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This study was conducted to investigate the influence of low-temperature reactions on the Homogeneous Charge Compression Ignition (HCCI) combustion process. Specifically, an investigation was made of the effect of the residual gas condition on low-temperature reactions, autoignition and the subsequent state of combustion following ignition. Light emission and absorption spectroscopic measurements were made in the combustion chamber in order to investigate low-temperature reactions in detail. In addition, chemical kinetic simulations were performed to validate the experimental results and to analyze the elemental reaction process. The results made clear the formation behavior of the chemical species produced during low-temperature HCCI reactions.

The Homogenous Charge Compression Ignition (HCCI) engine is positioned as a next-generation internal combustion engine and has been the focus of extensive research in recent years to develop a practical system. One reason is that this new combustion system achieves lower fuel consumption and simultaneous reductions of nitrogen oxide (NOx) and particulate matter (PM) emissions, which are major issues of internal combustion engines today. However, the characteristics of HCCI combustion can prevent suitable engine operation owing to the rapid combustion process that occurs accompanied by a steep pressure rise when the amount of fuel injected is increased to obtain higher power output. A major issue of HCCI is to control this rapid combustion so that the quantity of fuel injected can be increased for greater power. Controlling the ignition timing is also an issue because it is substantially influenced by the chemical reactions of the fuel.

In this study, optical measurements were made of the combustion chamber gas during operation of a Homogeneous Charge Compression Ignition (HCCI) engine in order to obtain a better understanding of the ignition and combustion characteristics. The principal issues of HCCI engines are to control the ignition timing and to optimize the combustion state following ignition. Autoignition in HCCI engines is strongly influenced by the complex low-temperature oxidation reaction process, alternatively referred to as the cool flame reaction or negative temperature coefficient (NTC) region. Accordingly, a good understanding of this low-temperature oxidation reaction process is indispensable to ignition timing control. In the experiments, spectroscopic measurement methods were applied to investigate the reaction behavior in the process leading to autoignition.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted much interest as a combustion system that can achieve both low emissions and high efficiency. But the operating region of HCCI combustion is narrow, and it is difficult to control the auto-ignition timing. This study focused on the use of a two-component fuel blend and supercharging. The blended fuel consisted of dimethyl ether (DME), which has attracted interest as alternative fuel for compression-ignition engines, and methane, the main component of natural gas. A spectroscopic technique was used to measure the light emission of the combustion flame in the combustion chamber in order to ascertain the combustion characteristics. HCCI combustion characteristics were analyzed in detail in the present study by measuring this light emission spectrum.

This study clarified the influence of hot gas jet on combustion enhancement effect for lean mixture in the plasma jet ignition. The hot gas jet was generated by the high temperature plasma and was ejected from igniter after plasma jet finished issuing. In combustion tests, propane-air mixture at equivalence ratio of 0.6 was used and the mixture was filled in the combustion chamber at atmosphere pressure and room temperature. For generation of the hot gas jet, the standard air was filled in chamber at same conditions and the hot gas jet was visualized by schlieren method in the absence of combustion. The combustion development processes were also visualized and the combustion pressure was measured. The discharge voltage, discharge current and the plasma luminescence were also measured. The plasma luminescence disappeared within 0.05 ms for any experimental conditions. When cavity depth was deep and orifice diameter was small, the maximum plasma luminescence height was short.

In this study, it was shown that Homogeneous Charge Compression Ignition (HCCI) combustion in a 4-stroke engine, operating under the conditions of a high compression ratio, wide open throttle (WOT) and a lean mixture, could be simulated by raising the compression ratio of a 2-stroke engine. On that basis, a comparison was then made with the characteristics of Active Thermo-Atmosphere Combustion (ATAC), the HCCI process that is usually accomplished in 2-stroke engines under the conditions of a low compression ratio, partial throttle and a large quantity of residual gas. One major difference observed between HCCI combustion and ATAC was their different degrees of susceptibility to the occurrence of cool flames, which was attributed to differences in the residual gas state. It was revealed that the ignition characteristics of these two combustion processes differed greatly in relation to the fuel octane number.

