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Technical Paper

Natural Gas and Diesel Transit Bus Emissions: Review and Recent Data

1997-11-17
973203
Natural Gas engines are viewed as an alternative to diesel power in the quest to reduce heavy duty vehicle emissions in polluted urban areas. In particular, it is acknowledged that natural gas has the potential to reduce the inventory of particulate matter, and this has encouraged the use of natural gas engines in transit bus applications. Extensive data on natural gas and diesel bus emissions have been gathered using two Transportable Heavy Duty Vehicle Emissions Testing Laboratories, that employ chassis dynamometers to simulate bus inertia and road load. Most of the natural gas buses tested prior to 1997 were powered by Cummins L-10 engines, which were lean-burn and employed a mechanical mixer for fuel introduction. The Central Business District (CBD) cycle was used as the test schedule.
Technical Paper

Fuel Chemistry Impacts on Gasoline HCCI Combustion with Negative Valve Overlap and Direct Injection

2007-10-29
2007-01-4105
Homogeneous Charge Compression Ignition (HCCI) combustion has the potential to produce low NOx and low particulate matter (PM) emissions while providing high efficiency. In HCCI combustion, the start of auto-ignition of premixed fuel and air depends on temperature, pressure, concentration history during the compression stroke, and the unique reaction kinetics of the fuel/air mixture. For these reasons, the choice of fuel has a significant impact on both engine design and control strategies. In this paper, ten (10) gasoline-like testing fuels, statistically representative of blends of four blending streams that spanned the ranges of selected fuel properties, were tested in a single cylinder engine equipped with a hydraulic variable valve train (VVT) and gasoline direct injection (GDI) system.
Technical Paper

Development of a Desulfurization Strategy for a NOx Adsorber Catalyst System

2001-03-05
2001-01-0510
The aggressive reduction of future diesel engine NOx emission limits forces the heavy- and light-duty diesel engine manufacturers to develop means to comply with stringent legislation. As a result, different exhaust emission control technologies applicable to NOx have been the subject of many investigations. One of these systems is the NOx adsorber catalyst, which has shown high NOx conversion rates during previous investigations with acceptable fuel consumption penalties. In addition, the NOx adsorber catalyst does not require a secondary on-board reductant. However, the NOx adsorber catalyst also represents the most sulfur sensitive emissions control device currently under investigation for advanced NOx control. To remove the sulfur introduced into the system through the diesel fuel and stored on the catalyst sites during operation, specific regeneration strategies and boundary conditions were investigated and developed.
Technical Paper

Vapor Pressures of Diesel Fuel Oxygenate Blends

2002-10-21
2002-01-2850
A gas chromatographic technique was used to determine the vapor pressures of blends of six candidate diesel fuel oxygenates with three diesel fuels at 0, 5, 10, 30, and 100 percent blend levels. Both the oxygenates and the diesel fuels were selected to represent a variety of chemical compositions. The vapor pressures were determined over a range of temperatures from -30 C to +30 C. In each case the fraction of the vapor pressure derived from the oxygenate and the fuel was identified. The vapor pressure results showed that there were significant deviations from ideality, leading to both higher and lower vapor pressures than would be predicted from Raoult's Law. These results are significant for fire safety and evaporative emissions as well as for a more basic understanding of the behavior of these blends. Data were also obtained on the heats of vaporization for each of the blends.
Technical Paper

Oxygenate Compatibility with Diesel Fuels

2002-10-21
2002-01-2848
Miscibility, water tolerance, cloud point, and flash point data are presented for seven candidate diesel fuel oxygenates: dipentyl ether, dibutoxymethane, 2-ethoxyethyl ether, diethyl maleate, tripropylene glycol monomethyl ether, dibutyl maleate, and glycerol tributrate. These oxygenates were blended with three different diesel fuels: an oil sands diesel, an ultra-low sulfur diesel, and a Fischer-Tropsch diesel. Blend levels included 0, 5, 10, 30, and 100 % oxygenate. Properties were measured at temperatures of -30, -15, 0, 15, and 30 C.
Technical Paper

Experimental Investigation of the Origin of Cyclic Fluctuations in a DISI Engine by Means of Advanced Laser Induced Exciplex Fluorescence Measurements

