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Combustion behaviour and emissions characteristics of different blending ratios of diesel and gasoline fuels (Dieseline) were investigated in a light-duty 4-cylinder compression-ignition (CI) engine operating on partially premixed compression ignition (PPCI) mode. Experiments show that increasing volatility and reducing cetane number of fuels can help promote PPCI and consequently reduce particulate matter (PM) emissions while oxides of nitrogen (NOx) emissions reduction depends on the engine load. Three different blends, 0% (G0), 20% (G20) and 50% (G50) of gasoline mixed with diesel by volume, were studied and results were compared to the diesel-baseline with the same combustion phasing for all experiments. Engine speed was fixed at 1800rpm, while the engine load was varied from 1.38 to 7.85 bar BMEP with the exhaust gas recirculation (EGR) application.

This study investigates the potential of using a partial flow filter (PFF) to assist a wall flow diesel particulate filter (DPF) and reduce the need for active regeneration phases that increase engine fuel consumption. First, the filtration efficiency of the PFF was studied at several engine operating conditions, varying the filter space velocity (SV), through modification of the exhaust gas flow rate, and engine-out particulate matter (PM) concentration. The effects of these parameters were studied for the filtration of different particle size ranges (10-30 nm, 30-200 nm and 200-400 nm). For the various engine operating conditions, the PFF showed filtration efficiency over 25% in terms of PM number and mass. The PFF filtration behaviour was also investigated at idle engine operation producing a high concentration of nuclei particulates for which the filter was able to maintain 60% filtration efficiency.

Transient emissions of a turbocharged three-litre V6 diesel engine fuelled by hydrogenated vegetable oil (HVO) blends were experimentally investigated and compared with transient emissions of diesel as reference. The transient emissions measurements were made by highly-dynamic emissions instrumentations including Cambustion HFR500, CLD500 and DMS500 particulate analyzer. The HVO blends used in this study were 30% and 60% of HVO in diesel by volume. The transient conditions were simulated by load increases over 5 s, 10 s and 20 s durations at a constant engine speed. The particulate, NO, HC concentrations were measured to investigate the mechanism of emission formation under such transient schedules. The results showed that as the load increased, NO concentrations initially had a small drop before dramatically increasing for all the fuels investigated which can be associated with the turbocharger lag during the load transient.

Two approaches were adopted to study soot oxidation by NO₂; firstly microreactor tests were performed on soot produced by a soot generator over a range of NO₂ concentrations and temperatures. This enabled measurement to be made under well-controlled conditions. Secondly, soot oxidation measurements were made on an engine bench to obtain data under more realistic, if less controlled, conditions. In the microreactor work NO₂ consumption by soot oxidation and the selectivity of the soot oxidation to CO and CO₂ were measured. The latter was found to vary only slightly with temperature and to be independent of NO₂ concentration. By modeling this data using a 1-dimensional model, rate equations for the soot-NO₂ reaction were determined. These were then tested against the engine data. The soot used in this study was characterized by thermogravimetric analysis, N₂ physisorption and transmission electron microscopy.

There is an increasing recognition of injector deposit (ID) formation in fuel injection equipment as direct injection spark ignition (DISI) engine technologies advance to meet increasingly stringent emission legislation and fuel economy requirements. While it is known that the phenomena of ID in DISI engines can be influenced by changes in fuel composition, including increasing usage of aliphatic alcohols and additive chemistries to enhance fuel performance, there is however still a great deal of uncertainty regarding the physical and chemical structure of these deposits, and the mechanisms of deposit formation. In this study, a mechanical cracking sample preparation technique was developed to assess the deposits across DISI injectors fuelled with gasoline and blends of 85% ethanol (E85).

Engine transient operation has attracted a lot of attention from researchers due to its high frequency of occurrence during daily vehicle operation. More emissions are expected compared to steady state operating conditions as a result of the turbo-lag problem. Ambient temperature has significant influences on engine transients especially at engine start. The effects of ambient temperature on engine-out emissions under the New European Driving Cycle (NEDC) are investigated in this study. The transient engine scenarios were carried out on a modern 3.0 L, V6 turbocharged common rail diesel engine fuelled with winter diesel in a cold cell within the different ambient temperature ranging between +20 °C and −7 °C. The engine with fuel, coolant, combustion air and lubricating oil were soaked and maintained at the desired test temperatures during the transient scenarios.

Particulate Emissions from Homogeneous Charge Compression Ignition (HCCI) combustion are routinely assumed to be negligible. It is shown here that this is not the case when HCCI combustion is implemented in a direct injection gasoline engine. The conditions needed to sustain HCCI operation were realized using the negative valve overlap method for trapping high levels of residual exhaust gases in the cylinder. Measurements of emitted particle number concentration and electrical mobility diameter were made with a Cambustion DMS500 over the HCCI operating range possible with this hardware. Emissions of oxides of nitrogen, carbon monoxide and unburned hydrocarbons were also measured. These data are presented and compared with similar measurements made under conventional spark ignition (SI) operation in the same engine. Under both SI and HCCI operation, a significant accumulation mode was detected with particle equivalent diameters between 80 and 100 nm.

