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Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.

Producing and using renewable fuels for transportation is one approach for a sustainable energy future for the United States, as well as the rest of the world. Renewable fuels may also substantially reduce contributions to global climate change. In the transportation sector, ethanol produced from biomass shows promise as a future fuel for spark-ignited engines because of its high octane quality. Ethanol, however, is not a high-quality compression-ignition fuel. Ethanol can be easily converted through a dehydration process to produce diethyl ether (DEE), which is an excellent compression-ignition fuel with higher energy density than ethanol. DEE has long been known as a cold-start aid for engines, but little is known about using DEE as a significant component in a blend or as a complete replacement for diesel fuel.

The objective of this project, which is supported by the U.S. Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL), is to provide a comprehensive comparison of heavy-duty trucks operating on alternative fuels and diesel fuel. Data collection from up to eight sites is planned. This paper summarizes the design of the project and early results from the first two sites. Data collection is planned for operations, maintenance, truck system descriptions, emissions, duty cycle, safety incidents, and capital costs and operating costs associated with the use of alternative fuels in trucking.

Biodiesel fuels benefit both from being a renewable energy source and from decreasing in carbon monoxide (CO), total hydrocarbons (THC), and particulate matter (PM) emissions relative to petroleum diesel. The oxides of nitrogen (NOx) emissions from biodiesel blended fuels reported in the literature vary relative to baseline diesel NOx, with no NOx change or a NOx decrease found by some to an increase in NOx found by others. To explore differences in NOx, two Cummins ISM engines (1999 and 2004) were operated on 20% biodiesel blends during the heavy-duty transient FTP cycle and the steady state Supplemental Emissions Test. For the 2004 Cummins ISM engine, in-cylinder pressure data were collected during the steady state and transient tests. Three types of biodiesel fuels were used in the blends: soy, tallow (animal fat), and cottonseed. The FTP integrated emissions of the B20 blends produced a 20-35% reduction in PM and no change or up to a 4.3% increase in NOx over the neat diesel.

The Fischer-Tropsch (F-T) catalytic conversion process can be used to synthesize diesel fuels from a variety of feedstocks, including coal, natural gas and biomass. Synthetic diesel fuels can have very low sulfur and aromatic content, and excellent autoignition characteristics. Moreover, Fischer-Tropsch diesel fuels may also be economically competitive with California diesel fuel if produced in large volumes. An overview of Fischer-Tropsch diesel fuel production and engine emissions testing is presented. Previous engine laboratory tests indicate that F-T diesel is a promising alternative fuel because it can be used in unmodified diesel engines, and substantial exhaust emissions reductions can be realized. The authors have performed preliminary tests to assess the real-world performance of F-T diesel fuels in heavy-duty trucks. Seven White-GMC Class 8 trucks equipped with Caterpillar 10.3 liter engines were tested using F-T diesel fuel.

Dual primary full-flow dilution tunnels represent an integral part of a heavy-duty transportable emissions measurement laboratory designed and constructed to comply with US Code of Federal Regulations (CFR) 40 Part 1065 requirements. Few data exist to characterize the evolution of particulate matter (PM) in full scale dilution tunnels, particularly at very low PM mass levels. Size distributions of ultra-fine particles in diesel exhaust from a naturally aspirated, 2.4 liter, 40 kW ISUZU C240 diesel engine equipped with a diesel particulate filter (DPF) were studied in one set of standard primary and secondary dilution tunnels with varied dilution ratios. Particle size distribution data, during steady-state engine operation, were collected using a Cambustion DMS500 Fast Particulate Spectrometer. Measurements were made at four positions that spanned the tunnel cross section after the mixing orifice plate for the primary dilution tunnel and at the outlet of the secondary dilution tunnel.

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

This paper summarizes the several of the studies in the Environmental Science Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of the Environmental Science Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources. The Program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. Each project in the Program is designed to address policy-relevant objectives. Current projects in the Environmental Science Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements; emission inventory development/improvement; ambient impacts, including health effects.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

Cummins Westport Inc. (CWI) released for production the latest version of its C8.3G natural gas engine, the C Gas Plus, in July 2001. This engine has increased ratings for horsepower and torque, a full-authority engine controller, wide tolerance to natural gas fuel (the minimum methane number is 65), and improved diagnostics capability. The C Gas Plus also meets the California Air Resources Board optional low-NOx (2.0 g/bhp-h) emission standard for automotive and urban buses. Two pre-production C Gas Plus engines were operated in a Viking Freight fleet for 12 months as part of the U.S. Department of Energy's Fuels Utilization Program. In-use exhaust emissions, fuel economy, and fuel cost were collected and compared with similar 1997 Cummins C8.3 diesel tractors. CWI and the West Virginia University developed an ad-hoc test cycle to simulate the Viking Freight fleet duty cycle from in-service data collected with data loggers.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

The recent oil crisis has once again emphasized the need to develop both fuel efficient engines and alternately fueled engines, particularly for automotive applications. Engines which burn coal or coal pyrolysis products are attractive, but ignition delay and metal erosion problems continue to limit high speed operation of such engines. Further, the throttled spark ignition engine often used with methanol and natural gas does not prove an efficient or tolerant device for the combustion of a wide range of fuel. Therefore, an novel approach must be taken in order to achieve the efficient and flexible operation of such an engine. A novel design of a fuel tolerant engine suitable for burning coal fuels separates the combustion from the piston in order to have more careful flame control and to exclude the particulate matter from the engine's piston rings.

