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Technical Paper

The Prediction of Connecting Rod Fretting and Fretting Initiated Fatigue Fracture

2004-10-25
2004-01-3015
The influence of big-end bore fretting on connecting rod fatigue fracture is investigated. A finite element model, including rod-bearing contact interaction, is developed to simulate a fatigue test rig where the connecting rod is subjected to an alternating uniaxial load. Comparison of the model results with a rod fracture from the fatigue rig shows good correlation between the fracture location and the peak ‘Ruiz’ criterion, rather than the peak tensile stress location, indicating the potential of fretting to initiate a fatigue fracture and the usefulness of the ‘Ruiz’ criterion as a measure of location and severity. The model is extended to simulate a full engine cycle using pressure loads from a bearing EHL analysis. A fretting map and a ‘Ruiz’ criterion map are developed for the full engine cycle, giving an indication of a safe ‘Ruiz’ level from an existing engine which has been in service for more than 5 years.
Technical Paper

The Effects of Thermal Degradation on the Performance of a NOX Storage/Reduction Catalyst

2009-04-20
2009-01-0631
The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.
Technical Paper

Sulfur Impact on Methane Steam Reforming over the Stoichiometric Natural Gas Three-Way Catalyst

2024-04-09
2024-01-2633
The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.
Journal Article

Simulation of Organic Rankine Cycle Power Generation with Exhaust Heat Recovery from a 15 liter Diesel Engine

2015-04-14
2015-01-0339
The performance of an organic Rankine cycle (ORC) that recovers heat from the exhaust of a heavy-duty diesel engine was simulated. The work was an extension of a prior study that simulated the performance of an experimental ORC system developed and tested at Oak Ridge National laboratory (ORNL). The experimental data were used to set model parameters and validate the results of that simulation. For the current study the model was adapted to consider a 15 liter turbocharged engine versus the original 1.9 liter light-duty automotive turbodiesel studied by ORNL. Exhaust flow rate and temperature data for the heavy-duty engine were obtained from Southwest Research Institute (SwRI) for a range of steady-state engine speeds and loads without EGR. Because of the considerably higher exhaust gas flow rates of the heavy-duty engine, relative to the engine tested by ORNL, a different heat exchanger type was considered in order to keep exhaust pressure drop within practical bounds.
Technical Paper

New Insights into the Unique Operation of Small Pore Cu-Zeolite SCR Catalyst: Overlapping NH3 Desorption and Oxidation Characteristics for Minimizing Undesired Products

2014-04-01
2014-01-1542
An operational challenge associated with SCR catalysts is the NH3 slip control, particularly for commercial small pore Cu-zeolite formulations as a consequence of their significant ammonia storage capacity. The desorption of NH3 during increasing temperature transients is one example of this challenge. Ammonia slipping from SCR catalyst typically passes through a platinum based ammonia oxidation catalyst (AMOx), leading to the formation of the undesired byproducts NOx and N2O. We have discovered a distinctive characteristic, an overlapping NH3 desorption and oxidation, in a state-of-the-art Cu-zeolite SCR catalyst that can minimize NH3 slip during temperature transients encountered in real-world operation of a vehicle.
Journal Article

Modeling Approach to Estimate EGR Cooler Thermal Fatigue Life

2015-04-14
2015-01-1654
Cooled EGR continues to be a key technology to meet emission regulations, with EGR coolers performing a critical role in the EGR system. Designing EGR coolers that reliably manage thermal loads is a challenge with thermal fatigue being a top concern. The ability to estimate EGR cooler thermal fatigue life early in the product design and validation cycle allows for robust designs that meet engine component reliability requirements and customer expectations. This paper describes a process to create an EGR cooler thermal fatigue life model. Components which make up the EGR cooler have differing thermal responses, consequently conjugate transient CFD must be used to accurately model metal temperatures during heating and cooling cycles. Those metal temperatures are then imported into FEA software for structural analysis. Results from both the CFD and FEA are then used in a simplified numerical model to estimate the virtual strain of the EGR cooler.
Technical Paper

Lean Breakthrough Phenomena Analysis for TWC OBD on a Natural Gas Engine using a Dual-Site Dynamic Oxygen Storage Capacity Model

