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Journal Article

Determination of PEMS Measurement Allowances for Gaseous Emissions Regulated Under the Heavy-Duty Diesel Engine In-Use Testing Program Part 3 – Results and Validation

2009-04-20
2009-01-0938
Beginning in 2007, heavy-duty engine manufacturers in the U.S. have been responsible for verifying the compliance on in-use vehicles with Not-to-Exceed (NTE) standards under the Heavy-Duty In-Use Testing Program (HDIUT). This in-use testing is conducted using Portable Emission Measurement Systems (PEMS) which are installed on the vehicles to measure emissions during real-world operation. A key component of the HDIUT program is the generation of measurement allowances which account for the relative accuracy of PEMS as compared to more conventional, laboratory based measurement techniques. A program to determine these measurement allowances for gaseous emissions was jointly funded by the U.S. Environmental Protection Agency (EPA), the California Air Resources Board (CARB), and various member companies of the Engine Manufacturer's Association (EMA).
Journal Article

Modeling and Validation of 48V Mild Hybrid Lithium-Ion Battery Pack

2018-04-03
2018-01-0433
As part of the midterm evaluation of the 2022-2025 Light-Duty Vehicle Greenhouse Gas (GHG) Standards, the U.S. Environmental Protection Agency (EPA) developed simulation models for studying the effectiveness of 48V mild hybrid electric vehicle (MHEV) technology for reducing CO2 emissions from light-duty vehicles. Simulation and modeling of this technology requires a suitable model of the battery. This article presents the development and validation of a 48V lithium-ion battery model that will be integrated into EPA’s Advanced Light-Duty Powertrain and Hybrid Analysis (ALPHA) vehicle simulation model and that can also be used within Gamma Technologies, LLC (Westmont, IL) GT-DRIVE™ vehicle simulations. The battery model is a standard equivalent circuit model with the two-time constant resistance-capacitance (RC) blocks.
Technical Paper

Impact of Real-World Drive Cycles on PHEV Battery Requirements

2009-04-20
2009-01-1383
Plug-in hybrid electric vehicles (PHEVs) have the ability to significantly reduce petroleum consumption. Argonne National Laboratory (Argonne), working with the FreedomCAR and Fuels Partnership, helped define the battery requirements for PHEVs. Previous studies demonstrated the impact of the vehicle's characteristics, such as its class, mass, or electrical accessories, on the requirements. However, questions on the impact of drive cycles remain outstanding. In this paper, we evaluate the consequences of sizing the electrical machine and the battery to follow standard drive cycles, such as the urban dynamometer driving schedule (UDDS), as well as real-world drive cycles in electric vehicle (EV) mode. The requirements are defined for several driving conditions (e.g., urban, highway) and types of driving behavior (e.g., smooth, aggressive).
Technical Paper

Evaluation of a Passenger Car Equipped with a Direct Injection Neat Methanol Engine

1992-02-01
920196
The cyclic and steady-state vehicle emissions, fuel economy, performance, and cold start behavior of an automobile equipped with a direct injection methanol engine are compared with those of three other comparable vehicles. One of the comparable vehicles was powered by a gasoline-fueled engine, and the other two were Diesels. One of the Diesel-powered vehicles was naturally aspirated and the other was turbocharged. All evaluations were made using the same road load horsepower and equivalent test weight. All the evaluations were conducted at low mileage. The emissions of the methanol vehicle are compared to California low emission vehicle standards, and to the emissions of another methanol vehicle.
Technical Paper

Operating Characteristics of Zirconia Galvanic Cells (Lambda Sensors) in Automotive Closed-Loop Emission Control Systems

1992-02-01
920289
Simple tests were performed to investigate the operating characteristics of zirconia galvanic cells (lambda sensors) in automotive closed loop “three-way” emission control systems. Commercially available cells were exposed to typical gaseous components of exhaust gas mixtures. The voltages generated by the cells were at their maximum values when hydrogen, and, in some instances, carbon monoxide, was available for reaction with atmospheric oxygen that migrated through the cells' ceramic thimbles in ionic form. This dependence of galvanic activity on the availability of these particular reducing agents indicated that the cells were voltaic devices which operated as oxidation/reduction reaction cells, rather than simple oxygen concentration cells.
Technical Paper

Modeling and Controls Development of 48 V Mild Hybrid Electric Vehicles

2018-04-03
2018-01-0413
The Advanced Light-Duty Powertrain and Hybrid Analysis tool (ALPHA) was created by EPA to evaluate the Greenhouse Gas (GHG) emissions of Light-Duty (LD) vehicles. ALPHA is a physics-based, forward-looking, full vehicle computer simulator capable of analyzing various vehicle types combined with different powertrain technologies. The ALPHA desktop application was developed using MATLAB/Simulink. The ALPHA tool was used to evaluate technology effectiveness and off-cycle technologies such as air-conditioning, electrical load reduction technology and road load reduction technologies of conventional, non-hybrid vehicles for the Midterm Evaluation of the 2017-2025 LD GHG rule by the U.S. Environmental Protection Agency (EPA) Office of Transportation and Air Quality (OTAQ).
Technical Paper

