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Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.

The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).

In the last three years, three quality surveys on ethanol-blended fuels intended for use in flex-fuel vehicles have been published. Two of these surveys cover Flex-Fuel quality, and the third encompasses the quality of mid-level ethanol blends (MLEBs) from blender pumps. The purpose of these surveys was to report on the quality of the fuels and provide a snapshot in time of fuel quality. This study examines the larger picture portrayed by these surveys and looks for broader trends in fuel quality. The analysis found that compliance with vapor pressure specification limits for Flex Fuel improved from 40% to 66% in Class 1, from 31% to 43% in Class 2, and from 12% to 30% in Class 3 between 2008 and 2010. Failures on other critical properties, such as acidity, pHe, water, and inorganic chloride were less than 6% in these studies. The 2010 Flex Fuel samples readily met the ethanol content specification, with 88%, 92%, and 95% compliance for Classes 1, 2, and 3, respectively.

The objective of this work was to measure knock resistance metrics for ethanol-hydrocarbon blends with a primary focus on development of methods to measure the heat of vaporization (HOV). Blends of ethanol at 10 to 50 volume percent were prepared with three gasoline blendstocks and a natural gasoline. Performance properties and composition of the blendstocks and blends were measured, including research octane number (RON), motor octane number (MON), net heating value, density, distillation curve, and vapor pressure. RON increases upon blending ethanol but with diminishing returns above about 30 vol%. Above 30% to 40% ethanol the curves flatten and converge at a RON of about 103 to 105, even for the much lower RON NG blendstock. Octane sensitivity (S = RON - MON) also increases upon ethanol blending. Gasoline blendstocks with nearly identical S can show significantly different sensitivities when blended with ethanol.

To meet the ignition system needs of large bore high pressure lean burn natural gas engines a laser diode side pumped passively Q-switched laser igniter was designed and tested. The laser was designed to produce the optical intensities needed to initiate ignition in a lean burn high brake mean effective pressure (BMEP) engine. The experimentation explored a variety of optical and electrical input parameters that when combined produced a robust spark in air. The results show peak power levels exceeding 2 MW and peak focal intensities above 400 GW/cm2. Future research avenues and current progress with the initial prototype are presented and discussed.

New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these vehicles was for street collection and transporting the collected refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

Emissions tests for heavy -duty diesel-fueled engines and vehicles are normally performed using engine dynamometers and chassis dynamometers, respectively, with laboratory grade gaseous concentration measurement analyzers and supporting test equipment. However, a considerable effort has been recently expended on developing in-use, on-board tools to measure brake-specific emissions from heavy -duty vehicles with the highest degree of accuracy and precision. This alternative testing methodology would supplement the emissions data that is collected from engine and chassis dynamometer tests. The on-board emissions testing methodology entails actively recording emissions and vehicle operating parameters (engine speed and load, vehicle speed etc.) from vehicles while they are operating on the road. This paper focuses on in-use measurements of NOX with zirconium oxide sensors and other portable NOX detectors.

Further growth of diesel engines in the light-duty and heavy-duty vehicular market is closely linked to the potential health risks of diesel exhaust. The California Air Resources Board and the Office of Environmental Health Hazard Assessment have identified diesel exhaust as a toxic air contaminant. The International Agency for Research on Cancer concluded that diesel particulate is a probable human carcinogen [1]. Cleaner burning liquid fuels, such as those derived from natural gas via the Fischer-Tropsch (FT) process, offer a potentially economically viable alternative to standard diesel fuel while providing reduced particulate emissions. Further understanding of FT operation may be realized by investigating the differences in toxicity and potential health effects between particulate matter(PM) derived from FT fuel and that derived from standard Federal diesel No. 2 (DF).

The emissions reduction of Fischer-Tropsch (FT) diesel fuel has been demonstrated in several recent publications in both laboratory engine testing and in-use vehicle testing. Reduced emission levels have been attributed to several chemical and physical characteristics of the FT fuels including reduced density, ultra-low sulfur levels, low aromatic content and high cetane rating. Some of the effects of these attributes on the combustion characteristics in diesel engines have only recently been documented. In this study, a Ricardo Proteous, single-cylinder, 4-stroke DI engine is instrumented for in-cylinder pressure measurements. The engine was run at several steady engine states at multiple timing conditions using both federal low sulfur and natural gas derived FT fuels. The emissions and performance data for each fuel at each steady state operating conditions were compared.

