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Journal Article

Hydrocarbon Permeation in Gasoline Vehicle Fuel Systems Using Isobutanol Blends

2012-09-10
2012-01-1582
In the past decade, a significant market has emerged for automotive fuels produced from renewable sources. Blends containing low concentrations of ethanol have been the readily-available choice for providing renewable content in gasoline fuels. The simple addition of ethanol to gasoline significantly increases the mixture's vapor pressure, which can promote higher vehicle evaporative emissions. Gasoline specifications and blending practices have been updated to help offset the increase to vapor pressure and evaporative emissions. However, recent studies have shown that even at reduced vapor pressure, ethanol can increase gasoline evaporative emissions by enhancing the permeation of hydrocarbons through the elastomeric materials found in vehicle fuel systems. Technology is currently in development that will allow for the production of isobutanol from renewable sources.
Technical Paper

The Effect of Hydrocarbon Composition on Lean NOx Catalysis

1997-10-01
973000
The effect of pre-catalyst speciation on lean NOx catalysis was investigated using a chemically defined fuel matrix. Nine model fuels and a diesel fuel were injected into the exhaust stream of a medium duty diesel engine prior to a DeNOx catalyst. NOx conversions ranged from 9% at a mid speed and load test point to 43% at a higher load test point. On an absolute basis, model fuels produced up to 34% greater NOx conversions relative to diesel. Speciation revealed that, compared with low temperature test points, cracking and oxidation at peak torque significantly modified the auxiliary HC input to the catalyst. The quantity of ‘cracked’ derivatives of the auxiliary fuel, namely alkene and carbonyl species, correlated well with NOx conversions.
Technical Paper

Particle Measurement Programme (PMP):Particle Size and Number Emissions Before, During and After Regeneration Events of a Euro 4 DPF Equipped Light-Duty Diesel Vehicle.

2007-07-23
2007-01-1944
By early 2007, all major manufacturers of light-duty diesel vehicles are marketing models equipped with diesel particulate filters (DPFs). However, there is still a lack of understanding of the particles emitted when the DPF undergoes regeneration. This paper focuses on measuring particle emissions of a representative light-duty diesel vehicle equipped with DPF and employing a fuel-borne catalyst (FBC) to aid regeneration. Particulate Matter (PM) and non-volatile particle number emissions are measured throughout testing according to the Particle Measurement Programme (PMP) proposals. In addition, an Engine Exhaust Particle Sizer (EEPS) connected directly to the CVS is used to give real time size distributions of both volatile and non-volatile particles. The paper focuses on particle emissions during regenerating New European Driving Cycles (NEDCs).
Technical Paper

The Effect of Diesel Fuel Properties on Engine-out Emissions and Fuel Efficiency at Mid-Load Conditions

2009-11-02
2009-01-2697
The influence of various diesel fuel properties on the steady state emissions and performance of a Cummins light-duty (ISB) engine modified for single cylinder operation has been studied at the mid-load “cruise” operating condition. Designed experiments involving independent manipulation of both fuel properties and engine control parameters have been used to build statistical engine response models. The models were then applied to optimize for the minimum fuel consumption subject to specific constraints on emissions and mechanical limits and also to estimate the optimum engine control parameter settings and fuel properties. The study reveals that under the high EGR, diffusion-burn dominated conditions encountered during the experiments, NOx is impacted by cetane number and the distillation characteristics. Lower T50 (mid-distillation temperature) resulted in simultaneous reductions in both NOx and smoke, and higher cetane number provided an additional small NOx benefit.
Technical Paper

Emission Reductions and Operational Experiences With Heavy Duty Diesel Fleet Vehicles Retrofitted with Continuously Regenerated Diesel Particulate Filters in Southern California

2001-03-05
2001-01-0512
Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.
Technical Paper

An Investigation Into the Effect of a Diesel/Water Emulsion on the Size and Number Distribution of the Particulate Emissions from a Heavy-Duty Diesel Engine

