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Low temperature combustion through in-cylinder blending of fuels with different reactivity offers the potential to improve engine efficiency while yielding low engine-out NOx and soot emissions. A Navistar MaxxForce 13 heavy-duty compression ignition engine was modified to run with two separate fuel systems, aiming to utilize fuel reactivity to demonstrate a technical path towards high engine efficiency. The dual-fuel engine has a geometric compression ratio of 14 and uses sequential, multi-port-injection of a low reactivity fuel in combination with in-cylinder direct injection of diesel. Through control of in-cylinder charge reactivity and reactivity stratification, the engine combustion process can be tailored towards high efficiency and low engine-out emissions. Engine testing was conducted at 1200 rpm over a load sweep.

Striving for sustainable transportation solutions, hydrogen is often identified as a promising energy carrier and internal combustion engines are seen as a cost effective consumer of hydrogen to facilitate the development of a large-scale hydrogen infrastructure. Driven by efficiency and emissions targets defined by the U.S. Department of Energy, a research team at Argonne National Laboratory has worked on optimizing a spark-ignited direct injection engine for hydrogen. Using direct injection improves volumetric efficiency and provides the opportunity to properly stratify the fuel-air mixture in-cylinder. Collaborative 3D-CFD and experimental efforts have focused on optimizing the mixture stratification and have demonstrated the potential for high engine efficiency with low NOx emissions. Performance of the hydrogen engine is evaluated in this paper over a speed range from 1000 to 3000 RPM and a load range from 1.7 to 14.3 bar BMEP.

This experimental work focuses on defining the detailed morphology of secondary emission products derived from the combustion of cerium (Ce) fuel-borne catalyst (FBC) doped with diesel fuel. Cerium is often used to promote the oxidation of diesel particulates collected in diesel aftertreatment systems, such as diesel particulate filters (DPFs). However, it is suspected that the secondary products could be emitted from the vehicle tailpipe without being effectively filtered by the aftertreatment systems. In this work, these secondary emissions were identified by means of a high-resolution transmission electron microscope (TEM), and their properties were examined in terms of morphology and chemistry. In preparation for fuel doping, a cerium-based aliphatic organic compound solution was mixed with a low-sulfur (110 ppm) diesel fuel at 50 ppm in terms of weight concentration.

Detailed diesel particulates morphology, nanostructures, fractal geometry, and nitrogen oxides (NOx) emissions were analyzed for five different test fuels in a 1.7-L, common-rail direct-injection diesel engine. The accurately formulated fuels permit the effects of sulfur, paraffins, aromatics, and naphthene concentrations to be determined. A novel thermophoretic sampling technique was used to collect particulates immediately after the exhaust valves. The morphology and nanostructures of particulate samples were examined, imaged with a high-resolution transmission electron microscope (HRTEM), and quantitatively analyzed with customized digital image processing/data acquisition systems. The results show that the particle sizes and the total mass of particulate matter (PM) emissions correlate most strongly with the fuels' aromatics and sulfur content.

In order to achieve the targets for hydrogen engines set by the U.S. Department of Energy (DOE) - a brake thermal efficiency of 45% and nitrogen oxide (NOx) emissions below 0.07 g/mi - while maintaining the same power density as comparable gasoline engines, researchers need to investigate advanced mixture formation and combustion strategies for hydrogen internal combustion engines. Hydrogen direct injection is a very promising approach to meeting DOE targets; however, there are several challenges to be overcome in order to establish this technology as a viable pathway toward a sustainable hydrogen infrastructure. This paper describes the use of endoscopic imaging as a diagnostic tool that allows further insight into the processes that occur during hydrogen combustion. It also addresses recent progress in the development of advanced direct-injected hydrogen internal combustion engine concepts.

Gas-to-Liquids (GTL) is a liquid diesel fuel produced from natural gas, which may have certain attributes different from conventional ultra low sulfur diesel (ULSD). In this investigation, GTL, ULSD, and their blends of 20% and 50% GTL in ULSD were tested in an older Mercedes C Class (MY1999, Euro 2) and a newer Opel Astra (MY2006, Euro 4) diesel vehicle to evaluate the performance in terms of fuel consumption and emissions. Each vehicle was pre-conditioned on-road with one tank full of test fuel before actual testing in a chassis dynamometer facility. Both vehicles were calibrated for European emission standards and operation, and they were not re-calibrated for the fuel tests at Argonne National Laboratory (ANL). In the two-vehicle EPA FTP-75, US06, and Highway drive-cycle tests, the emissions of carbon dioxide on a per-mile basis (g/mi) from all GTL-containing fuels were significantly lower than those from the ULSD.

