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A sampling system was developed to measure the evolution of the speciated hydrocarbon emissions from a single-cylinder SI engine in a simulated starting and warm-up procedure. A sequence of exhaust samples was drawn and stored for gas chromatograph analysis. The individual sampling aperture was set at 0.13 s which corresponds to ∼ 1 cycle at 900 rpm. The positions of the apertures (in time) were controlled by a computer and were spaced appropriately to capture the warm-up process. The time resolution was of the order of 1 to 2 cycles (at 900 rpm). Results for four different fuels are reported: n-pentane/iso-octane mixture at volume ratio of 20/80 to study the effect of a light fuel component in the mixture; n-decane/iso-octane mixture at 10/90 to study the effect of a heavy fuel component in the mixture; m-xylene and iso-octane at 25/75 to study the effect of an aromatics in the mixture; and a calibration gasoline.

Measurements were made of exhaust histories of the following species: unburned hydrocarbons (HC), carbon monoxide, carbon dioxide, oxygen, and nitric oxide (NO). The measurements show that the exhaust flow can be divided into two distinct phases: a leading gas low in HC and high in NO followed by a trailing gas high in HC and low in NO. Calculations of time resolved equivalence ratio throughout the exhaust process show no evidence of a stratified combustion. The exhaust mass flow rate is time resolved by forcing the flow to be locally quasi-steady at an orifice placed in the exhaust pipe. The results with the quasi-steady assumption are shown to be consistent with the measurements. Predictions are made of time resolved mass flow rate which compare favorably to the experimental data base. The composition and flow histories provide sufficient information to calculate the time resolved flow rates of the individual species measured.

The paper considers the thermodynamic irreversibility in Stirling cycle machines at the interface between components with different thermodynamic characteristics. The approach of the paper is to consider the simplest possible cases and to focus on the factors that influence the thermodynamic losses. For example, an ideal adiabatic cylinder facing an ideal isothermal heat exchanger is considered. If there is no mixing in the cylinder (gas remains one dimensionally stratified), there will be no loss (irreversibility) if the gas motion is in phase with the gas pressure changes. If there is a phase shift, as required to have a network for the cylinder, there will be a loss (entropy generation) because the gas will not match the heat exchanger temperature. There will also be a loss if the gas in the cylinder is mixed rather than stratified. Similar simple interface conditions can be considered between components and interconnecting open volumes and between heat exchangers and regenerators.

This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.

Diesel exhaust gas dilution and odor intensity were measured in the immediate vicinity of a transit bus equipped with a rear-mounted horizontal exhaust pipe, a rear-mounted vertical exhaust pipe, and a roof-top diffusion system. Exhaust dilution ratios were measured indoors during vehicle idle operation, using propane added to the exhaust gas as a tracer. Exhaust odor intensities were measured also indoors during vehicle idle operation by a human panel, using a threshold odor measurement technique. On the average, the dilution of the exhaust gas around the bus with the vertical exhaust pipe was about eight times greater than it was with the horizontal pipe. Odor intensity, as measured by the threshold response distance, was about 35% less with the vertical pipe than with the horizontal pipe. The roof-top diffuser was not as effective as the vertical exhaust pipe in increasing exhaust gas dilution or in reducing exhaust odor intensity.

The combustion process after auto-ignition is investigated. Depending on the non-uniformity of the end gas, auto-ignition could initiate a flame, produce pressure waves that excite the engine structure (acoustic knock), or result in detonation (normal or developing). For the “acoustic knock” mode, a knock intensity (KI) is defined as the pressure oscillation amplitude. The KI values over different cycles under a fixed operating condition are observed to have a log-normal distribution. When the operating condition is changed (over different values of λ, EGR, and spark timing), the mean (μ) of log (KI/GIMEP) decreases linearly with the correlation-based ignition delay calculated using the knock-point end gas condition of the mean cycle. The standard deviation σ of log(KI/GIMEP) is approximately a constant, at 0.63. The values of μ and σ thus allow a statistical description of knock from the deterministic calculation of the ignition delay using the mean cycle properties

