Technical Paper
A NOx Sensor for Feedback Control and Emissions Reduction
2002-03-04
2002-01-0479
Current emission control systems utilize a catalytic converter employing a three-way catalyst (TWC), composed of a mixture of noble metals to minimize the three main pollutant classes of NOx, CO, and HC. The TWC is most efficient when the air-to-fuel ratio (A/F) is at stoichiometry (i.e. A/F ≈ 14.7). The stoichiometric set-point region is maintained by the use of oxygen sensors composed of the solid-electrolyte yttria stabilized zirconia (YSZ) in an electronic feedback loop. As combustion gets leaner a different exhaust sensor can be utilized to give a measure of the level of pollutants. A NOx sensor is an alternative for an oxygen sensor that can be used for feedback control of engine combustion or exhaust NOx traps. A solid electrolyte disk composed of YSZ having two Pt electrodes with one being covered by a microporous zeolite material was tested as a sensor for combustion produced gases such as NO and NO2 in the presence of O2.