2017-03-28
2017-01-0962
Oxygen storage capacity (OSC) is one of the most critical characteristics of a three-way catalyst (TWC) and is closely related to the catalyst aging and performance. In this study, a dynamic OSC model involving two oxygen storage sites with distinct kinetics was developed. The dual-site OSC model was validated on a bench reactor and a natural gas engine. The model was capable of predicting temperature dependence on OSC with H2, CO and CH4 as reductants. Also, the effects of oxygen concentration and space velocity on the amount of OSC were captured by the model. The validated OSC model was applied to simulate lean breakthrough phenomena with varied space velocities and oxygen concentrations. It is found that OSC during lean breakthrough is not a constant for a particular TWC catalyst and is dependent on space velocity and oxygen concentration. Specifically, breakthrough time exhibits a non-linear, inverse correlation to oxygen flux.
Technical Paper

Interaction Between Fuel Additive and Oil Contaminant: (II) Its Impact on Fuel Stability and Filter Plugging Mechanism

2003-10-27
2003-01-3140
Sulfur containing species as well as other polar molecules provide lubricity and thermal stability to diesel fuels. During the refining process to produce low and ultra-low sulfur diesel fuels, these components are removed. As a result, fuel additives such as lubricity agents and antioxidant may be added to protect fuel stability and prevent fuel pump wear. Some lubricity additives, such as dimer acids, resulted in fuel filter plugging. The plugging mechanism was related to the capability of aliphatic acids to form agglomeration by interactions with the overbased detergents, delivered into the fuel as oil contaminants. Other sources of acids, derived from thermal degradation, can lead to the same problem. In this study, individual lubricant additives were mixed in the fuel to form single- and dual-component systems. Levels of compatibility and amounts of interaction products were evaluated for individual solutions.
Technical Paper

Finite Element Method Based Fatigue Analysis of a Gray Cast Iron Component

2013-04-08
2013-01-1205
Good understanding and accurate prediction of component fatigue strength is crucial in the development of modern engine. In this paper a detail analysis was conducted on an engine component made of gray cast iron with finite element method to evaluate the fatigue strength. This component has notches that cause local stress concentration. It is well known that fatigue behavior of a notch is not uniquely defined by the local maximum stress but depends on other factors determined by notch geometry and local stress distribution. The component fatigue strength was underestimated by only considering the stresses on the notch surface for fatigue life prediction. The critical distance approach was adopted to predict the fatigue behavior of this component. Good agreements are observed between predicted life by the critical distance method and actual field data.
Technical Paper

Experimental and Kinetic Modeling of Degreened and Aged Three-way Catalysts: Aging Impact on Oxygen Storage Capacity and Catalyst Performance

2018-04-03
2018-01-0950
The aging impact on oxygen storage capacity (OSC) and catalyst performance was investigated on one degreened and one aged (hydrothermally aged at 955 °C for 50 h) commercial three-way catalyst (TWC) by experiments and modeling. The difference of OSC between the degreened and aged TWCs was dependent on catalyst temperature. The largest difference was found at 600 °C, at which the amount of OSC decreased by 45.5%. Catalyst performance was evaluated through lightoff tests at two simulated engine exhaust conditions (lean and rich) on a micro-reactor. The aging impact on the catalyst performance was different under lean and rich environments and investigated separately. At the lean condition, oxidation of CO and C3H6 was significantly suppressed while oxidation of C3H8 was relatively less degraded. At the rich condition, the inhibition effect was more pronounced on the aged TWC and inhibiting hydrocarbon species from C3H6 partial oxidation can survive at temperatures up to 450 °C.
Journal Article

Effect of Transition Metal Ion Properties on the Catalytic Functions and Sulfation Behavior of Zeolite-Based SCR Catalysts

2017-03-28
2017-01-0939
Copper- and Iron- based metal-zeolite SCR catalysts are widely used in US and European diesel aftertreatment systems to achieve drastic reduction in NOx emission. These catalysts are highly selective to N2 under wide range of operating conditions. Nevertheless, the type of transition metal has a significant impact on the key performance and durability parameters such as NOx conversion, selectivity towards N2O, hydrothermal stability, and sensitivity to fuel sulfur content. In this study, we explained the differences in the performance characteristics of these catalysts based on their relative acidic-basic nature of transition metal present in these catalysts using practically relevant gas species present in diesel exhaust such as NO2, SOx, and NH3. These experiments show that Fe-zeolite has relatively acidic nature as compared to Cu-zeolite that causes NH3 inhibition and hence explains low NOx conversion on Fe-zeolite at low temperature under standard SCR conditions.
Technical Paper

EGR Cooler Field Return Rate Evaluation Based on Product and Application Variation