The objective of the current research was to predict and analyze the flow through the grill of air intake system which is positioned behind the front wheel arch of vehicle. Most of the vehicle used today locates the grill of air intake at the front side so to acquire benefit of ram effect. In some cases, however, the grill is located behind the vehicle to improve wading performance. The geometry of air intake system of Land Rover Freelander was used in the modelling approach. The study was focused on different flow speeds on the grill at high load operation where the air speed at the grill side is high and creates negative pressure. The CFD results are validated against experimental data of steady flow test bench.

A prototype catalyst has been developed and integrated within the aftertreatment exhaust system to control the HC, CO, PM and NOx emissions from diesel exhaust gas. The catalyst activity in removing HC and nano-particles was examined with exhaust gas from a diesel engine operating on biodiesel - Rapeseed Methyl Ester (RME). The tests were carried out at steady-state conditions for short periods of time, thus catalyst tolerance to sulphur was not examined. The prototype catalyst reduced the amount of hydrocarbons (HC) and the total PM. The quantity of particulate with electrical mobility diameter in nucleation mode size < 10nm, was significantly reduced over the catalyst. Moreover, it was observed that the use of EGR (20% vol.) for the biodiesel fuelled engine significantly increases the particle concentration in the accumulation mode with simultaneous reduction in the particle concentration in the nuclei mode.

Limits on the total future potential of biodiesel fuel due to the availability of raw materials mean that ambitious 20% fuel replacement targets will need to be met by the use of both first and next generation biodiesel fuels. The use of higher percentage biodiesel blends requires engine recalibration, as it affects engine performance, combustion patterns and emissions. Previous work has shown that the combustion of 50:50 blends of biodiesel fuels (first generation RME and next generation synthetic fuel) can give diesel fuel-like performance (i.e. in-cylinder pressure, fuel injection and heat release patterns). This means engine recalibration can be avoided, plus a reduction in all the regulated emissions. Using a 30% biodiesel blend (with different first and next generation proportions) mixed with Diesel may be a more realistic future fuel.

In earlier work we have shown that engine operation with oxygenated fuels (e.g., biodiesel) reduces the particulate matter (PM) emissions and extends the engine tolerance to exhaust gas recirculation (EGR) before it reaches smoke limited conditions. The same result has also been reported when high cetane number fuels such as gas-to-liquid (GTL) are used. A likely mechanism for engine-out particulate growth is the reintroduction of particle nuclei into the cylinder through EGR. These recirculated PM particles serve as sites for further condensation and accumulation promoting larger and greater number of particles. In order to further our understanding of EGR influence on total PM production, a diesel particulate filter (DPF) was integrated into the EGR loop. A PM reduction of approximately 50% (soot) was achieved with diesel fuel through filtered EGR, whilst still maintaining a significant NOX reduction.

Computational Fluid Dynamics (CFD) is used to simulate chemical reactions and transport phenomena occurring in a single channel of a honeycomb-type automotive catalytic converter under lean burn combustion. Microkinetic analysis is adopted to develop a detailed elementary reaction mechanism for propane oxidation on a silver catalyst. Activation energies are calculated based on the theory of the Unity Bond Index-Quadratic Exponential Potential (UBI-QEP) method. The order-of-magnitude of the pre-exponential factors is obtained from Transition State Theory (TST). Sensitivity analysis is applied to identify the important elementary steps and refine the pre-exponential factors of these reactions. These pre-exponential factors depend on inlet temperatures and propane concentration; therefore optimised pre-exponential factors are written in polynomial forms. The results of numerical simulations are validated by comparison with experimental data.

Ambient temperature has significant impact on engine start ability and cold start emissions from diesel engines. These cold start emissions are accounted for substantial amount of the overall regulatory driving cycle emissions like NEDC or FTP. It is likely to implement the low temperature emissions tests for diesel vehicles, which is currently applicable only for gasoline vehicles. This paper investigates the potential of the intake heating strategy on reducing the driving cycle emissions from the latest generation of turbocharged common rail direct injection diesel engines at low ambient temperature conditions. For this investigation an air heater was installed upstream of the intake manifold and New European Driving Cycle (NEDC) tests were conducted at -7°C ambient temperature conditions for the different intake air temperatures. Intake air heating reduced the cranking time and improved the fuel economy at low ambient temperatures.