In plasma jet ignition, combustion enhancement effects are caused toward the plasma jet issuing direction. Therefore, when the igniter is attached at the center of cylindrically shaped combustion chamber, the plasma jet should issues toward the round combustion chamber wall. The plasma jet igniter that had a concentric circular orifice has been developed. It is expected that the plasma jet is issued and is diffused from concentric circular orifice toward the combustion chamber wall. Relationship between plasma jet and igniter configuration was experimentally clarified. Plasma jet can issue from the entire concentric circular orifice for some igniter. Plasma jet is extended with increasing concentric circular orifice area. Plasma jet penetration increases with increasing concentric circular orifice width.

This research focused on the light emission behavior of the OH radical (characteristic spectrum of 306.4 nm) that plays a key role in combustion reactions, in order to investigate the influence of the residual gas on autoignition. The test engine used was a 2-stroke, air-cooled engine fitted with an exhaust pressure control valve in the exhaust manifold. When a certain level of internal EGR is forcibly applied, the temperature of the unburned end gas is raised on account of heat transfer from the hot residual gas and also due to compression by piston motion. As a result, the unburned end gas becomes active and autoignition tends to occur.

There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

This study attempted to elucidate combustion conditions in a progression from normal combustion to knocking by analyzing the ion current and light emission intensity that occurred during this transition. With the aim of understanding the combustion states involved, the ion current was measured at two positions in the combustion chamber. Light emission spectroscopy was applied to examine preflame reactions that are observed prior to autoignition in the combustion process of hydrocarbon fuels. The results obtained by analyzing the experimental data made clear the relationship between the ion current and light emission during the transition from normal combustion to knocking operation.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition in the combustion reaction process of hydrocarbon fuels. Attention was focused on light emission behavior at wavelengths corresponding to those of formaldehyde (HCHO), Vaidya's hydrocarbon flame band (HCO) and the OH radical in a forced progression from normal combustion to a knocking state. Light emission behavior was measured simultaneously in the center and in the end zone of the combustion chamber when the engine was operated on two different test fuels. The test fuels used were n-heptane (0 RON) and a blended fuel (70 RON) consisting of n-heptane (0 RON) and iso-octane (100 RON).

Homogenous Charge Compression Ignition (HCCI) combustion experiments were conducted in this study using a single-cylinder test engine fitted with a sapphire observation window to facilitate visualization of the entire cylinder bore area. In addition to in-cylinder visualization of combustion, spectroscopic measurements were made of light emission and absorption in the combustion chamber to investigate autoignition behavior in detail. Engine firing experiments were conducted to visualize HCCI combustion over a wide range of compression ratios from 12:1 to 22:1. The results showed that increasing the compression ratio advanced the ignition timing and increased the maximum pressure rise rate, making it necessary to moderate combustion. It was also found that autoignition can be induced even in a mixture lean enough to cause misfiring by raising the intake air temperature so as to advance the overall combustion process.

This study examined Homogeneous Charge Compression Ignition (HCCI) combustion characteristics in detail on the basis of in-cylinder combustion visualization, spectroscopic measurements of light emission and absorption and chemical kinetic simulations. Special attention was focused on investigating and comparing the effects of the fuel octane number and residual gas on combustion characteristics. The results made clear the relationship between the production/consumption of formaldehyde (HCHO) in the HCCI autoignition process and flame development behavior in the cylinder. Additionally, it was found that both the fuel octane number and residual gas have the effect of moderating low-temperature oxidation reactions. Furthermore, it was observed that residual gas has the effect of shifting the temperature for the occurrence of the hot flame to a higher temperature range.

