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Journal Article

Speciated Engine-Out Organic Gas Emissions from a PFI-SI Engine Operating on Ethanol/Gasoline Mixtures

2009-11-02
2009-01-2673
Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.
Journal Article

Assessment of Gasoline Direct Injection Engine Cold Start Particulate Emission Sources

2017-03-28
2017-01-0795
The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.
Journal Article

Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends

2011-04-12
2011-01-1305
The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.
Technical Paper

Spot Friction Welding of Aluminum to Steel

2007-04-16
2007-01-1703
Spot friction welding (SFW) is a cost-effective spot joining technology for aluminum sheets compared with resistance spot welding (RSW) [1]. In this study, coated mild steel was spot friction welded to 6000 series aluminum using a tool with shoulder diameter of 10 mm and welding conditions of 1500-2000 rpm and time of 5 s. Testing showed that tensile shear strength increased as the solidus temperature of the coating on the steel decreased. Microstructure characterizations of steel/Al joint interfaces showed that zinc from the coatings was incorporated into the stir nuggets and that intermetallic phases may have formed but not in continuous layers. Some Al-Zn oxides that appeared to be amorphous were also found in the joint interfaces.
Technical Paper

Characterization of Structural, Volume and Pressure Components to Space Suit Joint Rigidity

2009-07-12
2009-01-2535
Gas-pressurized space suits are highly resistive to astronaut movement, and this resistance has been previously explained by volume and/or structural effects. This study proposed that an additional effect, pressure effects due to compressing/expanding the internal gas during joint articulation, also inhibits mobility. EMU elbow torque components were quantified through hypobaric testing. Structural effects dominated at low joint angles, and volume effects were found to be the primary torque component at higher angles. Pressure effects were found to be significant only at high joint angles (increased flexion), contributing up to 8.8% of the total torque. These effects are predicted to increase for larger, multi-axis joints. An active regulator system was developed to mitigate pressure effects, and was found to be capable of mitigating repeated pressure spikes caused by volume changes.
Technical Paper

Alcohol Fueled Heavy Duty Vehicles Using Clean, High Efficiency Engines

2010-10-25
2010-01-2199
Non-petroleum based liquid fuels are essential for reducing oil dependence and greenhouse gas generation. Increased substitution of alcohol fuel for petroleum based fuels could be achieved by 1) use in high efficiency spark ignition engines that are employed for heavy duty as well as light duty operation and 2) use of methanol as well as ethanol. Methanol is the liquid fuel that is most efficiently produced from thermo-chemical gasification of coal, natural gas, waste or biomass. Ethanol can also be produced by this process but at lower efficiency and higher cost. Coal derived methanol is in limited initial use as a transportation fuel in China. Methanol could potentially be produced from natural gas at an economically competitive fuel costs, and with essentially the same greenhouse gas impact as gasoline. Waste derived methanol could also be an affordable low carbon fuel.
Technical Paper

Inverse Method for Measuring Weld Temperatures during Resistance Spot Welding

2001-03-05
2001-01-0437
A new monitoring system predicts the progression of welding temperature fields during resistance spot welding. The system captures welding voltages and currents to predict contact diameters and simulate temperature fields. The system accurately predicts fusion lines and heat-affected zones. Accuracy holds even for electrode tips used for a few thousand welds of zinc coated steels.
Technical Paper

An Analysis of Ambient Air Entrainment into Split Injection D.I. Gasoline Spray by LIF-PIV Technique

2002-10-21
2002-01-2662
Effects of split injection, with a relatively short time interval between the two sprays, on the spray development process, and the air entrainment into the spray, were investigated by using laser induced fluorescence and particle image velocimetry (LIF-PIV) techniques. The velocities of the spray and the ambient air were measured. The cumulative mass of the ambient air entrained into the spray was calculated by using the entrainment velocity normal to the spray boundary. The vortex structure of the spray, formed around the leading edge of the spray, showed a true rotating flow motion at low ambient pressures of 0.1 MPa, whereas at 0.4 MPa, it was not a true rotating flow, but a phenomenon of the small droplets separating from the leading edge of the spray and falling behind, due to air resistance. The development processes of the 2nd spray were considerably different from that of the 1st spray because the 2nd spray was injected into the flow fields formed by the 1st spray.
Technical Paper

Unsteady-Wake Analysis of the Aerodynamic Drag of a Notchback Model with Critical Afterbody Geometry