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Determining the fundamental role of gravity in vital biological systems in space is one of six science and research areas that provides the philosophical underpinning for why NASA exists. The study of cells, tissues, and microorganisms in a spaceflight environment holds the promise of answering multiple intriguing questions about how gravity affects living systems. To enable these studies, specimens must be maintained in an environment similar to that used in a laboratory. Cell culture studies under normal laboratory conditions involve maintaining a highly specialized environment with the necessary temperature, humidity control, nutrient, and gas exchange conditions. These same cell life support conditions must be provided by the International Space Station (ISS) Cell Culture Unit (CCU) in the unique environment of space. The CCU is a perfusion-based system that must function in microgravity, at unit gravity (1g) on earth, and from 0.1g up to 2g aboard the ISS centrifuge rotor.

Single Loop for Cell Culture (SLCC) consists of individual, self-contained, spaceflight cell culture systems with capabilities for automated growth initiation, feeding, sub-culturing and sampling. The cells are grown and contained within a rigid cell specimen chamber (CSC). Bladder tanks provide flush and media fluid. SLCC uses active perfusion flow to provide nutrients and gas exchange, and to dilute waste products by expelling depleted media fluid into a waste bladder tank. The cells can be grown quiescently, or suspended using magnetically coupled stirrers. This paper describes the functional and safety design features, the operational modes and the spaceflight qualification processes including science validation tests, using yeast as a model organism.

A running loss test procedure has been developed which integrates a point-source collection method to measure fuel evaporative running loss from vehicles during their operation on the chassis dynamometer. The point-source method is part of a complete running loss test procedure which employs the combination of site-specific collection devices on the vehicle, and a sampling pump with sampling lines. Fugitive fuel vapor is drawn into these collectors which have been matched to characteristics of the vehicle and the test cell. The composite vapor sample is routed to a collection bag through an adaptation of the ordinary constant volume dilution system typically used for vehicle exhaust gas sampling. Analysis of the contents of such bags provides an accurate measure of the mass and species of running loss collected during each of three LA-4* driving cycles. Other running loss sampling methods were considered by the Auto-Oil Air Quality Improvement Research Program (AQIRP or Program).

This paper presents the results from a joint research initiative between NASA Ames Research Center and Lawrence Berkeley National lab. The objective of the research is to produce activated carbon from life support wastes and to use the activated carbon to adsorb and chemically reduce the NOx and SO2 contained in incinerator flue gas. Inedible biomass waste from food production is the primary waste considered for conversion to activated carbon. Results to date show adsorption of both NOx and SO2 in activated carbon made from biomass. Conversion of adsorbed NOx to nitrogen has also been observed.

Pyrolysis is a very versatile waste processing technology which can be tailored to produce a variety of solid, liquid and/or gaseous products. The pyrolysis processing of pure and mixed solid waste streams has been under investigation for several decades for terrestrial use and a few commercial units have been built for niche applications. Pyrolysis has more recently been considered for the processing of mixed solid wastes in space. While pyrolysis units can easily handle mixed solid waste streams, the dependence of the pyrolysis product distribution on the component composition is not well known. It is often assumed that the waste components (e.g., food, paper, plastic) behave independently, but this is a generalization that can usually only be applied to the overall weight loss and not always to the yields of individual gas species.

This paper present a summary of the design studies for the suit port proof of concept. The Suit Port reduces the need for airlocks by docking the suits directly to a rover or habitat bulkhead. The benefits include reductions in cycle time and consumables traditionally used when transferring from a pressurized compartment to EVA and mitigation of planetary surface dust from entering into the cabin. The design focused on the development of an operational proof of concept evaluated against technical feasibility, level of confidence in design, robustness to environment and failure, and the manufacturability. A future paper will discuss the overall proof of concept and provide results from evaluation testing including gas leakage rates upon completion of the testing program.

This article reports on the potential of negative valve overlap (NVO) for improving the net indicated thermal efficiency (η NIMEP) of gasoline engines during part load. Three fixed fuel flow rates, resulting in indicated mean effective pressures of up to 6 bar, were investigated. At low load, NVO significantly reduces the pumping loses during the gas exchange loop, achieving up to 7% improvement in indicated efficiency compared to the baseline. Similar efficiency improvements are achieved by positive valve overlap (PVO), with the disadvantage of worse combustion stability from a higher residual gas fraction (xr). As the load increases, achieving the wide-open throttle limit, the benefits of NVO for reducing the pumping losses diminish, while the blowdown losses from early exhaust valve opening (EVO) increase.