2003-10-27
2003-01-3168
The current test programmes have measured emissions from a heavy-duty bus engine installed on a test bench and also on a chassis dynamometer whilst running on a Diesel/water emulsion fuel. Testing was carried out over both steady state and transient test cycles. Emissions were also measured on the test bed from the engine fitted with both a Diesel particulate filter and an oxidation catalyst. Alongside the measurement of the regulated emissions, particle number distributions (by size) and total particle counts were also measured. Size selected particle counts were made over the transient tests and are compared between engine test and chassis dynamometer. This paper demonstrates the influence of the emulsion on the particle size distribution, the effects of after-treatment and lubricant on the particle size emissions of an engine running on an emulsion and also the influence of sampling conditions on the measurements recorded.
Technical Paper

The Effect of Sulphur-Free Diesel Fuel on the Measurement of the Number and Size Distribution of Particles Emitted from a Heavy-Duty Diesel Engine Equipped with a Catalysed Particulate Filter

2003-10-27
2003-01-3167
Following concern about the association between adverse health effects and ambient particulate concentrations, there are now an increasing number of heavy-duty Diesel engines fitted with catalysed particulate filters. These filters virtually eliminate carbon particle emissions but there is some evidence suggesting a potential to form a cloud of secondary nucleation particles post trap. This event occurs at high temperature operating conditions and is produced mainly from the increased sulphate production over the catalyst. This paper investigates the measurement of particle emissions from a heavy-duty engine operating over the European legislated cycle, both with and without a filter fitted and investigates how emissions are affected by the use of a sulphur-free Diesel fuel. The work also demonstrates a contribution to the measured nucleation particles from material desorbed not only from the trap, but also from the exhaust system.
Technical Paper

Characterisation of the Soot Formation Processes in a High Pressure Combusting Diesel Fuel Spray

2003-10-27
2003-01-3086
As part of an ongoing investigation, the influence of In Cylinder Pressure (ICP) and fuel injection pressure on the soot formation processes in a diesel fuel spray were studied. The work was performed using a rapid compression machine at ambient conditions representative of a modern High Speed Direct Injection diesel engine, and with fuel injection more representative of full load. Future tests will aim to consider the effects of pilot injections and EGR rates. The qualitative soot concentration was determined using the Laser Induced Incandescence (LII) technique both spatially and temporally at a range of test conditions. Peak soot concentration values were determined, from which a good correlation between soot concentration and injection pressure was observed. The peak soot concentration was found to correlate well with the velocity of the injected fuel jet.
Technical Paper

The Emissions Performance of Oxygenated Diesel Fuels in a Prototype DI Diesel Engine

2001-03-05
2001-01-0650
As part of a cooperative development program, six diesel fuels (a reference and five blends containing oxygenates) were evaluated under four steady-state conditions using a prototype 1.26-L 3-cylinder four-valve common-rail DI diesel engine. All of the fuels contained low sulfur (mostly < 5 ppm by mass), and they were chosen to determine the impacts of oxygenate volatility, concentration, and chemical type (paraffinic or aromatic) on exhaust emissions - with particular emphasis on particulate emissions. In addition to HC, CO, NOx and PM emissions measurements, emissions of the volatile portion of the PM and particle size were determined. Relative to the very low sulfur reference fuel, the oxygenated fuels reduced PM and NOx under some operating conditions, but produced little effect on either HC or CO emissions. Aliphatic oxygenates at 6 wt. percent oxygen in the reference fuel reduced simulated FTP PM emissions by 15 - 27 %.
Technical Paper

