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Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

The effects of cooled exhaust gas recirculation (EGR) on a boosted direct-injection (DI) spark ignition (SI) engine operating at stoichiometric equivalence ratio, gross indicated mean effective pressure of 14-18 bar, and speed of 1500-2500 rpm, are studied under constant fuel condition at each operating point. In the presence of EGR, burn durations are longer and combustion is more retard. At the same combustion phasing, the indicated specific fuel consumption improves because of a decrease in heat loss and an increase in the specific heat ratio. The knock limited spark advance increases substantially with EGR. This increase is due partly to a slower combustion which is equivalent to a spark retard, as manifested by a retarded value of the 50% burn point (CA50), and due partly to a slower ignition chemistry of the diluted charge, as manifested by the knock limited spark advance to beyond the value offered by the retarded CA50.

In order to understand better the operation of spark-ignition engines during the warm-up period, a computer model had been developed which simulates the thermal processes of the engine. This model is based on lumped thermal capacitance methods for the major engine components, as well as the exhaust system. Coolant and oil flows, and their respective heat transfer rates are modeled, as well as friction heat generation relations. Piston-liner heat transfer is calculated based on a thermal resistance method, which includes the effects of piston and ring material and design, oil film thickness, and piston-liner crevice. Piston/liner crevice changes are calculated based on thermal expansion rates and are used in conjunction with a crevice-region unburned hydrocarbon model to predict the contribution to emissions from this source.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

This article reports on the potential of negative valve overlap (NVO) for improving the net indicated thermal efficiency (η NIMEP) of gasoline engines during part load. Three fixed fuel flow rates, resulting in indicated mean effective pressures of up to 6 bar, were investigated. At low load, NVO significantly reduces the pumping loses during the gas exchange loop, achieving up to 7% improvement in indicated efficiency compared to the baseline. Similar efficiency improvements are achieved by positive valve overlap (PVO), with the disadvantage of worse combustion stability from a higher residual gas fraction (xr). As the load increases, achieving the wide-open throttle limit, the benefits of NVO for reducing the pumping losses diminish, while the blowdown losses from early exhaust valve opening (EVO) increase.

A dynamometer-mounted four-cylinder Saturn engine was used to accumulate combustion chamber deposits (CCD), using an additized fuel. During each deposit accumulation test, the HC emissions were continuously measured. The deposit thickness at the center of the piston was measured at the beginning of each day. After the 50 and 35-hour tests, HC emissions were measured with isooctane, benzene, toluene, and xylene, with the deposited engine, and again after the deposits had been cleaned from the engine. The HC emissions showed a rapid rise in the first 10 to 15 hours and stabilization after about 25 hours of deposit accumulation. The HC increase due to CCD accumulation accounted for 10 to 20% of the total engine-out HC emissions from the deposit build-up fuel and 10 to 30% from benzene, isooctane, toluene, and xylene, making CCDs a significant HC emissions source from this engine. The HC emissions stabilized long before the deposit thickness.

A research program designed to measure the contribution from fuel absorption in the thin layer of oil, lubricating the cylinder liner, to the total and speciated HC emissions from a spark ignition engine has been performed. The logic of the experiment design was to test the oil layer mechanism via variations in the oil layer thickness (through the lubricant formulations), solubility of the fuel components in the lubricants, and variations in the crankcase gas phase HC concentration (through crankcase purging). A set of preliminary experiments were carried out to determine the solubility and diffusivity of the fuel components in the individual lubricants. Engine tests showed similar HC emissions among the tested lubricants. No consistent increase was observed with oil viscosity (oil film thickness), contrary to what would be expected if fuel-oil absorption was contributing significantly to engine-out HC. Similarly, no effect of crankcase purging could be observed.

The impact of market-fuel variations on the HCCI operating range was measured in a 2.3L four-cylinder engine, modified for single-cylinder operation. HCCI combustion was achieved through the use of residual trapping. Variable cam phasing was used to maximize the load range at each speed. Test fuels were blended to cover the range of variation in select commercial fuel properties. Within experimental measurement error, there was no change in the low-load limit among the test fuels. At the high-load limit, some small fuel effects on the operating range were observed; however, the observed trends were not consistent across all the speeds studied.

This paper presents the emission characteristics of a HCCI engine operation using n-heptane. The experiments were conducted in a single cylinder Co-operative Fuel Research (CFR) engine equipped with an air-assist port fuel injector. The effects of intake temperature, air/fuel ratio, compression ratio, turbo-charging, and EGR rate on exhaust emissions were explored. The analysis of the exhaust gases included oxides of nitrogen (NOx), nitrous oxide (N2O), carbon monoxide (CO), total hydrocarbon (THC), and soot. The hydrocarbon species present in exhaust gases and their concentrations at several operating conditions were also characterized. The strategies to obtain low HC, CO and NOx emissions are presented and discussed. The approaches to effectively retard HCCI combustion phase without deteriorating combustion efficiency are examined. It was found that HCCI combustion produces extremely low soot and NOx emissions.

