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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

Diesel engine exhaust aftertreatment components, especially the diesel particulate filter (DPF), are subject to various modes of degradation over their lifetimes. One particular adverse effect on the DPF is the significant rise in pressure drop due to the accumulation of engine lubricant-derived ash which coats the inlet channel walls effectively decreasing the permeability of the filter. The decreased permeability due to ash in the DPF can result in increased filter pressure drop and decreased fuel economy. A unique two-step approach, consisting of experimental measurements and direct numerical simulations using ultra-high resolution 3D imaging data, has been utilized in this study to better understand the effects of ash accumulation on engine aftertreatment component functionality.

For urea Selective Catalytic Reduction (SCR) systems, adaptive control is of interest to provide a capability of maintaining high NOx conversion efficiency and low ammonia slip in the presence of uncertainties in the system. In this paper, the dynamics of the urea SCR system are represented by a control-oriented model which is based on a linear transfer function, with parameters dependent on engine operating conditions. The parameters are identified from input-output data generated by a high fidelity full chemistry model of the urea SCR system. The use of the full chemistry model facilitated the representation of the dynamics of stored ammonia (not a directly measurable parameter) as well as post SCR NOx and ammonia slip. A closed-loop Proportional-plus-Integral (PI) controller was first designed using the estimate of stored ammonia as a feedback signal.

The Engine-Out Particulate Matter (EOPM) was collected from a spark ignition engine operating in steady state using a heated quartz fiber filter. The samples were weighted to obtain an EOPMindex and were analyzed using Scanning Electron Microscopy. The EOP Mindex was not sensitive to the engine rpm and load. When the mixture is very rich (air equivalence ratio λ less than ∼ 0.7), the EOPM comprise mostly of soot particles from fuel combustion. In the lean to slightly rich region (0.8 < λ < 1.2), however, the EOPM are dominated by particles derived from the lubrication oil.

This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.

The presence of liquid fuel inside the engine cylinder is believed to be a strong contributor to the high levels of hydrocarbon emissions from spark ignition (SI) engines during the warm-up period. Quantifying and determining the fate of the liquid fuel that enters the cylinder is the first step in understanding the process of emissions formation. This work uses planar laser induced fluorescence (PLIF) to visualize the liquid fuel present in the cylinder. The fluorescing compounds in indolene, and mixtures of iso-octane with dopants of different boiling points (acetone and 3-pentanone) were used to trace the behavior of different volatility components. Images were taken of three different planes through the engine intersecting the intake valve region. A closed valve fuel injection strategy was used, as this is the strategy most commonly used in practice. Background subtraction and masking were both performed to reduce the effect of any spurious fluorescence.

Computer simulation of extravehicular activity (EVA) is increasingly being used in planning and training for EVA. A space suit model is an important, but often overlooked, component of an EVA simulation. Because of the inherent difficulties in collecting angle and torque data for space suit joints in realistic conditions, little data exists on the torques that a space suit’s wearer must provide in order to move in the space suit. A joint angle and torque database was compiled on the Extravehicular Maneuvering Unit (EMU), with a novel measurement technique that used both human test subjects and an instrumented robot. Using data collected in the experiment, a hysteresis modeling technique was used to predict EMU joint torques from joint angular positions. The hysteresis model was then applied to EVA operations by mapping out the reach and work envelopes for the EMU.

The challenge of developing a robust, real-time driver gaze classification system is that it has to handle difficult edge cases that arise in real-world driving conditions: extreme lighting variations, eyeglass reflections, sunglasses and other occlusions. We propose a single-camera end-toend framework for classifying driver gaze into a discrete set of regions. This framework includes data collection, semi-automated annotation, offline classifier training, and an online real-time image processing pipeline that classifies the gaze region of the driver. We evaluate an implementation of each component on various subsets of a large onroad dataset. The key insight of our work is that robust driver gaze classification in real-world conditions is best approached by leveraging the power of supervised learning to generalize over the edge cases present in large annotated on-road datasets.

Diesel exhaust fluid, DEF, (32.5 wt.% urea aqueous solution) is widely used as the NH3 source for selective catalytic reduction (SCR) of NOx in diesel aftertreatment systems. The transformation of sprayed liquid phase DEF droplets to gas phase NH3 is a complex physical and chemical process. Briefly, it experiences water vaporization, urea thermolysis/decomposition and hydrolysis. Depending on the DEF doser, decomposition reaction tube (DRT) design and operating conditions, incomplete decomposition of injected urea could lead to solid urea deposit formation in the diesel aftertreatment system. The formed deposits could lead to engine back pressure increase and DeNOx performance deterioration etc. The formed urea deposits could be further transformed to chemically more stable substances upon exposure to hot exhaust gas, therefore it is critical to understand this transformation process.

Initial measurements of water vapor temperature using a Fourier domain mode locking (FDML) laser were performed in a carefully controlled homogenous charge compression ignition engine with optical access. The gas temperature was inferred from water absorption spectra that were measured each 0.25 crank angle degrees (CAD) over a range of 150 CAD. Accuracy was tested in a well controlled shock tube experiment. This paper will validate the potential of this FDML laser in combustion applications.

The fuel injection process in the port of a firing 4-valve SI engine at part load and 25°C head temperature was observed by a high speed video camera. Fuel was injected when the valve was closed. The reverse blow-down flow when the intake valve opens has been identified as an important factor in the mixture preparation process because it not only alters the thermal environment of the intake port, but also strip-atomizes the liquid film at the vicinity of the intake valve and carries the droplets away from the engine. In a series of “fuel-on” experiments, the fuel injected in the current cycle was observed to influence the fuel delivery to the engine in the subsequent cycles.

