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Sources of unburned hydrocarbon (UHC) emissions are examined for a highly dilute (10% oxygen concentration), moderately boosted (1.5 bar), low load (3.0 bar IMEP) operating condition in a single-cylinder, light-duty, optically accessible diesel engine undergoing partially-premixed low-temperature combustion (LTC). The evolution of the in-cylinder spatial distribution of UHC is observed throughout the combustion event through measurement of liquid fuel distributions via elastic light scattering, vapor and liquid fuel distributions via laser-induced fluorescence, and velocity fields via particle image velocimetry (PIV). The measurements are complemented by and contrasted with the predictions of multi-dimensional simulations employing a realistic, though reduced, chemical mechanism to describe the combustion process.

The objective of this research is a detailed investigation of multiple injections in a highly-dilute diesel low temperature combustion (LTC) regime. This research concentrates on understanding the performance and emissions benefits of multiple injections via experiments and simulations in a 0.48L signal cylinder light-duty engine operating at 2000 r/min and 5.5 bar IMEP. Controlled experiments in the single-cylinder engine are then combined with three computational tools, namely heat release analysis of measured cylinder pressure, a phenomenological spray model using in-cylinder thermodynamics [1], and KIVA-3V Chemkin CFD computations recently tested at LTC conditions [2]. This study examines the effects of fuel split distribution, injection event timing, rail pressure, and boost pressure which are each explored within a defined operation range in LTC.

The objective of this research is a detailed investigation of unburned hydrocarbon (UHC) in a highly-dilute diesel low temperature combustion (LTC) regime. This research concentrates on understanding the mechanisms that control the formation of UHC via experiments and simulations in a 0.48L signal-cylinder light duty engine operating at 2000 r/min and 5.5 bar IMEP with multiple injections. A multi-gas FTIR along with other gas and smoke emissions instruments are used to measure exhaust UHC species and other emissions. Controlled experiments in the single-cylinder engine are then combined with three computational tools, namely heat release analysis of measured cylinder pressure, analysis of spray trajectory with a phenomenological spray model using in-cylinder thermodynamics [1], and KIVA-3V Chemkin CFD computations recently tested at LTC conditions [2].

The volatile organic compounds (VOC) from diesel engines, including formaldehyde and benzene, are concerned and remain as unregulated harmful substances. The substances are positively correlated with THC emissions, but the VOC and aldehyde compounds at light load or idling conditions are more significant than THC. When coolant temperatures are low at light loads, there are notable increases in formaldehyde and acetaldehyde, and with lower coolant temperatures the increase in aldehydes is more significant than the increase in THC. When using ultra high EGR so that the intake oxygen content decreases below 10%, formaldehyde, acetaldehyde, benzene, and 1,3-butadiene increase significantly while smokeless and ultra low Nox combustion is possible.

The transient response of an engine with both High Pressure (HP) and Low Pressure (LP) EGR loops was compared by conducting step changes in EGR fraction at a constant engine speed and load. The HP EGR loop performance was shown to be closely linked to turbocharger performance, whereas the LP EGR loop was relatively independent of turbocharger performance and vice versa. The same experiment was repeated with the variable geometry turbine vanes completely open to reduce turbocharger action and achieve similar EGR rate changes with the HP and LP EGR loops. Under these conditions, the increased loop volume of the LP EGR loop prolonged the response of intake O2 concentration following the change in air-fuel ratio. The prolonged change of intake O2 concentration caused emissions to require more time to reach steady state as well. Strong coupling between the HP EGR loop and turbochargers was again observed using a hybrid EGR strategy.

Premixed diesel combustion blending high volatility fuels into diesel fuel were investigated in a modern diesel engine. First, various fractions of normal heptane and diesel fuel were examined to determine the influence of the blending of a highly ignitable and volatile fuel into diesel fuel. The indicated thermal efficiency improves almost linearly with increasing normal heptane fraction, particularly at advanced injection timings when the fuel is not injected directly into the piston cavity. This improvement is mainly due to decreases in the other losses, ϕother which are calculated with the following equation based on the energy balance. ηu: The combustion efficiency calculated from the exhaust gas compositions ηi: The indicated thermal efficiency ϕex: The exhaust loss calculated from the enthalpy difference between intake and exhaust gas The decreases in the other losses with normal heptane blends are due to a reduction in the unburned fuel which does not reach the gas analyzer.