This paper presents the findings of theoretical and practical studies of an exhaust-gas reforming process, as applied to hydrocarbon fuels. It is shown that hydrogen-containing gaseous reformed fuels can be produced by the interaction of hot combustion products and an n-heptane feedstock in a small-scale catalytic reforming reactor. Predicted and observed reformed fuel chemical compositions were found to correlate well at the lower reactor space velocities tested, where chemical equilibrium conditions can be closely approached. Under these conditions, respective hydrogen and carbon monoxide yields of around 32 and 20 volume per cent were obtained. Under certain conditions, it was found that carbon solids were deposited on the reforming catalyst. Measures taken to avoid this problem included changes in the reforming oxidant to fuel ratio, and the addition of excess steam to the oxidant composition.

Exhaust Gas Fuel Reforming has potential to be used for on-board generation of hydrogen rich gas, reformate, and to act as an energy recovery system allowing the capture of waste exhaust heat. High exhaust gas temperature drives endothermic reforming reactions that convert hydrocarbon fuel into gaseous fuel when combined with exhaust gas over a catalyst - the result is an increase in overall fuel energy that is proportional to waste energy capture. The paper demonstrates how the combustion of reformate in a direct injection gasoline (GDI) engine via Reformed Exhaust Gas Recirculation (REGR) can be beneficial to engine performance and emissions. Bottled reformate was inducted into a single cylinder GDI engine at a range of engine loads to compare REGR to conventional EGR. The reformate composition was selected to approximate reformate produced by exhaust gas fuel reforming at typical gasoline engine exhaust temperatures.

Diesel engines are the versatile power source and is widely used in passenger car and commercial vehicle applications. Environmental temperature conditions, fuel quality, fuel injection strategies and lubricant have influence on cold start performance of the diesel engines. Strategies to overcome the cold start problem at very low ambient temperature include preheating of intake air, coolant, cylinder block. The present research work investigates the effect of coolant temperatures on passenger car diesel engine’s performance and exhaust emission characteristics during the cold start at cold ambient temperature conditions. The engine is soaked in the -7°C environment for 6 hours. The engine coolant is preheated to the desired coolant temperatures of 10 and 20°C by an external heater and the start ability tests were performed.

Cold start is a critical operating condition for diesel engines because of the pollutant emissions produced by the unstable combustion and non-performance of after-treatment at lower temperatures. In this research investigation, a light-duty turbocharged diesel engine equipped with a common rail injection system was tested on a transient engine testing bed to study the starting process in terms of engine performance and emissions. The engine (including engine coolant, engine oil and fuel) was soaked in a cold cell at −7°C for at least 8 hours before starting the test. The engine operating parameters such as engine speed, air/fuel ratio, and EGR rate were recorded during the tests. Pollutant emissions (Hydrocarbon (HC), NOx, and particles both in mode of nucleation and accumulation) were measured before and after the Diesel Oxidation Catalyst (DOC). The results show that conversion efficiency of NOx was higher during acceleration period at −7°C start than the case of 20°C start.

A study of Multiple Premixed Compression Ignition (MPCI) with heavy naphtha is performed on a light-duty single cylinder diesel engine. The engine is operated at a speed of 1600rpm with the net indicated mean effective pressure (IMEP) from 0.5MPa to 0.9MPa. Commercial diesel is also tested with the single injection for reference. The combustion and emissions characteristics of the heavy naphtha are investigated by sweeping the first (−200 ∼ −20 deg ATDC) and the second injection timing (−5 ∼ 15 deg ATDC) with an injection split ratio of 50/50. The results show that compared with diesel combustion, the naphtha MPCI can reduce NOx, soot emissions and particle number simultaneously while maintaining or achieving even higher indicated thermal efficiency. A low pressure rise rate can be achieved due to the two-stage combustion character of the MPCI mode but with the penalty of high HC and CO emissions, especially at 0.5MPa IMEP.

Recent developments in diesel engines lead to increased fuel efficiency and reduced exhaust gas temperature. Therefore more energy efficient aftertreatment systems are required to comply with tight emission regulations. In this study, a computational fluid dynamics package was used to investigate the thermal behaviour of a diesel aftertreatment system. A parametric study was carried out to identify the most influential pipework material and insulation characteristics in terms of thermal performance. In the case of the aftertreatment pipework and canning material effect, an array of different potential materials was selected and their effects on the emission conversion efficiency of a Diesel Oxidation Catalyst (DOC) were numerically investigated over a driving cycle. Results indicate that although the pipework material's volumetric heat capacity was decreased by a factor of four, the total emission reduction was only considerable during the cold start.

In recent years magnetic resonance imaging (MRI) has been shown to be an attractive method for fluid flow visualization. In this work, we show how MRI velocimetry techniques can be used to non-invasively investigate and visualize the hydrodynamics of exhaust gas in a diesel particulate filter (DPF), both when clean and after loading with diesel engine exhaust particulate matter. The measurements have been used to directly measure the gas flow in the inlet and outlet channels of the DPF, both axial profiles along the length and profiles across the channel diameter. Further, from this information we show that it is possible to indirectly ascertain the superficial wall-flow gas velocity and the soot loading profiles along the filter channel length.