount of published work on the topic is gradually forming a consensus. In the current work, a Design-of-Experiments (DoE) procedure and regression analysis are used to investigate the influence of various operating conditions on post-injection scheduling and efficacy. The study targets emission reductions of soot and NOx, as well as fuel economy improvements. Experiments are conducted on a heavy-duty compression ignition engine at three load-speed combinations.

In recent years the automotive industry has been forced to reduce the harmful and pollutant emissions emitted by direct-injected diesel engines. To accomplish this difficult task various solutions have been proposed. One of these proposed solutions is the usage of gaseous fuels in addition to the use of liquid diesel. These gaseous fuels have more gasoline-like properties, such as high octane numbers, and thereby are resistant against auto-ignition. Diesel on the other hand, has a high cetane number which makes it prone to auto-ignition. In this case the gaseous fuel is injected in the inlet manifold, and the diesel is direct injected in the cylinder at the end of the compression stroke. Thereby the diesel fuel spontaneously ignites and acts as an ignition source. The main goals for the use of a dual-fuel operation with diesel and gaseous fuels are the reduction of particulate matter (PM) and nitrogen oxides (NOx) emission.

In this paper, computation fluid dynamics (CFD) simulations are employed to describe the effect of flow parameters on the formation of soot and NOx in a heavy duty engine under low load and high load. The complexity of diesel combustion, specially when soot, NOx and other emissions are of interest, requires using a detailed chemical mechanism to have a correct estimation of temperature and species distribution. In this work, Multiple Representative Interactive Flamelets (MRIF) method is employed to describe the chemical reactions, ignition, flame propagation and emissions in the engine. A phenomenological model for soot formation, including soot nucleation, coagulation and oxidation with O2 and OH is incorporated into the flamelet combustion model. Different strategies for modelling NOx are chosen to take into account the longer time scale for NOx formation. The numerical results are compared with experimental data to show the validity of the model for the cases under study.

The paper illustrates and validates a novel predictive combustion model for the estimation of performances and pollutant production in CI engines. The numerical methodology was developed by the authors for near real-time applications, while aiming at an accurate description of the air mixing process by means of a multi-zone approach of the air-fuel mass. Charge stratification is estimated via a 2D representation of the fuel spray distribution that is numerically derived by an axial one-dimensional control-volume description of the direct injection. The radial coordinate of each control volume is reconstructed a posteriori by means of a local distribution function. Fuel mass clustered in each zone is further split in ‘liquid’, ‘unburnt’ and ‘burnt’ sub-zones, given the local properties of the fuel spray control volumes with respect to space-time location of modelled ignition delay, liquid length, and flame lift-off.

The purpose of the ELEVATE (European Low Emission V4 Automotive Two-stroke Engine) industrial research project is to develop a small, compact, light weight, high torque and highly efficient clean gasoline 2-stroke engine of 120 kW which could industrially replace the relatively big existing automotive spark ignition or diesel 4-stroke engine used in the top of the mid size or in the large size vehicles, including the minivan vehicles used for multi people and family transportation. This new gasoline direct injection engine concept is based on the combined implementation on a 4-stroke bottom end of several 2-stroke engine innovative technologies such as the IAPAC compressed air assisted direct fuel injection, the CAI (Controlled Auto-Ignition) combustion process, the D2SC (Dual Delivery Screw SuperCharger) for both low pressure engine scavenging and higher pressure IAPAC air assisted DI and the ETV (Exhaust charge Trapping Valve).

Oxygen enriched air (EA) is a well known industrial mixture in which the content of oxygen is higher respect the atmospheric one, in the range 22-35%. Oxygen EA can be obtained by desorption from water, taking advantage of the higher oxygen solubility in water compared to the nitrogen one, since the Henry constants of this two gases are different. The production of EA by this new approach was already studied by experimental runs and theoretical considerations. New results using salt water are reported. EA promoted combustion is considered as one of the most interesting technologies to improve the performance in diesel engines and to simultaneously control and reduce pollution. This paper explores, by means of 3-dimensional computational fluid dynamics simulations, the effects of EA on the performance and exhaust emissions of a high-speed direct-injection diesel engine.

The accepted model of conventional diesel combustion [1] assumes a rich premixed flame slightly downstream of the maximum liquid penetration. The soot generated by this rich premixed flame is burnt out by a subsequent diffusion flame at the head of the jet. Even in situations in which the centre of combustion (CA50) is phased optimally to maximize efficiency, slow late stage combustion can still have a significant detrimental impact on thermal efficiency. Data is presented on potential late-stage combustion improvers in a EURO VI compliant HD engine at a range of speed and load points. The operating conditions (e.g. injection timings, EGR levels) were based on a EURO VI calibration which targets 3 g/kWh of engine-out NOx. Rates of heat release were determined from the pressure sensor data. To investigate late stage combustion, focus was made on the position in the cycle at which 90% of the fuel had combusted (CA90). An EN590 compliant fuel was tested.