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Methods to reduce direct injected diesel engine emissions in the combustion chamber will be discussed in this paper. The following NOx emission reduction technologies will be reviewed: charge air chilling, water injection, and exhaust gas recirculation (EGR). Emphasis will be placed on the development of an EGR system and the effect of EGR on NOx and particulates. The lower limit of NOx that can be obtained using conventional diesel engine combustion will be discussed. Further reductions in NOx may require changing the combustion process from a diffusion flame to a homogeneous charge combustion system.

The basic process of spark ignition in engines has changed little over the more than 100 years since its first application. The rapid evolution of several advanced engine concepts and the refinement of existing engine designs, especially applications of power boost technology, have led to a renewed interest in advanced spark ignition concepts. The increasingly large rates of in-cylinder dilution via EGR and ultra-lean operation, combined with increases in boost pressures are placing new demands on spark ignition systems. The challenge is to achieve strong and consistent ignition of the in-cylinder mixture in every cycle, to meet performance and emissions goals while maintaining or improving the durability of ignitor. The application of railplug ignition to some of these engine systems is seen as a potential alternative to conventional spark ignition systems that may lead to improved ignition performance.

A liquid-phase port injection system for liquefied petroleum gas (LPG) generally consists of a fuel storage tank with extended capability of operating up to 600 psi, a fuel pump, and suitable fuel lines to and from the LPG fuel injectors mounted in the fuel rail manifold. Port injection of LPG in the liquid phase is attractive due to engine emissions and performance benefits. However, maintaining the LPG in the liquid phase at under-hood conditions and re-starting after hot soak can be difficult. Multiphase behavior within a liquid-phase LPG injection system was investigated computationally and experimentally. A commercial chemical equilibrium code (ASPEN PLUS™) was used to model various LPG compositions under operating conditions.

This paper presents the latest developments in the design and performance of an electronic particulate matter (PM) sensor developed at The University of Texas at Austin (UT) and suitable, with further development, for applications in active engine control of PM emissions. The sensor detects the carbonaceous mass component of PM in the exhaust and has a time-resolution less than 20 (ms), allowing PM levels to be quantified for engine transients. Sample measurements made with the sensor in the exhaust of a single-cylinder light duty diesel engine are presented for both steady-state and transient operations: a steady-state correlation with gravimetric filter measurements is presented, and the sensor response to rapid increases in PM emission during engine transients is shown for several different tip-in (momentary increases in fuel delivery) conditions.

The engine selected for this work was a Caterpillar 3176 engine. Engine exhaust emissions, performance, and heat release rates were measured as functions of engine configuration, engine speed and load. Two engine configurations were used, a standard 1994 design and a 1994 configuration with EGR designed to achieve a NOx emissions level of 2.5 gm/hp-hr. Measurements were performed at 7 different steady-state, speed-load conditions on thirteen different test fuels. The fuel matrix was statistically designed to independently examine the effects of the targeted fuel properties. Cetane number was varied from 40 to 55, using both natural cetane number and cetane percent improver additives. Aromatic content ranged from 10 to 30 percent in two different forms, one in which the aromatics were predominantly mono-aromatic species and the other, where a significant fraction of the aromatics were either di- or tri-aromatics.

An electronic particulate matter sensor (EPMS) developed at the University of Texas was used to characterize exhaust gases from a single-cylinder diesel engine and a light-duty diesel vehicle. Measurements were made during transient tip-in events with multiple sensor configurations in the single-cylinder engine. The sensor was operated in two modes: one with the electric field energized, and the other with no electric field present. In each mode, different characteristic signals were produced in response to a tip-in event, highlighting the two primary mechanisms of sensor operation. The sensor responded to both the natural charge of the particulate matter (PM) emitted from the engine, and was also found to create a signal by charging neutral particles. The characteristics of the two mechanisms of operation are discussed as well as their implications on the placement and operation of the sensor.

