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A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.

Mobile source emissions standards are becoming more stringent and particulate emissions from gasoline direct injection (GDI) engines represent a particular challenge. Gasoline particulate filter (GPF) is deemed as one possible technical solution for particulate emissions reduction. In this work, a study was conducted on eight formulations of lubricants to determine their effect on GDI engine particulate emissions and GPF performance. Accelerated ash loading tests were conducted on a 2.4L GDI engine with engine oil injection in gasoline fuel by 2%. The matrix of eight formulations was designed with changing levels of sulfated ash (SASH) level, Zinc dialkyldithiophosphates (ZDDP) level and detergent type. Comprehensive evaluations of particulates included mass, number, size distribution, composition, morphology and soot oxidation properties. GPF performance was assessed through filtration efficiency, back pressure and morphology.

This experimental work focuses on defining the detailed morphology of secondary emission products derived from the combustion of cerium (Ce) fuel-borne catalyst (FBC) doped with diesel fuel. Cerium is often used to promote the oxidation of diesel particulates collected in diesel aftertreatment systems, such as diesel particulate filters (DPFs). However, it is suspected that the secondary products could be emitted from the vehicle tailpipe without being effectively filtered by the aftertreatment systems. In this work, these secondary emissions were identified by means of a high-resolution transmission electron microscope (TEM), and their properties were examined in terms of morphology and chemistry. In preparation for fuel doping, a cerium-based aliphatic organic compound solution was mixed with a low-sulfur (110 ppm) diesel fuel at 50 ppm in terms of weight concentration.

Detailed diesel particulates morphology, nanostructures, fractal geometry, and nitrogen oxides (NOx) emissions were analyzed for five different test fuels in a 1.7-L, common-rail direct-injection diesel engine. The accurately formulated fuels permit the effects of sulfur, paraffins, aromatics, and naphthene concentrations to be determined. A novel thermophoretic sampling technique was used to collect particulates immediately after the exhaust valves. The morphology and nanostructures of particulate samples were examined, imaged with a high-resolution transmission electron microscope (HRTEM), and quantitatively analyzed with customized digital image processing/data acquisition systems. The results show that the particle sizes and the total mass of particulate matter (PM) emissions correlate most strongly with the fuels' aromatics and sulfur content.

Gas-to-Liquids (GTL) is a liquid diesel fuel produced from natural gas, which may have certain attributes different from conventional ultra low sulfur diesel (ULSD). In this investigation, GTL, ULSD, and their blends of 20% and 50% GTL in ULSD were tested in an older Mercedes C Class (MY1999, Euro 2) and a newer Opel Astra (MY2006, Euro 4) diesel vehicle to evaluate the performance in terms of fuel consumption and emissions. Each vehicle was pre-conditioned on-road with one tank full of test fuel before actual testing in a chassis dynamometer facility. Both vehicles were calibrated for European emission standards and operation, and they were not re-calibrated for the fuel tests at Argonne National Laboratory (ANL). In the two-vehicle EPA FTP-75, US06, and Highway drive-cycle tests, the emissions of carbon dioxide on a per-mile basis (g/mi) from all GTL-containing fuels were significantly lower than those from the ULSD.

In an effort of providing better understanding of regeneration mechanisms of diesel particulate matter (PM), this experimental investigation focused on evaluating the amount of heat release generated during the thermal reaction of diesel PM and the concentrations of soluble organic compounds (SOCs) dissolved in PM emissions. Differences in oxidation behaviors were observed for two different diesel PM samples: a SOC-containing PM sample and a dry soot sample with no SOCs. Both samples were collected from a cordierite particulate filter membrane in a thermal reactor connected to the exhaust pipe of a light-duty diesel engine. A differential scanning calorimeter (DSC) and a thermogravimetric analyzer (TGA) were used to measure the amount of heat release during oxidation, along with subsequent oxidation rates and the concentrations of SOCs dissolved in particulate samples, respectively.

The limited spatial area in conventional diesel particulate filter (DPF) systems requires frequent regenerations to remove collected particulate matter (PM) emissions, consequently resulting in higher energy consumption and potential material failure. Due to the complex geometry and difficulty in access to the internal structure of diesel particulate filters, in addition, many important characteristics in filtration processes remain unknown. In this work, therefore, the geometry of DPF membrane channels was modified basically to increase the filtration areas, and their filtration characteristics were evaluated in terms of pressure drop across the DPF membranes, effects of soot loading on pressure drop, and qualitative soot mass distribution in the membrane channels. In this evaluation, an analytical model was developed for pressure drop, which allowed a parametric study with those modified membranes.