1992-02-01
920202
For both notchback-type and fastback-type models, it has been found that critical geometries which increase the aerodynamic drag exist, and the time-averaged wake patterns basically consist of an arch vortex behind the rear window and trailing vortices in the wake. The unsteady characteristics of the wake seem to be directly related to aerodynamic drag. However, the unsteady characteristics of these wake patterns for notchback and fastback cars were not clear. The purpose of present paper is to clarify these phenomena. We try to analyze experimentally the unsteady characteristics by measuring the velocity fluctuations in the wake, the pressure fluctuations on the trunk deck and the drag-force fluctuations acting on the model. At the same time, the analysis of the numerical simulation was made by using the same numerical model as the experimental model. The computed flow visualization behind the rear window showed a fluctuating arch vortex.
Technical Paper

Application of Vibration Damping Steel Sheet for Autobody Structural Parts

1992-02-01
920249
As a demand for vehicles of higher functionality grows, automakers and material suppliers are devoting increasing efforts to develop technologies for greater safety, lighter weight, higher corrosion resistance, and enhanced quietness. The resin-sandwiched vibration damping steel sheet (VDSS), developed as a highly functional material for reducing vehicle vibration and noise, has been used for oil pans1) and compartment partitions2). First applied for a structural dash panel of the new Mazda 929, a Zn-Ni electroplated VDSS which allows direct electric welding has contributed to greater weight reduction as well as improved quietness.
Technical Paper

Using Mass Spectrometry to Detect Ethanol and Acetaldehyde Emissions from a Direct Injection Spark Ignition Engine Operating on Ethanol/Gasoline Blends

2011-04-12
2011-01-1159
Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.
Technical Paper

Fuel Effects on HCCI Operation in a Spark Assisted Direct Injection Gasoline Engine

2011-08-30
2011-01-1763
The fuel effects on HCCI operation in a spark assisted direct injection gasoline engine are assessed. The low load limit has been extended with a pilot fuel injection during the negative valve overlap (NVO) period. The fuel matrix consists of hydrocarbon fuels and various ethanol blends and a butanol blend, plus fuels with added ignition improvers. The hydrocarbon fuels and the butanol blend do not significantly alter the high or the low limits of operation. The HCCI operation appears to be controlled more by the thermal environment than by the fuel properties. For E85, the engine behavior depends on the extent that the heat release from the pilot injected fuel in the NVO period compensates for the evaporative cooling of the fuel.
Technical Paper

Real World Performance of an Onboard Gasoline/Ethanol Separation System to Enable Knock Suppression Using an Octane-On-Demand Fuel System

2018-04-03
2018-01-0879
Higher compression ratio and turbocharging, with engine downsizing can enable significant gains in fuel economy but require engine operating conditions that cause engine knock under high load. Engine knock can be avoided by supplying higher-octane fuel under such high load conditions. This study builds on previous MIT papers investigating Octane-On-Demand (OOD) to enable a higher efficiency, higher-boost higher compression-ratio engine. The high-octane fuel for OOD can be obtained through On-Board-Separation (OBS) of alcohol blended gasoline. Fuel from the primary fuel tank filled with commercially available gasoline that contains 10% by volume ethanol (E10) is separated by an organic membrane pervaporation process that produces a 30 to 90% ethanol fuel blend for use when high octane is needed. In addition to previous work, this paper combines modeling of the OBS system with passenger car and medium-duty truck fuel consumption and octane requirements for various driving cycles.
Technical Paper

Fuel Spray Combustion of Waste Cooking Oil and Palm Oil Biodiesel: Direct Photography and Detailed Chemical Kinetics

2013-10-14
2013-01-2554
This paper studies the ignition processes of two biodiesel from two different feedstock sources, namely waste cooked oil (WCO) and palm oil (PO). They were investigated using the direct photography through high-speed video observations and detailed chemical kinetics. The detailed chemical kinetics modeling was carried out to complement data acquired using the high-speed video observations. For the high-speed video observations, an image intensifier combined with OH* filter connected to a high-speed video camera was used to obtain OH* chemiluminscence image near 313 nm. The OH* images were used to obtain the experimental ignition delay of the biodiesel fuels. For the high-speed video observations, experiments were done at an injection pressure of 100, 200 and 300 MPa using a 0.16 mm injector nozzle.
Technical Paper

Development of Simultaneous Zinc Phosphating Process for Aluminum and Steel Plates