2006-10-16
2006-01-3378
Cyclic fluctuations of the in-cylinder processes in a Direct Injection Spark Ignition (DISI) engine may strongly affect the engine operation causing misfires or variations in the indicated mean effective pressure (imep). Particularly misfires prevent compliance with current or future exhaust emission legislations. Nevertheless, the origin of cyclic fluctuations is not well understood since fluctuations of in-cylinder air flow, fuel injection and wall interaction have to be considered. This paper focusses on a detailed experimental analysis of the origin of cyclic fluctuations in a DISI engine with an air guided combustion process by means of advanced Laser Induced Exciplex Fluorescence (LIEF) measurements. It reveals that cycle-to-cycle variations primarily originate from the air/fuel ratio at the spark plug.
Technical Paper

Type Analysis of EGR-Strategies for Controlled Auto Ignition (CAI) by Using Numerical Simulations and Optical Measurements

2006-04-03
2006-01-0630
The main assignment of Controlled Auto Ignition (CAI) operation range expansion is to reduce the burn rate or combustion noise at high load and to minimize misfire at low load. The potential of two principal EGR strategies is well known to initiate CAI in a wide range of operation map by using a variable train system: the Exhaust Port Recirculation (EPR) for higher part load and the Combustion Chamber Recirculation (CCR - also called Negative Valve Overlap) for lower part load. However the detailed comparison of the ignition phenomena with each EGR strategy has not been fully studied yet. In this paper, EPR and CCR were compared with same operational condition (engine speed and load). For the analysis, flame luminescence and Raman scattering method for optical measurement and STAR-CD (CD-adapco) for numerical simulation are used.
Technical Paper

Evaluation of a Catalytic Converter for a 3.73 kW Natural Gas Engine

1993-03-01
930221
An oxidizing catalytic converter was evaluated in the exhaust train of a 3.73 kW (5 hp) natural gas engine. The engine was developed for use in a gas engine-driven heat pump and is designed for operation at lean air/fuel ratios. The converter tested had a metallic substrate with a cell density of 31 cells/cm2. Converter tests measured emission performance as a function of the key engine variables: speed, load, spark advance and air/fuel ratio. As expected, CO conversion averaged well above 90 percent. Hydrocarbon conversion varied between 68.6 and 89.8 percent over a range of eight speed and load combinations selected to cover the normal operating range of the engine. Conversion of individual hydrocarbon species was examined also. Although the converter tests were not designed to isolate the key converter variables, a simple mathematical model allowed us to explore the effect of these variables on conversion.
Technical Paper

Controlled Auto Ignition Combustion Process with an Electromechanical Valve Train

2003-03-03
2003-01-0032
The current discussion about possible limitation of CO2 emissions makes improvement of fuel consumption a central topic for gasoline engine development. Various technological solutions are available to realize this improvement. Concepts featuring direct fuel injection, engine downsizing and unthrottled control of engine load with variable valvetrains are currently considered the most promising ways to achieve this goal. Further concepts that are under development include Controlled Auto Ignition (CAI) and homogenous lean burn combustion as well as certain combinations of these technologies. Within the European market, direct injection is currently the most popular solution. The drawback is that a very expensive exhaust gas aftertreatment system is necessary to keep exhaust emissions within legal limits.
Technical Paper

Vehicle Emissions Results-CleanFleet Alternative Fuels Project

1995-02-01
950394
Vehicle exhaust emissions measurements are reported for full-size panel vans operating on four alternative motor fuels and control gasoline. The emissions tests produced data on in-use vans. The vans were taken directly from commercial delivery service for testing as they accumulated mileage over a 24-month period. The alternative fuels tested were compressed natural gas, propane gas, California Phase 2 reformulated gasoline (RFG), and methanol (M-85 with 15 percent RFG). The control gasoline for the emissions tests was an industry average unleaded blend (RF-A). The vehicle technologies tested represent those options available in 1992 that were commercially available from Ford, Chrysler, and Chevrolet or which these manufacturers agreed to provide as test vans for daily use in commercial service by FedEx.
Technical Paper

Long-Term Aging of NOx Sensors in Heavy-Duty Engine Exhaust

2005-10-24
2005-01-3793
Research has shown that there are many factors that affect the long-term performance of nitrogen oxides (NOx) control systems used in diesel engine applications. However, if the NOx emissions can be accurately monitored, it might be possible to restore performance by making adjustments to the control systems. This paper presents results from a study that tested the durability of 25 NOx sensors exposed to heavy-duty diesel exhaust for 6,000 hours. The study, conducted by the Advanced Petroleum-Based Fuels - Diesel Emission Controls (APBF-DEC) project, tested the sensors at various locations in the exhaust stream.
Technical Paper

Effects of Diesel Fuel Sulfur Level on Performance of a Continuously Regenerating Diesel Particulate Filter and a Catalyzed Particulate Filter