At the current stage of engine technology, diesel engines typically require diesel particulate filter (DPF) systems to meet recent particulate emissions standards. To assure the performance and reliability of DPF systems, profound understanding of filtration and regeneration mechanisms is required. Among extensive efforts for developing advanced DPF systems, the development of effective thermal management strategies, which control the thermal runaway taking place in oxidation of an excess amount of soot deposit in DPF, is quite challenging. This difficulty stems mainly from lack of sufficient knowledge and understanding about DPF regeneration mechanisms, which need detailed information about oxidation of diesel particulate matter (PM). Therefore, this work carried out a series of oxidation experiments of diesel particulates collected from a DPF on a diesel engine, and evaluated the oxidation rates of the samples using a thermo-gravimetric analyzer (TGA).

The physical and morphological properties of the particulate matter emitted from a 1.7-liter light-duty diesel engine were characterized by observing its evolution in size and fractal geometry along the exhaust system. A common-rail direct-injection diesel engine, the exhaust system of which was equipped with a turbocharger, EGR, and two oxidation catalysts, was powered with a California low-sulfur diesel fuel at various engine-operating conditions. A unique thermophoretic sampling system, a high-resolution transmission electron microscope (TEM), and customized image processing/data acquisition systems were key instruments that were used for the collection of particulate matter, subsequent imaging of particle morphology, and detailed analysis of particle dimensions and fractal geometry, respectively. The measurements were carried out at four different positions along the exhaust pipe.

Dual-fuel combustion using port-injection of low reactivity fuel combined with direct injection of a higher reactivity fuel, otherwise known as Reactivity Controlled Compression Ignition (RCCI), has been shown as a method to achieve high efficiency combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions. A key requirement for extending to high-load operation is reduce the reactivity of the premixed charge prior to the diesel injection. One way to accomplish this is to use a very low reactivity fuel such as natural gas. In this work, experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate using RCCI combustion with port injection of natural gas and direct injection of diesel fuel. Natural gas/diesel RCCI engine operation is compared over the EPA Heavy-Duty 13 mode supplemental emissions test with and without EGR.

A three-dimensional (3-D) computational fluid dynamics (CFD) code has been developed to predict flow dynamics and pressure drop characteristics in geometry-modified filters in which the normalized distance of the outlet channel plugs from the inlet has been varied at 0.25, 0.50, and 0.75. In clean filter simulations, the pressure drop in geometry-modified filters showed higher values than for conventional filters because of the significant change in the pressure field formed inside the channel that determines the amount of flow entering the modified channel. This flow through the modified channel depends on plug position initially but has a maximum limit when pressure difference and geometrical change are compromised. For soot loading simulations, a Lagrangian multiphase flow model was used to interpret the hydrodynamics of particle-laden flow with realistic inputs.

Detailed soot deposition and oxidation characteristics in a diesel particulate filter (DPF) have been experimentally examined on a unique bench-scale DPF test system that has a visualization window. The filtration and regeneration processes were visualized to examine soot deposition and oxidation behaviors on the filter channel surfaces, along with measurements of pressure drop across the filter. The pressure drop caused by trapped soot was separated from the measured total pressure drop by subtracting the pressure drop caused by the clean filter itself. Then, the soot-derived pressure-drop data, normalized (non-dimensionalized) by the volumetric flow rate, exhaust gas viscosity, and DPF volume, were used to compare filtration and regeneration characteristics at different experimental conditions, independently of flow conditions.

The objective of this paper is to present the results of diesel exhaust aftertreatment testing and analysis done under the FreedomCAR program. Nitrogen Oxides (NOx) adsorber technology was selected based on a previous investigation of various NOx aftertreatment technologies including non-thermal plasma, NOx adsorber and active lean NOx. Particulate Matter (PM) emissions were addressed by developing a catalyzed particulate filter. After various iterations of the catalyst formulation, the aftertreatment components were integrated and optimized for a light duty vehicle application. This compact exhaust aftertreatment system is dual leg and consists of a sulfur trap, NOx adsorbers, and catalyzed particulate filters (CPF). During regeneration, supplementary ARCO ECD low-sulfur diesel fuel is injected upstream of the adsorber and CPF in the exhaust. Steady state and transient emission test results with and without the exhaust aftertreatment system (EAS) are presented.