This paper evaluates the total lifecycle impacts for hauling freight long distances over land in the United States. The dominant modes of surface freight transport in the United States are large motor trucks (tractor-semitrailer combinations) and trains. These vehicles account for a significant portion of the transportation sector's petroleum usage and atmospheric emissions (among which nitrogen oxides and particulate matter are especially important). The objective of this paper is to evaluate the potential for reductions in energy use (in particular, petroleum use) and atmospheric emissions that result from freight transport, possibly as the result of research and development on improved technology or alternative fuels, such as Fischer-Tropsch diesel and natural gas, or from mode shifts in competitive markets. The impacts examined include energy use, both in toto and the petroleum fraction, and emissions of greenhouse gases and nitrogen oxides and particulate matter.

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests. The results showed that for the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel.

The limited spatial area in conventional diesel particulate filter (DPF) systems requires frequent regenerations to remove collected particulate matter (PM) emissions, consequently resulting in higher energy consumption and potential material failure. Due to the complex geometry and difficulty in access to the internal structure of diesel particulate filters, in addition, many important characteristics in filtration processes remain unknown. In this work, therefore, the geometry of DPF membrane channels was modified basically to increase the filtration areas, and their filtration characteristics were evaluated in terms of pressure drop across the DPF membranes, effects of soot loading on pressure drop, and qualitative soot mass distribution in the membrane channels. In this evaluation, an analytical model was developed for pressure drop, which allowed a parametric study with those modified membranes.

This paper reports on research activities aiming to improve the efficiency of direct injected, hydrogen powered internal combustion engines. In a recent major change in the experimental setup the hydrogen single cylinder research engine at Argonne National Laboratory was upgraded to a new engine geometry providing increased compression ratio and a longer piston stroke compared to its predecessor. The higher compression ratio and the more advantageous volume to surface ratio of the combustion chamber are both intended to improve the overall efficiency of the experimental setup. Additionally, a new series of faster acting, piezo-activated injectors is used with the new engine providing increased flexibility for the optimization of DI injection strategies. This study focuses on the comparison of experimental data of the baseline versus the improved single cylinder research engine for similar engine operating conditions.

At the current stage of engine technology, diesel engines typically require diesel particulate filter (DPF) systems to meet recent particulate emissions standards. To assure the performance and reliability of DPF systems, profound understanding of filtration and regeneration mechanisms is required. Among extensive efforts for developing advanced DPF systems, the development of effective thermal management strategies, which control the thermal runaway taking place in oxidation of an excess amount of soot deposit in DPF, is quite challenging. This difficulty stems mainly from lack of sufficient knowledge and understanding about DPF regeneration mechanisms, which need detailed information about oxidation of diesel particulate matter (PM). Therefore, this work carried out a series of oxidation experiments of diesel particulates collected from a DPF on a diesel engine, and evaluated the oxidation rates of the samples using a thermo-gravimetric analyzer (TGA).

Particulate and nitrogen oxide emissions from a 1.9-liter Volkswagen diesel engine were measured for three different fuels: neat diesel fuel, a blend of diesel fuel with 10% ethanol, and a blend of diesel fuel with 15% ethanol. Engine-out emissions were measured on an engine dynamometer for five different speeds and five different torques using the standard engine-control unit. Results show that particulate emissions can be significantly reduced over approximately two-thirds of the engine map by using a diesel-ethanol blend. Nitrogen oxide emissions can also be significantly reduced over a smaller portion of the engine map by using a diesel-ethanol blend. Moreover, there is an overlap between the regions where particulate emissions can be reduced by up to 75% and nitrogen oxide emissions are reduced by up to 84% compared with neat diesel fuel.

The medium and heavy duty vehicle industry has fostered an increase in emissions research with the aim of reducing NOx while maintaining power output and thermal efficiency. This research describes a proof-of-concept numerical study conducted on a Caterpillar single-cylinder research engine. The target of the study is to reduce NOx by taking a unique approach to combustion air handling and utilizing enriched nitrogen and oxygen gas streams provided by Air Separation Membranes. A large set of test cases were initially carried out for closed-cycle situations to determine an appropriate set of operating conditions that are conducive for NOx reduction and gas diffusion properties. Several parameters - experimental and numerical, were considered. Experimental aspects, such as engine RPM, fuel injection pressure, start of injection, spray inclusion angle, and valve timings were considered for the parametric study.

Dual-fuel combustion using port-injection of low reactivity fuel combined with direct injection of a higher reactivity fuel, otherwise known as Reactivity Controlled Compression Ignition (RCCI), has been shown as a method to achieve high efficiency combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions. A key requirement for extending to high-load operation is reduce the reactivity of the premixed charge prior to the diesel injection. One way to accomplish this is to use a very low reactivity fuel such as natural gas. In this work, experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate using RCCI combustion with port injection of natural gas and direct injection of diesel fuel. Natural gas/diesel RCCI engine operation is compared over the EPA Heavy-Duty 13 mode supplemental emissions test with and without EGR.