Emissions tests for heavy-duty diesel-fueled vehicles are normally performed using an engine dynamometer or a chassis dynamometer. Both of these methods generally entail the use of laboratory-grade emissions measurement instrumentation, a CVS system, an environment control system, a dynamometer, and associated data acquisition and control systems. The results obtained from such tests provide a means by which engines may be compared to the emissions standards, but may not be truly indicative of an engine's in-vehicle performance while operating on the road. An alternative to such a testing methodology would be to actively record the emissions from a vehicle while it was operating on-road. A considerable amount of discussion has been focused on the development of on-road emissions measurement systems (OREMS) that would provide for such in-use emissions data collection.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

Natural gas, coal, and biomass can be converted to diesel fuel through Fischer-Tropsch (F-T) processes. Variations of the F-T process and/or product work-up can be used to tailor the fuel properties to meet end-users needs. Regardless of feedstock or process, F-T diesel fuels typically have a number of very desirable properties. This review describes typical F-T diesel fuel properties, discusses how these fuel properties impact pollutant emissions, and draws together data from known engine and chassis dynamometer studies of emissions. The comparison of fuel properties reveals that F-T diesel fuel is typically one of two types - a very high cetane number (>74), zero aromatic product or a moderate cetane (∼60), low aromatic (≤15%) product. The very high cetane fuels typically have less desirable low temperature properties while the moderate cetane fuels have cold flow properties more typical of conventional diesel fuels.

The 1998 Consent Decrees between the United States Government and the settling heavy-duty diesel engine manufacturers require in-use emissions testing from post 2000 model year engines. The emissions gathered from these engines must be reported on a brake-specific mass basis. To report brake-specific mass emissions, three primary parameters must be measured. These are the concentration of each emission constituent, the exhaust mass flow rate, and the engine power output. The measurement of the concentration level and exhaust mass flow rate can be (and are generally) measured directly with instrumentation installed in the exhaust transfer tube. However, engine power cannot be measured directly for in-use emissions testing due to the direct coupling of the engine output shaft to the vehicle's transmission. Engine power can be inferred from the electronic control unit (ECU) broadcast of engine speed and engine torque.

The 1998 Consent Decrees between the settling heavy-duty diesel engine manufacturers and the United States Government require the engine manufacturer to perform in-use emissions testing to evaluate their engine designs and emissions when the vehicle is placed into service. This additional requirement will oblige the manufacturer to account for real-world conditions when designing engines and engine control algorithms and include driving conditions, ambient conditions, and fuel properties in addition to the engine certification test procedures. Engine operation and ambient conditions can be designed into the engine control algorithm. However, there will most likely be no on-board determination of fuel properties or composition in the near future. Therefore, the engine manufacturer will need to account for varying fuel properties when developing the engine control algorithm for when in-use testing is performed.

The need for a cleaner and less expensive alternative energy source to conventional petroleum fuels for powering the transportation sector has gained increasing attention during the past decade. Special attention has been directed towards natural gas (NG) which has proven to be a viable option due to its clean-burning properties, reduced cost and abundant availability, and therefore, lead to a steady increase in the worldwide vehicle population operated with NG. The heavy-duty vehicle sector has seen the introduction of natural gas first in larger, locally operated fleets, such as transit buses or refuse-haulers. However, with increasing expansion of the NG distribution network more drayage and long-haul fleets are beginning to adopt natural gas as a fuel.

Both field research and certification data show that the lean burn natural gas powered spark ignition engines offer particulate matter (PM) reduction with respect to equivalent diesel power plants. Concerns over PM inventory make these engines attractive despite the loss of fuel economy associated with throttled operation. Early versions of the Cummins L-10 natural gas engines employed a mixer to establish air/fuel ratio. Emissions measurements by the West Virginia University Transportable Heavy Duty Emissions Testing Laboratories on Cummins L-10 powered transit buses revealed the potential to offer low emissions of PM and oxides of nitrogen, (NOx) but variations in the mixture could cause emissions of NOx, carbon monoxide and hydrocarbons to rise. This was readily corrected through mixer repair or readjustment. Newer versions of the L-10 engine employ a more sophisticated fueling scheme with feedback control from a wide range oxygen sensor.