Exhaust gas recirculation (EGR) is a commonly used technique for the reduction of Nitrogen oxide (NOx) emissions from internal combustion engines. However, it is generally known that the use of EGR will cause an increase in emissions of particulate matter (PM). The effects of EGR operating mode on particulate morphology were investigated for a 1.7-liter light-duty diesel engine. This engine was equipped with a turbocharged and inter-cooled air induction system, a common-rail direct fuel injection system, and an EGR system. A rapid prototyping electronic control system (RPECS) was developed to operate this engine at various EGR rates under different conditions (i.e. constant boost pressure, constant oxygen-to-fuel ratio (OFR)). A unique thermophoretic sampling system was employed to collect particulates directly from exhaust manifold after exhaust valves.

The detailed morphological properties of diesel particulate matter were analyzed along the exhaust system at various engine operating conditions (in a range of 1000 - 2500 rpm and 10 - 75 % loads of maximum torques). A 1.7-L turbocharged light-duty diesel engine was powered with California low-sulfur diesel fuel injected by a common-rail injection system, of which particulate emissions were controlled by an exhaust gas recirculation (EGR) system and two oxidation catalysts. A unique thermophoretic sampling system first developed for internal combustion engine research, a high-resolution transmission electron microscope (TEM), and a customized image processing/data acquisition system were key instruments that were used for the collection of particulate matter, subsequent imaging of particle morphology, and detailed analysis of particle dimensions and fractal geometry, respectively.

DATA presented in this paper show temperature-time diagrams obtained from mufflers mounted on trucks which were traveling over their regular routes. Using these temperature data, specimens made of possible muffler materials were subjected to laboratory tests. A wide range of possible muffler materials and gas composition were covered in these tests. Results of the tests indicate that under long-run heavy-duty truck service, muffler failure occurs primarily because of high metal temperatures and that coated mild steel showed the most promise of longer muffler life.

A detailed description of a numerical method for computing unsteady flows in engine intake and exhaust systems is given. The calculations include the effects of heat transfer and friction. The inclusion of such calculations in a mathematically simulated engine cycle is discussed and results shown for several systems. In particular, the effects of bell-mouth versus plain pipe terminations and the effects of a finite surge tank are calculated. Experimental data on the effect of heat transfer from the back of the intake valve on wave damping are given and show the effect to be negligible. Experimental data on wave damping during the valve closed period and on the temperature rise of the air near the valve are also given.

The purpose of the tests conducted on a single-cylinder laboratory engine was to determine the mechanism of combustion that affect exhaust emissions and the relationship of those mechanisms to engine design and operating variables. For the engine used in this study, the exhaust emissions were found to have the following dependence on various engine variables. Hydrocarbon emission was reduced by lean operation, increased manifold pressure, retarded spark, increased exhaust temperature, increased coolant temperature, increased exhaust back pressure, and decreased compression ratio. Carbon monoxide emission was affected by air-fuel ratio and premixing the charge. Oxides of nitrogen (NO + NO2 is called NOx) emission is primarily a function of the O2 available and the peak temperature attained during the cycle. Decreased manifold pressure and retarded spark decrease NOx emission. Hydrocarbons were found to react to some extent in the exhaust port and exhaust system.

A detailed mathematical model of the thermodynamic events of a crankcase scavenged, two-stroke, SI engine is described. The engine is divided into three thermodynamic systems: the cylinder gases, the crankcase gases, and the inlet system gases. Energy balances, mass continuity equations, the ideal gas law, and thermodynamic property relationships are combined to give a set of coupled ordinary differential equations which describe the thermodynamic states encountered by the systems of the engine during one cycle of operation. A computer program is used to integrate the equations, starting with estimated initial thermodynamic conditions and estimated metal surface temperatures. The program iterates the cycle, adjusting the initial estimates, until the final conditions agree with the beginning conditions, that is, until a cycle results.

Particulate and gaseous emissions from a Mitsubishi Legnum GDI™ wagon were measured for FTP-75, HWFET, SC03, and US06 cycles. The vehicle has a 1.8-L spark-ignition direct-injection engine. Such an engine is considered a potential alternative to the compression-ignition direct-injection engine for the PNGV program. Both engine-out and tailpipe emissions were measured. The fuels used were Phase-2 reformulated gasoline and Indolene. In addition to the emissions, exhaust oxygen content and exhaust-gas temperature at the converter inlet were measured. Results show that the particulate emissions are measurable and are significantly affected by the type of fuel used and the presence of an oxidation catalyst. Whether the vehicle can meet the PNGV goal of 0.01 g/mi for particulates depends on the type of fuel used. Both NMHC and NOx emissions exceed the PNGV goals of 0.125 g/mi and 0.2 g/mi, respectively. Meeting the NOx goal will be especially challenging.