1993-11-01
931936
A method was studied for simultaneous zinc phosphating on aluminum and steel surfaces to obtain high corrosion resistance on aluminum surfaces, which conventional phosphatic processing could not provide with sufficient corrosion resistance. Since aluminum is protected by an oxide film on its surface, it has poor processability with zinc phosphating solutions applied to steel. An appropriate quantity of fluoride was therefore added to improve processing, and the coating film, aluminum composition and surface conditions were optimized to suppress filiform corrosion, which is characterized by string-like blisters of paint film starting from a paint defect. In addition, in view of the actual production environment, the corrosion resistance of the ground area made for readjustment after stamping was studied for the optimization of the processing solution.
Technical Paper

The Corrosion Resistance of Organic Composite-Coated Steel Sheets

1993-10-01
932365
In order to investigate the corrosion resistance of organic composite-coated steel sheets ( OCS ) in a real automotive environment, many kinds of corrosion tests were performed on test pieces and real automotive doors. Tests with a corrosive solution including iron rust were introduced to simulate the real corrosive environment of automotive doors. The relationship between the components of OCS and the corrosion resistance in the rust-including tests was examined. In addition, electrochemical studies were performed. Results indicate OCS has much better corrosion resistance than plated steel sheets with heavier coating weight in all tests. OCS shows excellent corrosion resistance in rust-free corrosive solution, however, some types of OCS do have corrosion concerns in rust-including tests. It became clear that these OCS types have an organic coating with lower cross-linking.
Technical Paper

An Experimental Investigation on Air-Fuel Mixture Formation Inside a Low-Pressure Direct Injection Stratified Charge Rotary Engine

1993-03-01
930678
Stratified charge engines have been getting attention for the drastic improvement in thermal efficiency at low-load region. There have been researchers on the two types of engines-the high pressure direct injection stratified charge type in which fuel is supplied directly at high pressure into its combustion chamber right before ignition timings, and the low pressure direct injection stratified charge type in which fuel is injected directly into its cylinder while the cylinder pressure is comparatively low[ 1- 3]. Rotary engines have higher freedom than reciprocating engines in terms of equipping direct fuel injection devices, since their combustion chambers rotate along the rotor housing. The fuel supply units, therefore, need not be exposed to high temperature combustion gas.
Technical Paper

Autoignition of Alcohols and Ethers in a Rapid Compression Machine

1993-10-01
932755
The autoignition characteristics of methanol, ethanol and MTBE (methyl tert-butyl ether) have been investigated in a rapid compression machine at pressures in the range 20-40 atm and temperatures within 750-1000 K. All three oxygenated fuels tested show higher autoignition temperatures than paraffins, a trend consistent with the high octane number of these fuels. The autoignition delay time for methanol was slightly lower than predicted values using reported reaction mechanisms. However, the experimental and measured values for the activation energy are in very good agreement around 44 kcal/mol. The measured activation energy for ethanol autoignition is in good agreement with previous shock tube results (31 kcal/mol), although ignition times predicted by the shock tube correlation are a factor of three lower than the measured values. The measured activation energy for MTBE, 41.4 kcal/mol, was significantly higher than the value previously observed in shock tubes (28.1 kcal/mol).
Technical Paper

Flame Kernel Development in a Methanol Fueled Engine

1993-10-01
932649
The combustion behavior in a modem 4-valve engine using a broad range of methanol/gasoline fuel mixtures was studied. The initial flame development was examined by using a spark plug fiber optics probe. Approximately, the kernel expansion speed, Sg, is relatively unchanged from M0 to M40; jumps by ∼30% from M40 to M60; and then remains roughly constant from M60 to M100. Statistics of the IMEP indicate that at a lean idle condition the combustion rate and robustness correlate with Sg: a higher value of Sg gives better combustion. Thus M60-M100 fuels give better idle combustion behavior than the M0-M40 fuels.
Technical Paper

Chemical Kinetic Modeling of the Oxidation of Unburned Hydrocarbons

1992-10-01
922235
The chemistry of unburned hydrocarbon oxidation in SI engine exhaust was modeled as a function of temperature and concentration of unburned gas for lean and rich mixtures. Detailed chemical kinetic mechanisms were used to model isothermal reactions of unburned fuel/air mixture in an environment of burned gases at atmospheric pressure. Simulations were performed using five pure fuels (methane, ethane, propane, n-butane and toluene) for which chemical kinetic mechanisms and steady state hydrocarbon (HC) emissions data were available. A correlation is seen between reaction rates and HC emissions for different fuels. Calculated relative amounts of intermediate oxidation products are shown to be consistent with experimental measurements.
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