A Lagrangian random vortex-boundary element method has been developed for the simulation of unsteady incompressible flow inside three-dimensional domains with time-dependent boundaries, similar to IC engines. The solution method is entirely grid-free in the fluid domain and eliminates the difficult task of volumetric meshing of the complex engine geometry. Furthermore, due to the Lagrangian evaluation of the convective processes, numerical viscosity is virtually removed; thus permitting the direct simulation of flow at high Reynolds numbers. In this paper, a brief description of the numerical methodology is given, followed by an example of induction flow in an off-centered port-cylinder assembly with a harmonically driven piston and a valve seat situated directly below the port. The predicted flow is shown to resemble the flow visualization results of a laboratory experiment, despite the crude approximation used to represent the geometry.

This paper presents an Axiomatic Design framework for manufacturing system design and illustrates how lean cellular manufacturing can achieve volume flexibility. Axiomatic Design creates a design framework by mapping the functional requirements of a system to specific design parameters. Volume flexibility is often neglected as a requirement of manufacturing systems. Very few industries are fortunate enough to experience stable or predictable product demand. In reality, demand is often volatile and uncertain. It is important that manufacturing system designers are aware of manufacturing system types which can accommodate volume flexibility and follow a structured design methodology that assures that all requirements are met by the system.

Optimal design of modern direct injection spark-ignition engines depends heavily on the characteristics and distribution of the fuel spray. This study was designed to compliment imaging experiments of changes in the spray structure due to fuel volatility and operating conditions. Use of phase-Doppler particle analysis (PDPA) allows quantitative point measurements of droplet diameter and velocity. In agreement with imaging experiments, the results show that the spray structure changes not only with ambient gas density, which is often measured, but also with fuel temperature and volatility. The mean droplet diameter was found to decrease substantially with increasing fuel temperature and decreasing ambient density. Under conditions of low potential for vaporization, the observed trends in mean droplet sizes agree with published correlations for pressure-swirl atomizers.

Optimal design of modern direct injection spark-ignition engines depends heavily on the characteristics and distribution of the fuel spray. This study was designed to investigate changes in the spray properties due to fuel volatility and operating conditions using a firing optically-accessible engine with planar laser-induced fluorescence (PLIF) imaging. The results show that the spray structure changes not only with ambient gas density, which is often measured, but also with fuel temperature and volatility. As ambient pressure decreases and fuel temperature increases, the volatile ends of multi-component fuels evaporate quickly, disrupting the spray structure and producing a vapor core along the axis of the spray. Beyond a certain point, evaporation is rapid enough to expand the initial cone angle of the spray while causing a decrease in the overall spray width.

The Cu-zeolite (CuZ) SCR catalyst enables higher NOx conversion efficiency in part because it can store a significant amount of NH3. “NH3 storage control”, where diesel exhaust fluid (DEF) is dosed in accord with a target NH3 loading, is widely used with CuZ catalysts to achieve very high efficiency. The NH3 loading actually achieved on the catalyst is currently estimated through a stoichiometric calculation. With future high-capacity CuZ catalyst designs, it is likely that the accuracy of this NH3 loading estimate will become limiting for NOx conversion efficiency. Therefore, a direct measurement of NH3 loading is needed; RF sensing enables this. Relative to RF sensing of soot in a DPF (which is in commercial production), RF sensing of NH3 adsorbed on CuZ is more challenging. Therefore, more attention must be paid to the “microwave resonance cavity” created within the SCR assembly. The objective of this study was to develop design guidelines to enable and enhance RF sensing.

Catalytic and non-catalytic engine aftertreatment components, such as the diesel oxidation catalyst (DOC), selective catalytic reduction on filter (SCRF), the gasoline particulate filter (GPF) and the diesel particulate filter (DPF) are complex, multifunctional emissions control technologies that are robustly designed for extended use in harsh automotive exhaust environments. Over the useful component lifetime, lubricant-derived inorganic and incombustible ash accumulates in and/or on the surface of the aforementioned aftertreatment components, resulting in degraded performance and other potential problems. In order to better understand effects of ash in such components, a multiscale analytical approach is necessary, requiring a variety of experimental tools.

Three-piece oil control rings (TPOCR) are widely used in the majority of modern gasoline engines and they are critical for lubricant regulation and friction reduction. Despite their omnipresence, the TPOCRs’ motion and sealing mechanisms are not well studied. With stricter emission standards, gasoline engines are required to maintain lower oil consumption limits, since particulate emissions are strongly correlated with lubricant oil emissions. This piqued our interest in building a numerical model coupling TPOCR dynamics and oil transport to explain the physical mechanisms. In this work, a 2D dynamics model of all three pieces of the ring is built as the main frame. Oil transport in different zones are coupled into the dynamics model. Specifically, two mass-conserved fluid sub-models predict the oil movement between rail liner interface and rail groove clearance to capture the potential oil leakage through TPOCR. The model is applied on a 2D laser induced fluorescence (2D-LIF) engine.

We report on a feasibility study of an optical micro-electro-mechanical systems (MEMS) flow sensor to measure flow rate using Moiré fringe displacement of a floating element. Due to constraints on weight, power, and size for space environmental systems, the development of sensor components that minimize the equivalent systems mass (ESM) while maintaining or exceeding required specifications is highly desirable. A feature of the optical detection method is a physical separation of electrical components from the flow stream. The geometric Moiré fringe shift optically amplifies small displacements by the ratio of the fringe pitch to the movable grating pitch that is detected using an external CCD imager, providing an electrically isolated, robust, direct scheme for detecting flow from shear stress induced displacement.