Search Results

Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.

The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).

In the last three years, three quality surveys on ethanol-blended fuels intended for use in flex-fuel vehicles have been published. Two of these surveys cover Flex-Fuel quality, and the third encompasses the quality of mid-level ethanol blends (MLEBs) from blender pumps. The purpose of these surveys was to report on the quality of the fuels and provide a snapshot in time of fuel quality. This study examines the larger picture portrayed by these surveys and looks for broader trends in fuel quality. The analysis found that compliance with vapor pressure specification limits for Flex Fuel improved from 40% to 66% in Class 1, from 31% to 43% in Class 2, and from 12% to 30% in Class 3 between 2008 and 2010. Failures on other critical properties, such as acidity, pHe, water, and inorganic chloride were less than 6% in these studies. The 2010 Flex Fuel samples readily met the ethanol content specification, with 88%, 92%, and 95% compliance for Classes 1, 2, and 3, respectively.

The objective of this work was to measure knock resistance metrics for ethanol-hydrocarbon blends with a primary focus on development of methods to measure the heat of vaporization (HOV). Blends of ethanol at 10 to 50 volume percent were prepared with three gasoline blendstocks and a natural gasoline. Performance properties and composition of the blendstocks and blends were measured, including research octane number (RON), motor octane number (MON), net heating value, density, distillation curve, and vapor pressure. RON increases upon blending ethanol but with diminishing returns above about 30 vol%. Above 30% to 40% ethanol the curves flatten and converge at a RON of about 103 to 105, even for the much lower RON NG blendstock. Octane sensitivity (S = RON - MON) also increases upon ethanol blending. Gasoline blendstocks with nearly identical S can show significantly different sensitivities when blended with ethanol.

Biodiesel fuels benefit both from being a renewable energy source and from decreasing in carbon monoxide (CO), total hydrocarbons (THC), and particulate matter (PM) emissions relative to petroleum diesel. The oxides of nitrogen (NOx) emissions from biodiesel blended fuels reported in the literature vary relative to baseline diesel NOx, with no NOx change or a NOx decrease found by some to an increase in NOx found by others. To explore differences in NOx, two Cummins ISM engines (1999 and 2004) were operated on 20% biodiesel blends during the heavy-duty transient FTP cycle and the steady state Supplemental Emissions Test. For the 2004 Cummins ISM engine, in-cylinder pressure data were collected during the steady state and transient tests. Three types of biodiesel fuels were used in the blends: soy, tallow (animal fat), and cottonseed. The FTP integrated emissions of the B20 blends produced a 20-35% reduction in PM and no change or up to a 4.3% increase in NOx over the neat diesel.

Heavy-duty trucks are an important sector to evaluate when seeking fuel consumption savings and emissions reductions. With fuel costs on the rise and emissions regulations becoming stringent, vehicle manufacturers find themselves spending large amounts of capital improving their products in order to be compliant with regulations. The Powertrain System Analysis Toolkits (PSAT), developed by the Argonne National Laboratory (ANL), is a simulation tool that helps mitigate costs associated with research and automotive system design. While PSAT has been widely used to predict the fuel consumption and exhaust emissions of conventional and hybrid light-duty vehicles, it also may be employed to test heavy-duty vehicles. The intent of this study was to develop an accurate model that predicts emissions and fuel economy for heavy-duty vehicles for use within PSAT.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

Cummins Westport Inc. (CWI) released for production the latest version of its C8.3G natural gas engine, the C Gas Plus, in July 2001. This engine has increased ratings for horsepower and torque, a full-authority engine controller, wide tolerance to natural gas fuel (the minimum methane number is 65), and improved diagnostics capability. The C Gas Plus also meets the California Air Resources Board optional low-NOx (2.0 g/bhp-h) emission standard for automotive and urban buses. Two pre-production C Gas Plus engines were operated in a Viking Freight fleet for 12 months as part of the U.S. Department of Energy's Fuels Utilization Program. In-use exhaust emissions, fuel economy, and fuel cost were collected and compared with similar 1997 Cummins C8.3 diesel tractors. CWI and the West Virginia University developed an ad-hoc test cycle to simulate the Viking Freight fleet duty cycle from in-service data collected with data loggers.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

Natural gas, coal, and biomass can be converted to diesel fuel through Fischer-Tropsch (F-T) processes. Variations of the F-T process and/or product work-up can be used to tailor the fuel properties to meet end-users needs. Regardless of feedstock or process, F-T diesel fuels typically have a number of very desirable properties. This review describes typical F-T diesel fuel properties, discusses how these fuel properties impact pollutant emissions, and draws together data from known engine and chassis dynamometer studies of emissions. The comparison of fuel properties reveals that F-T diesel fuel is typically one of two types - a very high cetane number (>74), zero aromatic product or a moderate cetane (∼60), low aromatic (≤15%) product. The very high cetane fuels typically have less desirable low temperature properties while the moderate cetane fuels have cold flow properties more typical of conventional diesel fuels.