With an intention to improve the performance of reciprocating engines used for distributed generation US-Dept. of Energy has launched ARES program. Under this program, the performance targets for these natural gas-fuelled stationary engines are ≻ 50% efficiency and NOx emissions ≺ 0.1 g/bhp-hr by 2013. This paper presents two technologies developed under this program. Lean-burn operation is very popular with engine manufacturers as it offers simultaneous low-NOx emissions and high engine efficiencies, while not requiring the use of any aftertreatment devices. Though engines operating on lean-burn operation are capable of better performance, they are currently limited by the inability to sustain reliable ignition under lean conditions. Addressing such an issue, research has evaluated the use of laser ignition as an alternative to the conventional Capacitance Discharge Ignition (CDI).

The Hybrid Electric Vehicle Team of Virginia Tech participated in the three-year EcoCAR Advanced Vehicle Technology Competition organized by Argonne National Laboratory, and sponsored by General Motors and the U.S. Department of Energy. The team established goals for the design of a plug-in, range-extended hybrid electric vehicle that meets or exceeds the competition requirements for EcoCAR. The challenge involved designing a crossover SUV powertrain to reduce fuel consumption, petroleum energy use, regulated tailpipe emissions, and well-to-wheel greenhouse gas emissions. To interface with and control the hybrid powertrain, the team added a Hybrid Vehicle Supervisory Controller, which enacts a torque split control strategy. This paper builds on an earlier paper [1] that evaluated the petroleum energy use, criteria tailpipe emissions, and greenhouse gas emissions of the Virginia Tech EcoCAR vehicle and control strategy from the 2nd year of the competition.

Many concepts of premixed diesel combustion at reduced temperatures have been investigated over the last decade as a means to simultaneously decrease engine-out particle and oxide of nitrogen (NO ) emissions. To overcome the trade-off between simultaneously low particle and NO emissions versus high "diesel-like" combustion efficiency, a new dual-fuel technique called Reactivity Controlled Compression Ignition (RCCI) has been researched. In the present study, particle size distributions were measured from RCCI for four gasoline:diesel compositions from 65%:35% to 84%:16%, respectively. Previously, fuel blending (reactivity control) had been carried out by a port fuel injection of the higher volatility fuel and a direct in-cylinder injection of the lower volatility fuel. With a recent mechanical upgrade, it was possible to perform injections of both fuels directly into the combustion chamber.

The purpose of this study was to determine the effect of injector nozzle hole size, shape, and finish on performance and emissions in a light-duty diesel engine. Two sets of six-hole valve covered orifice (VCO) nozzles were tested with nearly identical volumetric flow rates but varying geometry and finish. The 17% hydro-erosion (HE) nozzles had a 22% larger discharge coefficient (CD), compared to the 7% HE nozzles. In order to maintain similar volumetric flow rates, the orifice diameter of the 17% HE nozzles were reduced by almost 10%.The nozzles were tested in a 1.7L, four-cylinder, common rail diesel engine, operating on conventional D2 diesel fuel. The 17% HE, conical-shaped nozzles reduced fuel specific particulate matter (PM) and increased fuel specific oxides of nitrogen (NOx) emissions, over the 7% HE, straight-shaped nozzle.

SunDiesel fuel is a biomass-to-liquid (BTL) fuel that may have certain attributes different from conventional diesel. In this investigation, 100% SunDiesel was tested both in a Mercedes A-Class (MY1999) diesel vehicle and a single-cylinder heavy-duty compression-ignition direct-injection engine. The SunDiesel's emissions and fuel consumption were significantly better than conventional diesel fuel, especially in nitrogen oxides (NOx) reduction. In the vehicle U.S. Environmental Protection Agency (EPA), Federal Test Procedure 75 (FTP-75), and New European Drive Cycle (NEDC) tests, the carbon dioxide emissions on a mile basis (g/mile) from SunDiesel fuel were almost 10% lower than the conventional diesel fuel. Similarly, in the single-cylinder engine steady-state tests, the reductions in brake specific NOx, carbon monoxide (CO), and particulate matter (PM) are equally significant. Combustion analysis, though not conclusive, indicates that there are differences deserving further research.

Detailed soot deposition and oxidation characteristics in a diesel particulate filter (DPF) have been experimentally examined on a unique bench-scale DPF test system that has a visualization window. The filtration and regeneration processes were visualized to examine soot deposition and oxidation behaviors on the filter channel surfaces, along with measurements of pressure drop across the filter. The pressure drop caused by trapped soot was separated from the measured total pressure drop by subtracting the pressure drop caused by the clean filter itself. Then, the soot-derived pressure-drop data, normalized (non-dimensionalized) by the volumetric flow rate, exhaust gas viscosity, and DPF volume, were used to compare filtration and regeneration characteristics at different experimental conditions, independently of flow conditions.