Emissions Performance of Pure Vegetable Oil in Two European Light Duty Vehicles

2004-06-08
2004-01-1881
This programme involved the testing of two Euro II compliant diesel vehicles over the current European legislated drive cycle. The aim of the programme was to determine and compare the emissions of 100% virgin vegetable oil (VVO100) and a baseline UK marketplace Ultra Low Sulphur (ULSD) diesel fuel. A splash blend of 5% rapeseed methyl ester in ULSD (RME5) was also evaluated. Results of tests on RME5 showed that generally the effects on emissions compared to ULSD were small for regulated and most unregulated emissions. There was some evidence of a PM10 benefit for RME5 fuel. VVO100 showed large increases in HC (up to 250%) and CO emissions in both vehicles, as well as increases in polycyclic aromatic hydrocarbons (PAH), compared to ULSD. Effects on NOx and particulate were vehicle - specific.
Technical Paper

DETR/SMMT/CONCAWE Particulate Research Programme: Light Duty Results

2001-09-24
2001-01-3577
The DETR/SMMT/CONCAWE Particulate Research Programme was designed to investigate the effects of vehicle/engine technology level, fuel specification and various operating conditions on emissions of particle mass, number and size. Results from the heavy duty part of the programme and details of the measuring protocols have already been published. This paper gives the results of the light duty study. This consisted of six vehicles and eight fuels covering gasoline, Diesel and LPG technologies. These six vehicles represented Euro II (1996) and Euro III (2000) technologies. Diesel fuels included EN590 (1996), EN590 (2000), UK ultra low sulphur Diesel (UK ULSD) and Swedish Class I Diesel, while gasoline fuels comprised EN228 (1996), EN228 (1999) and UK ultra low sulphur gasoline (UK ULSG).
Technical Paper

Chemical Speciation of Exhaust Emissions from Trucks and Buses Fueled on Ultra-Low Sulfur Diesel and CNG

2002-03-04
2002-01-0432
A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.
Technical Paper

Speciation of Organic Compounds from the Exhaust of Trucks and Buses: Effect of Fuel and After-Treatment on Vehicle Emission Profiles

2002-10-21
2002-01-2873
A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).
Technical Paper

Impact of Engine Operating Conditions on Low-NOx Emissions in a Light-Duty CIDI Engine Using Advanced Fuels

2002-10-21
2002-01-2884
The control of NOx emissions is the greatest technical challenge in meeting future emission regulations for diesel engines. In this work, a modal analysis was performed for developing an engine control strategy to take advantage of fuel properties to minimize engine-out NOx emissions. This work focused on the use of EGR to reduce NOx while counteracting anticipated PM increases by using oxygenated fuels. A DaimlerChrysler OM611 CIDI engine for light-duty vehicles was controlled with a SwRI Rapid Prototyping Electronic Control System. Engine mapping consisted of sweeping parameters of greatest NOx impact, starting with OEM injection timing (including pilot injection) and EGR. The engine control strategy consisted of increased EGR and simultaneous modulation of both main and pilot injection timing to minimize NOx and PM emission indexes with constraints based on the impact of the modulation on BSFC, Smoke, Boost and BSHC.
Technical Paper

Development Experience of a Poppet-Valved Two-Stroke Flagship Engine

1992-02-01
920778
The gasoline-fuelled direct injection poppet-valved two-stroke engine described in (1) has been built in single cylinder form and tested to evaluate the potential of this concept as a passenger car powerplant. Development of the combustion and scavenge system is described. Following development, the engine produced a specific power output of 90 kW/litre at 5000 rev/min, with a peak torque of 200 Nm/litre at 2000-2500 rev/min. HC emissions were maintained in the range 3-15 g/kWh over the majority of the engine operating range and NOx emissions in the load range used in the FTP drive cycle were less than 3 g/kWh. Part load fuel consumption under steady state conditions was 8% lower than for a stoichiometric four-stroke engine sized for equal power output.
Technical Paper

Advanced Diesel Technology to Achieve Tier 2 Bin 5 Emissions Compliance in US Light-Duty Diesel Applications

