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The autoignition resistance of a practical gasoline is best characterized by the Octane Index, OI, defined as RON-KS, where RON and MON are respectively, Research and Motor Octane Numbers, S is the sensitivity (RON-MON) and K is a constant depending on the pressure and temperature history of the fuel/air mixture in an engine. Experiments in knocking SI engines, HCCI engines and in premixed compression ignition (PCI) engines have shown that if two fuels of different composition have the same OI and experience the same pressure/temperature history, they will have the same autoignition phasing. A practical gasoline is a complex mixture of hydrocarbons and a simple surrogate is needed to describe its autoignition chemistry. A mixture of toluene and PRF (iso-octane + n-heptane), TPRF, can have the same RON and S as a target gasoline and so will have the same OI at any given K value and will be a very good surrogate for the gasoline.

Demand for transport energy is growing but this growth is skewed heavily toward commercial transport, such as, heavy road, aviation, marine and rail which uses heavier fuels like diesel and kerosene. This is likely to lead to an abundance and easy availability of lighter fractions like naphtha, which is the product of the initial distillation of crude oil. Naphtha will also require lower energy to produce and hence will have a lower CO₂ impact compared to diesel or gasoline. It would be desirable to develop engine combustion systems that could run on naphtha. Many recent studies have shown that running compression ignition engines on very low Cetane fuels, which are very similar to naphtha in their auto-ignition behavior, offers the prospect of developing very efficient, clean, simple and cheap engine combustion systems. Significant development work would be required before such systems could power practical vehicles.

Extensive tests have been carried out in a single-cylinder Direct Injection Spark Ignition (DISI) engine using up to fifteen different fuels at inlet pressure of up to 3.4 bar abs. to study fuel effects as well as inlet pressure effects on knock. In addition fuel effects on particulate emissions at part-throttle were measured. Fuel anti-knock quality does not correlate with MON and is best described by the Octane Index, OI = RON-KS where S = RON -MON is the sensitivity of the fuel and K is a constant depending on the engine pressure/temperature regime. The RON of the fuels considered was in the range between 95 and 105 and the sensitivity between 8 and 13. K is negative at all the conditions tested, i.e., for a given RON, a higher sensitivity fuel has better anti-knock quality. K decreases with increasing intake pressure and more generally, decreases as Tcomp₁₅, the temperature of the unburned gas at a pressure of 15 bar decreases.

Previous work has shown that it may be advantageous to use gasoline type fuels with long ignition delays compared to today's diesel fuels in compression ignition engines. In the present work we investigate if high volatility is also needed along with low cetane (high octane) to get more premixed combustion leading to low NO and smoke. A single-cylinder light-duty compression ignition engine is run on four fuels in the diesel boiling range and three fuels in the gasoline boiling range. The lowest cetane diesel boiling range fuel (DCN = 22) also has very high aromatic content (75%vol) but the engine can be run on this to give very low NO (≺ 0.4 g/kWh) and smoke (FSN ≺ 0.1), e.g,. at 4 bar and 10 bar IMEP at 2000 RPM like the gasoline fuels but unlike the diesel fuels with DCNs of 40 and 56. If the combustion phasing and delay are matched for any two fuels at a given operating condition, their emissions behavior is also matched regardless of the differences in volatility and composition.

As SI engines strive for higher efficiency they are more likely to encounter knock and fuel anti-knock quality, which is currently measured by RON and MON, becomes more important. However, the RON and MON scales are based on primary reference fuels (PRF) - mixtures of iso-octane and n-heptane - whose autoignition chemistry is significantly different from that of practical fuels. Hence RON or MON alone can truly characterize a gasoline for its knock behavior only at their respective test conditions. The same gasoline will match different PRF fuels at different operating conditions. The true anti-knock quality of a fuel is given by the octane index, OI = RON −KS where S = RON − MON, is the sensitivity. K depends on the pressure and temperature evolution in the unburned gas during the engine cycle and hence is different at different operating conditions and is negative in modern engines.

In the context of stringent future emission standards as well as the need to reduce emissions of CO2 on a global scale, the cost of manufacturing engines is increasing. Naphtha has been shown to have beneficial properties for its use as a fuel in the transportation sector. Well to tank CO2 emissions from the production of Naphtha are lower than any other fuel produced in the refinery due to its lower processing requisites. Moreover, under current technology trends the demand for diesel is expected to increase leading to a possible surplus of light fuels in the future. Recent research has demonstrated that significant fuel consumption reduction is possible based on a direct injection gasoline engine system, when a low quality gasoline stream such as Naphtha is used in compression ignition mode. With this fuel, the engine will be at least as efficient and clean as current diesel engines but will be more cost effective (lower injection pressure, HC/CO after-treatment rather than NOx).

