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The use of catalyzed diesel particulate filter (CDPF) systems in light duty diesel (LDD) vehicles is becoming increasingly common. The primary functions of the system are to remove carbon monoxide (CO) and hydrocarbons (HC) from the vehicle exhaust stream, while simultaneously reducing the level of particulate matter (PM) emissions to ambient background levels. These systems can comprise either a separate diesel oxidation catalyst (DOC) and a downstream CDPF, or a single unit CDPF with the DOC functions incorporated within the CDPF. The single CDPF unit provides higher regeneration efficiency as it is located nearer to the engine and also cost benefits, as only a single unit is required compared to the alternative separate DOC and CDPF arrangement. A model describing the performance of the single unit CDPF for emissions control has been developed, with particular emphasis on achieving predictions of the CO and HC emissions over transient vehicle drive cycles.

Gasoline direct injection (GDI) engines have become very attractive in transportation due to several benefits over preceding engine technologies. However, GDI engines are associated with higher levels of particulate matter (PM) emissions, which is a major concern for human health. The aim of this work is to broaden the understanding of the effect of hydrogen combustion and the influence of the three way catalytic converter (TWC) on PM emission characteristics. The presence of hydrogen in GDI engines has been reported to reduce fuel consumption and improve the combustion process, making it possible to induce higher rates of EGR. A prototype exhaust fuel reformer build for on-board vehicle hydrogen-rich gas (reformate) production has been integrated within the engine operation and studied in this work.

The use of vanadia selective catalytic reduction (V-SCR) catalysts for NOX reduction from diesel engine exhaust is well known. These catalysts are also active for hydrocarbon (HC) and particulate matter (PM) oxidation. This dual functionality (oxidation and reduction) of V-SCR catalysts can help certain applications achieve the legislative limits with an improved margin. In this work, NOX reduction, HC and CO oxidation over V-SCR were studied independently and simultaneously in microreactor tests. The effect of various parameters (HC speciation, concentration, ANR, and NO₂/NOX ratio) was investigated and the data was used to develop a kinetic model. Oxidation of CO, C₃H₆, and n-C₁₀H₂₂ is first order in CO/HC, while C₇H₈ oxidation is less than first order in C₇H₈. All these reactions were zero order in O₂. Oxidation activity decreased in order: C₇H₈ ≻ n-C₁₀H₂₂ ≻ C₃H₆ ≻ CO. HC oxidation was inhibited by NH₃.

A one-dimensional model of a NOx trap system was developed to describe NOx storage during the lean operation, and NOx release and subsequent reduction during the rich regeneration process. The development of a NOx trap model potentially enables the optimisation of catalyst volume, precious metal loading, substrate type and regeneration strategy for these complex systems. To develop a fundamental description of catalytic activity, experiments were conducted to investigate the key processes involved in isolation (as far as possible), using a Pt/Rh/BaO/Al2O3 model catalyst. A description of the storage capacity as a function of temperature was determined using NOx breakthrough curves and the storage portion of more dynamic lean-rich cycling experiments. NOx breakthrough curves were also used for determination of rate of NOx storage. Kinetics for NOx reduction, as well as CO and HC oxidation, were determined using steady state reactor experiments.

Two approaches were adopted to study soot oxidation by NO₂; firstly microreactor tests were performed on soot produced by a soot generator over a range of NO₂ concentrations and temperatures. This enabled measurement to be made under well-controlled conditions. Secondly, soot oxidation measurements were made on an engine bench to obtain data under more realistic, if less controlled, conditions. In the microreactor work NO₂ consumption by soot oxidation and the selectivity of the soot oxidation to CO and CO₂ were measured. The latter was found to vary only slightly with temperature and to be independent of NO₂ concentration. By modeling this data using a 1-dimensional model, rate equations for the soot-NO₂ reaction were determined. These were then tested against the engine data. The soot used in this study was characterized by thermogravimetric analysis, N₂ physisorption and transmission electron microscopy.

In Gasoline Direct Injection engines, direct exposure of the injector to the flame can cause combustion products to accumulate on the nozzle, which can result in increased particulate emissions. This research observes the impact of injector fouling on particulate emissions and the associated injector spray pattern and shows how both can be reversed by utilising fuel detergency. For this purpose multi-hole injectors were deliberately fouled in a four-cylinder test engine with two different base fuels. During a four hour injector fouling cycle particulate numbers (PN) increased by up to two orders of magnitude. The drift could be reversed by switching to a fuel blend that contained a detergent additive. In addition, it was possible to completely avoid any PN increase, when the detergent containing fuel was used from the beginning of the test. Microscopy showed that increased injector fouling coincided with increased particulate emissions.

