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Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

Selective Catalytic Reduction (SCR), using urea injection, is being examined as a method for substantial reduction of oxides of nitrogen (NOx) for diesel engines, but the urea injection rates must be controlled to match the NOx production which may need to be predicted during open loop control. Unfortunately NOx is usually measured in the laboratory using a full-scale dilution tunnel and chemiluminescent analyzer, which cause delay and diffusion (in time) of the true manifold NOx concentration. Similarly, delay and diffusion of measurements of all emissions cause the task of creating instantaneous emissions models for vehicle simulations more difficult. Data were obtained to relate injections of carbon dioxide (CO2) into a tunnel with analyzer measurements. The analyzer response was found to match a gamma distribution of the input pulse, so that the analyzer output could be modeled from the tunnel CO2 input.

A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

Cummins Westport Inc. (CWI) released for production the latest version of its C8.3G natural gas engine, the C Gas Plus, in July 2001. This engine has increased ratings for horsepower and torque, a full-authority engine controller, wide tolerance to natural gas fuel (the minimum methane number is 65), and improved diagnostics capability. The C Gas Plus also meets the California Air Resources Board optional low-NOx (2.0 g/bhp-h) emission standard for automotive and urban buses. Two pre-production C Gas Plus engines were operated in a Viking Freight fleet for 12 months as part of the U.S. Department of Energy's Fuels Utilization Program. In-use exhaust emissions, fuel economy, and fuel cost were collected and compared with similar 1997 Cummins C8.3 diesel tractors. CWI and the West Virginia University developed an ad-hoc test cycle to simulate the Viking Freight fleet duty cycle from in-service data collected with data loggers.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

The recent oil crisis has once again emphasized the need to develop both fuel efficient engines and alternately fueled engines, particularly for automotive applications. Engines which burn coal or coal pyrolysis products are attractive, but ignition delay and metal erosion problems continue to limit high speed operation of such engines. Further, the throttled spark ignition engine often used with methanol and natural gas does not prove an efficient or tolerant device for the combustion of a wide range of fuel. Therefore, an novel approach must be taken in order to achieve the efficient and flexible operation of such an engine. A novel design of a fuel tolerant engine suitable for burning coal fuels separates the combustion from the piston in order to have more careful flame control and to exclude the particulate matter from the engine's piston rings.

Gaseous and particulate emissions from heavy-duty vehicles are affected by fuel types, vehicle/engine parameters, driving characteristics, and environmental conditions. Transient chassis tests were conducted on twenty-six heavy-duty vehicles fueled with methanol, compressed natural gas (CNG), #1 diesel, and #2 diesel, using West Virginia University (WVU) Transportable Heavy-Duty Vehicle Emissions Testing Laboratory. The vehicles were operated on the central business district (CBD) testing cycle, and regulated emissions of carbon monoxide (CO), total hydrocarbon (HC), nitrogen oxides (NOx), and particulate matter (PM) were measured. Comparisons of regulated emissions results revealed that the vehicles powered on methanol and CNG produced much lower particulate emissions than the conventionally fueled vehicles.

The West Virginia University (WVU) Transportable Heavy-Duty Vehicle Emissions Testing Laboratory was employed to conduct chassis dynamometer tests in the field to measure the exhaust emissions from heavy-duty buses and trucks. This laboratory began operation in the field in January, 1992. During the period January, 1992 through June, 1993, over 150 city buses, trucks, and tractors operated by 18 different authorities in 11 states were tested by the facility. The tested vehicles were powered by 14 different types of engines fueled with natural gas (CNG or LNG), methanol, ethanol, liquified petroleum gas (LPG), #2 diesel, and low sulfur diesel (#1 diesel or Jet A). Some of the tested vehicles were equipped with exhaust after-treatment systems. In this paper, a total of 12 CNG-fueled and #2 diesel-fueled transit buses equipped with Cummins L-10 engines, were chosen for investigation.

Results of a research effort directed towards identifying and measuring the genotoxic properties of respirable particulate matter involved in mining exposures, especially those which may synergistically affect genotoxic hazard, are presented. Particulate matter emissions from a direct injection diesel engine have been sampled and assayed to determine the genotoxic potential as a function of engine operating conditions. Diesel exhaust from a Caterpillar 3304 diesel engine, representative of the ones found in underground mines, rated 100 hp at 2200 rpm is diluted in a multi-tube mini-dilution tunnel and the particulate matter is collected on 70 mm fluorocarbon coated glass fiber filters as well as on 8″ x 10″ hi-volume filters. A six mode steady state duty cycle was used to relate engine operating conditions to the genotoxic potential.

Techniques have been developed to sample and speciate dilute heavy duty diesel exhaust to determine the specific reactivities and the ozone forming potential. While the Auto/Oil Air Quality Improvement Research Program (AQIRP) has conducted a comprehensive investigation to develop data on potential improvements in vehicle emissions and air quality from reformulated gasoline and various other alternative fuels. However, the development of sampling protocols and speciation of heavy duty diesel exhaust is still in its infancy [1, 2, 3, 4, 5 and 6]. This paper focuses on the first phase of the heavy duty diesel speciation program, that involves the development of a unique set of sampling protocols for the gas phase, semi-volatile and particulate matter from the exhaust of engines operating on different types of diesel fuel. Effects of sampling trains, sampling temperatures, semi-volatile adsorbents and driving cycles are being investigated.