Gasoline-electric hybrid vehicle technology has been gaining widespread acceptance and has the potential to reduce emissions through reduced fuel consumption. In this study, particulate matter number and mass emission rates, organic and elemental carbon compositions, and number-based size distributions were measured from four gasoline-electric hybrid vehicles (2005 Ford Escape Hybrid, 2004 Toyota Prius, 2003 Honda Civic Hybrid, and 2000 Honda Insight). In addition, one small conventional gasoline vehicle (2002 SmartCar) was tested. The vehicles were driven over five driving cycles and at steady-state speeds of 40 and 80 km/h. Each test was performed at 20°C and at -18°C. Testing took place at the Environmental Science & Technology Centre of Environment Canada using conventional chassis dynamometer procedures. Average distance based emission rates are given for each vehicle under each test condition.

Fuel consumption and gaseous emission data (CO, NOx, THC, and CO2) are reported for four commercially available gasoline-electric hybrid vehicles and one conventional gasoline vehicle tested on a chassis dynamometer over five transient driving cycles (LA4, LA92, HWFET, NYCC, US06), and two steady state modes (40 and 80 km/h), at two ambient temperatures (20 °C, and -18 °C). All vehicles exhibited higher fuel consumption during transient cycles compared to steady-state modes. Cold ambient temperature had a more detrimental effect on fuel consumption rates of the hybrid vehicles compared to those of the conventional gasoline vehicle.

Experiments were carried out to collect in-cylinder pressure data and microphone signals from a single-cylinder test engine using spark timingsbefore, at, and after knock onset for toluene reference fuels. The objective was to gain insight into the phenomena that determine knock onset, detected by an external microphone. In particular, the study examines how the end-gas autoignition process changes as the engine's spark timing is advanced through the borderline knock limit into the engine's knocking regime. Fast Fourier transforms (FFT) and bandpass filtering techniques were used to process the recorded cylinder pressure data to determine knock intensities for each cycle. Two characteristic pressure oscillation frequencies were detected: a peak just above 6 kHz and a range of peaks in the 15-22 kHz range. The microphone data shows that the audible knock signal has the same 6 kHz peak.

This paper reports the results of a fuel economy and regulated emissions survey of 15 gasoline powered generators. Tests were conducted at Environment Canada's Emission Research and Measurement Division (ERMD) facilities in Ottawa. The generators ranged in output capacity from 0.9kW to 7.0kW maximum rated output (MRO). They were obtained from a variety of sources including commercial rental companies and from other Environment Canada Divisions. The generators were operated on summer grade commercial fuel over a 6 mode test cycle when possible. The testing was designed to mimic the certification test the engines would undergo in an engine dynamometer test configuration with the exception that the loading was simulated by a load bank connected to the generators electrical output(s).

This paper assesses the potential improvement of automotive powertrain technologies 25 years into the future. The powertrain types assessed include naturally-aspirated gasoline engines, turbocharged gasoline engines, diesel engines, gasoline-electric hybrids, and various advanced transmissions. Advancements in aerodynamics, vehicle weight reduction and tire rolling friction are also taken into account. The objective of the comparison is the potential of anticipated improvements in these powertrain technologies for reducing petroleum consumption and greenhouse gas emissions at the same level of performance as current vehicles in the U.S.A. The fuel consumption and performance of future vehicles was estimated using a combination of scaling laws and detailed vehicle simulations. The results indicate that there is significant potential for reduction of fuel consumption for all the powertrains examined.

PGBA, a plant growth facility developed for commercial space biotechnology research, successfully grew a total of 50 plants (6 species) during 10 days aboard the Space Shuttle Endeavor (STS-77), and has reflown aboard the Space Shuttle Columbia (STS-83 for 4 days and STS-94 for 16 days) with 55 plants and 10 species. The PGBA life support system provides atmospheric, thermal, and humidity control as well as lighting and nutrient supply in a 33 liter microgravity plant growth chamber. The atmosphere treatment system removes ethylene and other hydrocarbons, actively controls CO2 replenishment, and provides passive O2 control. Temperature and humidity are actively controlled.

The presence of liquid fuel inside the engine cylinder is believed to be a strong contributor to the high levels of hydrocarbon emissions from spark ignition (SI) engines during the warm-up period. Quantifying and determining the fate of the liquid fuel that enters the cylinder is the first step in understanding the process of emissions formation. This work uses planar laser induced fluorescence (PLIF) to visualize the liquid fuel present in the cylinder. The fluorescing compounds in indolene, and mixtures of iso-octane with dopants of different boiling points (acetone and 3-pentanone) were used to trace the behavior of different volatility components. Images were taken of three different planes through the engine intersecting the intake valve region. A closed valve fuel injection strategy was used, as this is the strategy most commonly used in practice. Background subtraction and masking were both performed to reduce the effect of any spurious fluorescence.