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This study was aimed at experimentally investigating the impact of diesel/natural gas (NG) dual-fuel retrofitting onto gaseous emissions emitted by i) legacy, model year (MY) 2005 heavy-duty engines with cooled EGR and no after-treatment system, and ii) a latest technology engine equipped with DPF and urea-SCR after-treatment systems that is compliant with 2010 US-EPA emissions standards. In particular, two different dual-fuel conversion kits were evaluated in this study with pure methane (CH4) being used as surrogate for natural gas. Experiments were conducted on an engine dynamometer over a 13-mode steady-state test cycle as well as the transient FTP required for engine certification while gaseous emissions were sampled through a CVS system. Tailpipe NOx emissions were observed at a comparable level for diesel and diesel/CH4 dual-fuel operation for the 2010 compliant engine downstream the SCR.

This paper discusses the design and qualification of a High Temperature Sampling System (HTSS), capable of stripping the volatile fraction from a sample flow stream in order to provide for quantification of total, solid and volatile particulate matter (PM) on a near real-time basis. The sampling system, which incorporates a heated diesel oxidation catalyst, is designed for temperatures up to 450°C. The design accounts for molecular diffusion of volatile compounds, solid particles diffusion and reaction kinetics inside one channel of the oxidation catalyst. An overall solid particle loss study in the sampling was performed, and numerical results were compared with experimental data gathered at the West Virginia University Engine and Emissions Research Laboratory (EERL) and West Virginia University's Transportable Heavy-Duty Vehicle Emissions Testing Laboratory (THDVETL).

Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.

In the present study, a bench-flow reactor is used to perform lean/rich thermal cycling on model “Ba+K” LNT catalysts at temperatures of 700, 800, 900 and 1000°C using simulated diesel exhaust gases. Deterioration of NOx performance is measured and the deactivation mechanisms of thermally-aged “Ba+K” LNTs are identified using characterization techniques such as TEM, XRD and EPMA. Results indicate that the deterioration is minimal at 700 and 800°C, however, at aging temperatures exceeding 800°C the severity of thermal aging depends on aging temperature as well as number of aging cycles.

Biodiesel fuels benefit both from being a renewable energy source and from decreasing in carbon monoxide (CO), total hydrocarbons (THC), and particulate matter (PM) emissions relative to petroleum diesel. The oxides of nitrogen (NOx) emissions from biodiesel blended fuels reported in the literature vary relative to baseline diesel NOx, with no NOx change or a NOx decrease found by some to an increase in NOx found by others. To explore differences in NOx, two Cummins ISM engines (1999 and 2004) were operated on 20% biodiesel blends during the heavy-duty transient FTP cycle and the steady state Supplemental Emissions Test. For the 2004 Cummins ISM engine, in-cylinder pressure data were collected during the steady state and transient tests. Three types of biodiesel fuels were used in the blends: soy, tallow (animal fat), and cottonseed. The FTP integrated emissions of the B20 blends produced a 20-35% reduction in PM and no change or up to a 4.3% increase in NOx over the neat diesel.

New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these vehicles was for street collection and transporting the collected refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines.

For engine operations involving low load conditions for an extended amount of time, the exhaust temperature may be lower than that necessary to initiate the urea hydrolyzation. This would necessitate that the controller interrupt the urea supply to prevent catalyst fouling by products of ammonia decomposition. Therefore, it is necessary for the engine controller to have multiple calibrations available in regions of engine operation where the aftertreatment does not perform well, so that optimal exhaust conditions are guaranteed during the wide variety of engine operations. In this study the test engine was equipped with a catalyzed diesel particulate filter (DPF) and a selective catalytic reduction system (SCR), and programmed with two different engine calibrations, namely the low-NOx and the low fuel consumption (low-FC).

Dual primary full-flow dilution tunnels represent an integral part of a heavy-duty transportable emissions measurement laboratory designed and constructed to comply with US Code of Federal Regulations (CFR) 40 Part 1065 requirements. Few data exist to characterize the evolution of particulate matter (PM) in full scale dilution tunnels, particularly at very low PM mass levels. Size distributions of ultra-fine particles in diesel exhaust from a naturally aspirated, 2.4 liter, 40 kW ISUZU C240 diesel engine equipped with a diesel particulate filter (DPF) were studied in one set of standard primary and secondary dilution tunnels with varied dilution ratios. Particle size distribution data, during steady-state engine operation, were collected using a Cambustion DMS500 Fast Particulate Spectrometer. Measurements were made at four positions that spanned the tunnel cross section after the mixing orifice plate for the primary dilution tunnel and at the outlet of the secondary dilution tunnel.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

Greenhouse gas regulations and global economic growth are expected to drive a future demand shift towards diesel fuel in the transportation sector. This may create a market opportunity for cost-effective fuels in the light distillate range if they can be burned as efficiently and cleanly as diesel fuel. In this study, the emission performance of a low cetane number, low research octane number naphtha (CN 34, RON 56) was examined on a production 6-cylinder heavy-duty on-highway truck engine and aftertreatment system. Using only production hardware, both the engine-out and tailpipe emissions were examined during the heavy-duty emission testing cycles using naphtha and ultra-low-sulfur diesel (ULSD) fuels. Without any modifications to the hardware and software, the tailpipe emissions were comparable when using either naphtha or ULSD on the heavy duty test cycles.