The Texas Department of Transportation began using an emulsified diesel fuel in 2002. They initiated a simultaneous study of the effectiveness of this fuel in comparison to 2D on-road diesel fuel and 2D off-road diesel. The study included comparisons of fuel economy and emissions for the emulsion, Lubrizol PuriNOx®, relative to conventional diesel fuels. Two engines and eight trucks, four single-axle dump trucks, and four tandem-axle dump trucks were tested. The equipment tested included both older mechanically-controlled diesels and newer electronically-controlled diesels. The two engines were tested over two different cycles that were developed specifically for this project. The dump trucks were tested using the “route” technique over one or the other of two chassis dynamometer cycles that were developed for this project In addition to fuel efficiency, emissions of NOx, PM, CO, and HCs were measured. Additionally, second-by-second results were obtained for NOx and HCs.

The Texas Department of Transportation (TxDOT) began using an emulsified diesel fuel as an emissions control measure in July 2002. They initiated a study of the effectiveness of this fuel in comparison to conventional diesel fuel for TxDOT's Houston District operations and included the fleet operated by the Associated General Contractors (AGC) in the Houston area. Cost-effectiveness analyses, including the incremental cost per ton of NOx removed, were performed. NOx removal was the focus of this study because Houston is an ozone nonattainment area, and NOx is believed to be the limiting factor in ozone formation in the Houston area. The cost factors accounted for in the cost-effectiveness analyses included the incremental cost of the fuel (including an available rebate from the State of Texas), the cost of refueling more often, implementation costs, productivity costs, maintenance costs, and various costs associated with the tendency of the emulsion to separate.

Manufacturers of heavy-duty diesel engines for sale in the United States face an unprecedented reduction in emissions in 2007 and in 2010. Compared to today's levels, a 90% reduction in particulate matter (PM) must be achieved by 2007, and a 90% reduction in nitric oxides (NOx) must be achieved by 2010. This paper focuses on the technology solutions possible for engine makers for the interim 2007-2009 timeframe and discusses the additional NOx reduction strategies for a 2010 compliant engine. The possibility of achieving a larger portion of the interim 2007-2009 NOx standard through in-cylinder control methods rather than by NOx exhaust treatment is discussed. High levels of exhaust gas recirculation (EGR) and advanced injection strategies to modify the conventional diesel combustion process are just two processes that can be accommodated in many of today's engine designs.

A railplug is a new type of ignitor for SI engines. A model for optimizing energy deposition in a railplug ignition system is developed. The model is experimentally validated using a low voltage railplug ignition circuit. The effect of various ignition circuit parameters on the energy deposition and its rate are discussed. Durability of railplugs is an important factor in railplug circuit design. As for all spark ignitors, durability of a railplug decreases as energy deposition is increased. Therefore recommendations are made to minimize wear and increase durability, while depositing sufficient energy to attain ignition, using a railplug.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. All of our prior tests with the injector probe used California Phase 2 reformulated gasoline as the liquid fuel. In the present study, a variety of pure liquid hydrocarbon fuels are used to examine the influence of fuel volatility and structure. Additionally, the exhaust hydrocarbons are speciated to differentiate between the emissions resulting from the gaseous fuel and those resulting from the liquid fuel. It is shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs.

An optical access engine was used to image the liquid film evaporation off the piston of a simulated direct injected gasoline engine. A directional injector probe was used to inject liquid fuel (gasoline, i-octane and n-pentane) directly onto the piston of an engine primarily fueled on propane. The engine was run at idle conditions (750 RPM and closed throttle) and at the Ford World Wide Mapping Point (1500 RPM and 262 kPa BMEP). Mie scattering images show the liquid exiting the injector probe as a stream and directly impacting the piston top. Schlieren imaging was used to show the fuel vaporizing off the piston top late in the expansion stroke and during the exhaust stroke. Previous emissions tests showed that the presence of liquid fuel on in-cylinder surfaces increases engine-out hydrocarbon emissions.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. In a previous study, we used a variety of pure liquid hydrocarbon fuels to examine the influence of fuel volatility and structure on the HC emissions due to piston wetting. It was shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs. All of these prior tests of fuel effects were performed at a single operating condition: the Ford World Wide Mapping Point (WWMP). In the present study, the effects of load and engine speed are examined.