The hydrocarbon-SCR activity of a silver catalyst has been examined using actual exhaust gas from a diesel engine, without any fuel being added to the reactor inlet. This work is a further step in the development of an active lean-NOx catalyst for aftertreatment of exhaust streams that contain an excess of hydrocarbon relative to NOx. The engine tests follow on from laboratory studies, in which the activity was related to the composition and formulation of the catalyst, the concentration and speciation of the hydrocarbon reductants, and the composition and temperature of simulated exhaust gas. In all the tests described here, the exhaust gas has been provided by an engine operating on ultra-low sulphur diesel fuel. NOx-reduction has been measured as a function of engine load, engine speed, in-cylinder fuel injection timing, exhaust gas temperature, and exhaust gas recirculation. Over 60% conversion to N2 has been achieved at exhaust gas temperatures around 290°C.

Control of NOx and Particulate Matter (PM) emissions from diesel engines remains a significant challenge. One approach to reduce both emissions simultaneously without fuel economy penalty is the reformed exhaust gas recirculation (REGR) technique, where part of the fuel is catalytically reacted with hot engine exhaust gas to produce a hydrogen-rich combustible gas that is then fed to the engine. On the contrary to fuel cell technology where the reforming requirements are to produce a reformate with maximized H2 concentration and minimized (virtually zero) CO concentration, the key requirement of the application of the exhaust gas fuel reforming technique in engines is the efficient on-demand generation of a reformate with only a relatively low concentration of hydrogen (typically up to 20%).

Particulate Matter (PM) emissions are of increasing importance, as diesel emissions legislation continues to tighten around the world. Diesel PM can be controlled using Diesel Particulate Filters (DPFs), which can effectively reduce the level of carbon (soot) emissions to ambient background levels. The Johnson Matthey Continuously Regenerating Trap (CRT®) [1], which will be referred to as the Continuously Regenerating DPF (CR-DPF) for the remainder of this paper, has been widely applied in Heavy Duty Diesel (HDD) applications, and has been proved to have outstanding field durability [2]. To widen the potential application of this system, addition of a platinum based catalyst to the DPF has been shown to lead to a higher PM removal rate under passive regeneration conditions, using the NOx contained in the exhaust gases.

The blending of oxygenated compounds with gasoline is projected to increase because oxygenate fuels can be produced renewably, and because their high octane rating allows them to be used in substitution of the aromatic fraction in gasoline. Blending oxygenates with gasoline changes the fuels' properties and can have a profound affect on the distillation curve, both of which are known to affect engine-out emissions. In this work, the effect of blending methanol and ethanol with gasoline on unburned hydrocarbon and particulate emissions is experimentally determined in a spray guided direct injection engine. Particulate number concentration and size distribution were measured using a Cambustion DMS500. These data are presented for different air fuel ratios, loads, ignition timings and injection timings. In addition, the ASTM D86 distillation curve was modeled using the binary activity coefficients method for the fuel blends used in the experiments.

Biofuels development and specification are currently driven by the engine (mainly gasoline- and diesel-type) technology, existing fossil fuel specification and availability of feedstock. The ability to use biofuels with conventional fuels without jeopardising the standard fuel specifications is a very effective means for the implementation of these fuels. In this work the effect of dual fuelling with in-cylinder injected ULSD fuel or synthetic second generation biofuels (a Gas-To-Liquid GTL fuel as a surrogate of these biofuels as its composition, specifications and production process are very similar to second generation biofuels) and with inlet port injected bioethanol on the engine performance and emissions were investigated. The introduction of anhydrous bioethanol improved the NOx and smoke emissions, but increased total hydrocarbons and carbon monoxide.

The regeneration of a Diesel Particulate Filter (DPF) is dependent on both the amount and type of soot present on the filter. The objective of this work is to understand how the fuel can affect this ease with which soot can be oxidized. This soot was produced in a two-cylinder four-stroke direct-injection diesel engine, operated with a matrix of fuels with varying aromatic and sulphur level. Their oxidation behaviour in different environments was determined by Temperature Programmed Oxidation in TGA and a six-flow reactor. Transmission electron microscopy was used to examine the soot morphology. Oxidation with only O2 shows oxidation temperatures strongly dependent on the fuel type. Soot oxidation in the presence of NO and a Pt-catalyst results in a lower oxidation temperature. SO2 has an inhibiting effect leading to higher soot oxidation temperature.