A three country effort (U.S., Russia, and Bulgaria) has upgraded the plant growth facilities on the Mir Space Station and used the new facility to grow wheat for 90 days. The Svet plant-growth facility was reactivated and used in an initial experiment as part of the Shuttle/Mir program, August to November, 1995. The Svet system, used first to grow cabbage and radish during a 1990 experiment, was augmented by the addition of a U.S. developed Gas Exchange Measurement System (GEMS) that measures a range of environmental parameters plus transpiration, photosynthesis, and possibly respiration. Environmental parameters include cabin, chamber, root-zones, and leaf temperatures. Light levels, relative humidity, oxygen, and atmospheric pressure are also measured. High-accuracy water-vapor and carbon-dioxide concentrations and differences are measured using specially developed IRGA systems.

A fundamental question for Astrobiology is the question of the ability of life to expand beyond its planet of origin. Introducing life on Mars is the likely near-term step in addressing this question. Making Mars more suitable for life (terraforming) involves altering the martian environment so that microorganisms and plants from Earth could survive there. We define two principal goals: 1) determine the minimal change in pressure, gas composition, and temperature on Mars that would allow for growth of plants from arctic and alpine biomes. 2) Determine the characteristics of plant growth at 0.38 g. This paper reviews martian environmental factors in the context of plant survival, and discusses the use of Space Station as a hypogravity testbed.

This paper explores the combined effects of boosting, intake air temperature, trapped residual gas fraction, and dilution on the Maximum Pressure Rise Rate (MPRR) in a boosted single cylinder gasoline HCCI engine with combustion controlled by negative valve overlap. Dilutions by both air and by cooled EGR were used. Because of the sensitivity of MPRR to boost, the MPRR constrained maximum load (as measured by the NIMEP) did not necessarily increase with boosting. At the same intake temperature and trapped residual gas fraction, dilution by recirculated burn gas was effective in reducing the MPRR, but dilution by air increased the value of MPRR. The dependence of MPRR on the operating condition was interpreted successfully by a simple thermodynamic analysis that related the MPRR value to the volumetric heat release rate.

A detailed description of flow rate measurement technique for automotive exhaust is presented. The system consists of a sector field mass spectrometer for continuous analysis of helium concentration in the exhaust gas and a mass flow controller which injects pure helium at a constant rate into the intake manifold of an engine. The exhaust flow rate can be calculated by helium injection flow rate dividing by the concentration since the concentration value is a measure of the ratio of helium dilution taking place in the engine. The advantages of the technique consist of (1) no disturbance from strong pulsed flow present when an engine is idling, (2) easy time alignment with gas analyzers, and (3) measurement of dry based flow rate that can be directly multiplied by dry based gas concentration to obtain mass emission rate.

THIS paper outlines a new method of measuring end-gas temperatures within the cylinder of an operating engine. The new instrument measures the acoustical properties by the pulse method, transmitting an acoustical impulse through a gas path of known length and measuring the time of propagation through the gas. The method yields a value for the average velocity of sound in the path. The authors describe the instrument and engine modifications necessary. The results of tests are also discussed, with a detailed description of one series. The appendixes outline the mathematical steps of finding the sound velocity in gas mixtures and the fuel-air cycle for the detailed series of tests.

Technologies that can be used to extract oxygen and other useful products from the Martian atmosphere for exploration missions will require compression of the low-pressure Martian gas. One technique that appears ideally suited for this application is temperature-swing adsorption, which can produce purified and compressed CO2 in a virtually solid-state process whose energy requirements can be met mainly through the diurnal temperature cycle. This paper focuses on material selection and sensitivity of this adsorption process to variations in Mars surface conditions. Experimental results indicate that, of the zeolite and carbon materials studied, a NaX zeolite is a superior adsorbent in terms of the amount of pressurized gas it can produce per unit mass of sorbent.