West Virginia University redesigned a 2002 Ford Explorer and created a diesel electric hybrid vehicle to satisfy the goals of the 2002 FutureTruck competition. These goals were to demonstrate a 25% improvement in fuel economy, to reduce greenhouse gas emissions, to achieve California ULEV emissions, to demonstrate 1/8-mile acceleration of 11.5 seconds or less, and to maintain vehicular comforts and performance. West Virginia University's 2002 hybrid sport utility vehicle (SUV), the Exclaim!, meets or exceeds these goals. Using a post-transmission parallel configuration, WVU integrated a 2.5L Detroit Diesel Corporation engine along with a Unique Mobility 75kW electric motor to replace the stock drivetrain. With an emphasis on maintaining performance, WVU strived to improve areas where SUVs have traditionally performed poorly: fuel economy and emissions. Using regenerative braking, fuel economy has been significantly improved.

The recent oil crisis has once again emphasized the need to develop both fuel efficient engines and alternately fueled engines, particularly for automotive applications. Engines which burn coal or coal pyrolysis products are attractive, but ignition delay and metal erosion problems continue to limit high speed operation of such engines. Further, the throttled spark ignition engine often used with methanol and natural gas does not prove an efficient or tolerant device for the combustion of a wide range of fuel. Therefore, an novel approach must be taken in order to achieve the efficient and flexible operation of such an engine. A novel design of a fuel tolerant engine suitable for burning coal fuels separates the combustion from the piston in order to have more careful flame control and to exclude the particulate matter from the engine's piston rings.

With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.

Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).

Understanding the nitric oxide (NO) conversion process plays a major role in optimizing the Selective NOX Recirculation (SNR) technique. SNR has been proven in gasoline and diesel engines, with up to 90% NOX conversion rates being achieved. This technique involves adsorbing NOX from an exhaust stream, then selectively desorbing the NOX into a concentrated NOX stream, which is fed back into the engine's intake, thereby converting a percentage of the concentrated NOX stream into harmless gases. The emphasis of this paper is on the unique chemical kinetic modeling problem that occurs with high concentrations of NOX in the intake air of a spark ignited natural gas engine with SNR. CHEMKIN, a chemical kinetic solver software package, was used to perform the reaction modeling. A closed homogeneous batch reactor model was used to model the fraction of NOX versus time for varying initial conditions and constants.

Hybrid diesel electric buses offer the advantage of superior fuel economy through use of regenerative braking and lowered transient emissions by reducing the need of the engine to follow load as closely as in a conventional bus. With the support of the Department of Energy (DOE), five Lockheed Martin-Orion hybrid diesel-electric buses were operated on the West Virginia University Transportable Laboratory in Brooklyn, New York. The buses were exercised through a new cycle, termed the Manhattan cycle, that was representative of today's bus use as well as the accepted Central Business District Cycle and New York Bus Cycle. Emissions data were corrected for the state of charge of the batteries. The emissions can be expressed in units of grams/mile, grams/axle hp-hr and grams/gallon fuel. The role of improved fuel economy in reducing oxides of nitrogen relative to conventional automatic buses is evident in the data.

Emissions from trucks and buses equipped with Caterpillar dual-fuel natural gas (DFNG) engines were measured at two chassis dynamometer facilities: the West Virginia University (WVU) Transportable Emissions Laboratory and the Los Angeles Metropolitan Transportation Authority (LA MTA). Emissions were measured over four different driving cycles. The average emissions from the trucks and buses using DFNG engines operating in dual-fuel mode showed the same trends in all tests - reduced oxides of nitrogen (NOx) and particulate matter (PM) emissions and increased hydrocarbon and carbon monoxide (CO) emissions - when compared to similar diesel trucks and buses. The extent of NOx reduction was dependent on the type of test cycle used.

The objective of this project, which is supported by the U.S. Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL), is to provide a comprehensive comparison of heavy-duty trucks operating on alternative fuels and diesel fuel. Data collection from up to eight sites is planned. Currently, the project has four sites: Raley's in Sacramento, CA (Kenworth, Cummins L10-300G, liquefied natural gas - LNG); Pima Gro Systems, Inc. in Fontana, CA (White/GMC, Caterpillar 3176B Dual-Fuel, compressed natural gas - CNG); Waste Management in Washington, PA (Mack, Mack E7G, LNG); and United Parcel Service in Hartford, CT (Freightliner Custom Chassis, Cummins B5.9G, CNG). This paper summarizes current data collection and evaluation results from this project.