Due to increasingly stringent emissions regulations, Lean NOx Trap (LNT) catalysts are being researched as a potential solution for diesel engine emissions reduction. LNTs are practical for diesel NOx reduction due to their ability to reduce NOx from the O2 rich environment produced by diesel engines. LNTs function by storing NOx on the catalyst surface during efficient lean operation then, under rich conditions, releasing and reducing the trapped NOx. One method of producing this rich environment which regenerates a LNT involves manipulating the fuel injection parameters and throttling the air intake. This process is called in-cylinder regeneration. Experiments will be described here in which a 1.7 L common rail diesel engine has been used to regenerate LNTs at various stages of sulfur exposure, a known poison of the LNT.

We utilize physically-based models for diesel exhaust catalytic oxidation and urea-based selective catalytic NOx reduction to study their impact on drive cycle performance of hypothetical light-duty diesel-powered hybrid and plug-in hybrid vehicles (HEVs and PHEVs). The models have been implemented as highly flexible SIMULINK block modules that can be used to study multiple engine-aftertreatment system configurations. The parameters of the NOx reduction model have been adjusted to reflect the characteristics of commercially available Cu-zeolite catalysts, which are of widespread current interest. We demonstrate application of these models using the Powertrain System Analysis Toolkit (PSAT) software for vehicle simulations, along with a previously published methodology that accounts for emissions and temperature transients in the engine exhaust.

Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. Using an accelerated aging procedure, a set of production exhaust systems from a 2011 Ford F250 equipped with a 6.7L diesel engine have been aged to an equivalent of 150,000 miles of thermal aging and metal exposure. These exhaust systems included a diesel oxidation catalyst (DOC), selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ULSD containing no measureable metals, B20 containing sodium, B20 containing potassium and B20 containing calcium. Metals levels were selected to simulate the maximum allowable levels in B100 according to the ASTM D6751 standard. Analysis of the aged catalysts included Federal Test Procedure emissions testing with the systems installed on a Ford F250 pickup, bench flow reactor testing of catalyst cores, and electron probe microanalysis (EPMA).

Thermal conductivity detection has long been used in gas chromatography to detect hydrogen and other diatomic gases in a gas sample. Thermal conductivity instruments that are not coupled to gas chromatographs are useful for detecting hydrogen in binary gas mixtures, but suffer from significant cross-interference from other gas species that are separated when the detector is used with a gas chromatograph. This study reports a method for using a commercially-available thermal conductivity instrument to detect and quantify hydrogen in a diesel exhaust stream. The instrument time response of approximately 40 seconds is sufficient for steady-state applications. Cross-interference from relevant gas species are quantified and discussed. Measurement uncertainty associated with the corrections for the various species is estimated and practical implications for use of the instrument and method are discussed.

Beginning 2007, heavy-duty engine certification would require that in-use emissions from vehicles be measured under ‘real-world’ operating conditions using on-board measurement devices. An on-board portable emissions measurement system called Mobile Emissions Measurement System (MEMS) was developed at West Virginia University (WVU) to record in-use, continuous and brake-specific emissions from heavy-duty diesel-powered vehicles. The objective of this paper is to present a preliminary development of a test data quality assurance methodology for emissions measured using the any portable emissions measurement system (PEMS). The first stage of the methodology requires ensuring the proper operation of the different sensors and transducers during data collection. The second stage is data synchronization and pre-processing. The next stage is systematic checking of possible errors from transducers and sensors.

Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).

Phosphorous in diesel exhaust is derived via engine oil consumption from the zinc dialkyldithiophosphate (ZDDP) oil additive used for engine wear control. Phosphorous present in the engine exhaust can react with an exhaust catalyst and cause loss of performance through masking or chemical reaction. The primary effect is loss of light-off or low temperature performance. Although the amount of ZDDP used in lube oil is being reduced, it appears that there may is a minimum level of ZDDP needed for engine durability. One of the ways of reducing the effects of the resulting phosphorous on catalysts might be to alter the chemical state of the phosphorous to a less damaging form or to develop catalysts which are more resistant to phosphorous poisoning. In this study, lube oil containing ZDDP was added at an accelerated rate through a variety of engine pathways to simulate various types of engine wear or oil disposal practices.

A fleet of six 2001 International Class 6 trucks operating in southern California was selected for an operability and emissions study using gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (CDPF). Three vehicles were fueled with CARB specification diesel fuel and no emission control devices (current technology), and three vehicles were fueled with GTL fuel and retrofit with Johnson Matthey's CCRT™ diesel particulate filter. No engine modifications were made. Bench scale fuel-engine compatibility testing showed the GTL fuel had cold flow properties suitable for year-round use in southern California and was additized to meet current lubricity standards. Bench scale elastomer compatibility testing returned results similar to those of CARB specification diesel fuel. The GTL fuel met or exceeded ASTM D975 fuel properties. Researchers used a chassis dynamometer to test emissions over the City Suburban Heavy Vehicle Route (CSHVR) and New York City Bus (NYCB) cycles.

As interest has grown in diesel emissions and diesel engine aftertreatment, so has the importance of analyzing all components of the exhaust. One of the more costly and difficult measurements to make is the collection and analysis of semivolatile organic compounds (SOCs) in the exhaust. These compounds include alkane and alkenes from C12-C24, and the 2-5 ring polycyclic aromatic hydrocarbons (PAH). These compounds can be present in both the particulate (i.e. on the filter) and gaseous phase, and cannot be collected with bag samples. Typically, a sorbent is used downstream of the particulate collection filters to collect these compounds. Sorbent phases include polyurethane foam (PUF), Tenax™, XAD-type resins, and activated carbon. The SOCs are removed from the sorbent either by solvent extraction (PUF and XAD) or thermal desorption (Tenax™ and activated carbon). Each of these methods have advantages and disadvantages.