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Journal Article

Study of On-Board Ammonia (NH3) Generation for SCR Operation

2010-04-12
2010-01-1071
Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.
Journal Article

Safety Assessment of Complex, Software-Intensive Systems

2012-10-22
2012-01-2134
This paper presents a new methodology for the safety assessment of complex software intensive systems such as is envisioned for the coming major upgrade of the air traffic management system known as NextGen. This methodology is based on a new, more inclusive model of accident causation called Systems Theoretic Accident Model and Process (STAMP) [1]. STAMP includes not just the standard component failure mechanisms but also the new ways that software and humans contribute to accidents in complex systems. A new hazard analysis method, called Systems Theoretic Process Analysis (STPA), is built on this theoretical foundation. The STPA is based on systems theory rather than reliability theory; it treats safety as a control problem rather than a failure problem with interactive and possibly nested control loops that may include humans. In this methodology, safety is assured by closed loop control of safety parameters.
Journal Article

NOx Reduction Using a Dual-Stage Catalyst System with Intercooling in Vehicle Gasoline Engines under Real Driving Conditions

2018-04-03
2018-01-0335
Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.
Journal Article

Ash Permeability Determination in the Diesel Particulate Filter from Ultra-High Resolution 3D X-Ray Imaging and Image-Based Direct Numerical Simulations

2017-03-28
2017-01-0927
Diesel engine exhaust aftertreatment components, especially the diesel particulate filter (DPF), are subject to various modes of degradation over their lifetimes. One particular adverse effect on the DPF is the significant rise in pressure drop due to the accumulation of engine lubricant-derived ash which coats the inlet channel walls effectively decreasing the permeability of the filter. The decreased permeability due to ash in the DPF can result in increased filter pressure drop and decreased fuel economy. A unique two-step approach, consisting of experimental measurements and direct numerical simulations using ultra-high resolution 3D imaging data, has been utilized in this study to better understand the effects of ash accumulation on engine aftertreatment component functionality.
Technical Paper

Engine-Out “Dry” Particular Matter Emissions from SI Engines

1997-10-01
972890
The Engine-Out Particulate Matter (EOPM) was collected from a spark ignition engine operating in steady state using a heated quartz fiber filter. The samples were weighted to obtain an EOPMindex and were analyzed using Scanning Electron Microscopy. The EOP Mindex was not sensitive to the engine rpm and load. When the mixture is very rich (air equivalence ratio λ less than ∼ 0.7), the EOPM comprise mostly of soot particles from fuel combustion. In the lean to slightly rich region (0.8 < λ < 1.2), however, the EOPM are dominated by particles derived from the lubrication oil.
Technical Paper

The Effects of Sulfated Ash, Phosphorus and Sulfur on Diesel Aftertreatment Systems - A Review

2007-07-23
2007-01-1922
This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.
Technical Paper

Liquid Fuel Visualization Using Laser-Induced Fluoresence During Cold Start

1998-10-19
982466
The presence of liquid fuel inside the engine cylinder is believed to be a strong contributor to the high levels of hydrocarbon emissions from spark ignition (SI) engines during the warm-up period. Quantifying and determining the fate of the liquid fuel that enters the cylinder is the first step in understanding the process of emissions formation. This work uses planar laser induced fluorescence (PLIF) to visualize the liquid fuel present in the cylinder. The fluorescing compounds in indolene, and mixtures of iso-octane with dopants of different boiling points (acetone and 3-pentanone) were used to trace the behavior of different volatility components. Images were taken of three different planes through the engine intersecting the intake valve region. A closed valve fuel injection strategy was used, as this is the strategy most commonly used in practice. Background subtraction and masking were both performed to reduce the effect of any spurious fluorescence.
Technical Paper

Anthropometric and Blood Flow Characteristics Leading to EVA Hand Injury

2009-07-12
2009-01-2471
The aim of this study was to explore if fingernail delamination injury following EMU glove use may be caused by compression-induced blood flow occlusion in the finger. During compression tests, finger blood flow decreased more than 60%, however this occurred more rapidly for finger pad compression (4 N) than for fingertips (10 N). A pressure bulb compression test resulted in 50% and 45% decreased blood flow at 100 mmHg and 200 mmHg, respectively. These results indicate that the finger pad pressure required to articulate stiff gloves is more likely to contribute to injury than the fingertip pressure associated with tight fitting gloves.
Technical Paper

Crashworthiness of Thin Ultra-light Stainless Steel Sandwich Sheets: From the Design of Core Materials to Structural Applications