Previous work has showed that it may be advantageous to use fuels of lower cetane numbers compared to today's diesel fuels in compression ignition engines. The benefits come from the longer ignition delays that these fuels have. There is more time available for the fuel and air to mix before combustion starts which is favourable for achieving low emissions of NOx and smoke though premixing usually leads to higher emissions of CO and unburned hydrocarbons. In the present work, operation of a single-cylinder light-duty compression ignition engine on four different fuels of different octane numbers, in the gasoline boiling range, is compared to running on a diesel fuel. The gasoline fuels have research octane numbers (RON) of 91, 84, 78, and 72. These are compared at a low load/low speed condition (4 bar IMEP / 1200 rpm) in SOI sweeps as well as at a higher load and speeds (10 bar IMEP / 2000 and 3000 rpm) in EGR sweeps.

This research describes the potential to adopt detailed chemical kinetics for practical and potential future fuels using tri-component surrogate mixtures capable of simulating fuel octane “sensitivity” . Since the combustion characteristics of modern fuels are routinely measured using the RON and MON of the fuel, a methodology to generate detailed chemical kinetic mechanisms for these fuels based on these data is presented. Firstly, a novel correlation between various tri-component blends (comprised of i-octane, n-heptane and toluene) and fuel RON and MON was obtained by carrying out standard octane tests. Secondly, a chemical kinetic mechanism for tri-component fuels was validated using a Stochastic Reactor Model (SRM) suite, an in-cylinder engine combustion simulator, and a series of engine experiments conducted in HCCI operating mode.

The objective of this paper is to present a simulation model for controlling combustion phasing in order to avoid knock in turbocharged SI engines. An empirically based knock model was integrated in a one-dimensional simulation tool. The empirical knock model was optimized and validated against engine tests for a variety of speeds and λ. This model can be used to optimize control strategies as well as design of new engine concepts. The model is able to predict knock onset with an accuracy of a few crank angle degrees. The phasing of the combustion provides information about optimal engine operating conditions.

A field problem associated with flakes of combustion chamber deposits getting trapped on the exhaust valve seat and causing starting problems has appeared recently. Four fuels have been tested in three different car models using a deposit flaking road test procedure. For each piston top, flaking can be characterised using T1 and T2, the mean deposit thickness on the piston crown before and after flaking respectively. A new measure of deposit flaking, ΔT, the mean of (T1-T2) averaged over all cylinders has been introduced and its variance established for the standard test using one of the models. ΔT quantifies the actual amount of deposits that have flaked and is likely to be a more relevant indicator of flaking for startability problems than Rw, the mean of the ratio of T2 to T1, used in previous work. Deposit flaking is directly related to an increase in valve leakage rates and startability problems.

The auto-ignition quality of a fuel of any chemistry at a given engine condition is described by an octane index defined as, OI = (1-K) RON + K MON, where RON and MON are the Research and Motor Octane numbers respectively and K depends only on the engine design and operating conditions. The higher the OI value, the greater is the resistance to auto-ignition. A single cylinder homogeneous charge compression ignition (HCCI) engine has been run at thirty seven different operating conditions using fuels of different chemistries and different known RON and MON values. At each operating condition CA50, the crank angle for 50% of the total heat release, is established for different fuels and from this the value of K is determined. We take Tcomp15, the temperature when the pressure reaches 15 bar during the compression stroke, as a generic engine parameter. K is strongly dependent on and increases with Tcomp15 and is less strongly dependent on the mixture strength.

This is the first part of a two-part study on how to define the anti-knock quality of practical fuels. Knock intensity is measured in two single-cylinder research engines using different fuels at different mixture strengths, throttle settings and two compression ratios. The anti-knock quality of a fuel in a given engine operating condition is defined by its octane index OI = RON - KS where K is a constant for that condition and S is the sensitivity, (RON-MON), and RON and MON are the Research and Motor Octane numbers respectively. The higher the octane index, the better the anti-knock quality of the fuel. K is often assumed to be 0.5 so that OI=(RON+MON)/2. However, it is found that K depends on engine operating conditions and in some cases, K is negative so that for a given RON, a fuel with higher sensitivity (lower MON) has better anti-knock quality. The value of K decreases as the engine becomes more prone to knock i.e. as its octane requirement increases.

A new field problem associated with flakes of combustion chamber deposit (CCD) getting trapped on the exhaust valve seat has been reported by several car manufacturers in Europe. This causes difficulties in start-up and poor driveability. A road test procedure that is reasonably quick and sensitive to fuel changes has been developed to study the deposit flaking problem. The flaking of the deposits is believed to be caused by water - either generated by combustion or existing in the ambient air as water vapour - condensing on the deposits. Water is much more effective than fuel in causing deposit flaking. A way of quantifying the deposit flaking tendency has been defined and its repeatability established based on twenty-nine tests using two different cars and different fuels and additives. There are large differences between base fuels in terms of CCD flaking.