Start Catalyst Systems Employing Heated Catalyst Technology for Control of Emissions from Methanol-Fueled Vehicles

1993-03-01
930382
EPA published the first results from evaluations of electrically heated catalyst (EHC) technology for light-duty automotive applications. Since then, a number of automakers, suppliers, and government agencies have published results from their heated catalyst development and evaluation programs. EPA has evaluated a number of start catalyst systems incorporating an EHC start catalyst followed by a larger, conventional main catalyst. These systems have proven very effective at reducing cold start related emissions from methanol vehicles at low mileage. This paper compares the results from several EHC + main catalyst evaluations conducted by EPA.
Technical Paper

Investigation into the Vehicle Exhaust Emissions of High Percentage Ethanol Blends

1995-02-01
950777
Six in-use vehicles were tested on a baseline gasoline and nine gasoline/ethanol blends to determine the effect of ethanol content in fuels on automotive exhaust emissions and fuel economy. The baseline gasoline was representative of average summer gasoline and served as the base from which the other fuels were blended. For the majority of the vehicles, total hydrocarbon, and carbon monoxide exhaust emissions as well as fuel economy decreased while NOx and acetaldehyde exhaust emissions increased as the ethanol content in the test fuel increased. Formaldehyde and carbon dioxide emissions were relatively unaffected by the addition of ethanol. The emission responses to the increased fuel oxygen levels were consistent with what would be expected from leaning-out the air/fuel ratio for a spark ignition engine. The results are shown graphically and a linear regression is performed utilizing the method of least squares to investigate statistically significant trends in the data.
Technical Paper

Emissions from Catalyst Cars Beyond 50 000 Miles and the Implications for the Federal Motor Vehicle Control Program

1978-02-01
780027
High mileage vehicles (in excess of 50,000 miles) contribute more than half of all vehicular emissions. With the new catalytic converter equipped cars, the proportional contribution of these vehicles may be even higher than for pre-catalyst vehicles. Thus a substantial portion of motor vehicle related air pollution may be caused by vehicles not subject to the manufacturer directed provisions of the Clean Air Act. This paper presents a modeling effort based on hypotheses and some preliminary data, and suggests some alternatives to combat this potential problem.
Technical Paper

In-Use Emissions of 1980 and 1981 Passenger Cars: Results of EPA Testing

1982-02-01
820975
This paper presents the results of several emission testing programs conducted by the U.S. Environmental Protection Agency. The test vehicles were primarily 1980 and 1981 passenger cars which were obtained at random from private owners. Some 1982 models were also tested. The 1328 vehicles were selected from the Los Angeles area as well as from a number of other low-altitude locations. The test sequence included the Federal Test Procedure, the Highway Fuel Economy Test and several short cycle tests. The primary purpose of the program was to gather information on current vehicles which could be used in calculations and projections of air quality and aid development of programs to improve it. The results of the program indicate that these vehicles are capable of maintaining low emission levels although high levels are also possible due to defects, deterioration, or tampering. Inspection/Maintenance programs are a feasible and effective means for correcting high levels when they occur.
Technical Paper

Toxicologically Acceptable Levels of Methanol and Formaldehyde Emissions from Methanol-Fueled Vehicles

1984-10-01
841357
The increased interest in use of methanol makes it important to determine what levels of methanol and formaldehyde emissions may be acceptable. This paper reviews the available health data for methanol and formaldehyde to define what approximate ranges of concentrations, termed ranges of concern, could be acceptable from a toxicological viewpoint. Air quality models are then used to predict the in-use fleet average exhaust emission levels in localized situations (heavily impacted by mobile sources) corresponding to these ranges of concern. Using predicted fleet compositions, approximate target emission levels are given for the light-duty portion of the fleet which could yield these fleet averages. Finally, there is a brief summary of available methanol and formaldehyde emissions data from neat methanol-fueled vehicles which are compared to the target levels.
Technical Paper

A Study of the Potential Impact of Some Unregulated Motor Vehicle Emissions

1983-06-06
830987
Studies of emissions from vehicles equipped with catalysts have shown that some unregulated emissions can increase when a catalyst is used. One example of this is sulfuric acid, which has been studied extensively. Other unregulated emissions include ammonia and hydrogen cyanide. In a number of studies, these unregulated pollutant emissions have been measured from light-duty vehicles and heavy-duty engines. These emission levels were used in air quality dispersion models to predict the resultant air quality levels. The ambient concentrations predicted for each pollutant were then compared to suggested concentrations at which adverse health effects may be found to determine if additional monitoring or control would be indicated for these pollutants. It was determined that mobile source emissions of sulfuric acid, hydrogen cyanide, and ammonia do not in general result in ambient levels of concern for the air quality situations studied.
Technical Paper