2004-03-08
2004-01-0886
Thin sandwich sheets hold a promise for widespread use in automotive industry due to their good crash and formability properties. In this paper, thin stainless steel sandwich sheets with low-density core materials are investigated with regard to their performance in crashworthiness applications. The total thickness of the sandwich materials is about 1.2mm: 0.2mm thick facings and a 0.8mm thick sandwich core. Throughout the crushing of prismatic sandwich profiles, the sandwich facings are bent and stretched while the sandwich core is crushed under shear loading. Thus, a high shear crushing strength of the sandwich core material is beneficial for the overall energy absorption of the sandwich profile. It is shown theoretically that the weight specific shear crushing strength of hexagonal metallic honeycombs is higher than the one of fiber cores - irrespective of their relative density or microstructural geometry.
Technical Paper

Requirements and Potential for Enhanced EVA Information Interfaces

2003-07-07
2003-01-2413
NASA has long recognized the advantages of providing improved information interfaces to EVA astronauts and has pursued this goal through a number of development programs over the past decade. None of these activities or parallel efforts in industry and academia has so far resulted in the development of an operational system to replace or augment the current extravehicular mobility unit (EMU) Display and Controls Module (DCM) display and cuff checklist. Recent advances in display, communications, and information processing technologies offer exciting new opportunities for EVA information interfaces that can better serve the needs of a variety of NASA missions. Hamilton Sundstrand Space Systems International (HSSSI) has been collaborating with Simon Fraser University and others on the NASA Haughton Mars Project and with researchers at the Massachusetts Institute of Technology (MIT), Boeing, and Symbol Technologies in investigating these possibilities.
Technical Paper

Modeling Space Suit Mobility: Applications to Design and Operations

2001-07-09
2001-01-2162
Computer simulation of extravehicular activity (EVA) is increasingly being used in planning and training for EVA. A space suit model is an important, but often overlooked, component of an EVA simulation. Because of the inherent difficulties in collecting angle and torque data for space suit joints in realistic conditions, little data exists on the torques that a space suit’s wearer must provide in order to move in the space suit. A joint angle and torque database was compiled on the Extravehicular Maneuvering Unit (EMU), with a novel measurement technique that used both human test subjects and an instrumented robot. Using data collected in the experiment, a hysteresis modeling technique was used to predict EMU joint torques from joint angular positions. The hysteresis model was then applied to EVA operations by mapping out the reach and work envelopes for the EMU.
Technical Paper

A Framework for Robust Driver Gaze Classification

2016-04-05
2016-01-1426
The challenge of developing a robust, real-time driver gaze classification system is that it has to handle difficult edge cases that arise in real-world driving conditions: extreme lighting variations, eyeglass reflections, sunglasses and other occlusions. We propose a single-camera end-toend framework for classifying driver gaze into a discrete set of regions. This framework includes data collection, semi-automated annotation, offline classifier training, and an online real-time image processing pipeline that classifies the gaze region of the driver. We evaluate an implementation of each component on various subsets of a large onroad dataset. The key insight of our work is that robust driver gaze classification in real-world conditions is best approached by leveraging the power of supervised learning to generalize over the edge cases present in large annotated on-road datasets.
Technical Paper

Lab Study of Urea Deposit Formation and Chemical Transformation Process of Diesel Aftertreatment System

2017-03-28
2017-01-0915
Diesel exhaust fluid, DEF, (32.5 wt.% urea aqueous solution) is widely used as the NH3 source for selective catalytic reduction (SCR) of NOx in diesel aftertreatment systems. The transformation of sprayed liquid phase DEF droplets to gas phase NH3 is a complex physical and chemical process. Briefly, it experiences water vaporization, urea thermolysis/decomposition and hydrolysis. Depending on the DEF doser, decomposition reaction tube (DRT) design and operating conditions, incomplete decomposition of injected urea could lead to solid urea deposit formation in the diesel aftertreatment system. The formed deposits could lead to engine back pressure increase and DeNOx performance deterioration etc. The formed urea deposits could be further transformed to chemically more stable substances upon exposure to hot exhaust gas, therefore it is critical to understand this transformation process.
Technical Paper

Aggregate Vehicle Emission Estimates for Evaluating Control Strategies

1994-03-01
940303
Currently, states that are out of compliance with the National Ambient Air Quality Standards must, according to the Clean Air Act Amendments of 1990 (CAAA), develop and implement control strategies that demonstrate specific degrees of reduction in emissions-with the degree of reduction depending upon the severity of the problem. One tool that has been developed to aid regulators in both deciding an appropriate course of action and to demonstrate the desired reductions in mobile emissions is EPA's Mobile 5a emission estimation model. In our study, Mobile 5a has been used to examine the effects of regulatory strategies, as applied to the Northeast United States, on vehicle emissions under worst-case ozone-forming conditions.
Technical Paper

