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The local equivalence ratio, Φ, was measured in fuel jets using laser-induced spontaneous Raman scattering in an optical heavy duty diesel engine. The measurements were performed at 1200 rpm and quarter load (6 bar IMEP). The objective was to study factors influencing soot formation, such as gas entrainment and lift-off position, and to find correlations with engine-out particulate matter (PM) levels. The effects of nozzle hole size, injection pressure, inlet oxygen concentration, and ambient density at TDC were studied. The position of the lift–off region was determined from OH chemiluminescence images of the flame. The liquid penetration length was measured with Mie scattering to ensure that the Raman measurement was performed in the gaseous part of the spray. The local Φ value was successfully measured inside a fuel jet. A surprisingly low correlation coefficient between engine-out PM and the local Φ in the reaction zone were observed.

Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

Detailed chemistry and turbulence-chemistry interaction need to be properly taken into account for a realistic combustion simulation of IC engines where advanced combustion modes, multiple injections and stratified combustion involve a wide range of combustion regimes and require a proper description of several phenomena such as auto-ignition, flame stabilization, diffusive combustion and lean premixed flame propagation. To this end, different approaches are applied and the most used ones rely on the well-stirred reactor or flamelet assumption. However, well-mixed models do not describe correctly flame structure, while unsteady flamelet models cannot easily predict premixed flame propagation and triple flames. A possible alternative for them is represented by transported probability density functions (PDF) methods, which have been applied widely and effectively for modeling turbulent reacting flows under a wide range of combustion regimes.

In the last couple of decades, countries have enacted new laws concerning environmental pollution caused by heavy-duty commercial and passenger vehicles. This is done mainly in an effort to reduce smog and health impacts caused by the different pollutions. One of the legislated pollutions, among a wide range of regulated pollutions, is nitrogen oxides (commonly abbreviated as NOx). The SCR (Selective Catalytic Reduction) was introduced in the automotive industry to reduce NOx emissions leaving the vehicle. The basic idea is to inject a urea solution (AdBlue™) in the exhaust gas before the gas enters the catalyst. The optimal working temperature for the catalyst is somewhere in the range of 300 to 400 °C. For the reactions to occur without a catalyst, the gas temperature has to be at least 800 °C. These temperatures only occur in the engine cylinder itself, during and after the combustion.

The use of fast response emissions analyzers to correlate spikes of emissions with engine parameters such as lambda and EGR is well known for engine test cell and chassis dynamometer work. However, the adaption of these analyzers for in-vehicle use allows engineers to identify real world situations where significant tailpipe emissions occur over short durations which may not be visible with standard PEMS equipment and to correlate these events with other engine parameters. Sampling raw exhaust gas pre muffler eliminates the extra gas mixing due to these sound deadening devices and allows high fidelity identification of emission breakthroughs during transients. Through such identification, engine calibrators can adjust ECU parameters enabling such transient emissions problems to be cured. Accurate and adequate urea dosing and EGR transients are of particular interest in diesel vehicles.

Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).

CO2 is a greenhouse gas that is believed to be one of the main contributors to global warming. Recent studies show that a combination of methanol as a renewable fuel and advanced combustion concepts could be a promising future solution to alleviate this problem. However, high unburned hydrocarbon (UHC) and carbon monoxide (CO) emissions can be stated as the main drawback in low load operations when using methanol under advanced combustion concepts. This issue can be mitigated by modifying the stratification of the local equivalence ratio to achieve a favorable level. The stratifications evolved, and the regimes that can simultaneously produce low emissions, and high combustion efficiency can be identified by sweeping the injection timing from homogeneous charge compression ignition (HCCI) to partially premixed combustion (PPC). Understanding how the stratification of the local equivalence ratio for methanol evolves during the sweep is essential to gain these benefits.

In this study, tailpipe-sampling was used to sample the exhaust aerosol of a Stage IV tractor equipped with Diesel Oxidation Catalyst (DOC) and Selective Catalytic Reduction (SCR) aftertreatment systems. The particle emissions were characterized in terms of number concentration (particle size of > 2.5 nm), mass concentration (particle size of 6-612 nm) BC mass concentration and chemical composition (particle size of > 30 nm). The measurements were conducted on-road by setting a mobile laboratory on a trailer and pulling it with the tractor. In addition to driving, heavy-lift work cycles were tested, where separate lifts of a 1000 kg weight were conducted with the front fork of the tractor with two minutes of idling between consecutive lifts. Both a Porous Tube Diluter (PTD) with ambient temperature dilution air as well as an ejector diluter with hot dilution air were used to sample the exhaust aerosol.

Methanol is not a fuel typically used in compression ignition engines due to the high resistance to auto-ignition. However, conventional diesel combustion and PPC offer high engine efficiency along with low HC and CO emissions, albeit with the trade-off of increased NOx and PM emissions. This trade-off balance is mitigated in the case of methanol and other alcohol fuels, as they bring oxygen in the combustion chamber. Thus methanol compression ignition holds the potential for a clean and effective alternative fuel proposition. Most existing research on methanol is on SI engines and very little exists in the literature regarding methanol auto-ignition engine concepts. In this study, the spray characteristics of methanol inside the optically accessible cylinder of a DI-HD engine are investigated. The liquid penetration length at various injection timings is documented, ranging from typical PPC range down to conventional diesel combustion.