2019-04-02
2019-01-0915
The automotive industry drives some of the most stringent product requirements to ensure long product life and customer satisfaction. To demonstrate compliance with these requirements new and more accurate evaluation methods are needed. Thermal fatigue life in EGR coolers for heavy duty diesel applications have historically been a critical focus for engine OEMs. Being able to accurately evaluate product return rates due to thermal fatigue failures gives the OEM confidence that all end users will be satisfied, and allows program management to properly make fiscal decisions. Additionally, weight and cost optimization can be conducted with greater confidence. This is accomplished by accounting for product variation and application variation in thermal fatigue life evaluations. Including these variations requires a simplified numerical method to calculate product life, as tens of thousands of samples will be run through the analysis to represent real life random variation.
Technical Paper

Durability Test Suite Optimization Based on Physics of Failure

2018-04-03
2018-01-0792
Dynamometer (dyno) durability testing plays a significant role in reliability and durability assessment of commercial engines. Frequently, durability test procedures are based on warranty history and corresponding component failure modes. Evolution of engine designs, operating conditions, electronic control features, and diagnostic limits have created challenges to historical-based testing approaches. A physics-based methodology, known as Load Matrix, is described to counteract these challenges. The technique, developed by AVL, is based on damage factor models for subsystem and component failure modes (e.g. fatigue, wear, degradation, deposits) and knowledge of customer duty cycles. By correlating dyno test to field conditions in quantifiable terms, such as customer equivalent miles, more effective and efficient durability test suites and test procedures can be utilized. To this end, application of Load Matrix to a heavy-duty diesel engine is presented.
Journal Article

Durability Study of a High Pressure Common Rail Fuel Injection System Using Lubricity Additive Dosed Gasoline-Like Fuel - Additional Cycle Runtime and Teardown Analysis

2019-04-02
2019-01-0263
This study is a continuation of previous work assessing the robustness of a Cummins XPI common rail injection system operating with gasoline-like fuel. All the hardware from the original study was retained except for the high pressure pump head and check valves which were replaced due to cavitation damage. An additional 400 hour NATO cycle was run on the refurbished fuel system to achieve a total exposure time of 800 hours and detect any other significant failure modes. As in the initial investigation, fuel system parameters including pressures, temperatures and flow rates were logged on a test bench to monitor performance over time. Fuel and lubricant samples were taken every 50 hours to assess fuel consistency, metallic wear, and interaction between fuel and oil. High fidelity driving torque and flow measurements were made to compare overall system performance when operating with both diesel and light distillate fuel.
Technical Paper

Development of a Kinetic Model to Evaluate Water Storage on Commercial Cu-Zeolite SCR Catalysts during Cold Start

2017-03-28
2017-01-0968
Commercial Cu-Zeolite SCR catalyst can store and subsequently release significant amount of H2O. The process is accompanied by large heat effects. It is critical to model this phenomenon to design aftertreatment systems and to provide robust tuning strategies to meet cold start emissions and low temperature operation. The complex reaction mechanism of water adsorption and desorption over a Cu-exchanged SAPO-34 catalyst at low temperature was studied through steady state and transient experiments. Steady state isotherms were generated using a gravimetric method and then utilized to predict water storage interactions with respect to feed concentration and catalyst temperature. Transient temperature programmed desorption (TPD) experiments provided the kinetic information required to develop a global kinetic model from the experimental data. The model captures fundamental characteristics of water adsorption and desorption accompanied by the heat effects.
Technical Paper

Automotive Selective Catalytic Reduction System Model-Based Estimators for On-ECU Implementation: A Brief Overview

2016-04-05
2016-01-0972
The amount of ammonia stored on the walls of the catalyst (or ammonia storage) is a parameter with significant impact on NOx reduction efficiency and undesired ammonia slip of Selective Catalytic Reduction catalysts. This makes the ammonia storage interesting for utilization in urea injection control. However, ammonia storage is not directly measurable onboard vehicles, it can only be estimated. Model-based online estimation requires models that are capable of capturing the main phenomena of the SCR and at the same time can be computed onboard vehicle. While the modeling of SCR and model-based control is well present in the literature, it is apparent that few attempts of implementing the models on production ECUs were published. This paper reviews literature on ammonia storage, outlet NH3 and NOx concentration estimation in SCR and SCR/DPF systems-including the estimation of NOx sensor cross-sensitive to NH3-in order to present the state of the art.
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