2006-04-03
2006-01-1145
Future growth of the US light-duty diesel market is highly dependent on achieving cost effective and robust emissions solutions. For this reason, ACTION (Advanced Combustion Technology to Improve engine-Out NOx) is being developed by Ricardo. This research is delivering reduced emissions through the application of Highly Premixed Cool Combustion (HPCC). NOx reduction is primarily achieved through the reduction of charge oxygen concentration, accomplished by reducing air/fuel ratio and increasing exhaust gas recirculation. This approach coupled with enhanced combustion system efficiency delivers a practical approach to meet future emissions compliance while minimizing aftertreatment requirement. The paper will examine key engine technology developments to deliver US Tier 2 Bin 5 emissions in Light Duty Diesel applications. In particular, Bin 5 emissions compliance will be possible in passenger car applications.
Technical Paper

The Effect of Gasoline Composition on Stoichiometry and Exhaust Emissions

1994-10-01
941868
Six full range gasolines were tested in two engines (one with a catalyst) operated at 4 steady states. Engine-out regulated emissions responded to equivalence ratio, Φ, in the accepted manner. For both CO and NOx, there was a characteristic, single emissions response to changes in Φ. Changing fuel composition will primarily alter the production of these emissions by modifying the stoichiometric air/fuel ratio, projecting engine operation onto another part of the Φ response curve. These Φ effects, which are independent of engine design, also determine how operating conditions affect engine-out CO and NOx. Speciated hydrocarbon measurements at engine-out and tail-pipe confirm results seen in previous test-cycle based programmes.
Technical Paper

Evaluation of a Low Emissions Concept on a 50cc 2-Stroke Scooter Engine

1995-09-01
951783
A preliminary test bed evaluation of a potentially simple and low cost stratified charging concept is presented for small capacity 2-stroke scooter engines. The end development objectives of the concept are to reduce engine out hydrocarbon emissions and to improve fuel economy while providing engine fuelling by a simple carburettor type fuel metering device. Such a concept, when combined with a catalyst, could achieve significant vehicle emissions reductions with potentially improved catalyst durability. The results presented in this paper, from a preliminary test bed evaluation of the stratified charging concept using electronic fuel injection to provide the fuelling, have shown that engine out hydrocarbon emissions can be effectively reduced at medium to high load without a loss in wide open throttle torque.
Technical Paper

Optimising Engine Performance and Emissions Using Bayesian Techniques

1997-05-01
971612
Research and development (R&D) programmes to optimise engine performance and emissions involve a large number of experimental variables and the optimum solution will normally be a trade-off between several measured responses (e.g. fuel consumption, exhaust emissions and combustion noise). The increasing number of experimental variables and the search for smaller improvements make identification of optimum configurations and robust solutions more demanding. Empirical models are routinely used to explore the trade-offs and identify the optimum engine hardware build and parameter settings. The use of Bayesian methods enables prior engineering knowledge to be explicitly incorporated into the model generation process, which allows useful models to be developed at an earlier stage in the test programme. It also enables a sequential approach to experimental design to be adopted in which the ultimate engineering objectives can be more effectively taken into account.
Technical Paper

Fuel and Lubricant Effects on Nucleation Mode Particle Emissions From a Euro III Light Duty Diesel Vehicle

2004-06-08
2004-01-1989
The impact of lubricant sulphur and phosphorus levels on the formation of nucleation mode particles was explored in a light duty diesel vehicle operating over the New European Drive Cycle (NEDC). All measurements were undertaken using a Scanning Mobility Particle Sizer (SMPS), sampling from a conventional Constant Volume Sampler (CVS) system. Rigorous sampling system and vehicle conditioning procedures were applied to eliminate oil carry-over and nanoparticle artifact formation. An initial vehicle selection process was undertaken on vehicles representing three fuel injection strategies, namely; distributor pump, common rail and unit injector. The vehicles met Euro III specifications and were all equipped with oxidation catalysts. Idle and low load stability were key requirements, since these conditions are the most significant in terms of their propensity to generate nucleation mode particles.
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