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A kinetic carbon monoxide (CO) emission model is developed to simulate engine out CO emissions for conventional diesel combustion. The model also incorporates physics governing CO emissions for low temperature combustion (LTC). The emission model will be used in an integrated system level model to simulate the operation and interaction of conventional and low temperature diesel combustion with aftertreatment devices. The Integrated System Model consists of component models for the diesel engine, engine-out emissions (such as NOx and Particulate Matter), and aftertreatment devices (such as DOC and DPF). The addition of CO emissions model will enhance the capability of the Integrated System Model to predict major emission species, especially for low temperature combustion. In this work a CO emission model is developed based on a two-step global kinetic mechanism [8].

There has been considerable interest in applying remote measuring methods to sample in-use vehicle emissions, and to characterize fleet emission behavior. A Remote Sensing Device (RSD) was used to measure on-road carbon monoxide (CO) emissions from approximately 350 in-use vehicles that had undergone transient mass emission testing at a centralized I/M lane. On-road hydrocarbon (HC) emissions were also measured by the RSD on about 50 of these vehicles. Analysis of the data indicates that the RSD identified a comparable number of the high CO emitters as the two speed I/M test only when an RSD cutpoint much more stringent than current practice was used. Both RSD and I/M had significant errors of omission in identifying High CO Emitters based on the mass emission test. The test data were also used to study the ability of the RSD to characterize fleet CO emissions.

Unique silver/alumina (Ag-Al₂O₃) catalysts developed using high-throughput discovery techniques in collaboration with BASF Corporation were investigated at General Motors Corporation under simulated lean-burn engine exhaust feed conditions for the selective catalytic reduction of NOx using hydrocarbons (HC-SCR). Hydrocarbon mixtures were used as the reductant to model the multi-component nature of diesel fuel and gasoline. Previous work has shown promising HC-SCR results in both laboratory reactor and engine dynamometer testing. This report investigates several aspects of HC-SCR catalyst durability, including thermal durability, sulfur tolerance, and hydrocarbon deactivation.

A unique catalyst developed using high-throughput discovery techniques in collaboration with BASF Corporation and Accelrys, Inc. was investigated at General Motors under simulated diesel engine exhaust feed conditions for the selective catalytic reduction of NOx. A hydrocarbon mixture was used as the reductant to model the multi-component nature of diesel fuel and the catalyst was evaluated over a wide range of temperatures (150 - 550°C) relevant to light-duty diesel exhaust. This report investigates the effects of NOx (as NO or NO2), hydrocarbon concentration level (HC:NOx ratio), oxygen concentration, NO concentration, catalyst space velocity, catalyst temperature, and the co-presence of hydrogen on steady-state NOx reduction activity. Using these results, a control strategy was developed to maximize NOx conversion over the wide-ranging exhaust conditions likely to be encountered in light-duty diesel applications.

This paper describes a method used to compare the emissions from transient operation of an engine with the emissions from steady state operating modes of the engine. Weightings were assigned to each mode based on the transient cycle under evaluation. The method of assigning the weightings for each mode took into account several factors, including the distance between each second of the transient cycle's speed-and-torque point requests (in a speed vs. torque coordinate system) and the given mode. Two transient cycles were chosen. The transient cycles were taken from actual in-use data collected on nonroad engines during in-field operation. The steady state modes selected were based on both International Standard Organization (ISO) test modes, as well as, augmentation based on contour plots of the emissions from nonroad diesel engines. Twenty-four (24) steady-state modes were used. The transient cycle's speed-and-torque points are used to weight each steady state mode in the method.

A model is presented in which distinction is made between the contributions of the different mechanisms of heat transfer to an air bag fabric during deployment. An experimental setup, designed for simulation and recording of the thermal response of permeable and coated (impermeable) air bag fabrics, is described. Comparisons between the experimental results and numerical predictions show fair agreement. The preliminary results show that the model provides a framework in which the interplay between the three convective heat transfer coefficients (two surface and one volumetric) that affect the fabric temperature (and the heat loss from the upstream bag gas) can be examined. Currently the magnitude of these surface convective heat fluxes are being examined experimentally.

The effects of varying nozzle spray angle and rail pressure on emissions and thermal efficiency each were explored using a 103-mm bore direct-injection single-cylinder diesel engine. Spray angles from 120° to 158° significantly changed the spray targeting within the 16:1 compression ratio reentrant-shaped piston bowl. At one part load operating condition injection timing was varied over a range of 15° to 30° btc to investigate pre-mixed compression ignition (PCI) combustion with 800 bar rail pressure while varying EGR to maintain a constant low NOx emission index of 0.4 g/kg. The observed trends are explained by the combined effects of spray angle and injection timing and, in particular, the calculated amount of liquid spray that misses the piston bowl is directly linked to the measured increases in HC, CO, and smoke emissions and a reduction in thermal efficiency.