Novel Experiment on In-Cylinder Desorption of Fuel from the Oil Layer

1994-10-01
941963
A technique has been developed to measure the desorption and subsequent oxidation of fuel in the oil layer by spiking the oil with liquid fuel and firing the engine on gaseous fuel or motoring with air. Experiments suggest that fuel desorption is not diffusion limited above 50 °C and indicated that approximately two to four percent of the cylinder oil layer is fresh oil from the sump. The increase in hydrocarbon emissions is of the order of 100 ppmC1 per 1% liquid fuel introduced into the fresh oil in a methane fired engine at mid-speed and light load conditions. Calculations indicate that fuel desorbing from oil is much more likely to produce hydrocarbon emissions than fuel emerging from crevices.
Technical Paper

Visualization of Mixture Preparation in a Port-Fuel Injection Engine During Engine Warm-up

1995-10-01
952481
The fuel injection process in the port of a firing 4-valve SI engine at part load and 25°C head temperature was observed by a high speed video camera. Fuel was injected when the valve was closed. The reverse blow-down flow when the intake valve opens has been identified as an important factor in the mixture preparation process because it not only alters the thermal environment of the intake port, but also strip-atomizes the liquid film at the vicinity of the intake valve and carries the droplets away from the engine. In a series of “fuel-on” experiments, the fuel injected in the current cycle was observed to influence the fuel delivery to the engine in the subsequent cycles.
Technical Paper

3D Vortex Simulation of Intake Flow in a Port-Cylinder with a Valve Seat and a Moving Piston

1996-05-01
961195
A Lagrangian random vortex-boundary element method has been developed for the simulation of unsteady incompressible flow inside three-dimensional domains with time-dependent boundaries, similar to IC engines. The solution method is entirely grid-free in the fluid domain and eliminates the difficult task of volumetric meshing of the complex engine geometry. Furthermore, due to the Lagrangian evaluation of the convective processes, numerical viscosity is virtually removed; thus permitting the direct simulation of flow at high Reynolds numbers. In this paper, a brief description of the numerical methodology is given, followed by an example of induction flow in an off-centered port-cylinder assembly with a harmonically driven piston and a valve seat situated directly below the port. The predicted flow is shown to resemble the flow visualization results of a laboratory experiment, despite the crude approximation used to represent the geometry.
Technical Paper

Implications of Contingency Planning Support for Weather and Icing Information

2003-06-16
2003-01-2089
A human-centered systems analysis was applied to the adverse aircraft weather encounter problem in order to identify desirable functions of weather and icing information. The importance of contingency planning was identified as emerging from a system safety design methodology as well as from results of other aviation decision-making studies. The relationship between contingency planning support and information on regions clear of adverse weather was investigated in a scenario-based analysis. A rapid prototype example of the key elements in the depiction of icing conditions was developed in a case study, and the implications for the components of the icing information system were articulated.
Technical Paper

Design of Manufacturing Systems to Support Volume Flexibility

1999-05-10
1999-01-1621
This paper presents an Axiomatic Design framework for manufacturing system design and illustrates how lean cellular manufacturing can achieve volume flexibility. Axiomatic Design creates a design framework by mapping the functional requirements of a system to specific design parameters. Volume flexibility is often neglected as a requirement of manufacturing systems. Very few industries are fortunate enough to experience stable or predictable product demand. In reality, demand is often volatile and uncertain. It is important that manufacturing system designers are aware of manufacturing system types which can accommodate volume flexibility and follow a structured design methodology that assures that all requirements are met by the system.
Technical Paper

Effects of Fuel Volatility and Operating Conditions on Fuel Sprays in DISI Engines: (2) PDPA Investigation

2000-03-06
2000-01-0536
Optimal design of modern direct injection spark-ignition engines depends heavily on the characteristics and distribution of the fuel spray. This study was designed to compliment imaging experiments of changes in the spray structure due to fuel volatility and operating conditions. Use of phase-Doppler particle analysis (PDPA) allows quantitative point measurements of droplet diameter and velocity. In agreement with imaging experiments, the results show that the spray structure changes not only with ambient gas density, which is often measured, but also with fuel temperature and volatility. The mean droplet diameter was found to decrease substantially with increasing fuel temperature and decreasing ambient density. Under conditions of low potential for vaporization, the observed trends in mean droplet sizes agree with published correlations for pressure-swirl atomizers.
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