A study has been undertaken with a single-cylinder engine, based on the Mitsubishi GDi combustion system, that has the option of either port injection or direct injection. Tests have been undertaken with pure fuel components (methane, iso-octane, toluene and methanol), and a representative gasoline that has also been tested with the addition of 10% methanol and 10% ethanol. The volumetric efficiency depends both on the fuel and its time and place of injection. For stoichiometric operation with unleaded gasoline, changing from port injection to direct injection led to a 9% increase in volumetric efficiency, which was improved by a further 3% when 10% methanol was blended with the gasoline. The improvements in volumetric efficiency will be used to quantify the extent of charge cooling by fuel evaporation, and these will be compared with predictions assuming the maximum possible level of fuel evaporation.

Knock in spark ignition engines is stochastic in nature. It is caused by autoignition in hot spots in the unburned end-gas ahead of the expanding flame front. Knock onset in an engine cycle can be predicted using the Livengood-Wu integral if the variation of ignition delay with pressure and temperature as well as the pressure and temperature variation with crank angle are known. However, knock intensity (KI) is determined by the evolution of the pressure wave following knock onset. In an earlier paper (SAE 2017-01-0689) we showed that KI can be approximated by KI = Z (∂T/∂x)-2 at a fixed operating condition, where Z is a function of Pko, the pressure, and (∂T/∂x) is the temperature gradient in the hot spot at knock onset. Then, from experimental measurements of KI and Pko, using five different fuels, with the engine operating at boosted conditions, a probability density function for (∂T/∂x) was established.

This paper is the first of a two part study which investigates the use of advanced combustion modes as a means of improving the efficiency and environmental impact of conventional light-duty vehicles. This first study focuses on the application of so-called Octane-on-Demand combustion, whereby the fuel anti-knock quality is customized to match the real-time requirements of an otherwise conventional spark-ignition engine. Methanol is utilized as the high octane fuel, while three alternative petroleum-derived fuels with Research octane numbers (RONs) ranging from 61 to 90 are examined as candidates for the lower octane fuel. Experimental engine calibration maps are first developed to quantify the minimum amount of methanol that must be added to each lower octane fuel in order to reproduce the baseline engine performance attained on a market gasoline (RON 95). The properties of the lower octane fuel are shown to affect the engine performance significantly.

Oxides of nitrogen (NOx) and smoke can be simultaneously reduced in compression ignition engines by getting combustion to occur at low temperatures and by delaying the heat release till after the fuel and air have been sufficiently mixed. One of the ways to obtain such combustion in modern engines using common-rail direct injection is to inject the fuel near top dead centre with high levels of exhaust gas recirculation (EGR) - Nissan MK style combustion. In this work we study the effect of fuel auto-ignition quality, using four fuels ranging from diesel to gasoline, on such combustion at two inlet pressures and different EGR levels. The experiments are done in a 2 litre single-cylinder engine with a compression ratio of 14 at an engine speed of 1200 RPM. The engine can be easily run on gasoline with a single injection near TDC, even though it cannot be run with very early injection, in the HCCI mode.

In this paper blends of diesel and gasoline (dieseline) fuelled Partially Premixed Compression Ignition (PPCI) combustion and the comparison to conventional diesel combustion is investigated. The tests are carried out using a light duty four cylinder Euro IV diesel engine. The engine condition is maintained at 1800 rpm, 52 Nm (equivalent IMEP around 4.3 bar). Different injection timings and different amounts of EGR are used to achieve the PPCI combustion. The results show that compared to the conventional diesel combustion, the smoke and NOx emissions can be reduced by more than 95% simultaneously with dieseline fuelled PPCI combustion. The particle number total concentration can be reduced by 90% as well as the mean diameter (from 54 nm for conventional diesel to 16 nm for G50 fuelled PPCI). The penalty is a slightly increased noise level and lower indicated efficiency, which is decreased from 40% to 38.5%.

Premixed Charge Compression Ignition (PCCI) is a combustion concept that holds the promise of combining emission levels of a spark-ignition engine with the efficiency of a compression-ignition engine. In a short term scenario, PCCI would be used in the lower load operating range only, combined with conventional diesel combustion at higher loads. This scenario relies on using near standard components and conventional fuels; therefore a set of fuels is selected that only reflects short term changes in diesel fuel composition. Experiments have been conducted in one dedicated test cylinder of a modified 6-cylinder 12.6 liter heavy duty DAF engine. This test cylinder is equipped with a stand-alone fuel injection system, EGR circuit and air compressor. For the low load operating range the compression ratio has been lowered to 12:1 by means of a thicker head gasket.

More stringent emissions standards along with higher fuel economy demands have obliged auto makers to develop technical solutions that exploit synergistic features from gasoline and diesel engines. To minimize NOx and soot trade-off, diesel powertrain has been developed to adopt increasingly complex and expensive technology such as extremely high pressure fuel injection systems, low pressure EGR, and variable valve timing. These attempts are associated with promoting Partially Premixed Charge Compression Ignition (PPC-CI) combustion via increasing mixing time and ignition delay. Alternatively, PPC-CI combustion can be achieved easier by using fuels with higher resistance to auto-ignition than conventional diesel fuel. Previous work has demonstrated the possibility of reducing the cost of future diesel after-treatment systems by using gasoline-like fuels.