Six heavy-duty diesel engines were tested for exhaust emissions on the ISO 8-mode nonroad steady-state duty cycle and the U.S. FTP highway transient test cycle. Two of these engines were baseline nonroad engines, two were Tier 1 nonroad engines, and two were highway engines. One of the Tier 1 nonroad engines and both of the highway engines were also tested on three transient cycles developed for nonroad engines. In addition, published data were collected from an additional twenty diesel engines that were tested on the 8-mode as well as at least one transient test cycle. Data showed that HC and PM emissions from diesel engines are very sensitive to transient operation while NOx emissions are much less so. Although one of the nonroad transient duty cycles showed lower PM than the steady-state duty cycles, all four of the other cycles showed much higher PM emissions than the steady-state cycle.

In 2005, the United States Environmental Protection Agency (EPA) and Southwest Research Institute (SwRI) embarked on a mission to help the city of Beijing, China, clean its air. Working with the Beijing Environmental Protection Bureau (BEPB), the effort was a pilot diesel retrofit demonstration program involving three basic retrofit technologies to reduce particulate matter (PM). The three basic technologies were the diesel oxidation catalyst (DOC), the flowthrough diesel particulate filter (FT-DPF), and the wallflow diesel particulate filter (WF-DPF). The specific retrofit systems selected for the project were verified through the California Air Resources Board (CARB) or the EPA verification protocol [1]. These technologies are generally verified for PM reductions of 20-40 percent for DOCs, 40-50 percent for the FT-DPF, and 85 percent or more for the high efficiency WF-DPF.

The attractiveness of the hydraulic hybrid concept stems from the high power density and efficiency of the pump/motors and the accumulator. This is particularly advantageous in applications to heavy vehicles, as high mass translates into high rates of energy flows through the system. Using dry case hydraulic pumps further improves the energy conversion in the system, as they have 1-4% better efficiency than traditional wet-case pumps. However, evacuation of fluid from the case introduces air bubbles and it becomes imperative to address the deaeration problems. This research develops a bubble elimination efficiency testing apparatus (BEETA) to establish quantitative results characterizing bubble removal from hydraulic fluid in a cyclone deaeration device. The BEETA system mixes the oil and air according to predetermined ratio, passes the mixture through a cyclone deaeration device, and then measures the concentration of air in the exiting fluid.

Airbag deployments are associated with loud noise of short duration, called impulse noise. Research performed in the late 1960's and early 1970's established several criteria for assessment of the risk of impulse noise-induced hearing loss for military weapons and general exposures. These criteria were modified for airbag noise in the early 1970's, but field accident statistics and experimental results with human volunteers exposed to airbags do not seem to agree with the criteria. More recent research on impulse noise from weapons firing, in particular that of Price & Kalb of the US Army Research Laboratory, has led to development of a mathematical model of the ear. This model incorporates transfer functions which alter the incident sound pressure through various parts of the ear. It also calculates a function, called the “hazard”, that is a measure of mechanical fatigue of the hair cells in the inner ear.

The two most common NOx reducing technologies, in an oxygen abundant exhaust stream, are urea selective catalytic reduction urea-SCR and lean NOx trap (LNT) catalysts. Each technology has advantages and disadvantages. Another selective catalytic reduction (SCR) catalyst that uses hydrocarbons (HC-SCR), specifically diesel fuel, as the reductant to reduce NOx emissions was investigated. This catalyst is a result of a high throughput discovery project and conducted in cooperation with BASF, Accelrys and funded by the Department of Energy (DOE.) Several full size 5.0L monolith catalysts were made and evaluated using a V6 turbo charged diesel engine connected to a dynamometer running light-duty transient test cycles. The NOx efficiency on the HWYFET and US06 tests were measured to be 92% and 76% respectively. The FTP was 60% on a weighted basis.

At the current state of diesel engine technology, all diesel engines require some sort of NOx control device to comply with Tier II Bin 5 light-duty or 2010 heavy-duty NOx emission standards. Selective Catalytic Reduction of NOx with hydrocarbons (HC-SCR) to reduce NOx from diesel exhaust emissions is an attractive technology for lean NOx control, especially when diesel fuel is used as the reductant. However, it has been reported that when diesel fuel is used as the reductant catalyst deactivation occurred. Even though this kind of deactivation is reversible at high enough temperatures, it is a deficiency that needs to be overcome for the successful implementation of the technology. We studied the HC-SCR catalyst deactivation using diesel fuel as the reductant. The variables investigated included catalyst temperature, HC:NOx ratio, NOx concentration, and space velocity. The results showed that one single parameter can be used to measure the catalyst deactivation: the HC-SCR activity.

To comply with Tier II Bin 5 light-duty or 2010 heavy-duty NOx emission standards, all diesel engines require some sort of NOx control device. Selective Catalytic Reduction of NOx with hydrocarbons (HC-SCR) to reduce NOx from diesel exhaust emissions is an attractive technology for lean NOx control, especially when diesel fuel is used as the reductant. However, it has been reported that when diesel fuel is used as the reductant catalyst deactivation occurred (1). In a companion paper, we demonstrated that the HC-deactivation is caused by the mismatch of the adsorption and desorption processes of either the reactants or the products of a normal SCR reaction (2). In this paper, we probe the nature of the catalyst deactivation with various reductants. Both hydrocarbons and oxygenates were used as the reductants. The deactivation or the mismatch in adsorption and desorption rates is molecular size or chain length dependent.