A detailed comparison of cylinder pressure derived combustion performance and engine-out emissions is made between an all-metal single-cylinder light-duty diesel engine and a geometrically equivalent engine designed for optical accessibility. The metal and optically accessible single-cylinder engines have the same nominal geometry, including cylinder head, piston bowl shape and valve cutouts, bore, stroke, valve lift profiles, and fuel injection system. The bulk gas thermodynamic state near TDC and load of the two engines are closely matched by adjusting the optical engine intake mass flow and composition, intake temperature, and fueling rate for a highly dilute, low temperature combustion (LTC) operating condition with an intake O2 concentration of 9%. Subsequent start of injection (SOI) sweeps compare the emissions trends of UHC, CO, NOx, and soot, as well as ignition delay and fuel consumption.

This paper investigates flow and combustion in a full-cycle simulation of a four-stroke, three-valve HCCI engine by visualizing the flow with pathlines. Pathlines trace massless particles in a transient flow field. In addition to visualization, pathlines are used here to trace the history, or evolution, of flow fields and species. In this study evolution is followed from the intake port through combustion. Pathline analysis follows packets of intake charge in time and space from induction through combustion. The local scalar fields traversed by the individual packets in terms of velocity magnitude, turbulence, species concentration and temperatures are extracted from the simulation results. The results show how the intake event establishes local chemical and thermal environments in-cylinder and how the species respond (chemically react) to the local field.

Deviations between transient and steady state operation of a modern light duty diesel engine were identified by comparing rapid load transitions to steady state tests at the same speeds and fueling rates. The validity of approximating transient performance by matching the transient charge air flow rate and intake manifold pressure at steady state was also assessed. Results indicate that for low load operation with low temperature combustion strategies, transient deviations of MAF and MAP from steady state values are small in magnitude or short in duration and have relatively little effect on transient engine performance. A new approximation accounting for variations in intake temperature and excess oxygen content of the EGR was more effective at capturing transient emissions trends, but significant differences in magnitudes remained in certain cases indicating that additional sources of variation between transient and steady state performance remain unaccounted for.

In current systems, for a given nozzle and injection pressure (pump speed), the shape of the injection rate is fixed and the injection timing is the only variable the engine designer can vary. For this non-interactive injection system, changing the injector nozzle (number and diameter of holes) will proportionately change the injection shape. New injection systems in which the rate of injection is a controlled variable are being developed. Results from one such injector, called the UCORS (Universal Combustion Optimization and Rate Shaping), are reported in this paper. The system can dynamically control its injection rate shape by controlling the position and size of a pilot injection relative to the main injection. Data and analysis from an out-of-engine and combustion chamber study of the UCORS injection system are presented.

Diesel soot suppression effects of catalytic fuel additives for a range of fuels with different properties were investigated with calcium naphthenate. A single cylinder DI diesel engine and a thermobalance were used to determine the soot reduction and its mechanism for seven kinds of fuels. Experimental results showed that the catalytic effect of the fuel additive was different for the different fuels, and could be described by a parameter considering cetane number and kinematic viscosity. The fuel additives reduced soot more effectively for fuels with higher cetane number and lower kinematic viscosity. This result was explained by soot oxidation characteristics for the different fuels. Oxidation of soot with the metallic additive proceeds in two stages: stage I, a very rapid oxidation stage; and stage II, a following slow or ordinary oxidation stage.

A homogeneous-charge compression-ignition (HCCI) engine system that was fuelled with dimethyl ether (DME) and methanol-reformed gas (MRG) has been proposed in the previous research. Adjusting the proportion of DME and MRG can effectively control the ignition timing of the engine. In the system, both fuels are to be produced from methanol in onboard reformers utilizing the engine exhaust gas heat. While hydrogen contained in MRG has the main role of the ignition control, hydrogen increases with carbon dioxide in the methanol reforming. This paper investigates the influence of carbon dioxide on HCCI combustion engine with the ignition control by hydrogen. Both thermal and chemical effects of carbon dioxide are analyzed.

This research investigates the influences of the injection timing, injection pressure, and compression ratio on the combustion and exhaust emissions in a single cylinder 1.0 L DI diesel engine operating with ultra-high EGR. Longer ignition delays due to either advancing or retarding the injection timing reduced the smoke emissions, but advancing the injection timing has the advantages of maintaining the thermal efficiency and preventing misfiring. Smokeless combustion is realized with an intake oxygen content of only 9-10% regardless of the injection pressure. Reduction in the compression ratio is effective to reduce the in-cylinder temperature and increase the ignition delay as well as to expand the smokeless combustion range in terms of EGR and IMEP. However, the thermal efficiency deteriorates with excessively low compression ratios.