A prototype catalyst has been developed and integrated within the aftertreatment exhaust system to control the HC, CO, PM and NOx emissions from diesel exhaust gas. The catalyst activity in removing HC and nano-particles was examined with exhaust gas from a diesel engine operating on biodiesel - Rapeseed Methyl Ester (RME). The tests were carried out at steady-state conditions for short periods of time, thus catalyst tolerance to sulphur was not examined. The prototype catalyst reduced the amount of hydrocarbons (HC) and the total PM. The quantity of particulate with electrical mobility diameter in nucleation mode size < 10nm, was significantly reduced over the catalyst. Moreover, it was observed that the use of EGR (20% vol.) for the biodiesel fuelled engine significantly increases the particle concentration in the accumulation mode with simultaneous reduction in the particle concentration in the nuclei mode.

Limits on the total future potential of biodiesel fuel due to the availability of raw materials mean that ambitious 20% fuel replacement targets will need to be met by the use of both first and next generation biodiesel fuels. The use of higher percentage biodiesel blends requires engine recalibration, as it affects engine performance, combustion patterns and emissions. Previous work has shown that the combustion of 50:50 blends of biodiesel fuels (first generation RME and next generation synthetic fuel) can give diesel fuel-like performance (i.e. in-cylinder pressure, fuel injection and heat release patterns). This means engine recalibration can be avoided, plus a reduction in all the regulated emissions. Using a 30% biodiesel blend (with different first and next generation proportions) mixed with Diesel may be a more realistic future fuel.

Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.

The aftertreatment challenge in the non-road market is making the same system work and fit not just in one machine, but in hundreds of different machines, some of which can be used for many different purposes. This huge diversity of applications and the relatively small unit numbers for each application, coupled with the rapid introduction of new standards and the very high performance needed from the engines and machines, requires a sophisticated approach to product development. Furthermore, as emissions requirements become ever more stringent, designing a system to meet the legislation subject to packaging and cost constraints becomes progressively more difficult. This is further exacerbated by increasing system complexity, where more than one technology may be required to control all the legislated pollutants and/or an active control strategy is involved. Also a very high degree of component integration is required.

A 1-D numerical model describing the ammonia selective catalytic reduction (SCR) de-NOx process has been developed based on data measured on a laboratory microreactor for a vanadia-titania washcoated catalyst system. Kinetics for various NH3-NOx reactions were investigated, as well as those for ammonia, CO and hydrocarbon oxidation. The model has been successfully validated against engine bench measurements, over light-off and ESC tests, under a wide range of conditions, e.g. flow rate, temperature, NO2/NO ratio, and ammonia injection rate. A very good agreement between the experimental data and the model has been achieved. The model has now been used to predict the effect of NO2/NO ratio on NOx conversion, and the effect of different ammonia injection rates on the efficiency of the SCR process.

The objective of this paper is to present a simulation model for controlling combustion phasing in order to avoid knock in turbocharged SI engines. An empirically based knock model was integrated in a one-dimensional simulation tool. The empirical knock model was optimized and validated against engine tests for a variety of speeds and λ. This model can be used to optimize control strategies as well as design of new engine concepts. The model is able to predict knock onset with an accuracy of a few crank angle degrees. The phasing of the combustion provides information about optimal engine operating conditions.

The health threat from sub-100 nm particulates, emitted in significant numbers from gasoline vehicles, and anticipated changes in legislation to address this, have prompted investigation of techniques capable of trapping and oxidizing particulates from gasoline engines. Numerical studies have indicated that cooling to encourage particle capture by thermophoresis is less effective than use of electrostatic fields. A laboratory wire-cylinder electrostatic trap is under development, showing promising initial results. As an alternative trapping technique, the effectiveness of a cordierite wall-flow filter has been demonstrated, in simulation experiments and on a GDI-engined vehicle. Catalysts have been identified for particulate oxidation at typical exhaust temperatures, using water vapour and carbon dioxide as the oxygen source and retaining activity after short-term high-temperature aging.

This paper presents a prospective combustion study about dilution effects on turbocharged SI engine at full load. It proposes a comparative analysis between lean burn and cooled exhaust gas recirculation (EGR) operation as knock improvement artifice in substitute of enrichment. The study was led on a four cylinder 2L engine on stationary test bench. A specific EGR circuit was designed in order to achieve high control of the temperature and mass flow of the recirculated gas. Thanks to instantaneous pressure cylinder transducers, a combustion analysis was carried out using an home-made code. 1-D simulations (WAVE code) were used to complete the analysis on volumetric efficiency and turbocharger behaviour. A real advantage of cooled EGR was observed in the study compared to lean burn or enrichment in terms of performance, heat exchange and specific fuel consumption.