Search Results

Effects of methyl ester biodiesel fuel blends on NOx emissions are studied experimentally and analytically. A precisely controlled single cylinder diesel engine experiment was conducted to determine the impact of a 20% blend of soy methyl ester biodiesel (B20) on NOx emissions. The data were then used to calibrate KIVA chemical kinetics models which were used to determine how the biodiesel blend affects NOx production during the combustion process. In addition, the impact on the engine control system of the lower specific energy content of biodiesel was determined. Both factors, combustion and controls, must be taken into account when determining the net NOx effect of biodiesel compared to conventional diesel fuel. Because the magnitude and even direction of NOx effect changes with engine load, the NOx effect associated with burning biodiesel blends over a duty cycle depends on the duty cycle average power and fuel cetane number.

Combustion systems with advanced injection strategies have been extensively studied, but there still exists a significant fundamental knowledge gap on fuel spray interactions with the piston surface and chamber walls. This paper is meant to provide detailed data on spray-wall impingement physics and support the spray-wall model development. The experimental work of spray-wall impingement with non-vaporizing spray characterization, was carried out in a high pressure-temperature constant-volume combustion vessel. The simultaneous Mie scattering of liquid spray and schlieren of liquid and vapor spray were carried out. Diesel fuel was injected at a pressure of 1500 bar into ambient gas at a density of 22.8 kg/m3 with isothermal conditions (fuel, ambient, and plate temperatures of 423 K). A Lagrangian-Eulerian modeling approach was employed to characterize the spray-gas and spray-wall interactions in the CONVERGETM framework by means of a Reynolds-Averaged Navier-Stokes (RANS) formulation.

A technique for rapid in situ measurement of the fuel dilution of oil in a diesel engine is presented. Fuel dilution can occur when advanced in-cylinder fuel injection techniques are employed for the purpose of producing rich exhaust for lean NOx trap catalyst regeneration. Laser-induced fluorescence (LIF) spectroscopy is used to monitor the oil in a Mercedes 1.7-liter engine operated on a dynamometer platform. A fluorescent dye suitable for use in diesel fuel and oil systems is added to the engine fuel. The LIF spectra are monitored to detect the growth of the dye signal relative to the background oil fluorescence; fuel mass concentration is quantified based on a known sample set. The technique was implemented with fiber optic probes which can be inserted at various points in the engine oil system. A low cost 532-nm laser diode was used for excitation.

In the early years of antifreeze/coolants (1920s & 30s) glycerin saw some usage, but because of higher cost and weaker freeze point depression, it was not competitive with ethylene glycol. Glycerin is a by-product of the manufacture of biodiesel (fatty acid methyl esters) made by reacting natural vegetable or animal fats with methanol. Biodiesel fuel is becoming increasingly important and is expected to gain a large market share in the next several years. Regular diesel fuels blended with 2%, 5%, and 20% biodiesel are now commercially available. The large amount of glycerin generated from high volume usage of biodiesel fuel has resulted in this chemical becoming cost competitive with the glycols currently used in engine coolants. For this reason, and lower toxicity comparable to that of propylene glycol, glycerin deserves to be reconsidered as a base for antifreeze/coolant.

A quasi-steady 1-dimensional computer model of a catalyzed particulate filter (CPF) capable of simulating active regeneration of the CPF via diesel fuel injection upstream of a diesel oxidation catalyst (DOC) or other means to increase the exhaust gas temperature has been developed. This model is capable of predicting gaseous species concentrations (HC's, CO, NO and NO2) and exhaust gas temperatures within and after the CPF, for given input values of gaseous species and PM concentrations before the CPF and other inlet variables such as time-varying temperature of the exhaust gas at the inlet of the CPF and volumetric flow rate of exhaust gas.

Sulfur containing species as well as other polar molecules provide lubricity and thermal stability to diesel fuels. During the refining process to produce low and ultra-low sulfur diesel fuels, these components are removed. As a result, fuel additives such as lubricity agents and antioxidant may be added to protect fuel stability and prevent fuel pump wear. Some lubricity additives, such as dimer acids, resulted in fuel filter plugging. The plugging mechanism was related to the capability of aliphatic acids to form agglomeration by interactions with the overbased detergents, delivered into the fuel as oil contaminants. Other sources of acids, derived from thermal degradation, can lead to the same problem. In this study, individual lubricant additives were mixed in the fuel to form single- and dual-component systems. Levels of compatibility and amounts of interaction products were evaluated for individual solutions.

Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure.

Heat rejection, liner temperature, exhaust valve seat temperature, and head gasket temperature data were recorded during a full load torque sweep of a compression ignition engine when fueled by No. 2 diesel and an ethanol/diesel fuel blend containing 10% ethanol by volume. Heat balances were calculated for engine operation at various load-speed combinations. The results of this study indicated that a greater than expected volume of E-diesel was required to operate the compression ignition engine at the same torque-speed compared to No. 2 diesel. More E-diesel fuel was required due to lower brake thermal efficiencies for E-diesel. Other than exhaust seat temperatures, there were no appreciable differences in component temperatures measured throughout the engine or the results of the heat balances calculated for the No. 2 diesel and E-diesel fuels.

Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed.

The increased availability of natural gas (NG) in the United States (US) and its relatively low cost versus diesel fuel has increased interest in the conversion of medium duty (MD) and heavy duty (HD) engines to NG fueled combustion systems. The aim for development for these NG engines is to realize fuel cost savings and increase operating range while reduce harmful emissions and maintaining durability. Traditionally, port-fuel injection (PFI) or premixed NG spark-ignited (SI) combustion systems have been used for light duty LD, and MD engines with widespread use in the US and Europe [1]. However, this technology exhibits poor thermal efficiency and is load limited due to knock phenomenon that has prohibited its use for HD engines. Spark Ignited Direct Injection (SIDI) can be used to create a partially stratified combustion (PSC) mixture of NG and air during the compression stroke.

The accurate modeling of fuel spray behavior under diesel engine conditions requires well-characterized boundary conditions. Among those conditions, the spray cone angle is important due to its impact on the spray mixing process, flame lift-off locations and subsequent soot formation. The spray cone angle is a highly dynamic variable, but existing correlations have been developed mainly for diesel fuels at quasi-steady state and relatively low injection pressures. The objective of this study was to develop spray cone angle correlations for both diesel and a light-end gasoline fuel over a wide range of diesel-engine operating conditions that are capable of capturing both the transient and quasi-steady state processes. Two important macroscopic characteristics of solid cone sprays, the spray cone angle and spray penetration, were measured using a single-hole heavy-duty injector using two fuels at diesel engine conditions in an optical constant volume vessel.

Plug flow reactors, simulating engine exhaust gas, are widely used in emissions control research to gain insight into the reaction mechanisms and engineering aspects that controls activity, selectivity, and durability of catalyst components. The choice of relevant hydrocarbon (HC) species is one of the most challenging factor in such laboratory studies, given the variety of compositions that can be encountered in different application scenarios. Furthermore, this challenge is amplified by the experimental difficulties related to introducing heavier and multi-component HCs and analyzing the reaction products.

Increasing fuel injection pressure has enabled reduction of diesel emissions while retaining the advantage of the high thermal efficiency of diesel engines. With production diesel injectors operating in the range from 300 to 2400 bar, there is interest in injection pressures of 3000 bar and higher for further emissions reduction and fuel efficiency improvements. Fundamental understanding of diesel spray characteristics including very early injection and non-vaporizing spray penetration is essential to improve model development and facilitate the integration of advanced injection systems with elevated injection pressure into future diesel engines. Studies were conducted in an optically accessible constant volume combustion vessel under non-vaporizing conditions. Two advanced high pressure multi-hole injectors were used with different hole diameters, number of holes, and flow rates, with only one plume of each injector being imaged to enable high frame rate imaging.

The increase in regulatory demand to reduce CO2 emissions resulted in a focus on the development of novel combustion modes such as gasoline compression ignition (GCI). It has been shown by others that GCI can improve the overall engine efficiency while achieving soot and NOx emissions targets. In comparison with diesel fuel, gasoline has a higher volatility and has more resistance to autoignition, therefore, it has a longer ignition delay time which facilitates better mixing of the air-fuel charge before ignition. In this study, a GCI combustion system has been tested using a 2.2L compression ignition engine as part of a US Department of Energy funded project. For this purpose, a multiple injection strategy was developed to improve the pressure rise rates and soot emission levels for the same engine out NOx emissions.