To extend the operational range of premixed diesel combustion, fuel reformation by piston induced compression of rich homogeneous air-fuel mixtures was conducted in this study. Reformed gas compositions and chemical processes were first simulated with the chemistry dynamics simulation, CHEMKIN Pro, by changing the intake oxygen content, intake air temperature, and compression ratio. A single cylinder diesel engine was utilized to verify the simulation results. With the simulation and experiments, the characteristics of the reformed gas with respect to the reformer cylinder operating condition were obtained. Further, the thermal decomposition and partial oxidation reaction mechanisms of the fuel in extremely low oxygen concentrations were obtained with the characteristics of the gas production at the various reaction temperatures.

The influence of fuel properties on the operational range and the thermal efficiency of premixed diesel combustion was evaluated with an ordinary diesel fuel, a primary reference fuel for cetane numbers, three primary reference fuels for octane numbers, and two normal heptane-toluene blend fuels in a single-cylinder DI diesel engine. The fuel injection timing was set at 25°CA BTDC and the maximum rate of pressure rise was maintained below 1.0 MPa/°CA when lowering the intake oxygen concentration by cooled EGR. With increasing octane numbers, the higher intake oxygen concentration can be used, resulting in higher indicated thermal efficiency due to a higher combustion efficiency. The best thermal efficiency at the optimum intake oxygen concentration with the ordinary diesel fuel is lower than with the primary reference fuels with the similar ignitability but higher volatility.

Combustion and exhaust gas emissions of alcohol and vegetable oil blends including a 20% ethanol + 40% 1-butanol + 40% vegetable oil blend and a 50% 1-butanol + 50% vegetable oil blend were examined in a single cylinder, four-stroke cycle, 0.83L direct injection diesel engine, with a supercharger and a common rail fuel injection system. A 50% diesel oil + 50% vegetable oil blend and regular unblended diesel fuel were used as reference fuels. The boost pressure was kept constant at 160 kPa (absolute pressure), and the cooled low pressure loop EGR was realized by mixing with a part of the exhaust gas. Pilot injection is effective to suppress rapid combustion due to the lower ignitability of the alcohol and vegetable oil blends. The effects of reductions in the intake oxygen concentration with cooled EGR and changes in the fuel injection pressure were investigated for the blended fuels.

Port injection of ethanol addition as an ignition inhibitor was implemented to control ignition timing and expand the operating range in DME fueled HCCI combustion. The ethanol reduced the rate of low-temperature oxidation and consequently delayed the onset of the high-temperature reaction with ultra-low NOx over a wide operating range. Along with the ethanol addition, changes in intake temperature, overall equivalence ratio, and engine speed are investigated and shown to be effective in HCCI combustion control and to enable an extension of operation range. A chemical reaction analysis was performed to elucidate details of the ignition inhibition on low-temperature oxidation of DME-HCCI combustion.

The chemical composition of marketed gasoline varies depending on the crude oil, refinery processes of oil refineries, and season. The combustion characteristics of HCCI engines are very sensitive to the fuel composition, and a fuel standard for HCCI is needed for HCCI vehicles to be commercially viable. In this paper, the effects of the structure of the fuel components on auto-ignition characteristics and HCCI engine performance were investigated. The engine employed in the experiments is a research, single cylinder HCCI engine with a compression ratio of 14.7. The intake manifold was equipped with a heater attachment allowing control of the intake air temperature up to 150 °C at 2000 rpm. Thirteen kinds of hydrocarbons, 4 kinds of paraffins, 3kinds of naphthenes, and 6 kinds of aromatics, were chosen for the investigation, and 20vol% of each of the pure hydrocarbons was blended with the 80 vol% of PFR50 fuel.

A new method to simultaneously measure temperature and concentration distributions in unsteady gas jets was established with an adaptation of the laser-induced fluorescence of iodine molecules seeded into ambient gas. Using the temperature dependence of iodine fluorescence spectra, the local temperature inside jets was determined with the ratio between the fluorescence intensities of two visualized images with different wavelengths. Jet concentrations were also determined with the images for the temperature measurements. The method was applied to an unsteady argon jet injected into hot argon-iodine ambient gases. The experimental results showed that the local temperature distribution in an unsteady gas jet were quite similar to the local concentration distributions.

Diesel combustion and emissions with four kinds of oxygenated agents as main fuels were investigated. Significant improvements in smoke, particulate matter, NOx, THC, and thermal efficiency were simultaneously realized with the oxygenates, and engine noise was also remarkably reduced for the oxygenates with higher ignitability. The improvements in the exhaust emissions and the thermal efficiency depended almost entirely on the oxygen content in the fuels regardless of the oxygenate to diesel fuel blend ratios and type of oxygenate. The unburned THC emission and odor intensity under starting condition with an oxygenate were also much lower than with conventional diesel fuel.