A nephelometer system was developed to characterize engine particulate emissions from DISI engines. Results were correlated with images showing the location and history of particulates in the cylinder of an optical engine. The nephelometer's operation is based upon the dependence of scattered laser light on particulate size from a flow sampled from the exhaust of an engine. The nephelometer simultaneously measured the scattered light from angles of 20° to 160° from the forward scattering direction in 4° increments. The angular scattering measurements were then compared with calculations using a Mie scattering code to infer information regarding particulate size. Measurements of particulate mass were made based upon a correlation developed between the scattered light intensity and particulate mass samples trapped in a 0.2-micron filter. Measurements were made in a direct injection single-cylinder spark ignition research engine having a transparent quartz cylinder.

A new combustion concept has been developed and tested for improving the low to moderate load efficiency and NOx emissions of natural gas engines. This concept involves operation of a dual-fuel natural gas engine on Homogeneous Charge Compression Ignition (HCCI) in the load regime of idle up to 35 % of the peak torque. A dual-fuel approach is used to control the combustion phasing of the engine during HCCI operation, and conventional spark-ignited natural gas combustion is used for the high-load regime. This concept has resulted in an engine with power output and high-load fuel efficiency that are unchanged from the base engine, but with a 10 - 15 % improvement to the low to moderate load fuel efficiency. In addition, the engine-out NOx emissions during HCCI operation are over 90% lower than on spark-ignited natural gas operation over the equivalent load range.

The engine-out emissions and fuel consumption rates for a modern, heavy-duty diesel engine were compared when fueling with a conventional diesel fuel and three water-blend-fuel emulsions. Four different fuels were studied: (1) a conventional diesel fuel, (2) PuriNOx,™ a water-fuel emulsion using the same conventional diesel fuel, but having 20% water by mass, and (3,4) two other formulations of the PuriNOx™ fuel that contained proprietary chemical additives intended to improve combustion efficiency and emissions characteristics. The emissions data were acquired with three different injection-timing strategies using the AVL 8-Mode steady-state test method in a Caterpillar 3176 engine, which had a calibration that met the 1998 nitrogen oxides (NOX) emissions standard.

Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.

A fiber optic instrumented spark plug was used to make time-resolved measurements of the fuel vapor concentration history near the spark gap in a four-valve DISI engine. Four different bulk flow were investigated. Several early and late injection timings were examined. The fuel concentration at the spark gap was correlated with IMEP. Emissions of CO, HCs, and NOx were related to the type of bulk flow. For both early and late injection the CoVs of fuel concentration were generally lowest for the weakest bulk flow which resulted in a stable stratification. Strong bulk flows convected the inhomogeneities through the measurement area near the spark plug resulting in both large intracycle and cycle-to-cycle variation in equivalence ratio at the time of ignition.

We have examined the influence of piston wetting on the size distribution and mass of particulate matter (PM) emissions in a SI engine using several different fuels. Piston wetting was isolated as a source of PM emissions by injecting known amounts of liquid fuel onto the piston top using an injector probe. The engine was run predominantly on propane with approximately 10% of the fuel injected as liquid onto the piston. The liquid fuels were chosen to examine the effects of fuel volatility and molecular structure on the PM emissions. A nephelometer was used to characterize the PM emissions. Mass measurements from the nephelometer were compared with gravimetric filter measurements, and particulate size measurements were compared with scanning electron microscope (SEM) photos of particulates captured on filters. The engine was run at 1500 rpm at the Ford world-wide mapping point with an overall equivalence ratio of 0.9.

Improved submodels for use in a dynamic engine/vehicle model have been developed and the resulting code has been used to analyze the tip-in, tip-out behavior of a computer-controlled port fuel injected SI engine. This code consists of four submodels. The intake simulation submodel is similar to prior intake models, but some refinements have been made to the fuel flow model to more properly simulate a timed port injection system, and it is believed that these refinements may be of general interest. A general purpose engine simulation code has been used as a subroutine for the cycle simulation submodel. A conventional vehicle simulation submodel is also included in the model formulation. Perhaps most importantly, a submodel has been developed that explicitly simulates the response of the on-board computer (ECM) control system.