The paper describes an experimental activity on the spatial and temporal liquid- and vapor-phase distributions of diesel fuel at engine-like conditions. The influence of the k-factor (0 and 1.5) of a single-hole axial-disposed injector (0.100 mm diameter and 10 L/d ratio) has been studied by spraying fuel in an optically-accessible constant-volume combustion vessel. A high-speed imaging system, capable of acquiring Mie-scattering and Schlieren images in a near simultaneous fashion mode along the same line of sight, has been developed at the Michigan Technological University using a high-speed camera and a pulsed-wave LED system. The time resolved pair of schlieren and Mie-scattering images identifies the instantaneous position of both the vapor and liquid phases of the fuel spray, respectively. The studies have been performed at three injection pressures (70, 120 and 180 MPa), 23.9 kg/m3 ambient gas density and 900 K gas temperature in the vessel.

Passive regeneration (oxidation of particulate matter without using an external energy source) of particulate filters in combination with active regeneration is necessary for low load engine operating conditions. For low load conditions, the exhaust gas temperatures are less than 250°C and the PM oxidation rate due to passive regeneration is less than the PM accumulation rate. The objective of this research was to experimentally investigate active regeneration of a catalyzed particulate filter (CPF) using diesel fuel injection in the exhaust gas after the turbocharger and before a diesel oxidation catalyst (DOC) and to collect data for extending the MTU 1-D 2-layer model to include the simulation of active regeneration. The engine used in this study was a 2002 Cummins ISM turbo charged 10.8 L heavy duty diesel engine with cooled EGR. The exhaust after-treatment system consisted of a Johnson Matthey DOC and CPF (a CCRT®).

Despite drastic reduction of sulfur content in diesel fuel in the recent years, especially with the introduction of Ultra-Low Sulfur Diesel (ULSD), sulfur poisoning remains one of the most significant factors impacting performance of various catalysts in diesel aftertreatment systems. This is because even with ULSD, cumulative exposure of a catalyst over its lifetime in a heavy-duty diesel system may amount to kilograms of sulfur. In this study, we have found that the impact of sulfur poisoning on the performance of various diesel oxidation catalysts (DOC) strongly depends on the catalyst's operation history. For example, exposing a DOC to limited amounts of freshly deposited sulfur in bench reactor testing was shown to have a substantial detrimental effect. On the other hand, several samples which returned from vehicle or test-cell aging with high sulfur loading, have shown no signs of poisoning.

Global emission legislations for diesel engines are becoming increasingly stringent. While the exhaust gas composition requirements for prior iterations of emission legislation could be met with improvements in the engine's combustion process, the next issue of European, North American and Japanese emission limits greater than 2005 will require more rigorous measures, mainly employment of exhaust gas aftertreatment systems. As a result, many American diesel OEMs are considering NOx adsorbers as a means to achieve 2007+ emission standards. Since the efficacy of a NOx adsorber over its lifetime is significantly affected by sulfur (“sulfur poisoning”), forthcoming reductions in diesel fuel sulfur (down to 15 ppm), have raised industry concerns regarding compatibility and possible poisoning effects of sulfur from the lubricant.

A new diesel van with a reference weight of 1661 kg and a pre-chamber engine with a displacement of 2400cc was tested on a chassis dynamometer. The fuel consumption and emissions of carbon monoxide, unburned hydrocarbons, nitrogen oxides, carbon dioxide, particulate matter and associated organic material (SOF) as well as PAH (Polycyclic Aromatic Hydrocarbons) were measured under different driving conditions. The driving patterns used were recorded with a chase car at real traffic conditions on several roads in Copenhagen. The emissions were measured using different kind of diesel fuels as well as RME and biodiesel. CO, CO2, HC, and NOx levels generally decreased with increasing average speed of the driving cycle for all fuels tested. Cold start emissions were generally higher than for warm start.

A model for calculating the trap pressure drop, particulate mass inside the trap and various particulate and trap properties was developed using the steady-state data and the theory developed by Konstandopoulos & Johnson, 1989. Changes were made with respect to the calculation of clean pressure drop, particulate layer porosity and the particulate layer permeability. This model was validated with the data obtained from the steady-state data run with different traps supplied by Corning Inc. The data were collected using the 1988 Cummins L-10 heavy-duty diesel engine using No.2 low sulfur diesel fuel. The three different traps were EX 80 (100 cell density), EX 80 (200 cell density) and EX 66 (100 cell density) all with a 229 mm diameter and 305 mm length. These traps were subjected to different particulate matter loadings at different speeds. The traps were not catalyzed.