With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.

Gaseous and particulate emissions from heavy-duty vehicles are affected by fuel types, vehicle/engine parameters, driving characteristics, and environmental conditions. Transient chassis tests were conducted on twenty-six heavy-duty vehicles fueled with methanol, compressed natural gas (CNG), #1 diesel, and #2 diesel, using West Virginia University (WVU) Transportable Heavy-Duty Vehicle Emissions Testing Laboratory. The vehicles were operated on the central business district (CBD) testing cycle, and regulated emissions of carbon monoxide (CO), total hydrocarbon (HC), nitrogen oxides (NOx), and particulate matter (PM) were measured. Comparisons of regulated emissions results revealed that the vehicles powered on methanol and CNG produced much lower particulate emissions than the conventionally fueled vehicles.

The West Virginia University (WVU) Transportable Heavy-Duty Vehicle Emissions Testing Laboratory was employed to conduct chassis dynamometer tests in the field to measure the exhaust emissions from heavy-duty buses and trucks. This laboratory began operation in the field in January, 1992. During the period January, 1992 through June, 1993, over 150 city buses, trucks, and tractors operated by 18 different authorities in 11 states were tested by the facility. The tested vehicles were powered by 14 different types of engines fueled with natural gas (CNG or LNG), methanol, ethanol, liquified petroleum gas (LPG), #2 diesel, and low sulfur diesel (#1 diesel or Jet A). Some of the tested vehicles were equipped with exhaust after-treatment systems. In this paper, a total of 12 CNG-fueled and #2 diesel-fueled transit buses equipped with Cummins L-10 engines, were chosen for investigation.

Results of a research effort directed towards identifying and measuring the genotoxic properties of respirable particulate matter involved in mining exposures, especially those which may synergistically affect genotoxic hazard, are presented. Particulate matter emissions from a direct injection diesel engine have been sampled and assayed to determine the genotoxic potential as a function of engine operating conditions. Diesel exhaust from a Caterpillar 3304 diesel engine, representative of the ones found in underground mines, rated 100 hp at 2200 rpm is diluted in a multi-tube mini-dilution tunnel and the particulate matter is collected on 70 mm fluorocarbon coated glass fiber filters as well as on 8″ x 10″ hi-volume filters. A six mode steady state duty cycle was used to relate engine operating conditions to the genotoxic potential.

Techniques have been developed to sample and speciate dilute heavy duty diesel exhaust to determine the specific reactivities and the ozone forming potential. While the Auto/Oil Air Quality Improvement Research Program (AQIRP) has conducted a comprehensive investigation to develop data on potential improvements in vehicle emissions and air quality from reformulated gasoline and various other alternative fuels. However, the development of sampling protocols and speciation of heavy duty diesel exhaust is still in its infancy [1, 2, 3, 4, 5 and 6]. This paper focuses on the first phase of the heavy duty diesel speciation program, that involves the development of a unique set of sampling protocols for the gas phase, semi-volatile and particulate matter from the exhaust of engines operating on different types of diesel fuel. Effects of sampling trains, sampling temperatures, semi-volatile adsorbents and driving cycles are being investigated.

Understanding the nitric oxide (NO) conversion process plays a major role in optimizing the Selective NOX Recirculation (SNR) technique. SNR has been proven in gasoline and diesel engines, with up to 90% NOX conversion rates being achieved. This technique involves adsorbing NOX from an exhaust stream, then selectively desorbing the NOX into a concentrated NOX stream, which is fed back into the engine's intake, thereby converting a percentage of the concentrated NOX stream into harmless gases. The emphasis of this paper is on the unique chemical kinetic modeling problem that occurs with high concentrations of NOX in the intake air of a spark ignited natural gas engine with SNR. CHEMKIN, a chemical kinetic solver software package, was used to perform the reaction modeling. A closed homogeneous batch reactor model was used to model the fraction of NOX versus time for varying initial conditions and constants.

Emissions from trucks and buses equipped with Caterpillar dual-fuel natural gas (DFNG) engines were measured at two chassis dynamometer facilities: the West Virginia University (WVU) Transportable Emissions Laboratory and the Los Angeles Metropolitan Transportation Authority (LA MTA). Emissions were measured over four different driving cycles. The average emissions from the trucks and buses using DFNG engines operating in dual-fuel mode showed the same trends in all tests - reduced oxides of nitrogen (NOx) and particulate matter (PM) emissions and increased hydrocarbon and carbon monoxide (CO) emissions - when compared to similar diesel trucks and buses. The extent of NOx reduction was dependent on the type of test cycle used.

The objective of this project, which is supported by the U.S. Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL), is to provide a comprehensive comparison of heavy-duty trucks operating on alternative fuels and diesel fuel. Data collection from up to eight sites is planned. Currently, the project has four sites: Raley's in Sacramento, CA (Kenworth, Cummins L10-300G, liquefied natural gas - LNG); Pima Gro Systems, Inc. in Fontana, CA (White/GMC, Caterpillar 3176B Dual-Fuel, compressed natural gas - CNG); Waste Management in Washington, PA (Mack, Mack E7G, LNG); and United Parcel Service in Hartford, CT (Freightliner Custom Chassis, Cummins B5.9G, CNG). This paper summarizes current data collection and evaluation results from this project.