A unique silver/alumina selective catalytic reduction (SCR) catalyst which used hydrocarbons (HC-SCR) to reduce NOx emissions was investigated. Diesel fuel or ethanol were used as the reductants to evaluate catalyst performance. Several full size 5.0L monolith 2.0 and 3.0 wt.% Ag2O-Al2O3 catalysts were created. Testing was conducted using a 6.6L Duramax turbocharged heavy duty diesel engine. Dynamometer testing on the heavy duty FTP and SET 13 transient test cycles was conducted. The NOx conversion efficiency was evaluated as a function of catalyst volume, inlet cone angle, hydrocarbon to NOx ratio (HC:NOx), and space velocity. Oxygen effects on the NOx reaction and the HC slip past the HC-SCR catalyst were also determined. An FTIR was used to evaluate unregulated emissions. Testing on the heavy duty FTP and SET 13 test cycles, with diesel fuel as the reductant, resulted in a 60% and 65% NOx conversion reduction respectively.

One way to achieve low temperature regeneration on diesel particulate traps is to employ NO2 as the oxidant. However, the engine may not produce sufficient NOx to achieve the required particulate regeneration. An RRT (rolling regeneration trap) was proposed as a way to enhance the effective concentration in diesel engine exhaust. The RRT uses catalyzed ceramic foam, which allows repeated use of existing NOx in the exhaust stream. The ceramic foam is a filter itself: thus, it can reduce the particulate loading on the wall-flow filter, which is more prone to plugging by the particulate deposits. Furthermore, the presence of particulate matter in the catalyzed section circumvents the high temperature limit imposed by thermodynamic equilibrium of a simple NO+NO2 +O2 system. However, experimental results revealed that the regeneration efficiency on the wall-flow section was very low and NO2 slip is an issue.

Simple devices have been shown to be capable of tailoring the flow field around a vehicle and reducing aerodynamic drag. An experimental and computational investigation of a drag reduction device for bluff bodies in ground proximity has been conducted. The main goal of the research is to gain a better understanding of the drag reduction mechanisms in bluff-body square-back geometries. In principle, the device modifies the flow field behind the test model by disturbing the shear layer. As a consequence, the closure of the wake is altered and reductions in aerodynamic drag of more than 20 percent are observed. We report unsteady base pressure, hot-wire velocity fluctuations and Particle Image Velocimetry (PIV) measurements of the near wake of the two models (baseline and the modified models). In addition, the flows around the two configurations are simulated using the Reynolds Averaged Navier-Stokes (RANS) equations in conjunction with the V2F turbulence model.

The steady-state reduction of NOx at temperatures between 150-300°C has been investigated under simulated lean-burn conditions using a two-stage transient flow reactor system consisting of non-thermal plasma in combination with a sodium Y zeolite catalyst. Reactivity comparisons were made with and without plasma operation in order to identify the plasma-generated hydrocarbon species necessary for the selective catalytic reduction (SCR) of NOx. With propene as the hydrocarbon in the feed, NO is completely oxidized to NO2 in the plasma and the formation of oxidized carbon-containing species include formaldehyde, acetaldehyde, carbon monoxide, carbon dioxide, and methanol. Fourier transform infrared (FTIR) measurements indicate a close carbon balance between plasma inlet and outlet gas feed concentrations, signifying the major species have been identified.

The use of a partial flow sampling system (PFSS) to measure nonroad steady-state diesel engine particulate matter (PM) emissions is a technique for certification approved by a number of regulatory agencies around the world including the US EPA. Recently, there have been proposals to change future nonroad tests to include testing over a nonroad transient cycle. PFSS units that can quantify PM over the transient cycle have also been discussed. The full flow constant volume sampling (CVS) technique has been the standard method for collecting PM under transient engine operation. It is expensive and requires large facilities as compared to a typical PFSS. Despite the need for a cheaper alternative to the CVS, there has been a concern regarding how well the PM measured using a PFSS compared to that measured by the CVS. In this study, three PFSS units, including AVL SPC, Horiba MDLT, and Sierra BG-2 were investigated in parallel with a full flow CVS.

Simple tests were performed to investigate the operating characteristics of zirconia galvanic cells (lambda sensors) in automotive closed loop “three-way” emission control systems. Commercially available cells were exposed to typical gaseous components of exhaust gas mixtures. The voltages generated by the cells were at their maximum values when hydrogen, and, in some instances, carbon monoxide, was available for reaction with atmospheric oxygen that migrated through the cells' ceramic thimbles in ionic form. This dependence of galvanic activity on the availability of these particular reducing agents indicated that the cells were voltaic devices which operated as oxidation/reduction reaction cells, rather than simple oxygen concentration cells.