Automotive Hydrocarbon Emission Patterns in the Measurement of Nonmethane Hydrocarbon Emission Rates

1977-02-01
770144
The advent of emission control technology has resulted in significant changes in both the total mass and detailed patterns of hydrocarbons emitted from automobiles. Emission rates of 56 hydrocarbons from 22 motor vehicles, including catalyst and noncatalyst configurations, were determined for the Federal Urban Driving Cycle. An increased relative abundance of methane is indicated for vehicles equipped with oxidation catalysts. In view of the photochemically non-reactive nature of methane, simple and economic procedures for determination of vehicle nonmethane hydrocarbon emission rates are evaluated. In general the procedures evaluated require independent total hydrocarbon and methane analysis, with the nonmethane hydrocarbon level calculated by difference. The procedures are evaluated by comparison of indicated nonmethane hydrocarbon emission rates with rates obtained by summation of individual compound rates determined by advanced gas chromatographic procedures.
Technical Paper

A Quality Control Technique for Correlating Exhaust Gas Analysis Systems

1977-02-01
770138
A simple, inexpensive, critical flow blender has been developed for filling a tedlar bag with controllable concentrations of HC, NOx, CO2, and CO gases at levels encountered in automobile emissions testing. According to a daily schedule, a technician takes the bag to all analyzer sites in the laboratory for analysis. The concentrations indicated by each site are compared to the overall averages. The results are stored in a computerized data base from which control charts, statistical analyses, and interpretations of significant differences among test sites can be made. The precision, accuracy, and statistical interpretations of the data are discussed.
Technical Paper

Sulfuric Acid Emissions from Light Duty Vehicles

1976-02-01
760034
This paper discusses the systems used by the Office of Mobile Source Air Pollution Control of EPA to measure and analyze automotive sulfuric acid emissions. This system involves mixing the entire vehicle exhaust with dilution air in a dilution tunnel. Sulfuric acid samples are collected by passing a small portion of the dilute exhaust through Fluoropore filters. The sulfuric acid content of the filters is determined by an automated barium chloranilate method. This paper also discusses test results from a number of advanced prototype vehicles including two stratified charge cars, a Dresser carburetor vehicle, three dual catalyst cars, and a 3-way catalyst car.
Technical Paper

Light Duty Automotive Fuel Economy … Trends thru 1985

1985-05-01
850550
This, the thirteenth in a series of papers on trends in EPA fuel economy, covers both passenger cars and light trucks and concentrates on the current model year, 1985. It differs from previous papers in two ways: 1) Model years 1975, 1980 and 1985 are highlighted, with the model years in between these rarely discussed; 2) The progress of the industry, as a whole, in improving fuel economy since 1975 is emphasized, and individual manufacturer data are de-emphasized. Conclusions are presented on the trends in fuel economy of the car and light truck fleets; the Domestic, European and Japanese market sectors; and various vehicle classes.
Technical Paper

Resistive Materials Applied to Quick Light-off Catalysts

1989-02-01
890799
The application of resistive materials as part of an exhaust emission control system is presented and discussed. The importance of cold start emissions is emphasized, and results are presented from experiments conducted with two different conductive materials. Most of the testing was conducted using methanol as the fuel, although some tests were run using gasoline-fueled vehicles.
Technical Paper

Light Duty Automotive Trends Through 1986

1986-04-01
860366
This, the fourteenth in this series of papers, examines trends in fuel economy, technology usage and estimated 0 to 60 MPH acceleration time for model year 1986 passenger cars. Comparisons with previous year's data are made for the fleet as a whole and using three measures of vehicle/engine size: number of cylinders, EPA car class, and inertia weight class. Emphasis on vehicle performance and fuel metering has been expanded and analysis of individual manufacturers has been deemphasized; comparisons of the Domestic, European, and Japanese market sectors are given increased emphasis.
Technical Paper

Catalysts for Methanol Vehicles

1987-11-01
872052
A Methanol catalyst test program has been conducted in two phases. The purpose of Phase I was to determine whether a base metal or lightly-loaded noble metal catalyst could reduce Methanol engine exhaust emissions with an efficiency comparable to conventional gasoline engine catalytic converters. The goal of Phase II was the reduction of aldehyde and unburned fuel emissions to very low levels by the use of noble metal catalysts with catalyst loadings higher than those in Phase I. Catalysts tested in Phase I were evaluated as three-way converters as well as under simulated oxidation catalyst conditions. Phase II catalysts were tested as three-way converters only. For Phase I, the most consistently efficient catalysts over the range of pollutants measured were platinum/rhodium configurations. None of the catalysts tested in Phase I were able to meet a NOx level of 1 gram per mile when operated in the oxidation mode.
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