A heavy-duty engine testing project involving Cummins Engine Company, Southwest Research Institute (SwRI), and West Virginia University (WVU) has been completed. This project evaluated the transient exhaust gas emissions rate of Cummins N-14 heavy-duty diesel engines converted to natural gas. Three heavy-duty N-14 diesel engines were converted to run on natural gas using a lean burn strategy by SwRI and are in field service in Santa Barbara Air Pollution Control District (SBAPCD). Two of the engines were tested under a steady-state cycle that simulates the U.S. heavy-duty transient cycle. The third engine was tested at the WVU Engine Research Laboratory following the U.S. Federal Test Procedure (FTP). However, at WVU, lean burn combustion strategy was shifted rich of stoichiometric during idling time of the FTP test. This may have caused the engine to produce more total hydrocarbons (THC) and carbon monoxide (CO).

Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).

Hybrid diesel electric buses offer the advantage of superior fuel economy through use of regenerative braking and lowered transient emissions by reducing the need of the engine to follow load as closely as in a conventional bus. With the support of the Department of Energy (DOE), five Lockheed Martin-Orion hybrid diesel-electric buses were operated on the West Virginia University Transportable Laboratory in Brooklyn, New York. The buses were exercised through a new cycle, termed the Manhattan cycle, that was representative of today's bus use as well as the accepted Central Business District Cycle and New York Bus Cycle. Emissions data were corrected for the state of charge of the batteries. The emissions can be expressed in units of grams/mile, grams/axle hp-hr and grams/gallon fuel. The role of improved fuel economy in reducing oxides of nitrogen relative to conventional automatic buses is evident in the data.

The emissions reduction benefits of Fischer-Tropsch (FT) diesel fuel have been shown in several recent published studies in both engine testing and in-use vehicle testing. FT diesel fuel shows significant advantages in reducing regulated engine emissions over conventional diesel fuel primarily to: its zero sulfur specification, implying reduced particulate matter (PM) emissions, its relatively lower aromaticity, and its relatively high cetane rating. However, the actual effect of FT diesel formulation on the in-cylinder combustion characteristics of unmodified modern heavy-duty diesel engines is not well documented. As a result, a Navistar T444E (V8, 7.3 liter) engine, instrumented for in-cylinder pressure measurement, was installed on an engine dynamometer and subjected to steady-state emissions measurement using both conventional Federal low sulfur pump diesel and a natural gas-derived FT fuel.

Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California #2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NOx) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state #2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without.

Emissions from heavy-duty vehicles may be reduced through the introduction of clean diesel formulations, and through the use of catalyzed particulate matter filters that can enjoy increased longevity and performance if ultra-low sulfur diesel is used. Twenty over-the-road tractors with Detroit Diesel Series 60 engines were selected for this study. Five trucks were operated on California (CA) specification diesel (CARB), five were operated on ARCO (now BP Amoco) EC diesel (ECD), five were operated on ARCO ECD with a Johnson-Matthey Continuously Regenerating Technology (CRT) filter and five were operated on ARCO ECD with an Engelhard Diesel Particulate Filter (DPX). The truck emissions were characterized using a transportable chassis dynamometer, full-scale dilution tunnel, research grade gas analyzers and filters for particulate matter (PM) mass collection. Two test schedules, the 5 mile route and the city-suburban (heavy vehicle) route (CSR), were employed.

Hybrid-electric transit buses offer benefits over conventional transit buses of comparable capacity. These benefits include reduced fuel consumption, reduced emissions and the utilization of smaller engines. Factors allowing for these benefits are the use of regenerative braking and reductions in engine transient operation through sophisticated power management systems. However, characterization of emissions from these buses represents new territory: the whole vehicle must be tested to estimate real world tailpipe emissions levels and fuel economy. The West Virginia University Transportable Heavy Duty Emissions Testing Laboratories were used to characterize emissions from diesel hybrid-electric powered as well as diesel and natural gas powered transit buses in Boston, MA and New York City.

West Virginia University characterized the emissions and fuel economy performance of a 30-foot 2010 transit bus equipped with urea selective catalytic reduction (u-SCR) exhaust aftertreatment. The bus was exercised over speed-time driving schedules representative of both urban and on-highway activity using a chassis dynamometer while the exhaust was routed to a full-scale dilution tunnel with research grade emissions analyzers. The Paris speed-time driving schedule was used to represent slow urban transit bus activity while the Cruise driving schedule was used to represent on-highway activity. Vehicle weights representative of both one-half and empty passenger loading were evaluated. Fuel economy observed during testing with the urban driving schedule was significantly lower (55%) than testing performed with the on-highway driving schedule.

Relationships between diesel particulate matter (PM) mass and gaseous emissions mass produced by engines have been explored to determine whether any gaseous species may be used as surrogates to infer PM quantitatively. It was recognized that sulfur content of fuel might independently influence PM mass, since PM historically is composed of elemental carbon, organic carbon, sulfuric acid, ash and wear particles. Previous research has suggested that PM may be correlated with carbon monoxide (CO) for an engine that is exercised through a variety of speed and load cycles, but that the correlation does not extend to a group of engines. Large databases from the E-55/59 and Gasoline/Diesel PM Split programs were employed, along with the IBIS bus emissions database and several additional data sets for on- and off-road engines to examine possible relationships.