The growing severity of global environmental issues in recent years, including air pollution and the depletion of fossil fuels, has made it necessary for internal combustion engines to achieve higher efficiency and lower exhaust emission levels. Calls for reducing atmospheric emissions of carbon dioxide (CO₂) necessitate thoroughgoing measures to lower the levels of CO₂ originating in the combustion process of internal combustion engines and to facilitate operation on diverse energy sources. Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest because it achieves high efficiency and can reduce particulate matter (PM) and nitrogen oxide (NOx) emissions simultaneously. These characteristics are obtainable because HCCI combustion can take place at ultra-lean conditions exceeding the limits of flame propagation.

Controlled Autoignition (CAI) combustion processes can be broadly divided between a CAI process that is applied to four-stroke engines and a CAI process that is applied to two-stroke engines. The former process is generally referred to as Homogeneous Charge Compression Ignition (HCCI) combustion and the later process as Active Thermo-Atmosphere Combustion (ATAC). The region of stable engine operation differs greatly between these two processes, and it is thought that the elucidation of their differences and similarities could provide useful information for expanding the operation region of HCCI combustion. In this research, the same two-stroke engine was operated under both the ATAC and HCCI combustion processes to compare their respective combustion characteristics. The results indicated that the ignition timing was less likely to change in the ATAC process in relation to changes in the fuel octane number than it was in the HCCI combustion process.

In this research, an investigation was made of ion current and OH radical luminescence behavior in the progression from normal combustion to knocking operation. One pair each of an ion probe and a quartz observation window was fitted in the center and on the end of the combustion chamber. The peak values of the ion voltage drop and the OH radical emission intensity both increased as the cylinder head temperature and the cylinder pressure rose. It is possible to understand combustion conditions by analyzing measured waveformes of the ion voltage drop and the OH radical emission intensity.

This research focused on the light emission behavior of the OH radical (characteristic spectrum of 306.4 [nm]) that plays a key role in combustion reactions, in order to investigate the influence of the residual gas on autoignition. Authors also analyzed on the heat release and thermodynamic mean temperature due to research activity state of unburned gas. The test engine used was a 2-stroke, air-cooled engine fitted with an exhaust pressure control valve in the exhaust manifold. Raising the exhaust pressure forcibly recirculated more exhaust gas internally. When a certain level of internal EGR is forcibly applied, the temperature of the unburned end gas is raised on account of heat transfer from the hot residual gas and also due to compression by piston motion. As a result, the unburned end gas becomes active and autoignition tends to occur.

The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.(1-3) Absorption spectroscopy was used to measure the behavior of HCHO and OH radicals during a progression from normal combustion to knocking operation. Emission spectroscopic measurements were obtained in the same way that radical added HCO. Radical behavior in preflame reactions was thus examined on the basis of simultaneous measurements, which combined each absorption wavelength with three emission wavelength by using a monochromator and a newly developed polychromator.(4-5) When n-heptane (0 RON) and blended fuel (50 RON) were used as test fuel, it was observed that radical behavior differed between normal combustion and knocking operation and a duration of the preflame reaction was shorter during the progression from normal combustion to a condition of knocking.

In this research, the effect of high-temperature residual gas, resulting from the application of a certain level of EGR, on combustion was investigated using a two-stroke engine and alcohol fuels (ethanol and methanol) and gasoline as the test fuels. Measurements were made of the light emission intensity of the OH radical on the intake and exhaust port sides of the combustion chamber and of the combustion chamber wall temperature (spark plug washer temperature) and the exhaust gas temperature. Data were measured and analyzed in a progression from normal combustion to autoignited combustion to preignition and to knocking operation.

This study investigated the effect of streamer discharge on autoignition and combustion in a Homogeneous Charge Compression Ignition (HCCI) engine. A continuous streamer discharge was generated in the center of the combustion chamber of a 2-stroke optically accessible engine that allowed visualization of the entire bore area. The experimental results showed that the flame was initiated and grew from the vicinity of the electrode under the application of a streamer discharge. Subsequently, rapid autoignition (HCCI combustion) occurred in the unburned mixture in the end zone, thus indicating that HCCI combustion was accomplished assisted by the streamer discharge. In other word, ignition timing of HCCI combustion was advanced after the streamer discharging process, and the initiation behavior of the combustion flame was made clear under that condition.