2000-06-19
2000-01-1876
This paper reports the test results from the DPF (diesel particulate filter) portion of the DECSE (Diesel Emission Control - Sulfur Effects) Phase 1 test program. The DECSE program is a joint government and industry program to study the impact of diesel fuel sulfur level on aftertreatment devices. A systematic investigation was conducted to study the effects of diesel fuel sulfur level on (1) the emissions performance and (2) the regeneration behavior of a continuously regenerating diesel particulate filter and a catalyzed diesel particulate filter. The tests were conducted on a Caterpillar 3126 engine with nominal fuel sulfur levels of 3 parts per million (ppm), 30 ppm, 150 ppm and 350 ppm.
Technical Paper

Vehicle Study on the Impact of Diesel Fuel Sulfur Content on the Performance of DeNOX Catalysts and the Influence of DeNOX Catalysts on Particle Size and Number

2000-06-19
2000-01-1877
A vehicle investigation programme was initiated to evaluate the influence of diesel fuel sulfur content on the performance of a DeNOx catalyst for NOx control. The programme was conducted with a passive DeNOx catalyst, selected for its good NOx reduction performance and two specially prepared fuels with different sulfur contents. Regulated emissions were measured and analysed during the course of the programme. The NOx conversion efficiency of the DeNOx catalyst increased from 14 to 26% over the new European test cycle when the sulfur content of the diesel fuel was reduced from 49 to 6 wt.-ppm. In addition the number and size of particles produced using 6 wt.-ppm sulfur fuel were measured by two different techniques: mobility diameter by SMPS and aerodynamic diameter by impactor. The influence of the assumed density of the particulate on the apparent diameters measured by the two techniques is discussed.
Technical Paper

Statistical Issues in the Evaluation of the Impact of Sulfur in Diesel Fuel on the Performance of Diesel Particulate Filter Emission Control Devices

2000-06-19
2000-01-1958
The Diesel Emission Control - Sulfur Effects (DECSE) program is a joint U.S. government/industry program that studies the impact of diesel sulfur levels on four types of emission control systems. One type of system, Diesel Particulate Filters (DPF), removes particulate matter (PM) from the exhaust stream by collection on a filter. The critical operating issue for DPF technology is the cleaning or regeneration of the control device (by oxidation of the collected PM) to prevent plugging. However, oxidation of sulfur in the exhaust forms sulfates, which are measured as PM. Two types of tests are conducted to evaluate the impacts of fuel sulfur on DPF performance: (1) emissions tests for PM components and gases, and (2) experiments to measure the effect of fuel sulfur on the regeneration temperature required by the filter devices.
Technical Paper

Fatigue Evaluation Procedure Development for Self-Piercing Riveted Joints Using the Battelle Structural Stress Method

2016-04-05
2016-01-0384
Lightweight, optimized vehicle designs are paramount in helping the automotive industry meet reduced emissions standards. Self-piercing rivets are a promising new technology that may play a role in optimizing vehicle designs, due to their superior fatigue resistance compared with spot welds and ability to join dissimilar materials. This paper presents a procedure for applying the mesh-insensitive Battelle Structural Stress Method to self-piercing riveted joints for fatigue life prediction. Additionally, this paper also examines the development of an interim fatigue design master S-N curve for self-piercing rivets. The interim fatigue design master S-N curve accounts for factors such as various combinations of similar and dissimilar metal sheets, various sheet thicknesses, stacking sequence, and load ratios. A large amount of published data was collapsed into a single interim S-N curve with reasonable data scattering.
Technical Paper

Fatigue Evaluation Procedure Development for Aluminum Alloy Spot Welds Using the Battelle Structural Stress Method

2015-04-14
2015-01-0545
As the automotive industry seeks to remove weight from vehicle chasses to meet increased fuel economy standards, it is increasingly turning to composites and aluminum. In spite of increasing demands for quality aluminum alloy spot welds that enable more fuel efficient automobiles, fatigue evaluation procedures for such welds are not well-established. This article discusses the results of an evaluation Battelle performed of the fatigue characteristics of aluminum alloy spot welds based on experimental data and observations from the literature. In comparison with spot welds in steel alloys, aluminum alloy spot welds exhibit several significant differences including a different hardness distribution at and around the weld, different fatigue failure modes, and more. The effectiveness and applicability of the Battelle structural stress-based simplified procedure for modeling and simulating automotive spot welds has previously been demonstrated by Battelle investigations.
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