The European Union road transport CO2 emissions regulation foresees mandatory targets for passenger vehicles. However, several studies have shown that there is a divergence between official and real-world values that could range up to 40% compared to the NEDC reference value. The introduction of the Worldwide Harmonized Test Protocol (WLTP) limited this divergence, but it is uncertain whether it can adequately address the problem, particularly considering future evolutions of vehicle technology. In order to address this issue, the recent EU CO2-standards regulation introduces the monitoring of on-road fuel consumption and subsequently CO2 emissions by utilizing On-Board Fuel Consumption Meters (OBFCM). In the near future, all vehicles should provide instantaneous and lifetime-cumulative fuel consumption signals at the diagnostics port. Currently, the fuel consumption signal is not always available.

The major challenge of the post-processing of soot aggregates in transmission electron microscope (TEM) images is the detection of soot primary particles that have no clear boundaries, vary in size within the fractal aggregates, and often overlap with each other. In this study, we propose an automated detection code for primary particles implementing the Canny Edge Detection (CED) and Circular Hough Transform (CHT) on pre-processed TEM images for particle edge enhancement using unsharp filtering as well as image inversion and self-subtraction. The particle detection code is tested for soot TEM images obtained at various ambient and injection conditions, and from five different combustion facilities including three constant-volume combustion chambers and two diesel engines.

Soot emissions from diesel engines are the net result of two competing processes: soot formation and soot oxidation. Previous studies have shown poor correlation between soot formation rates and the soot emissions. This article presents a systematic study of a number of parameters affecting soot oxidation rate and how it correlates with the soot emissions. An optical heavy-duty engine is used in conjunction with a laser extinction setup in order to collect time resolved data of the soot concentration in the cylinder during the expansion stroke. Laser extinction is measured using a red (685 nm) laser beam, which is sent vertically through the cylinder and modulated to produce 10 pulses per crank angle degree. Information is obtained about the amount of soot formed and the soot oxidation rate. The parameters studied are the motored density at top dead center (TDC), motored temperature at TDC, injection pressure, engine speed, swirl level and injector orifice diameter.

The focus has recently been directed towards the engine out soot from Diesel engines. Running an engine in PPC (Partially Premixed Combustion) mode has a proven tendency of reducing these emissions significantly. In addition to combustion strategy, several studies have suggested that using alcohol fuels aid in reducing soot emissions to ultra-low levels. This study analyzes and compares the characteristics of PM emissions from naphtha gasoline PPC, ethanol PPC, methanol PPC and methanol diffusion combustion in terms of soot mass concentration, number concentration and particle size distribution in a single cylinder Scania D13 engine, while varying the intake O2. Intake temperature and injection pressure sweeps were also conducted. The fuels emitting the highest mass concentration of particles (Micro Soot Sensor) were gasoline and methanol followed by ethanol. The two alcohols tested emitted nucleation mode particles only, whereas gasoline emitted accumulation mode particles as well.

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

The effects of injection pressure and swirl ratio on the in-cylinder soot oxidation are studied using simultaneous PLIF imaging of OH and LII imaging of soot in an optical diesel engine. Images are acquired after the end of injection in the recirculation zone between two adjacent diesel jets. Scalars are extracted from the images and compared with trends in engine-out soot emissions. The soot emissions decrease monotonically with increasing injection pressure but show a non-linear dependence on swirl ratio. The total amount of OH in the images is negatively correlated with the soot emissions, as is the spatial proximity between the OH and soot regions. This indicates that OH is an important soot oxidizer and that it needs to be located close to the soot to perform this function. The total amount of soot in the images shows no apparent correlation with the soot emissions, indicating that the amount of soot formed is a poor predictor of the emission trends.

The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

Modern ‘DOC-cDPF’ systems for diesel exhaust are employing Pt-, Pd- as well as Pt/Pd alloy- based coatings to ensure high conversion efficiency of CO, HC even at low temperatures. Depending on the target application, these coatings should be also optimized towards NO2 generation which is involved in low temperature soot oxidation as well as in SCR-based deNOx. Zeolite materials are also frequently used to control cold-start HC emissions. Considering the wide variety of vehicles, engines and emission targets, there is no single optimum coating technology. The main target is therefore to maximize synergies rather than to optimize single components. At the same time, the system designer has nowadays a wide range of technologies to choose from, including PGM alloyed combinations (Pt/Pd), multiple layers and zones applicable to both DOCs and DPFs.

In this article we present a design of a new miniaturized sensor with the capacity to measure exhaust particle concentrations on board vehicles and engines. The sensor is characterized by ultra-fast response time, high sensitivity, and a wide dynamic range. In addition, the physical dimensions of the sensor enable its placement along the exhaust line. The concentration response and temporal performance of a prototype sensor are discussed and characterized with aerosol laboratory test measurements. The sensor performance was also tested with actual engine exhaust in both chassis and engine dynamometer measurements. These measurements demonstrate that the sensor has the potential to meet and even exceed any requirements around the world in terms of on-board diagnostic (OBD) sensitivity and frequency of monitoring.

Gas engines (fuelled with CNG, LNG or Biogas) for generation of power and heat are, to this date, taking up larger shares of the market with respect to diesel engines. In order to meet the limit imposed by the TA-Luft regulations on stationary engines, lean combustion represents a viable solution for achieving lower emissions as well as efficiency levels comparable with diesel engines. Leaner mixtures however affect the combustion stability as the flame propagation velocity and consequently heat release rate are slowed down. As a strategy to deliver higher ignition energy, an active pre-chamber may be used. This work focuses on assessing the performance of a pre-chamber combustion configuration in a stationary heavy-duty engine for power generation, operating at different loads, air-to-fuel ratios and spark timings.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.